CN100388548C - Improved version of hold-down gear for fuel cell pile - Google Patents

Improved version of hold-down gear for fuel cell pile Download PDF

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Publication number
CN100388548C
CN100388548C CNB2004100670283A CN200410067028A CN100388548C CN 100388548 C CN100388548 C CN 100388548C CN B2004100670283 A CNB2004100670283 A CN B2004100670283A CN 200410067028 A CN200410067028 A CN 200410067028A CN 100388548 C CN100388548 C CN 100388548C
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fuel cell
board
end plate
hold
version
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Expired - Lifetime
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CN1761094A (en
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夏建伟
胡里清
章波
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State Grid Corp of China SGCC
Shanghai Municipal Electric Power Co
Shanghai Shenli Technology Co Ltd
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Shanghai Shen Li High Tech Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Fuel Cell (AREA)

Abstract

The present invention relates to an improved fuel battery pack compressing arrangement which comprises at least a set of single batteries, a front afflux mother board, a rear afflux mother board, a pop-up jacket board with uniform pressure, a front end board and a rear end board, wherein each single battery is composed of a diversion polar board and a proton exchange membrane electrode, the front afflux mother board and the rear mother board are clamped on both ends of at least one set of single batteries, the pop-up jacket board with uniform pressure is arranged between the afflux mother board and each end board, the front end board and the rear end board are arranged outside the front afflux mother board and the pop-up jacket board with uniform pressure, and the front end board and the rear end board are provided with at least two draw rods. Both ends of each draw rod are provided with a fastening screw cap respectively. Through regulating the fastening screw cap, the front end board and the rear end board are compressed, and thereby, the fuel battery pile is fastened. Compared with the prior art, the present invention has the characteristics of uniform pressure, etc.

Description

A kind of improved fuel cell heap hold down gag
Technical field
The present invention relates to fuel cell, relate in particular to a kind of improved fuel cell heap hold down gag.
Background technology
Electrochemical fuel cell is a kind of device that hydrogen and oxidant can be changed into electric energy and product.The internal core parts of this device are membrane electrode (Membrane Electrode Assembly are called for short MEA), and membrane electrode (MEA) is made up of as carbon paper a proton exchange membrane, two porous conductive materials of film two sides folder.The catalyst that contains the initiation electrochemical reaction of even tiny dispersion on two boundary faces of film and carbon paper is as the metal platinum catalyst.The membrane electrode both sides can electrochemistry will take place with conductive body to be sent out and answers the electronics that generates in the process, draws by external circuit, constitutes current circuit.
At the anode tap of membrane electrode, fuel can pass porousness diffusion material (carbon paper) by infiltration, and electrochemical reaction takes place on catalyst surface, lose electronics, form cation, cation can pass proton exchange membrane by migration, arrives the other end cathode terminal of membrane electrode.At the cathode terminal of membrane electrode, contain the gas of oxidant (as oxygen), as air, pass porousness diffusion material (carbon paper), and the generation electrochemical reaction obtains electronics on catalyst surface, forms anion by infiltration.The cation of coming in the anion and the anode tap migration of cathode terminal formation reacts, and forms product.
Adopting hydrogen is fuel, and the air that contains oxygen is in the Proton Exchange Membrane Fuel Cells of oxidant (or pure oxygen is an oxidant), and fuel hydrogen has just produced hydrogen cation (or being proton) in the catalytic electrochemical reaction of anode region.Proton exchange membrane helps the hydrogen cation to move to the cathodic region from the anode region.In addition, proton exchange membrane is separated the air-flow and the oxygen containing air-flow of hydrogen fuel, they can not mixed mutually and produces explosion type reaction.
In the cathodic region, oxygen obtains electronics on catalyst surface, forms anion, and moves the hydrogen cation reaction of coming, reaction of formation product water with the anode region.In the Proton Exchange Membrane Fuel Cells that adopts hydrogen, air (oxygen), anode reaction and cathode reaction can be expressed in order to following equation:
Anode reaction: H 2→ 2H ++ 2e
Cathode reaction: 1/2O 2+ 2H ++ 2e → H 2O
In typical Proton Exchange Membrane Fuel Cells, membrane electrode (MEA) generally all is placed in the middle of the pole plate of two conductions, and quarter is milled by die casting, punching press or machinery in the surface that every guide plate contacts with membrane electrode, and formation is the guiding gutter of one or more at least.These guide plates can be the pole plates of metal material, also can be the pole plates of graphite material.Fluid duct on these guide plates and guiding gutter import fuel and oxidant the anode region and the cathodic region on membrane electrode both sides respectively.In the structure of a Proton Exchange Membrane Fuel Cells monocell, only there is a membrane electrode, the membrane electrode both sides are respectively the baffler of anode fuel and the baffler of cathode oxidant.These bafflers are both as current collector plate, and also as the mechanical support on membrane electrode both sides, the guiding gutter on the baffler acts as a fuel again and enters the passage of anode, cathode surface with oxidant, and as the passage of taking away the water that generates in the fuel cell operation process.
In order to increase the gross power of whole Proton Exchange Membrane Fuel Cells, two or more monocells can be connected into battery pack or be unified into battery pack by the mode that tiles usually by straight folded mode.In straight folded, in-line battery pack, can there be guiding gutter on the two sides of a pole plate, and wherein one side can be used as the anode guide face of a membrane electrode, and another side can be used as the cathode diversion face of another adjacent membranes electrode, and this pole plate is called bipolar plates.A series of monocell connects together by certain way and forms a battery pack.Battery pack tightens together by front end-plate, end plate and pull bar usually and becomes one.
A typical battery stack generally includes: the water conservancy diversion import and the flow-guiding channel of (1) fuel and oxidant gas are distributed to fuel (hydrogen-rich gas that obtains as hydrogen, methyl alcohol or methyl alcohol, natural gas, gasoline) and oxidant (mainly being oxygen or air) in the guiding gutter of each anode, cathode plane equably after reforming; (2) import and export and the flow-guiding channel of cooling fluid (as water) are evenly distributed to cooling fluid in each battery pack inner cooling channel, and the heat absorption that hydrogen in the fuel cell, the exothermic reaction of oxygen electrochemistry are generated is also taken battery pack out of and dispelled the heat; (3) outlet of fuel and oxidant gas and corresponding flow-guiding channel, fuel gas and oxidant gas are when discharging, and portability goes out the liquid that generates in the fuel cell, the water of steam state.Usually, the import and export of all fuel, oxidant, cooling fluid are all opened on the end plate of fuel battery or on two end plates.
Proton Exchange Membrane Fuel Cells can be used as the dynamical system of delivery vehicles such as car, ship, can make portable, portable, fixed Blast Furnace Top Gas Recovery Turbine Unit (TRT) again.
Proton Exchange Membrane Fuel Cells is generally fitted together by the mode of several monocells by serial or parallel connection becomes fuel cell pack.
As Fig. 1 is the guide plate that has now in the fuel-cell single-cell, and it comprises air inlet 1a, water inlet 2a, hydrogen inlet 3a, runner 4a, air gas outlet 5a, delivery port 6a, hydrogen gas outlet 7a; As Fig. 2 is the three in one membreane electrode that has now in the fuel-cell single-cell, and it comprises air inlet 1a, water inlet 2a, hydrogen inlet 3a, electrode activity zone 8a, air gas outlet 5a, delivery port 6a, hydrogen gas outlet 7a; As Fig. 3 is existing fuel cell pack, and it comprises fuel cell pack 9a, flow-collection mother-board 10a, 10b, end plate 11a, 11b, metal pull bar 12a, nut 13a.
Existing fuel cell pack is generally by some monocells (monocell is made of guide plate, three in one membreane electrode), the forward and backward end plate of flow-collection mother-board assembles, many pull bars are arranged on the forward and backward end plate, generally make pull bar that forward and backward end plate is packed together to a fuel cell pack with securing member; The method that the securing member pull bar adds screw is common fastening method.
Fuel cell pack must fully compress forward and backward end plate with securing member, but must be pressed to uniformly in a certain suitable pressure limit, guarantees fuel cell pack safety, efficient operation.
At present, this common fastening method that adds securing member with pull bar has following technological deficiency:
1. high especially to the fastening matching requirements of fuel cell pack pull bar, must reach whole fuel cell pack before, each zone is subjected to basically identical and identical fastening force on the end plate, this requirement is very difficult, practical operation tend to make whole fuel cell pack before, the fastening force that certain zone is subjected on the end plate is less, and the fastening force that certain zone is subjected to is bigger, and it is not enough to cause some zone on the fuel battery pole board to be subjected to thrust, cause electrode and guide plate contact resistance too big, and that some zone is subjected to thrust is too big, cause pole plate distortion or cracked, or cause electrode injured.
2. when this fuel cell pack was assemblied in fuel cell expanded by heating or shrinkage by pull bar is fastening, the pressure that is subjected on the forward and backward end plate of fuel cell pack was made a world of difference, and can cause pole plate or electrode injured when serious.
In addition, Chinese patent (patent No.: 97228898.8,1999 years) discloses the fuel cell pack that a kind of its pressing plate inboard is placed with rubber buffer.China Patent No. be 02265903.X patent disclosure another kind of fuel cell pack with even fastening pressure, this patented technology is provided with an air cushion bag before the fuel cell pack end plate, and reach 2~5 atmospheric pressure in air cushion bag the inside inflation, make each zone of the fuel cell pack electrode pad after fastening bear uniform fastening pressure.Above-mentioned two kinds of patented technologies also have following technological deficiency:
1. first kind of patented technology adopts rubber buffer, the front and back end plate of fastening fuel cell pack again.In fact, rubber slab is what can take place than large deformation after being subjected to fastening pressure, and often is being subjected to the bigger zone of fastening pressure, and deformation takes place also bigger.As time goes on, the zone that deformation is bigger takes place easily aging, follows the string at first, and it is inhomogeneous that the electrode of fuel cell pack and fastening force that each zone of pole plate is subjected to finally take place.
2. second kind of patented technology needs an air cushion bag, and this parts are made inconvenient, and inflation is also inconvenient, and accidents such as gas leakage also take place after the inflation easily.
Summary of the invention
Purpose of the present invention is exactly to provide the uniform improved fuel cell heap of a kind of pressure hold down gag for the defective that overcomes above-mentioned prior art existence.
Purpose of the present invention can be achieved through the following technical solutions: a kind of improved fuel cell heap hold down gag, comprise at least one group of monocell that constitutes by guide plate and proton exchange membrane electrode, before, back flow-collection mother-board, before, end plate, before described, back flow-collection mother-board is located in the two ends of at least one group of monocell, before described, two outsides of flow-collection mother-board before and after end plate is located in, before described, end plate is provided with at least two pull bars, these pull bar two ends are provided with fastening nut, by regulating this fastening nut, the front and back end plate is compressed, thereby it is fuel cell pack is fastening, it is characterized in that comprise that also a pressure evenly ejects the chuck plate, this pressure evenly ejects the chuck plate and is located between flow-collection mother-board and the end plate.
Described pressure evenly ejects the chuck plate and comprises inner splint, spring, and the one side of described inner splint is close to flow-collection mother-board, and another side is evenly laid a plurality of springs.
The one side by spring of described inner splint is provided with a plurality of recessed circles, and described spring is arranged in this recessed circle.
Described inner splint can be that plastics or hardness that a small amount of deformation takes place are difficult for aging rubber slab more greatly.
But described end plate inboard is provided with the recessed circle that a plurality of ammunition feed springs are provided with.
Described end plate is a metallic plate.
Described pressure evenly ejects the chuck plate and comprises inner splint, spring, external splint, and the one side of described inner splint is close to flow-collection mother-board, and another side is evenly laid a plurality of springs, and the one side of described external splint touch spring, and another side is close to end plate.
Described inner splint and external splint are provided with a plurality of recessed circles for this spring setting by the one side of spring.
Described pull bar is four pull bars, and these four pull bars are arranged in four jiaos of forward and backward end plate respectively.
Be provided with packing ring between described fastening nut and the end plate.
The present invention is owing to adopted above technical scheme, promptly be provided with a kind of pressure and evenly eject chuck at fuel cell pack (as Fig. 4), therefore the present invention can remedy the defective of the end plate discontinuity that causes because of each draw-bar pull is inconsistent when fuel cell piles up assembling, make pole plate and electrode stressed more even, thereby guaranteed the normal operation of fuel cell pack and can improve its useful life.
Description of drawings
Fig. 1 is the structural representation of existing fuel cell pack guide plate;
Fig. 2 is the structural representation of existing fuel cell pack three in one membreane electrode;
Fig. 3 is the structural representation of existing fuel cell pack;
Fig. 4 is a structural representation of the present invention;
Fig. 5 evenly ejects the inner splint of chuck by spring face structural representation for a kind of pressure of the present invention;
Fig. 6 evenly ejects the external splint (end plate) of chuck by spring face structural representation for a kind of pressure of the present invention;
Fig. 7 evenly ejects the structural representation of chuck for a kind of pressure of the present invention.
In the accompanying drawing:
314,341: place the recessed circle of spring (spill circular hole);
31: have the inner splint that pressure evenly ejects chuck;
34: have the external splint that pressure evenly ejects chuck, double as fuel cell pack end plate;
32: spring;
342: tie rod hole.
Embodiment
Below in conjunction with accompanying drawing, the invention will be further described.
Embodiment
As shown in Figure 4, a kind of version of hold-down gear for fuel cell pile with even fastening pressure comprises the monocells 1 that many groups are made of guide plate and proton exchange membrane electrode, forward and backward flow-collection mother-board 2, and a kind of have pressure and evenly eject chuck 3, front end-plate 4, end plate 34; Described forward and backward flow-collection mother-board 2 is located in the two ends of many group monocells 1; Described a kind ofly have pressure and evenly eject the shape that chuck 3 generally is the guide plate and the end plate 34 of fuel cell pack 1 (present embodiment near square), a kind of have pressure and evenly eject chuck 3 and be located between back flow-collection mother-board 2 and the end plate 34 (as shown in Figure 7), and end plate 34 has a kind of external splint that pressure evenly ejects chuck 3 that has concurrently.
Described forward and backward end plate 34 is located in preceding flow-collection mother-board 2 respectively and has the outside that uniform pressure ejects chuck 3; Four jiaos of described forward and backward end plate 34 are equipped with four pull bars 5 and (two pull bars can be set also, these two pull bars are arranged in respectively in the middle of the centre, left and right limit or upper and lower limit of forward and backward end plate, to guarantee pressure balance), these pull bar 5 two ends are provided with fastening nut 6, be provided with packing ring 7 between this fastening nut 6 and the end plate 4, by regulating this fastening nut 6, forward and backward end plate 4 is compressed, thus fuel cell pack 1 is fastening.
Shown in Fig. 5~7, in the above-described embodiments, the size of fuel battery pole board and electrode Gao Yukuan is respectively 206mm and 206mm.Wherein have uniform pressure ejection chuck 3 and form, wherein external splint double as fuel cell pack end plate by inner splint 31 and external splint (end plate) 34.Fuel cell pack has 100 monocells, be of a size of 206mm * 206mm * 450mm, the inner splint of chuck plate is of a size of 206mm * 206mm * 8mm, end plate is of a size of 210mm * 245mm * 6mm, adopt 25 springs altogether, the every about 3cm of spring length produces about 50 kilograms power when every spring tightens 1cm, so whole chuck produces 1250 kilograms power.When pull bar was fastening, whole chuck tightened 1cm, and evenly the pressure that ejects is applied on flow-collection mother-board on the fuel cell pack and all electrode, the pole plate.

Claims (10)

1. version of hold-down gear for fuel cell pile, comprise at least one group of monocell that constitutes by guide plate and proton exchange membrane electrode, before, back flow-collection mother-board, before, end plate, before described, back flow-collection mother-board is located in the two ends of at least one group of monocell, before described, two outsides of flow-collection mother-board before and after end plate is located in, before described, end plate is provided with at least two pull bars, these pull bar two ends are provided with fastening nut, by regulating this fastening nut, the front and back end plate are compressed, thereby it is fuel cell pack is fastening, it is characterized in that comprise that also a pressure evenly ejects the chuck plate, this pressure evenly ejects the chuck plate and is located between flow-collection mother-board and the end plate.
2. a kind of version of hold-down gear for fuel cell pile according to claim 1 is characterized in that, described pressure evenly ejects the chuck plate and comprises inner splint, spring, and the one side of described inner splint is close to flow-collection mother-board, and another side is evenly laid a plurality of springs.
3. a kind of version of hold-down gear for fuel cell pile according to claim 2 is characterized in that, the one side by spring of described inner splint is provided with a plurality of recessed circles, and described spring is arranged in this recessed circle.
4. a kind of version of hold-down gear for fuel cell pile according to claim 3 is characterized in that, described inner splint is that plastics or hardness that a small amount of deformation takes place are difficult for aging rubber slab more greatly.
5. according to claim 1,2,3 or 4 described a kind of version of hold-down gear for fuel cell pile, it is characterized in that, but described end plate inboard is provided with the recessed circle that a plurality of ammunition feed springs are provided with.
6. a kind of version of hold-down gear for fuel cell pile according to claim 5 is characterized in that, described end plate is a metallic plate.
7. a kind of version of hold-down gear for fuel cell pile according to claim 1, it is characterized in that, described pressure evenly ejects the chuck plate and comprises inner splint, spring, external splint, the one side of described inner splint is close to flow-collection mother-board, another side is evenly laid a plurality of springs, the one side of described external splint touch spring, and another side is close to end plate.
8. a kind of version of hold-down gear for fuel cell pile according to claim 7 is characterized in that, described inner splint and external splint are provided with a plurality of recessed circles for this spring setting by the one side of spring.
9. a kind of version of hold-down gear for fuel cell pile according to claim 1 is characterized in that, described pull bar is four pull bars, and these four pull bars are arranged in four jiaos of forward and backward end plate respectively.
10. a kind of version of hold-down gear for fuel cell pile according to claim 1 is characterized in that, is provided with packing ring between described fastening nut and the end plate.
CNB2004100670283A 2004-10-11 2004-10-11 Improved version of hold-down gear for fuel cell pile Expired - Lifetime CN100388548C (en)

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Publication number Priority date Publication date Assignee Title
JP5026461B2 (en) * 2009-04-14 2012-09-12 本田技研工業株式会社 Fuel cell stack
US10651492B2 (en) * 2010-06-22 2020-05-12 Vrb Energy Inc. Integrated system for electrochemical energy storage system
CN103633358A (en) * 2013-12-05 2014-03-12 新源动力股份有限公司 High-integration-level metal plate fuel cell stack
WO2016205139A1 (en) * 2015-06-19 2016-12-22 Ballard Power Systems Inc. Compression apparatus for fuel cell stack
CN106735958B (en) * 2016-12-20 2018-12-14 湖北华工法利莱切焊系统工程有限公司 The processing method for laser machining clamping sleeve, pressing device and laser welding electrode slice
DE112018000798T5 (en) * 2017-02-13 2019-12-12 Ess Tech, Inc LEAF SPRING COMPRESSION SYSTEM DESIGN
CN107154503B (en) * 2017-04-20 2019-09-27 清华大学 A kind of long-life fuel cell galvanic pile module that can be quickly cold-started
TWI797397B (en) * 2019-11-20 2023-04-01 財團法人工業技術研究院 Adjustable stress structure for fuel cell

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0845535A (en) * 1994-08-01 1996-02-16 Ishikawajima Harima Heavy Ind Co Ltd Fuel cell fastening device
CN2329088Y (en) * 1997-11-24 1999-07-14 钟家轮 Proton exchanging film fuel battery
CN1245981A (en) * 1998-08-19 2000-03-01 松下电器产业株式会社 Solid macromolecular electrolyte type fuel cell
CN2554805Y (en) * 2002-07-31 2003-06-04 上海神力科技有限公司 Fuel cell stack with uniform fasteniy pressure
WO2004079850A1 (en) * 2003-03-06 2004-09-16 Toyota Jidosha Kabushiki Kaisha Fuel cell
CN2735553Y (en) * 2004-10-11 2005-10-19 上海神力科技有限公司 An improved fuel battery pack compressing arrangement

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0845535A (en) * 1994-08-01 1996-02-16 Ishikawajima Harima Heavy Ind Co Ltd Fuel cell fastening device
CN2329088Y (en) * 1997-11-24 1999-07-14 钟家轮 Proton exchanging film fuel battery
CN1245981A (en) * 1998-08-19 2000-03-01 松下电器产业株式会社 Solid macromolecular electrolyte type fuel cell
CN2554805Y (en) * 2002-07-31 2003-06-04 上海神力科技有限公司 Fuel cell stack with uniform fasteniy pressure
WO2004079850A1 (en) * 2003-03-06 2004-09-16 Toyota Jidosha Kabushiki Kaisha Fuel cell
CN2735553Y (en) * 2004-10-11 2005-10-19 上海神力科技有限公司 An improved fuel battery pack compressing arrangement

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