CN100375771C - Wipes impregnated with biliquid foam treating liquids - Google Patents
Wipes impregnated with biliquid foam treating liquids Download PDFInfo
- Publication number
- CN100375771C CN100375771C CNB2003801046750A CN200380104675A CN100375771C CN 100375771 C CN100375771 C CN 100375771C CN B2003801046750 A CNB2003801046750 A CN B2003801046750A CN 200380104675 A CN200380104675 A CN 200380104675A CN 100375771 C CN100375771 C CN 100375771C
- Authority
- CN
- China
- Prior art keywords
- wiper
- dispersion liquid
- thickening material
- abandoned
- tensio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000007788 liquid Substances 0.000 title claims abstract description 53
- 239000006260 foam Substances 0.000 title claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 37
- -1 polysiloxane Polymers 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 24
- 230000008719 thickening Effects 0.000 claims description 22
- 239000013543 active substance Substances 0.000 claims description 15
- 229920002125 Sokalan® Polymers 0.000 claims description 11
- 238000007598 dipping method Methods 0.000 claims description 9
- 239000004744 fabric Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 229960001631 carbomer Drugs 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 229920001206 natural gum Polymers 0.000 claims description 5
- 241000282326 Felis catus Species 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 230000008595 infiltration Effects 0.000 claims description 3
- 238000001764 infiltration Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 238000013508 migration Methods 0.000 abstract description 5
- 230000005012 migration Effects 0.000 abstract description 5
- 239000000077 insect repellent Substances 0.000 abstract description 3
- 239000002562 thickening agent Substances 0.000 abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 230000024042 response to gravity Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 229940060184 oil ingredients Drugs 0.000 description 13
- 239000003921 oil Substances 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 229920002884 Laureth 4 Polymers 0.000 description 6
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 6
- 229940061515 laureth-4 Drugs 0.000 description 6
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 6
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RJQCTTTVWBJFJD-UHFFFAOYSA-N S1(N=CC=C1)=O.CCl Chemical class S1(N=CC=C1)=O.CCl RJQCTTTVWBJFJD-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- 241000157282 Aesculus Species 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229960001673 diethyltoluamide Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 235000010181 horse chestnut Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 229940113174 imidurea Drugs 0.000 description 1
- 229940040145 liniment Drugs 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A disposable wipe impregnated with furniture polish or another surface treating liquid such as a hard surface cleaner or insect repellant is disclosed. The liquid is in the form of a dispersion which is a biliquid foam with a thickener, where the foam is structured as an oil-in-water complex. The dispersion has an oil portion having a polysiloxane and/or a hydrocarbon oil. There is also surfactant such as one nonionic surfactant and one polar surfactant. Water is also provided. The biliquid structure stabilizes the dispersion even with very low levels of surfactant, while the thickener retards migration of the impregnated liquid in response to gravity.
Description
Background of invention
The present invention relates to the biliquid foam surface treatment liquid wiper of furniture polish or sanitising agent dipping for example.Especially, it relates to such wiper: wherein liquid be stable and opposing because gravity and migration by wiper.
Cleaning liquor, polishing fluid and other treatment solution impregnated wipes of broad variety had been adopted in the past.
Referring to for exampleUnited States Patent (USP) 4,725,489,4,753,844,4,963,432,5,914,177,6,121,165,6,136,775 and 6,270,878.Pre-soaked wiper particularly advantageous is because they are coated to required liquid processed surface simultaneously, make this material sprawl and remove undesirable material surfacewise.Under the situation of furniture polish wiper, wiper can also be used as snubber.
For example, at United States Patent (USP) 3,965, in 518, it proposes in order to the plain wiper of the furniture polish impregnation of fibers of emulsion form, and this polishing varnish also contains water, mineral oil, silicone oil, nonionogenic tenside and/or anion surfactant, sanitas and pH regulator agent except other material.Yet when this wiper is deposited in when being used to store in the container, emulsion trends towards along with the gravity migration.The polishing varnish that therefore, can contain less dipping at the wiper of stacking the top.
And some emulsions can influence the effect of some antiseptic-germicide.For the wiper that is designed to have antibacterial effect on they handled surfaces, this may be special problem.
In addition, lack the tensio-active agent that uses high level, some emulsions are unstable for a long time.The tensio-active agent of high level may cause residue problems, particularly in the furniture polish field.
In the furniture polish special composition of wishing be silicone oil.Yet, lacking the use hydrocarbon solvent, conventional emulsion can have stability problem when they contain silicone oil.Because environment or flammable consideration, these hydrocarbon solvents may be undesirable.
In incoherent works, prior art has been developed the oil-in-water dispersion liquid that is known as biliquid foam.In these dispersion liquids, oil is present in the discrete droplets of being surrounded by the first surface promoting agent.Remainder water is dissolved in it in second surface promoting agent.The second surface promoting agent is moved to the oil meter face of surfactant-coated, to generate at least some by drop (most preferably oil droplet) that double-layer surface-active agent surrounded.
Usually referring toUnited States Patent (USP) 4,486,333 and 6,312,760.
Also referring toF.Sebba, biliquid foam-Preliminary report, 40J.Colloid.Interface Sci.468-474 (1972); O.Sonneville-Aubrun etc., the surfactant film in the biliquid foam, 16 Langmuir 1566-1579 (2000) and exercise question are the Disperse Technologies Limited 1998 technology statement of " advanced local dispersion technology ".
The early stage kind of these foamy suffers significant unstable.Yet, United States Patent (USP) 6,165,479 have instructed: can obviously improve foamy stability by viscosity modifier/thickening material being joined in these foams.Yet this patent mainly concentrates on the preparing cosmetics, does not relate to the design problem that is used for the preparation of wiper in generation.
Therefore, still there are needs, particularly those of the opposing gravity trend that causes the liquid of dipping to move to stack the bottom for improved impregnated wipes.
Summary of the invention
In one form, the invention provides a kind of be used for treatment of selected select the surface (for example, as have the furniture of furniture polish, for example have the floor of floor polishing lacquer, for example have other crusts of hard surface cleaner, for example have the skin etc. of insect control protective agent) the wiper abandoned.This wiper contains the fabric in order to the liquid infiltration of dispersion.Dispersion liquid comprises biliquid foam (being preferably oil-in-water) and is selected from the thickening material of carbomer, colloidal polymer and natural gum.Most preferably, this dispersion liquid also comprises except thickening material: the tensio-active agent of the oil that is selected from polysiloxane and hydrocarbon ils of 0.01wt%, 0.0001wt%-2wt% and the water of 10wt% at least at least.
This dispersion liquid will contain the tensio-active agent that the basic non-polar surfactant of 0.0001wt%-2wt% (for example nonionogenic tenside) and 0.0001wt%-2wt% are selected from the more multipolarity of anion surfactant, cats product and amphoterics usually except thickening material.
In the context of furniture polish wiper, this dispersion liquid also preferably contains the mineral oil of 1wt% at least and the polysiloxane of 1wt% at least except thickening material.For other application, can use the polysiloxane and/or the hydrocarbon ils of different quantities.
Dispersion liquid opposing since gravity along the downward migration of wiper.This make when wiper by the human consumer along with the past of time when use, the stacking of these wipers (when in the distributor disk that is stored in routine) has more uniform dispersion liquid concentration from the wiper to the wiper easily.
In another aspect, the invention provides a kind of method with a piece of furniture polishing.We have obtained this wiper and it have been transferred on the furniture with the steeping liq that some is obtained from wiper in wiping on the furniture surface.Wiper is expanded the liquid that is shifted along the surface of furniture then.
Wipe fabric can be made by the material based on paper pulp.Yet, this fabric can contain the mixture of cellulosic fibre and other natural or synthon (for example cotton or wool), and perhaps complete natural or synthon (for example regenerated fiber, tynex, acryl fibre, trevira, vinyl fiber, protein fibre, perfluorocarbon fibre, dintrile fiber etc.) by other form.
Dispersion liquid should comprise be generally the dispersion liquid gross weight 0.05% or on thickening material/viscosity modifier.Suitable thickening is included in carbomer (for example having used the crosslinked acrylate copolymer of multifunctional reagent), colloidal polymer or the natural gum under 0.05-20% (preferably the being no more than 2wt%) concentration of dispersion liquid.
Other examples are your natural gum of alginate gums or their salt, melon, locust bean is gummy, xanthan is gummy, salt, wilkinite, zeopan and glyceryl polymethacrylate and their dispersion liquids in glycol of Sudan Gum-arabic, gelatin, Walocel MT 20.000PV, Natvosol, hydroxypropylcellulose, carboxymethyl cellulose, these compounds, and composition thereof.The most preferred thickener that is used for our furniture polish wiper is the salt of crosslinked acrylate copolymer, is known as Carbopol
Ultrez5 (it can obtain from B.F.Goodrich).Especially, this thickening material is with the crosslinked acrylate copolymer of allyl group tetramethylolmethane.
Dispersion liquid can also contain other selection component.For example sanitas can be arranged, such as Kathon
CG/ICP, it can obtain from Rohm and Haas, adopts sodium hydroxide to regulate pH aptly.When product is furniture polish, can also there be scratch cover colorants, spices and other routines to be used for the additive in furniture polish field.
The nonionogenic tenside of broad variety shows and is used for purpose of the present invention.We prefer using Laureth-4 (polyglycol ether of lauryl alcohol) especially.Yet, we can replace using alkanolamide, polyol ester (for example ethylene glycol, Diethylene Glycol or propylene glycol, perhaps glycerol or polyglycerol, the perhaps ester of sorbitanic, glucose or sucrose), the polyoxyethylene or the polyoxypropylene derivative of alcohol, acid amides or ester, perhaps polyoxyethylene/polyoxypropylene block copolymers, perhaps its suitable compatibility mixture.
Other tensio-active agents (when two kinds of common uses) can be selected from the tensio-active agent of the more multipolarity of broad variety.We prefer anionic surfactant sodium lauryl ether sulphate.Yet many other anionic species should be suitable.Example is alkyl-sulphate, sulfonated and the ester banded sulfonate of acyl group-lactic acid salt, N-acyl sarcosinate, alkyl-carboxylate salt (list or multivalence), alkyl ether carboxy acid salt, N-alkyl-glutaminate, lipid acid-peptide condenses, phosphated ethoxylated alcohol, alkyl-sulphate, ethoxyquin.
Other tensio-active agents can also be cats products, and its example is an amidoamines.As selection, other tensio-active agents can be for example alkylamine, N-alkyl-β-An Jibingsuan salt, N-alkyl betaine, alkyl imidazoline and the sultaine of acylamino acid, N-replacement of amphoteric.
Preferred polysiloxane is a dimethyl polysiloxane.Yet, can also use other silicone.In addition, the hydrocarbon ils of broad variety should be suitable.
Will be appreciated that and the invention provides the wiper that has high stability steeping liq.This liquid has the trend along with the gravity migration that the situation as the others similar liquids of the routine of emulsion form and/or not thickening greatly reduces that is compared to astoundingly.In addition, our thickening material of relatively small amount can not influence surface treatment characteristics (for example, the wiping easily of liquid; The resistates of seeing; Deng).
When liquid is hard surface cleaner, the additive (be used for before for example liquid emulsion those) that routine is used for those products will be attached to these dispersion liquids (though tensio-active agent correspondingly reduces) with similar concentration.Similarly, at liquid is under the situation of insect-controlling agent (for example sterilant, expellent or insect growth regulator(IGR)), additive will be those (had been used for for example liquid emulsion those) of the routine product that is used for those kinds, once more with lower tensio-active agent degree combination.
Although embodiment preferred has also been discussed above and will be discussed below, it should be understood that these only are examples of the present invention.For complete evaluation four corner of the present invention more, should look back claims.
Description of Preferred Embodiments
We have obtained exsiccant Vicel6012 cellulosic fabric by Buckeye Technologies, and its about 21cm length * 33cm is wide * and 1mm is thick.We adopt the dispersion liquid be suitable for use as furniture polish by fabric being immersed the container of filling this dispersion liquid with this textile impregnation.As selection, dispersion liquid can drip, spray or other modes are applied on the fabric to cause dipping.
Behind steeping process, in our preferred embodiment, the weight of the polishing liquid of dipping approximates half of pre-soaked wiper weight greatly.Certainly, can be with more or less liquid infiltration wiper, make it more or less saturated thus.
Preferred furniture polish dispersion liquid as steeping liq has following prescription:
Wt% | Common name (can be trade(brand)name) | Chemical name |
To 100% | Water | |
0.1% | Carbopol Ultrez5 | Carbomer |
5% | Klearol | Slab oil |
2% | PDMS100cts | Polydimethylsiloxane |
2% | PDMS1000cts | Polydimethylsiloxane |
0.07?5% | Laureth-4 | |
0.01% | Sodium lauryl ether sulphate | |
0.0255% | Kathon CG/ICP | The methyl chloride isothiazolones |
0.265% | Sodium hydroxide |
Klearol mineral oil can be formed from Witco Corp. acquisition and by saturated aliphatic series and alicyclic non-polar hydrocarbon.Polysiloxane can for example obtain among Wacker Silicones or the Dow Corning from various source.Laureth-4 is the nonionogenic tenside (being also known as the polyglycol ether of lauryl alcohol) that extensively can get.
In the preparation dispersion liquid, preferably at first three kinds of oil ingredients are mixed with nonionogenic tenside (Laureth-4).Independent then mixing water, thickening material, anion surfactant (sodium lauryl ether sulphate), Kathon
Sanitas and sodium hydroxide.In this, obtain about 10% water and being placed in the container.Lentamente oil phase is splashed into water then, the upper surface at oil phase leniently stirs simultaneously.
In case oil phase has added container fully, so add the water of remainder.This back one step can more promptly be carried out than the step that oil is added 10% water.
Provide the oil that can be surrounded fully by water in suitable orderly mode for the reason of the method for this particularly preferred formation biliquid foam.This greatly helps to form biliquid foam.
It should be understood that steeping liq can be cleaning fluid, be used for the waxing liquid on floor or or even contain the wet-liniment of the insect repellants that is useful on human skin rather than furniture polish.In any case, under the situation of these wipers, importantly make the biliquid foam thickening.
As an example, be applicable to that the wiper of cleaning of hard surfaces can be with the dispersion liquid of following prescription dipping:
Wt% | Common name (can be trade(brand)name) | Chemical name |
To 100% | Water | |
0.1% | Carbopol | Carbomer |
5% | Klearol | Slab oil |
0.05% | Laureth-4 | |
0.007% | Sodium lauryl ether sulphate | |
0.051% | Kathon CG/ICP | The methyl chloride isothiazolones |
0.5?31% | Sodium hydroxide |
Should pay special attention to:, for example pure even comprising that under polysiloxane or other oil conditions, the wiper of gained does not need to contain volatile solvent yet.This is highly favourable.
Although preferred sanitas is Kathon
CG/ICP, said preparation can also contain other antiseptic-germicide for example right-hydroxybenzoate, formalin or Imidurea.
As another example, the wiper that is suitable for offering the protection of human consumer's insect repellent can be with the dispersion liquid dipping of following prescription:
Wt% | Common name (can be trade(brand)name) | Chemical name |
To 100% | Water | |
0.2% | Carbopol Ultrez5 | Carbomer |
1% | Klearol | Mineral oil |
15% | DEET | Sterilant |
0.1?8% | Nonionogenic tenside | Laureth-4 |
0.02% | Anion surfactant | Sodium lauryl ether sulphate |
0.05% | Kathon CG/ICP | The methyl chloride isothiazolones |
0.53% | Sodium hydroxide |
Although described embodiment preferred in the above, there are many other embodiments to be in the spirit and scope of the present invention.Therefore, should scrutinize claims estimating four corner of the present invention, and claims should not be understood as that and only limit to embodiment preferred.
Industrial applicibility
The invention provides improved impregnated wipes and their using method, this wiper can be processed furniture and other surfaces.
Claims (9)
1. one kind is used for the wiper abandoned that treatment of selected is selected the surface, and this wiper is characterised in that:
In order to the fabric of the liquid infiltration of dispersion, this dispersion liquid comprises biliquid foam, this foam contains the thickening material that is selected from carbomer, colloidal polymer and natural gum, and wherein the content of this thickening material is the 0.05-20wt% of this dispersion liquid, and this dispersion liquid also comprises except thickening material:
At least the oil that is selected from polysiloxane and hydrocarbon ils of 0.01wt%;
The tensio-active agent of 0.002wt%-2wt%; With
At least the water of 10wt%;
Wherein this tensio-active agent comprises the nonionogenic tenside of 0.001wt%-1wt%; The tensio-active agent that is selected from anion surfactant, cats product and amphoterics with 0.001wt%-1wt%.
2. the wiper abandoned of claim 1, wherein fabric is made by cellulose materials.
3. the wiper abandoned of claim 1, wherein liquid is selected from: furniture polish, hard surface cleaner and insect-controlling agent.
4. the wiper abandoned of claim 1, wherein thickening material is the salt of crosslinked acrylate copolymer.
5. the wiper abandoned of claim 1, wherein this dispersion liquid comprises the polysiloxane of 2wt% at least except thickening material.
6. the wiper abandoned of claim 5, wherein this dispersion liquid comprises two kinds of different polysiloxane with the viscosity of differing from one another except thickening material.
7. the wiper abandoned of claim 1 is further characterized in that antiseptic-germicide.
8. the wiper abandoned of claim 1, wherein this dispersion liquid comprises the tensio-active agent that amounts to 0.002wt%-1wt% except thickening material.
9. method with a piece of furniture polishing is characterized in that:
Obtain to abandon wiper, it comprises the fabric that coats with lacquer dipping in order to the liquor finish of dispersion liquid formation, this dispersion liquid comprises biliquid foam, this foam contains the thickening material that is selected from carbomer, colloidal polymer and natural gum, wherein the content of this thickening material is the 0.05-20wt% of this dispersion liquid, and this dispersion liquid comprises except thickening material:
At least the silicone oil of 1wt%;
The nonionogenic tenside of 0.0001wt%-1wt%;
The tensio-active agent that is selected from anion surfactant, cats product and amphoterics of 0.0001wt%-1wt%; With
At least the water of 10wt%; And
Wiper is transferred on the furniture with near small part foam facing to the furniture wiping.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/291,284 | 2002-11-08 | ||
US10/291,284 US6930080B2 (en) | 2002-11-08 | 2002-11-08 | Wipes impregnated with biliquid foam treating liquids |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1720304A CN1720304A (en) | 2006-01-11 |
CN100375771C true CN100375771C (en) | 2008-03-19 |
Family
ID=32229231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003801046750A Expired - Lifetime CN100375771C (en) | 2002-11-08 | 2003-11-06 | Wipes impregnated with biliquid foam treating liquids |
Country Status (13)
Country | Link |
---|---|
US (1) | US6930080B2 (en) |
EP (1) | EP1563025B1 (en) |
JP (1) | JP4368307B2 (en) |
KR (1) | KR100844916B1 (en) |
CN (1) | CN100375771C (en) |
AR (1) | AR042018A1 (en) |
AT (1) | ATE430787T1 (en) |
AU (1) | AU2003287552B2 (en) |
CA (1) | CA2503769C (en) |
DE (1) | DE60327547D1 (en) |
MX (1) | MXPA05004932A (en) |
TW (1) | TWI307272B (en) |
WO (1) | WO2004044078A1 (en) |
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US7378382B2 (en) * | 2004-05-05 | 2008-05-27 | The Clorox Company | Rheologically stabilized silicone dispersions comprising a polydimethylsiloxane mixture |
US8258066B2 (en) | 2005-12-12 | 2012-09-04 | Milliken & Company | Cleaning device |
US20070243239A1 (en) * | 2006-04-13 | 2007-10-18 | Lanser Dale E | Patch capable of dispensing a scent |
US20080016764A1 (en) * | 2006-07-20 | 2008-01-24 | Wolfe James H | Plant care wipes |
US7803726B2 (en) * | 2006-08-07 | 2010-09-28 | The Procter & Gamble Company | Duster system for damp and dry dusting |
US8030226B2 (en) * | 2009-04-10 | 2011-10-04 | Kimberly-Clark Worldwide, Inc. | Wet wipes having a liquid wipe composition with anti-adhesion component |
US8071524B2 (en) * | 2009-05-18 | 2011-12-06 | Hoover, Inc. | Biodegradable wipe utilizing bio-based lubricant comprising refined soybean oil |
EP2780440B1 (en) * | 2011-11-17 | 2018-09-19 | Sano Bruno's Enterprises Ltd. | Floor cleaning formulation comprising an agent for controlling insects |
CN102634285B (en) * | 2012-03-27 | 2013-08-28 | 河北永泰柯瑞特化工有限公司 | Fur brightener composition and preparation method and application thereof |
CA2907703A1 (en) * | 2013-03-20 | 2014-09-25 | The Procter & Gamble Company | Articles of manufacture comprising water-soluble polymer particles and processes for making same |
CN105860856A (en) * | 2016-04-29 | 2016-08-17 | 四川力久知识产权服务有限公司 | Leather polishing wax emulsion and preparation method thereof |
JPWO2020045465A1 (en) * | 2018-08-29 | 2021-09-02 | 富士フイルム株式会社 | Antiviral wiper |
WO2020053106A1 (en) * | 2018-09-14 | 2020-03-19 | Unilever Plc | Wipe |
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- 2002-11-08 US US10/291,284 patent/US6930080B2/en not_active Expired - Lifetime
-
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- 2003-11-06 KR KR1020057008105A patent/KR100844916B1/en not_active IP Right Cessation
- 2003-11-06 WO PCT/US2003/035477 patent/WO2004044078A1/en active Application Filing
- 2003-11-06 JP JP2004551838A patent/JP4368307B2/en not_active Expired - Fee Related
- 2003-11-06 AU AU2003287552A patent/AU2003287552B2/en not_active Expired
- 2003-11-06 EP EP03781794A patent/EP1563025B1/en not_active Expired - Lifetime
- 2003-11-06 CA CA002503769A patent/CA2503769C/en not_active Expired - Lifetime
- 2003-11-06 AT AT03781794T patent/ATE430787T1/en not_active IP Right Cessation
- 2003-11-06 DE DE60327547T patent/DE60327547D1/en not_active Expired - Lifetime
- 2003-11-06 MX MXPA05004932A patent/MXPA05004932A/en active IP Right Grant
- 2003-11-06 CN CNB2003801046750A patent/CN100375771C/en not_active Expired - Lifetime
- 2003-11-07 TW TW092131223A patent/TWI307272B/en not_active IP Right Cessation
- 2003-11-07 AR ARP030104117A patent/AR042018A1/en active IP Right Grant
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Also Published As
Publication number | Publication date |
---|---|
US20040092417A1 (en) | 2004-05-13 |
CA2503769A1 (en) | 2004-05-27 |
JP2006505354A (en) | 2006-02-16 |
ATE430787T1 (en) | 2009-05-15 |
CN1720304A (en) | 2006-01-11 |
MXPA05004932A (en) | 2005-07-22 |
TWI307272B (en) | 2009-03-11 |
KR100844916B1 (en) | 2008-07-09 |
CA2503769C (en) | 2010-01-19 |
EP1563025B1 (en) | 2009-05-06 |
WO2004044078A1 (en) | 2004-05-27 |
US6930080B2 (en) | 2005-08-16 |
JP4368307B2 (en) | 2009-11-18 |
DE60327547D1 (en) | 2009-06-18 |
TW200414885A (en) | 2004-08-16 |
AR042018A1 (en) | 2005-06-08 |
KR20050074984A (en) | 2005-07-19 |
EP1563025A1 (en) | 2005-08-17 |
AU2003287552A1 (en) | 2004-06-03 |
AU2003287552B2 (en) | 2007-12-13 |
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