CN100365206C - Surface paper of wall paper - Google Patents
Surface paper of wall paper Download PDFInfo
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- CN100365206C CN100365206C CNB2004100397525A CN200410039752A CN100365206C CN 100365206 C CN100365206 C CN 100365206C CN B2004100397525 A CNB2004100397525 A CN B2004100397525A CN 200410039752 A CN200410039752 A CN 200410039752A CN 100365206 C CN100365206 C CN 100365206C
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- paper
- raw material
- evenness
- fiber
- pulp
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004049 embossing Methods 0.000 claims abstract description 25
- 229920000875 Dissolving pulp Polymers 0.000 claims description 20
- 229920002994 synthetic fiber Polymers 0.000 claims description 18
- 239000012209 synthetic fiber Substances 0.000 claims description 18
- 230000005250 beta ray Effects 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 230000004927 fusion Effects 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 31
- 239000011121 hardwood Substances 0.000 abstract 1
- 239000012943 hotmelt Substances 0.000 abstract 1
- 230000000873 masking effect Effects 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 66
- 239000002994 raw material Substances 0.000 description 34
- 229920001131 Pulp (paper) Polymers 0.000 description 15
- 238000010009 beating Methods 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000004537 pulping Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 2
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 240000000907 Musa textilis Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002761 deinking Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 1
- 230000002344 fibroplastic effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/02—Synthetic cellulose fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0082—Wall papers
Landscapes
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Provided is an overlay paper for wallpaper having high bulkiness, giving good texture even by producing with a Fourdrinier paper machine, friendly to the environment and having embossing property and masking power.The overlay paper for wallpaper is composed of a blended sheet containing mainly a hot-melt fiber and a dissolved hardwood pulp.
Description
Technical field
The present invention relates to Surface paper of wall paper, particularly relate to and have sense of fulfillment and simultaneously, be fit to the Surface paper of wall paper that uses fourdrinier machine to make.
Background technology
In the past, what most wallpaper used is the vinyl chloride wallpaper.It is excellent that the vinyl chloride wallpaper is compared with other material at aspects such as cost, design, machinabilitys.But, vinyl chloride used herein, when handling as castoff burning, because the misgivings that produce diox are arranged, from the environment aspect is considered to change to " no vinyl chloride wallpaper ".So as substituting of vinyl chloride wallpaper, the wallpaper or the paper wallpaper of synthetic resin such as coating or applying olefin type resin increase.
Usually, the paper wallpaper is made of the two-layer of upper paper and interior lining paper.In addition, when using adhesive or bonding upper paper of hot-melt-bondable film and interior lining paper, behind bonding aforesaid upper paper and the interior lining paper, carry out the printing or the embossing processing of Hard copy body, use as the paper wallpaper.In this case, be cellulosic material owing in upper paper, use the main material of the paper wallpaper of paper, be excellent for the environment aspect.On the other hand, because the embossing handling ease makes structure become fine and close, so have the shortcoming of sense of fulfillment and design difference.
In order to solve the aforesaid drawbacks, propose to mix the Surface paper of wall paper of copying wood pulp and synthetic fiber, in this case, shortcoming is to be difficult to obtain the enough senses of fulfillment and the good uniformity (opening the 2000-96495 communique referring to the Japan Patent spy).This shortcoming may be enhanced by the combined amount of the synthetic fiber of increase, but cost uprises, and intensity also weakens.In addition, have good evenness when being present in cylinder papermaking or the papermaking of inclination net, but can well and in the papermaking cheaply then can not obtain good evenness with the productivity ratio of fourdrinier wire papermaking.In addition, making beating can obtain good intensity or evenness to wood pulp, but can not obtain sense of fulfillment.Use fourdrinier machine to be difficult to make like this, up to now and have the also good Surface paper of wall paper of sense of fulfillment, evenness.
Present inventors, good in order to obtain sense of fulfillment excellence and evenness, and have embossing, concealed Surface paper of wall paper and carried out conscientiously research, found that, use contains under the situation of mixed copy paper of hot-melt-bondable synthetic fiber and broad leaf tree dissolving pulp, can obtain good Surface paper of wall paper, finish the present invention thus.
Summary of the invention
Therefore, the purpose of this invention is to provide and in fourdrinier wire papermaking, have sense of fulfillment and evenness is also good, and environmentally friendly, and Surface paper of wall paper disguised, the design excellence.
Above-mentioned purpose of the present invention is to realize by the Surface paper of wall paper that the mixed copy paper that mainly contains hot-melt-bondable synthetic fiber and broad leaf tree dissolving pulp forms.Preferred 15~50 weight % of the mixed proportion of above-mentioned hot-melt-bondable synthetic fiber.And preferred 100~180 ℃ of the fusing point of this hot-melt-bondable fiber is preferably 0.25~0.45g/cm as the density of Surface paper of wall paper
3Below, quantitatively coefficient of variation is preferably below 7%.
As the hot melt adhesive synthetic fiber that use among the present invention, preferably use embossing, disguised excellent pulpous state multiple-limb fiber.As such pulpous state multiple-limb fiber, preferably dried fiber and the fibroplastic form of telling by the branch of this dried fiber of branch (for example, No. 2732483, Japanese patent gazette).
The average fiber of above-mentioned dried fiber directly is preferably the scope of 0.5~5 μ m, and preferably, the average fiber of this branch's fiber footpath is less than 0.5 μ m, and is the synthetic paper-pulp of 0.01mm~10mm by the end of branch's fiber to the average fiber length of the end of other branch's fiber.As the preferred examples of the multiple-limb fiber of this pulpous state, what can exemplify is the synthetic paper-pulp of commercially available TPO of the commodity SWP by name of Mitsui Chemicals, Inc.
The dissolving pulp of Shi Yonging is a paper pulp made from extra care alpha-cellulose to heavens in the present invention, under the situation of sulfite method dissolving pulp (DSP), the content that means alpha-cellulose is more than the 89 weight %, under the situation of sulfuric ester method dissolving pulp (DKP), the content that means alpha-cellulose is 93 weight % above (JIS P2701).
Among the dissolving pulp, coniferous tree dissolving pulp and broad leaf tree dissolving pulp are arranged.For loosing character (being also referred to as bulkiness) aspect, the big coniferous tree in fiber footpath is favourable, and the long stapled coniferous tree of comparing with broad leaf tree is difficult to guarantee good evenness.On the other hand, because the dissolving pulp of broad leaf tree is a staple fibre, the aspect of evenness is favourable, the loosing character excellence of comparing with wood pulp.In addition, it also is possible removing microfibre and obtain loosing character.Therefore, for the present invention, should mix the broad leaf tree dissolving pulp as neccessary composition.
The ratio of the hot-melt-bondable synthetic fiber in the Surface paper of wall paper of the present invention is preferably 15~50 weight %, and the ratio of broad leaf tree dissolving pulp is preferably 10~85 weight %.The ratio of hot-melt-bondable synthetic fiber is below 15 weight %, and embossing is poor, and surpasses the increase that 50 weight % are accompanied by combined amount.Can not get the improvement of quality and uneconomical, " drier idle running " etc. takes place easily, operability is also poor.On the other hand, during the ratio less than 10 weight % of broad leaf tree dissolving pulp, can not obtain sense of fulfillment or enough evenness, if surpass 85 weight %, owing to fully do not mix with the hot-melt-bondable synthetic fiber, embossing is poor.
If have above-mentioned composition, even use fourdrinier machine also can make the good paper of evenness.
And above-mentioned evenness can use β ray evenness instrumentation fixed.
The β ray evenness meter of Shi Yonging is quantitatively to utilize high β ray transmitance down low in the present invention, measures the device of the quantitative inhomogeneities of certain area.The value of the quantitative coefficient of variation of measuring is low more, shows that then evenness is good more.If quantitatively coefficient of variation is below 7%, be very good value as the evenness of the upper paper of wallpaper.
In the present invention, except the broad leaf tree dissolving pulp, also can in the scope of 0~50 weight %, mix wood pulp, non-wood pulp, other the paper pulp of synthetic fiber etc.Above-mentioned wood pulp, for example can be from chemical pulp (the bleaching sulfite pulp (LBSP) of the bleached kraft pulp (LBKP) of acerose bleached kraft pulp (NBKP), broad leaf tree, acerose bleaching sulfite pulp (NBSP), broad leaf tree etc.), CTMP (CTMP), the deinking of the wastepaper as raw material of high-quality slurry (DIP), and can under high concentration, carry out selection in the caustic dip paper pulp etc. of alkali treatment.
Non-wood-fiber for example can be selected from mestha, jute, cotton linter fiber, abaca, bamboo, wheat straw, bagasse, Spanish grass (Esparto) etc.Synthetic fiber for example can be selected from polyethylene fiber, polyester fiber, acrylic fiber, various composite fibres etc.
In order to obtain enough senses of fulfillment, Surface paper of wall paper of the present invention, preferably choosing density is 0.25~0.45g/m
3Following.The not enough 0.25g/m of density
3Can not obtain enough intensity, the papermaking difficulty is if density surpasses 0.45g/m
3, can not obtain enough embossing and sense of fulfillment.
Add man-hour in the wallpaper applying, greater strength is no more than 0.45g/m in density if desired
3Scope in, the preferred timber slurry that mixes making beating.Keep bigger loosing character, preferred mixed polyester fiber, or core is divided into the polyolefin composite fibre that polyester fiber, sheath partly are polyethylene fibers.
Surface paper of wall paper among the present invention quantitatively be preferably 85~500g/m
2Upper paper is that side is bonding in the interior lining paper as the upper paper supporting layer within it, as required further in this surface design of lining paper with respect to the structure of the adhesive layer of wall and obtain wallpaper.Interior lining paper is commonly used in the wallpaper, preferably quantitatively is 65~80g/cm
2, this scope is not had concrete limit.
Surface paper of wall paper of the present invention is to print processing or knurling rolls by photogravure roller etc. to carry out embossing processing and make.In addition, wallpaper also is worn easily because pollute easily on its purposes surface, can be on surface sides be the synthetic resin emulsion of purpose coated with soil resistance or mar proof etc., applying EVOH film etc.
Surface paper of wall paper density of the present invention is 0.25~0.45g/cm
3Below, the quantitative coefficient of variation in the β ray evenness meter is below 7%, is all excellent Surface paper of wall paper of embossing and stability, and also is easy by the fourdrinier machine manufacturing.In addition, print processing by photogravure roller etc. and obtain excellent Surface paper of wall paper, and owing to do not use vinyl chloride, also excellent to the adaptability of environment, very useful in practicality.
Embodiment
Next, more specifically describe the present invention, but the present invention is defined in following embodiment by embodiment.And, if there is no particular limitation " % " expression " weight % ".
<hot-melt-bondable synthetic fiber (raw material A) 〉
Disassociation polyolefin synthetic paper-pulp (trade name: SWP E400, average fiber length 0.9mm, density 0.96g/cm
3, 135 ℃ of fusing points pulpous state multiple-limb fiber, Mitsui Chemicals, Inc makes), obtain raw material A.
<not the making beating broad leaf tree dissolving pulp (raw material B)
The long content for 0.9mm, alpha-cellulose of disassociation average fiber is 93.2% commercially available broad leaf tree dissolving pulp LDKP, obtains raw material B.
<making beating LBKP (raw material C) 〉
Use two disc pulping machines to LBKP making beating (Japanese papermaking Co., Ltd. make), obtain Canadian Standard Freeness (below, CSF) be the raw material C of 440ml.
<cotton linter pulp (raw material D) 〉
Dissociate and use two disc pulping machines making beating behind the commercially available paper grade (stock) cotton linter pulp, obtaining CSF is the raw material D of 650ml.
<synthetic fiber (raw material E) 〉
The disassociation core segment is a polyester fiber, and sheath partly is polyolefin composite fibre (trade name: N710S, the long 5mm of average fiber, the density 1.37g/cm of polyethylene fiber
3, sheath part non-branch fiber, Network ラ レ Co., Ltd. of 130 ℃ of fusing points make), obtain raw material E.
<caustic dip paper pulp (raw material F) 〉
Commercially available coniferous tree bleached kraft pulp (in the not making beating product of NBKP (Japanese papermaking Co., Ltd. make), be 5% to add the sodium hydrate aqueous solution of concentration 15% in order to make slurry concentration, 20 ℃ down dipping 30 minutes to alkalize.Then, to regulate pH to 7, obtain raw material F with enough washings.In addition, the content of cellulose II is 100% in the slurry that obtains.The CSF of such caustic dip paper pulp (raw material F) is 750ml.
<not the making beating NBKP (raw material G)
The commercially available NBKP (Japanese papermaking Co., Ltd. make) that dissociates, obtaining CSF is the raw material G of 720ml.
The NBKP (raw material H) of<making beating 〉
Use two disc pulping machines to commercially available NBKP (Japanese papermaking Co., Ltd. make) making beating, obtaining CSF is the raw material H of 510ml.
<making beating NBKP (raw material I) 〉
Use two disc pulping machines to commercially available NBKP (Japanese papermaking Co., Ltd. make) making beating, obtaining CSF is the raw material I of 600ml.
Embodiment 1
The manufacturing of<Surface paper of wall paper 〉
The mixed weight ratio of raw material (A) and raw material (B) is adjusted into A/B=15/85, adds sizing agent, paper power reinforcing agent, in fourdrinier machine, making quantitatively is 100g/cm
2Paper, to make Surface paper of wall paper.The page that (23 ℃, 50%RH) damping is made under constant temperature and humidity.After the damping, by the density of JIS P8118 mensuration page, as the index of loosing character.In addition, use the quantitative coefficient of variation of β ray evenness instrumentation of ア Application バ one テ ッ Network society, as the index of evenness.
The evaluation of<embossing 〉
On the one side of the converted paper that obtains, add ethylene-vinyl acetate copolymer resins adhesive, make quantitatively to be 65g/m
2Interior lining paper bonding, put into the gap of metal knurling rolls and the end liner rubber rollers that has an even surface, the surface temperature of choosing knurling rolls is 210 ℃, and the face side of page is carried out embossing processing.If the concavo-convex clear of the embossing that obtains chooses zero, if unclear choosing *, between this, would choose △.The result is as shown in table 1.
Embodiment 2
Except that the ratio of raw material (A) and raw material (B) is chosen A/B=45/55, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Embodiment 3
Remove and to use (A), (B) and (H) to be that raw material components, the ratio of choosing them are beyond the A/B/H=45/15/40, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Embodiment 4
Remove and to use (A), (B) and (C) to be that raw material components, the ratio of choosing them are beyond the A/B/C=45/15/40, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Embodiment 5
Remove and to use (A), (B) and (D) to be that raw material components, the ratio of choosing them are beyond the A/B/D=45/15/40, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Embodiment 6
Remove and to use (A), (B) and (E) to be that raw material components, the ratio of choosing them are beyond the A/B/E=45/15/40, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Comparative example 1
Except that the ratio of raw material (A) and raw material (B) is chosen A/B=5/95, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Comparative example 2
Remove and to use (A) and (F) to be that raw material components, the ratio of choosing them are beyond the A/F=45/55, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Comparative example 3
Remove and to use (A) and (G) to be that raw material components, the ratio of choosing them are beyond the A/G=45/55, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Comparative example 4
Remove and to use (A) and (I) to be that raw material components, the ratio of choosing them are beyond the A/I=45/55, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
Comparative example 5
Remove and to use (A) and (C) to be that raw material components, the ratio of choosing them are beyond the A/C=45/55, under condition similarly to Example 1, carry out the evaluation of loosing character, evenness, embossing.The result is as shown in table 1.
[table 1]
Density g/cm 3 | Quantitative coefficient of variation % | Embossing | |
Embodiment 1 | 0.366 | 5.5 | ○ |
Embodiment 2 | 0.352 | 5.5 | ○ |
Embodiment 3 | 0.416 | 4.5 | ○ |
Embodiment 4 | 0.431 | 4.0 | ○ |
Embodiment 5 | 0.363 | 6.0 | ○ |
Embodiment 6 | 0.335 | 6.0 | ○ |
Comparative example 1 | 0.371 | 5.5 | × |
Comparative example 2 | 0.301 | 13.0 | ○ |
Comparative example 3 | 0.390 | 10.5 | ○ |
Comparative example 4 | 0.491 | 6.0 | △ |
Comparative example 5 | 0.504 | 4.0 | △ |
Shown in the table 1 that the Surface paper of wall paper of the present invention of the hot-melt-bondable synthetic fiber of mixing 15~60% and 10~85% broad leaf tree dissolving pulp confirms that it has loosing character, also has good evenness when fourdrinier wire papermaking.
Claims (4)
1. Surface paper of wall paper, it is formed by the mixed copy paper that mainly contains hot-melt-bondable synthetic fiber and broad leaf tree dissolving pulp, and the content of the alpha-cellulose in the wherein said broad leaf tree dissolving pulp is more than the 89 weight %.
In the claim 1 record Surface paper of wall paper, wherein, the content of described hot-melt-bondable synthetic fiber is 15~50 weight % at least, the content of described broad leaf tree dissolving pulp is 10~85 weight % at least.
3. the Surface paper of wall paper of record in the claim 1 or 2, wherein, described hot-melt-bondable synthetic fiber are that fusing point is 100~180 ℃, adds the hot-melt-bondable synthetic fiber of fusion in man-hour in embossing.
4. the Surface paper of wall paper of each record in the claim 1~3, wherein, density is 0.25~0.45g/cm
3, and the quantitative coefficient of variation that gets at β ray evenness instrumentation is below 7%.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003031399A JP2004238772A (en) | 2003-02-07 | 2003-02-07 | Overlay paper for wallpaper |
JP031399/2003 | 2003-02-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1542223A CN1542223A (en) | 2004-11-03 |
CN100365206C true CN100365206C (en) | 2008-01-30 |
Family
ID=32958007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100397525A Expired - Fee Related CN100365206C (en) | 2003-02-07 | 2004-02-06 | Surface paper of wall paper |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2004238772A (en) |
KR (1) | KR20040072039A (en) |
CN (1) | CN100365206C (en) |
HK (1) | HK1070931A1 (en) |
TW (1) | TW200420809A (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4637629B2 (en) * | 2005-03-31 | 2011-02-23 | ユニチカ株式会社 | Shoji paper |
JP5120244B2 (en) * | 2008-12-25 | 2013-01-16 | 大日本印刷株式会社 | Adhesive wallpaper |
EP2966222A1 (en) * | 2014-07-10 | 2016-01-13 | Schoeller Technocell GmbH & Co. KG | Base material for wallpapers |
JP6266543B2 (en) * | 2015-01-22 | 2018-01-24 | 三菱製紙株式会社 | Non-woven fabric for wallpaper backing |
JP6266547B2 (en) * | 2015-02-05 | 2018-01-24 | 三菱製紙株式会社 | Non-woven fabric for wallpaper backing |
US10815395B2 (en) * | 2015-07-10 | 2020-10-27 | Aica Kogyo Co., Ltd. | Decorative sheet |
CN114934404B (en) * | 2022-05-31 | 2023-05-12 | 华南理工大学 | Easily-dispersed plant fiber mask base cloth and preparation method and application thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003003397A (en) * | 2001-06-22 | 2003-01-08 | Komei Seishi Kk | Two-layered foamed paper and method for producing the same |
WO2003010384A1 (en) * | 2001-07-24 | 2003-02-06 | Nippon Paper Industries Co., Ltd. | Bulky pulp, method for production thereof and converted paper or multi-ply paper using the bulky pulp |
-
2003
- 2003-02-07 JP JP2003031399A patent/JP2004238772A/en active Pending
-
2004
- 2004-02-04 KR KR1020040007176A patent/KR20040072039A/en not_active Application Discontinuation
- 2004-02-05 TW TW093102604A patent/TW200420809A/en unknown
- 2004-02-06 CN CNB2004100397525A patent/CN100365206C/en not_active Expired - Fee Related
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2005
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003003397A (en) * | 2001-06-22 | 2003-01-08 | Komei Seishi Kk | Two-layered foamed paper and method for producing the same |
WO2003010384A1 (en) * | 2001-07-24 | 2003-02-06 | Nippon Paper Industries Co., Ltd. | Bulky pulp, method for production thereof and converted paper or multi-ply paper using the bulky pulp |
Non-Patent Citations (1)
Title |
---|
纸用聚酯纤维. 杨瑞玲.中华纸业,第25卷第1期. 2004 * |
Also Published As
Publication number | Publication date |
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TW200420809A (en) | 2004-10-16 |
JP2004238772A (en) | 2004-08-26 |
HK1070931A1 (en) | 2005-06-30 |
CN1542223A (en) | 2004-11-03 |
KR20040072039A (en) | 2004-08-16 |
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