CN100348789C - Multifunctional radiation proof fabric and its production process - Google Patents

Multifunctional radiation proof fabric and its production process Download PDF

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Publication number
CN100348789C
CN100348789C CN 02110608 CN02110608A CN100348789C CN 100348789 C CN100348789 C CN 100348789C CN 02110608 CN02110608 CN 02110608 CN 02110608 A CN02110608 A CN 02110608A CN 100348789 C CN100348789 C CN 100348789C
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present
synthetic fiber
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CN1361315A (en
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商思善
黎桂娟
鲁远望
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Shanghai Green Tech Development Co
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Abstract

The present invention relates to a multifunctional radiation-resistant textile and a manufacture method thereof. The weight percentage of the components of the textile in the present invention is: 20% or more than 20% of current conducting materials, 10% or more than 10% of magnetic conduction materials, 3% or more than 3% of far infrared emission materials and 3% or more than 3% of oxygen releasing materials, and the remaining quantity is natural fiber or/and synthetic fiber. The method of the present invention comprises the following steps that (1). the natural fiber and the synthetic fiber are used as main base materials; (2). the current conducting materials, the magnetic conduction materials, the far infrared emission materials and the oxygen releasing materials are processed into nanometer particles and then dispersed by using dispersing agents; (3). the multifunctional materials are uniformly added into the natural fiber and the synthetic fiber by using high-efficiency swelling agents, penetrating agents and diffusing agents. The present invention has substantive features and obvious progress and is mainly used for shielding an electromagnetic field and improving the microcirculation in human bodies, sterilization, stink elimination, oxygen release, antistatic property, etc. The product of the present invention has the double functions of protection and health care, and can be widely used for national defence, scientific researches, industrial and mining enterprises, medical sanitation and tens of thousands of residents.

Description

Multifunctional radiation proof fabric and preparation method thereof
Technical field: what the present invention relates to is a kind of fabric and preparation method thereof, and particularly a kind of multifunctional radiation proof fabric and preparation method thereof belongs to the fabric field.
Background technology: electromagnetic radiation pollution, now become great society public hazards, bring potential threat for people's psychosomatic health, especially the very low frequency electromagnetic field has short cancer effect; Staphylococcus aureus, Escherichia coli, read strain coccus, typhoid bacillus and Aspergillus flavus etc. in vain, the people is caused a disease, high-pressure electrostatic can influence the human body electrocardio normal conduction, and in view of above reason, each state is all at the multi-functional fabric of one that is of concentrating on studies.Find by literature search: Chinese patent application number is: 88100557.6, name is called: contain conductive fabric of polyacrylonitrile fibre and preparation method thereof, this patent application readme is: " behind conductive processing liquid place type; contain the cuprous sulfide that accounts for its weight 0.1-30% (weight) in the fabric (butt) ", and further specify " material that is applicable to conductive processing is meant that polyacrylonitrile content accounts for fabric gross weight 1% or above knitted fabric, woven fabric, braided fabric, woolen fabric, pile fabrics or bondedfibre fabric ".Utilize slaine such as copper sulphate, copper chloride, cuprous sulfate and stannous chloride and bleeding agent, levelling agent, make copper and fiber combination, though the cuprous sulfide that generates is water insoluble, have certain electric conductivity, washability, still, cuprous weatherability is relatively poor, very easily disproportionation makes original performance failure.
The summary of the invention and the specific embodiment: the present invention is directed to the deficiencies in the prior art, a kind of multifunctional radiation proof fabric and preparation method thereof is provided, the present invention is a base material with natural fabric and synthetic fiber, adopt physical-chemical method, through swelling agent, bleeding agent, diffusant, fast conduction, magnetic conduction, emission far infrared, oxygen release, sterilization, the multiple functional mass kind such as smelly that disappears are gone into the manufacturing technique that fibrous inside is characteristics.
The percentage by weight of multifunctional radiation proof fabric content of the present invention is: conductive materials 〉=20%, and magnetic conduction substance 〉=10%, emission far infrared materials 〉=5%, oxygen release material 〉=3%, surplus is: natural fabric is or/and synthetic fiber.Below the percentage by weight of content of the present invention is further specified: copper sulphate 400-700 gram, nickel chloride 300-600 gram, aluminium chloride 80-200 gram, iron chloride 30-150 gram, cobalt chloride 20-100 gram, manganese chloride 5-50 gram, editic acid 1000-2000 gram, sodium borohydride 30-200 gram, titanium dioxide 0.8-20 gram, silica 0.5-15 gram, zirconium carbide 0.1-2 gram, oxygen release agent 5-40 gram, nickel 2-15 gram, copper 5-30 gram, cobalt 0.5-10 gram, swelling agent SA 5--80 gram, bleeding agent BA 10-90 gram, dispersant N 30-150 gram, surplus is: natural fabric is or/and synthetic fiber.
The preparation method of multifunctional radiation proof fabric of the present invention is specific as follows: (1) is main base material with natural fabric and synthetic fiber; (2) conduction, magnetic conduction, emission far infrared and oxygen release material, be processed into nano particle, relend dispersion aids and disperse; (3) adopt high-efficiency bulking agent, bleeding agent and diffusant, multi-functional material is planted equably into natural fabric and adding synthetic fiber inside.
Below preparation method of the present invention is further specified:
(1) to natural fabric, or/and silk fiber adopts normal pressure, temperature makes fiber height expanded between room temperature~80 ℃ as: cotton or/and hair, adopts to soak-roll-process integration that dry by the fire, and functional mass is permeated quickly and evenly, spreads, and kind is gone into fibrous inside; (2) to synthetic fiber, as: terylene or/and nylon or/and acrylic fiber adopts and earlier functional mass is processed into nano particle and sneaks into equably in the resin, carries out spinning again; (3) adopt the high-efficiency bulking agent, make natural fabric extremely expanded, by dispersant, diffusant, can go into fibrous inside to conductive materials, magnetic conduction substance, far infrared materials and oxygen release material kind, (4) adopt conductive materials, magnetic conduction substance, emission fine outer material far away and oxygen release material, be nano-scale particle.
The present invention has substantive distinguishing features and marked improvement, product of the present invention is mainly used in shield electromagnetic (comprising the very low frequency electromagnetic field), improve microcirculation in human body, sterilization, disappear smelly, discharge oxygen, antistatic etc.Product strength of the present invention is big, elasticity is high, quality is frivolous, chromatogram is complete, bright-coloured smoothness, can keep the style of taking of source textile, has protection and health care dual-use function, can be widely used in national defence, scientific research, industrial and mining enterprises and health care and huge numbers of families.
Below provide embodiment to further specify:
Example 1 cotton fiber 1000 grams, cotton fine: water=1: 40; Copper sulphate 539 grams; Iron chloride 75 grams; Aluminium chloride 112 grams; Cobalt chloride 52 grams; Nickel chloride 418 grams; Manganese chloride 23 grams; Editic acid 1200 grams; Sodium borohydride 80 grams; Swelling agent 40 grams; Bleeding agent 50 grams.
Pre-treatment: in the sodium hydrate aqueous solution of cotton fiber immersion 15%, normal pressure, 80 ℃, soaked 60 minutes, be washed till neutral dehydration.Immerse in the aqueous solution of 1% stannous chloride (20 liters), room temperature was soaked rinsing 10 minutes again.0.5% silver nitrate aqueous solution interior (15 liters) is immersed in the dehydration back, and room temperature was soaked 5 minutes, took out washing, and dehydration is stand-by.Above-mentioned substance dissolved in 50 liters the stainless steel tank, transfer PH=7.5-8, again the fiber of handling is put into wherein, when room temperature, soak one and rolled about 10 minutes earlier.Again solution in the groove is heated to 80 ℃, soak one again and rolled about 40 minutes, take out, clean, dry, promptly get multifunctional fibre.
Get 1000 gram polyester granules again; Titanium dioxide (nanoscale) 3 grams; Silica (nanoscale) 3 grams; Silver (nanoscale) 1 gram; Zirconium carbide (nanoscale) 0.5 gram; Copper (nanoscale) 15 grams; Nickel (nanoscale) 8 grams; Cobalt (nanoscale) 2 grams; Oxygen release agent 20 grams; Dispersant 80 grams.
Get above-mentioned substance and pour in the blender, room temperature is disperseed, and mixes after 1 hour, adds 1000 gram polyester granules again, continues to mix 2 hours, carries out granulation.On the molten spinning machine of routine, carry out spinning, drawing-off, curl, cut off then, promptly get multifunctional fibre (cotton type).With multi-functional cotton fine: multifunctional terylene fibre=80: 20, on the traditional textile machine, spin, weave cotton cloth, put in order, promptly obtain " multifunctional radiation proof fabric ".
Example 2 is got wool 1000 grams, wool: water=1: 30; Copper sulphate 500 grams; Iron chloride 65 grams; Aluminium chloride 100 grams; Cobalt chloride 40 grams; Nickel chloride 350 grams; Manganese chloride 15 grams; Editic acid 1000 grams; Bleeding agent 40 grams; Sodium borohydride 50 grams; Swelling agent 30 grams.
Pre-treatment: wool is immersed softener (S2S) 4% (heavy to wool), bath raio=1: 10,45 ℃ of temperature were soaked 15 minutes, and 1% the stannous chloride aqueous solution interior (20 liters) is immersed in the washing dehydration again, and normal temperature soaks 10 minutes, rinsing.Immerse 0.5% silver nitrate aqueous solution interior (15 liters) after dewatering, room temperature was soaked 5 minutes, and taking-up is washed, dewaters stand-by.Above-mentioned substance dissolved in 50 liters the stainless steel tank, transfer PH=5.5-6, again the fiber of handling is put into wherein, when room temperature, soak one and roll about 10 minutes earlier.Again solution in the groove is heated to 80 ℃, soak one again and rolled about 40 minutes, take out, clean, dry, promptly get multifunctional fibre.
Get nylon particle 1000 grams; Titanium dioxide (nanoscale) 2 grams; Silica (nanoscale) 2 grams; Zirconium carbide (nanoscale) 0.2 gram; Silver (nanoscale) 0.5 gram; Nickel (nanoscale) 5 grams; Copper (nanoscale) 10 grams; Cobalt (nanoscale) 1 gram; Oxygen release agent 15 grams; Dispersant 80 grams.
Get above-mentioned substance and pour in the blender, room temperature is disperseed, and mixes after 1 hour, adds 1000 gram nylon particles again, continues to mix 2 hours, carries out granulation.On the molten spinning machine of routine, carry out spinning, drawing-off, curl, cut off then, promptly get multifunctional fibre (wool type).With multi-functional wool: multifunctional nylon fibre=85: 15, on the traditional textile machine, spin, weave cotton cloth, put in order, promptly obtain " multifunctional radiation proof fabric ".
Example 3 is got wool 1000 grams, and technology is with example 2
Get acrylic fibers slurry 1000 grams; Titanium dioxide (nanoscale) 1 gram; Silica (nanoscale) 1 gram; Zirconium carbide (nanoscale) 0.1 gram; Nickel (nanoscale) 2 grams; Silver (nanoscale) 0.2 gram; Copper (nanoscale) 5 grams; Cobalt (nanoscale) 0.5 gram; Oxygen release agent 5 grams; Dispersant 30 grams.
Get above-mentioned additive and pour in the blender, room temperature is disperseed, and mixes after 1 hour, joins in the 1000 gram acrylic fibers slurries again, continues to mix 2 hours, can carry out spinning (wool type).With multi-functional wool: multifunctional nitrilon=80: 20, on the traditional textile machine, spin, weave cotton cloth, put in order, promptly obtain " multifunctional radiation proof fabric ".

Claims (1)

1, a kind of multifunctional radiation proof fabric is characterized in that,
Comprising natural fabric and synthetic fiber, in natural fabric, is benchmark with 1000 gram natural fabrics, weight percentages of components is as follows: copper sulphate 40-70%, iron chloride 3-15%, aluminium chloride 8-20%, cobalt chloride 2-10%, nickel chloride 30-60%, manganese chloride 0.5-5%, editic acid 100-200%, sodium borohydride 3-20%, swelling agent SA 0.5-8%, bleeding agent BA 1-9%, natural fabric 1000 grams;
In synthetic fiber, with 1000 gram synthetic fiber is benchmark, weight percentages of components is as follows: titanium dioxide 0.8-2%, silica 0.05-1.5%, zirconium carbide 0.01-0.2%, oxygen release material 0.5-4%, nickel 0.2-1.5%, copper 0.5-3%, cobalt 0.05-1%, dispersant N 3-15%, synthetic fiber 1000 grams.
CN 02110608 2002-01-22 2002-01-22 Multifunctional radiation proof fabric and its production process Expired - Fee Related CN100348789C (en)

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CN100348789C true CN100348789C (en) 2007-11-14

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Families Citing this family (20)

* Cited by examiner, † Cited by third party
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CN1300399C (en) * 2003-08-27 2007-02-14 天津市有声针织公司 Process for preparing far infrared magnetic fabric
CN1715473B (en) * 2004-06-29 2011-06-08 上海利昂高科技有限公司 Flexible electric conductive fabric and its producing method
CN101385091B (en) * 2004-12-20 2012-12-26 全盛研究与开发公司 Radiation protective clothes articles
CN1710187B (en) * 2005-07-04 2010-05-12 西安工程科技学院 Nano composite metal coated fabric and its preparing process
CN101845753B (en) * 2010-05-14 2012-06-06 苏州新纶超净技术有限公司 Anti-static/conductive fabric and manufacture method thereof
US9493892B1 (en) 2012-08-15 2016-11-15 Arun Agarwal Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
US9131790B2 (en) 2013-08-15 2015-09-15 Aavn, Inc. Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
CN102851767A (en) * 2012-08-29 2013-01-02 昆山铁牛衬衫厂 Electromagnetic radiation shielding fiber, and its manufacturing method
US10443159B2 (en) 2013-08-15 2019-10-15 Arun Agarwal Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
US11359311B2 (en) 2013-08-15 2022-06-14 Arun Agarwal Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
US11168414B2 (en) 2013-08-15 2021-11-09 Arun Agarwal Selective abrading of a surface of a woven textile fabric with proliferated thread count based on simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
US10808337B2 (en) 2013-08-15 2020-10-20 Arun Agarwal Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
US12091785B2 (en) 2013-08-15 2024-09-17 Aavn, Inc. Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package
CN103484959B (en) * 2013-09-30 2016-08-17 周雷生 A kind of preparation method of the zirconium carbide compositions in fibrous material
CN104088031B (en) * 2014-01-02 2016-04-20 浙江美丝邦化纤有限公司 Multi-functional nylon-6 fiber and manufacture method thereof
US9394634B2 (en) 2014-03-20 2016-07-19 Arun Agarwal Woven shielding textile impervious to visible and ultraviolet electromagnetic radiation
US20160160406A1 (en) 2014-05-29 2016-06-09 Arun Agarwal Production of high cotton number or low denier core spun yarn for weaving of reactive fabric and enhanced bedding
CN109957898A (en) * 2017-12-14 2019-07-02 蔡佳真 A kind of preparation method and equipment and textile fabric obtained of the textile fabric having far infrared irradiation energy
CN108523878A (en) * 2018-04-16 2018-09-14 北京航空航天大学 A kind of wearable ECG monitoring end product
US11225733B2 (en) 2018-08-31 2022-01-18 Arun Agarwal Proliferated thread count of a woven textile by simultaneous insertion within a single pick insertion event of a loom apparatus multiple adjacent parallel yarns drawn from a multi-pick yarn package

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