CN100342054C - Pantograph slip plate for electric locomotive and mfg. method thereof - Google Patents
Pantograph slip plate for electric locomotive and mfg. method thereof Download PDFInfo
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- CN100342054C CN100342054C CNB2005101367659A CN200510136765A CN100342054C CN 100342054 C CN100342054 C CN 100342054C CN B2005101367659 A CNB2005101367659 A CN B2005101367659A CN 200510136765 A CN200510136765 A CN 200510136765A CN 100342054 C CN100342054 C CN 100342054C
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Abstract
The present invention relates to electric locomotive pantograph pan material and a manufacturing method thereof, which uses copper powder as a base body and uses coppered carbon material powder bodies as an anti-frictional and anti-wear agent and uses coppered carbon fiber as a reinforcing agent and uses lead, iron, chrome, lanthanum metal powder bodies as additive. All components are evenly mixed and are formed by molding, and then, are sintered so as to obtain the pantograph pan material. The manufactured pantograph pan material of the present invention has the characteristics of low resistivity, strong toughness of impact resistance, small friction coefficient, good combination property, simple manufacturing process, and no pollution, etc., serves as self lubrication material to use within ranges between room temperature and 300DEG. C, simultaneously, is easy to control a technological process, and is suitable for carrying out mass production. The pantograph pan material is suitable for a pantograph pan manufacturing an electric locomotive, and is used for pantograph slide blocks and other collecting products for manufacturing trolleybuses.
Description
Technical field: the present invention relates to carbon fiber reinforced carbon-copper material and preparation method thereof, this carbon-copper material can be used for making the pantograph pan of electric locomotive, belongs to the accessory that a kind of transportation and communication uses; The method for preparing this carbon-copper material relates to carbon granule surface chemistry plating metal, carbon fiber surface electrochemistry metal lining and powder metallurgy and produces technical field of composite materials.
Background technology: in the track traffic transportation, generally adopt electric locomotive at present, the important current collection element that the pantograph pan in the electric locomotive is as towing mechanism.Known Material for Pantograph Slide and preparation method thereof has following several:
1, pure metal material slide plate
Such slide plate adopts materials processings such as steel, copper to make, and is the pantograph pan product that China's electric locomotive sixties in 20th century uses.Such slide plate physical strength height, the current collection capacity is big, and wear resistance and electroconductibility are all better.But, strong because slide plate is close with lead material with contact line conducting wire avidity, there is not self-lubricating property in addition, thus very serious to the contact system lead abrasion, be limited to use.
2, composite powder metallurgy material slide plate
The powder metallurgy slide plate is divided into iron-based and copper base two classes.Iron-based be applicable to the steel aluminium conductor, the copper base be applicable to copper conductor.The powder metallurgy slide plate is a basal component with metallic iron, copper powder, adds some lubricated compositions, as carbon, lead and molybdenumdisulphide sulfides, by mechanically mixing, makes various homogenization of composition.Utilize hydropress with the batch mixing compression molding, then with the blank high temperature sintering, dip lubrication oil behind the sintering, last machining moulding.Powder metallurgy slide plate physical strength height, good impact resistance has electroconductibility, arc resistance and lower intrinsic resistance preferably, the thermotolerance height, heat conductivity is good, and wear resistance and anti-attrition are good, certain self-lubricating property is arranged, and electrocorrosion is less, and work-ing life is longer.Yet, because the powder metallurgy sliding material is that metallic object and lead material are similar, so the powder metallurgy slide plate is more serious to lead abrasion.
3, carbon material slide plate
The carbon material slide plate can be made with the following method: a certain proportion of pitch coke, refinery coke, Graphite Powder 99, carbon black or hard carbon are mixed in mixer, add a certain amount of coal-tar pitch then, stir into the charcoal pasty state, then charcoal is stuck with paste extrusion molding; Shaping blank roasting in the high temperature protection atmosphere sintering furnace; Dipping high temperature kerosene pyrobitumen in baked article; Carry out solidification treatment behind the dipping and make the slide plate blank; At last the blank of being produced is carried out machining and shaping.The dipping hard pitch both can reduce the porosity of slide plate in slide plate, made the slide plate water-intake rate be lower than 2%, reached the purpose of sealing of hole and waterproof, increased the work-ing life under the overcast and rainy wet weather, can also improve the comprehensive mechanical performance of slide plate.The carbon material slide plate itself is exactly good lubricant, and self-lubricating property and anti-attrition performance are good, and little to the contact line conducting wire wearing and tearing, electromagnetic noise is little during slip, and high temperature resistant, is difficult for and contact line conducting wire generation weldering phenomenon.The carbon slide plate can form one deck carbon film on lead when rubbing with the copper contact line conducting wire, improved the abrasion situation of lead greatly.But carbon slide plate physical strength is low, poor impact resistance, and the lead hard spot that runs in service causes slide plate to fracture easily and breaks, and work-ing life is low.Particularly in rainy season and humid area, easily ditch is drawn in the part, accident between pantograph often occurs.In addition, carbon slide plate intrinsic resistance is big, and the current collection capacity is little, and contact temperature height might cause that lead crosses thermooxidizing, burns till continuous pockmark, quickens lead abrasion.Carbon slide plate powder also can pollute locomotive insulator and contact system insulator, causes insulator generation electric discharge phenomena, causes puncture.
4, metal-impregnated carbon material slide plate
The basic manufacture method of metal-impregnated carbon material slide plate is as follows: make carbon slide plate blank earlier, impregnated with molten metal in blank forms hard mesh skeleton then, reaches the purpose that improves slide plate intensity, shock-resistance, wear resistance and increase the service life.The metal that is used to flood must have the physical strength height, wear-resisting, thermal conductivity is high, corrosion resistant characteristics, and viscosity is little under molten state, good fluidity is generally selected tin, antimony, pot metal or Babbitt metal for use.Metal-impregnated carbon slide had both had powder metallurgy slide plate physical strength height, characteristics that resistivity is little, have again the carbon material slide plate little to lead abrasion, easily form lubricant film and the strong premium properties of blow-out at the lead friction surface.This slide plate is a comparatively ideal pantograph pan of copper conductor section.But this class slide plate toughness is poor, is prone to the piece phenomenon in the use.
In order to solve above-mentioned pantograph pan deficiency in use, occurred some in succession and improved one's methods.
Publication number is that the application for a patent for invention of CN1178745A discloses a kind of carbon-carbon composite material pantograph slide for electric locomotive.This slide plate is a body material with the coppered carbon powder, adopts short carbon fiber as toughener, and with thermosetting resin as binding agent, adopt hygrometric state to mix or dry state blended method, with the raw material thorough mixing, cold pressing then with hot-forming.This slide plate has excellent friction and wear behavior, but poor impact toughness, the resistivity height.
Publication number is that the application for a patent for invention of CN1265429A discloses a kind of composite carbon-copper material reinforced with continuous long carbon fiber pantograph pan, and this invention is a kind of improvement to above-mentioned carbon-carbon composite material pantograph slide for electric locomotive patent of invention.This invention is a substrate aggregate with the copper facing composite powder, composite powder comprises carbonaceous materials such as copper, graphite, coke, carbon black, metal-powders such as lead, tin and binding agent etc., make toughener with continuous long carbon fiber, to cold pressing behind the raw material thorough mixing, in cold pressure procedure, add continuous long carbon fiber, and then carry out hot pressing or hot extrusion molding processing.Though this slide plate has good friction and wear behavior, impelling strength is still not enough, and resistivity is higher.
Summary of the invention: the objective of the invention is the deficiency that still exists at the pantograph pan after the above-mentioned improvement, propose a kind of New Material for Pantograph Slide and preparation method thereof.
Technical scheme of the present invention is as follows: be matrix with the copper powder, with coppered carbon material powder, copper carbon fiber is modified component, mixed powder with iron, chromium, lead, lanthanum is an additive, and all components is mixed and compression molding, can obtain Material for Pantograph Slide through sintering again.
Copper has good conductivity, and the purpose of use copper powder is to strengthen the conductivity of sliding material.The copper powder size range that the present invention uses is 43～89 μ m, and copper powder shared quality percentage composition in total component is 62～86wt%; Carbon material has good wear, wear resisting property, and the coppered carbon material that the present invention uses can be copper-plated graphite, carbon black or coke, and its granularity is 43～89 μ m, and shared quality percentage composition is 10～24wt% in total component; Carbon fiber not only has good wear, antiwear characteristic, can also improve the impelling strength of matrix material.The copper carbon fiber that the present invention uses can be copper facing polyacrylonitrile type carbon fiber, asphalt base carbon fiber or celion, and its purity is greater than 99%, diameter 6～7 μ m, and shared quality percentage composition is 1～6wt% in total component; Iron, chromium, lead, lanthanum powder additive have the copper of optimization base tissue, crystal grain thinning, improve effects such as copper-based material wear resisting property, wherein to account for the quality percentage composition of total component be 2～8wt% to the addition of lead powder, iron powder is 0.02～0.04wt%, chromium powder is 0.008～0.02wt%, and the lanthanum powder is 0.002～0.01wt%.Therefore, sliding material of the present invention belongs to a kind of matrix material, and this matrix material that contains copper, carbon material, carbon fiber, metal-powder has good electrical conductivity, wear resistance and impelling strength.
Bring dysgenic problem for the performance of carbon-copper material for overcoming because of carbon copper interface bond strength is very poor, first copper facing on the surface of carbon material and carbon fiber, and then they are mixed with copper powder etc., the carbon copper product is by original carbon copper contact becoming copper copper contact like this, and the interface bond strength of carbon-copper material is improved.
But, to carbon material, carbon fiber copper facing the time, have bigger difficulty.Only can make part carbon material plated with copper when showing as, and copper facing speed is very slow to carbon material copper facing.During to a branch of carbon fiber bundle copper facing that contains a large amount of monofilament, only can make the outside surface plated with copper of a branch of carbon fiber, copper is not plated in the inside of carbon fiber bundle, has so-called " evil mind " problem.The present invention to the solution of carbon material powder copper facing difficulty is: with the salts solution of zinc powder reduction copper, adopt the chain alkyl sodium soap, acetic acid is as dispersion agent, make all plated with copper of whole carbon material powder in the mode of electroless copper, and copper facing speed is very fast.Solution to carbon fiber copper facing difficulty is: with pyrophosphate salt is solution, and adopting ammonium citrate, tin anhydride, OP-21 is additive, to carbon fiber bundle copper facing, can make all plated with copper of whole carbon fiber monofilament, and copper facing speed is very fast in the mode of electro-coppering.
The technological process and the processing condition of preparation Material for Pantograph Slide are as follows:
The first step prepares coppered carbon material and copper carbon fiber.
Preparation coppered carbon material method: preparation quality percentage composition is the salts solution (representing mass percent with wt%) of the copper of 3～10wt%, add the carbon material powder that 2～10wt% handled in this solution, stirred solution adds 0.5～4.3wt% zinc powder again after 2～6 minutes; Then dodecyl sodium soap and sodium-acetate are joined among the salts solution of copper, add-on is 0.1～0.2wt%, stirs afterwards 3～8 minutes.Clean up with deionized water after the carbon material copper facing, and carry out Passivation Treatment, in case the copper on the blocking material is oxidized with 0.013～0.105wt% benzotriazole solution; At last the coppered carbon material powder after the Passivation Treatment is placed in the vacuum drying oven and dries.The content range of copper is between 4～40wt% in the coppered carbon material powder.
Preparation copper carbon fiber method: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 5～12wt%, K
4P
2O
7The quality percentage composition be 30～45wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and add-on is 0.004～0.01wt%.Anode is a red copper during plating, and negative electrode is a carbon fiber, regulates the voltage of direct supply, and making strength of current is 0.8～1.8A.Electroplate the end back and use the washed with de-ionized water copper carbon fiber, be placed in the vacuum drying oven and dry.The content range of copper is between 4～20wt% in the copper carbon fiber.
The second step batch mixing
Take by weighing the metal-powder of required copper powder, coppered carbon material, copper carbon fiber and iron, chromium, lead, lanthanum, wherein the quality percentage composition of copper powder is 62～86wt%, the coppered carbon material is 10～24wt%, copper carbon fiber is 1～6wt%, and lead powder is 2～8wt%, and iron powder is 0.02～0.04wt%, chromium powder is 0.008～0.02wt%, the lanthanum powder is 0.002～0.01wt%, carries out batch mixing then, and mixing time is 0.5～4h.
The 3rd step compression molding
Material for Pantograph Slide adopts compression molding compression moulding.To mix uniform material and put among the mould, and compression moulding.Pressing pressure is 200～400MPa, and the dwell time is 1～10min.
The 4th step sintering
The sample of being suppressed is carried out sintering processes, and sintering temperature is 800 ℃～950 ℃, and soaking time 3～8h can obtain Material for Pantograph Slide.
The Material for Pantograph Slide of the present invention's preparation has characteristics such as resistivity is low, toughness is strong, frictional coefficient is little, and good combination property can use as self-lubricating material in ℃ scope of room temperature～300; Preparation technology is simple simultaneously, and technological process is controlled easily, and pollution-free, is suitable for producing in enormous quantities.Following table be with the present invention preparation pantograph pan and domestic and international product of the same race, apply for a patent the comparative result of goods.
| The slide plate type | Resistivity/(μ Ω m) | Impelling strength/(J/cm 2) | Frictional coefficient | Remarks |
| The self-control pantograph pan | 0.20 | 3.40 | 0.08 | Adopt sliding material preparation of the present invention |
| Homemade carbon slide plate | 17.6 | 0.32 | 0.22 | Production code member C 26 |
| Homemade metal-impregnated carbon slide | 5.4 | 0.78 | 0.12 | Production code member C 26p |
| The domestic carbon fibre slide plate | 6 | 3.8 | / | The JM-1 of excessive Yang Mogen group |
| Germany's metal-impregnated carbon slide | 13 | 1.24 | 0.10 | Production code member Rh82Mb |
| Japan's carbon slide plate | 9 | 1.10 | 0.13 | Production code member MC |
| The short carbon fiber slide plate | 2.8 | 0.44 | / | Publication number is the application for a patent for invention of CN1178745A |
| The long carbon fiber slide plate | 8.5 | 1.33 | / | Publication number is the application for a patent for invention of CN1265429A |
Annotate: above data are the mean value of observed value.
Description of drawings: Fig. 1 is preparation technology's schema of Materials for Electric Locomotive Pantograph Slide Plate of the present invention; Fig. 2 is the main performance index of the pantograph pan for preparing of the present invention.
Embodiment: technology contents of the present invention is described in further detail below in conjunction with embodiment.
Embodiment 1:
The first step prepares copper coated graphite powder and polyacrylonitrile type copper carbon fiber.
Preparation copper coated graphite powder method: preparation quality percentage composition is the copper-bath of 3wt%, and adding granularity in this solution is that 43 μ m, quality percentage composition are the Graphite Powder 99 that 2wt% handled, and stirred solution adds the zinc powder of 0.5wt% again after 2 minutes; And then dodecyl sodium soap and sodium-acetate joined among the copper-bath, add-on is 0.1wt%, the mass ratio of dodecyl sodium soap and sodium-acetate is 1: 10, stirs afterwards 3 minutes.Clean up with deionized water after the Graphite Powder 99 copper facing, and carry out Passivation Treatment with 0.013wt% benzotriazole solution; At last the copper coated graphite powder after the Passivation Treatment is placed in the vacuum drying oven and dries.The content of copper is 19wt% in the copper coated graphite powder.
Preparation polyacrylonitrile type copper carbon fiber method: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 5wt%, K
4P
2O
7The quality percentage composition be 30wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and add-on is 0.004wt%, and the ratio of ammonium citrate, tin anhydride and OP-21 three's quality is 10: 0.4: 0.2.Anode is a red copper during plating, and negative electrode is a polyacrylonitrile type carbon fiber, regulates the voltage of direct supply, and making strength of current is 0.8A.Electroplate the end back and use the washed with de-ionized water copper carbon fiber, be placed in the vacuum drying oven and dry.The content of copper is 4wt% in the polyacrylonitrile type copper carbon fiber.
The second step batch mixing
Take by weighing the metal-powder of required copper powder, copper coated graphite powder, polyacrylonitrile type copper carbon fiber and iron, chromium, lead, lanthanum, wherein the quality percentage composition of copper powder is 86wt%, copper coated graphite powder is 10.97wt%, polyacrylonitrile type copper carbon fiber is 1.0wt%, and lead powder is 2wt%, and iron powder is 0.02wt%, chromium powder is 0.008wt%, the lanthanum powder is 0.002wt%, carries out batch mixing then, and mixing time is 0.5h.
The 3rd step compression molding
Above-mentioned batch mixing is put into mould, use the compression moulding of ME-100 type oil press then.Pressing pressure is 200MPa, and the dwell time is 1min.
The 4th step sintering
With SRJG-5-10 type crucible electrical resistance furnace the sample of being suppressed is carried out sintering, sintering temperature is 800 ℃, soaking time 3h.
The resistivity of the Material for Pantograph Slide of gained is 0.16 μ Ω m, and impelling strength is 3.20J/cm
2, frictional coefficient is 0.081.
Embodiment 2:
The first step prepares copper coated graphite powder and polyacrylonitrile type copper carbon fiber.
Preparation copper coated graphite powder method: preparation quality percentage composition is the copper-bath of 6wt%, and adding granularity in this solution is that 50 μ m, quality percentage composition are the Graphite Powder 99 that 6wt% handled, and stirred solution adds 4% zinc powder again after 4 minutes; And then dodecyl sodium soap and sodium-acetate joined among the copper-bath, add-on is 1.2wt%, the mass ratio of dodecyl sodium soap and sodium-acetate is 1: 10, stirs afterwards 5 minutes.Clean up with deionized water after the Graphite Powder 99 copper facing, and carry out Passivation Treatment with 0.085wt% benzotriazole solution; At last the copper coated graphite powder after the Passivation Treatment is placed in the vacuum drying oven and dries.The content of copper is 39wt% in the copper coated graphite powder.
Preparation polyacrylonitrile type copper carbon fiber method: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 8wt%, K
4P
2O
7The quality percentage composition be 36wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and add-on is 0.008wt%, and the ratio of ammonium citrate, tin anhydride and OP-21 three's quality is 10: 0.4: 0.2.Anode is a red copper during plating, and negative electrode is a carbon fiber, regulates the voltage of direct supply, and making strength of current is 1.2A.Electroplate the end back and use the washed with de-ionized water copper carbon fiber, be placed in the vacuum drying oven and dry.The content of copper is 12wt% in the polyacrylonitrile type copper carbon fiber.
The second step batch mixing
Take by weighing the metal-powder of required copper powder, copper coated graphite powder, polyacrylonitrile type copper carbon fiber and iron, chromium, lead, lanthanum, wherein the quality percentage composition of copper powder is 78wt%, copper coated graphite powder is 14.95wt%, polyacrylonitrile type copper carbon fiber is 4.0wt%, and lead powder is 3wt%, and iron powder is 0.03wt%, chromium powder is 0.015wt%, the lanthanum powder is 0.005wt%, carries out batch mixing then, and mixing time is 2h.
The 3rd step compression molding
Above-mentioned batch mixing is added in the mould, use the compression moulding of ME-100 type oil press then.Pressing pressure is 300MPa, and the dwell time is 4min.
The 4th step sintering
With SRJG-5-10 type crucible electrical resistance furnace the sample of being suppressed is carried out sintering, sintering temperature is 850 ℃, soaking time 5h.
The resistivity of the Material for Pantograph Slide that obtains is 0.07 μ Ω m, and impelling strength is 3.28J/cm
2, frictional coefficient is 0.070.
Embodiment 3:
The first step prepares copper coated graphite powder and polyacrylonitrile type copper carbon fiber.
Preparation copper coated graphite powder method: preparation quality percentage composition is the copper-bath of 10wt%, and adding granularity in this solution is that 89 μ m, quality percentage composition are the Graphite Powder 99 that 10wt% handled, and stirred solution adds 4.3% zinc powder again after 6 minutes; And then dodecyl sodium soap and sodium-acetate joined among the copper-bath, add-on is 0.2wt%, the mass ratio of dodecyl sodium soap and sodium-acetate is 1: 10, stirs afterwards 8 minutes.Clean up with deionized water after the Graphite Powder 99 copper facing, and carry out Passivation Treatment with 0.105wt% benzotriazole solution; At last the copper coated graphite powder after the Passivation Treatment is placed in the vacuum drying oven and dries.The content of copper is 29wt% in the copper coated graphite powder.
Preparation copper carbon fiber method: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 12wt%, K
4P
2O
7The quality percentage composition be 45wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and add-on is 0.01wt%, and the ratio of ammonium citrate, tin anhydride and OP-21 three's quality is 10: 0.4: 0.2.Anode is a red copper during plating, and negative electrode is a carbon fiber, regulates the voltage of direct supply, and making strength of current is 1.8A.Electroplate the end back and use the washed with de-ionized water copper carbon fiber, be placed in the vacuum drying oven and dry.The content of copper is 20wt% in the polyacrylonitrile type copper carbon fiber.
The second step batch mixing
Take by weighing the metal-powder of required copper powder, copper coated graphite powder, polyacrylonitrile type copper carbon fiber and iron, chromium, lead, lanthanum, wherein the quality percentage composition of copper powder is 62wt%, copper coated graphite powder is 23.93wt%, polyacrylonitrile type copper carbon fiber is 6.0wt%, and lead powder is 8wt%, and iron powder is 0.04wt%, chromium powder is 0.02wt%, the lanthanum powder is 0.01wt%, carries out batch mixing then, and mixing time is 4h.
The 3rd step compression molding
Above-mentioned batch mixing is added in the mould, use the compression moulding of ME-100 type oil press then.Pressing pressure is 400MPa, and the dwell time is 8min.
The 4th step sintering
With SRJG-5-10 type crucible electrical resistance furnace the sample of being suppressed is carried out sintering, sintering temperature is 950 ℃, soaking time 8h.
The resistivity of the Material for Pantograph Slide that obtains is 0.21 μ Ω m, and impelling strength is 3.40J/cm
2, frictional coefficient is 0.065.
Embodiment 4:
The first step prepares copper facing coke powder and asphaltic base copper carbon fiber.
Preparation copper facing coke powder method: preparation quality percentage composition is the copper nitrate solution of 6wt%, and adding granularity in this solution is that 60 μ m, quality percentage composition are the coke powder that 8wt% handled, and stirred solution adds 2.0% zinc powder again after 4 minutes; And then dodecyl sodium soap and sodium-acetate joined among the copper nitrate solution, add-on is 0.12wt%, the mass ratio of dodecyl sodium soap and sodium-acetate is 1: 10, stirs afterwards 3 minutes.Clean up with deionized water after the coke powder copper facing, and carry out Passivation Treatment with 0.018wt% benzotriazole solution; At last the copper facing coke powder after the Passivation Treatment is placed in the vacuum drying oven and dries.The content of copper is 17wt% in the copper facing coke powder.
Preparation asphaltic base copper carbon fiber method: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 10wt%, K
4P
2O
7The quality percentage composition be 40wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and add-on is 0.005wt%, and the ratio of ammonium citrate, tin anhydride and OP-21 three's quality is 10: 0.4: 0.2.Anode is a red copper during plating, and negative electrode is a carbon fiber, regulates the voltage of direct supply, and making strength of current is 1.4A.Electroplate the end back and use the washed with de-ionized water copper carbon fiber, be placed in the vacuum drying oven and dry.The content of copper is 14wt% in the asphaltic base copper carbon fiber.
The second step batch mixing
Take by weighing the metal-powder of required copper powder, copper facing coke powder, asphaltic base copper carbon fiber and iron, chromium, lead, lanthanum, wherein the quality percentage composition of copper powder is 69wt%, the copper facing coke powder is 19.94wt%, the asphaltic base copper carbon fiber is 5wt%, and lead powder is 6wt%, and iron powder is 0.03wt%, chromium powder is 0.015wt%, the lanthanum powder is 0.015wt%, carries out batch mixing then, and mixing time is 3.5h.
The 3rd step compression molding
Above-mentioned batch mixing is added in the mould, use the compression moulding of ME-100 type oil press then.Pressing pressure is 320MPa, and the dwell time is 5min.
The 4th step sintering
With SRJG-5-10 type crucible electrical resistance furnace the sample of being suppressed is carried out sintering, sintering temperature is 910 ℃, soaking time 4h.
The resistivity of the Material for Pantograph Slide that obtains is 0.20 μ Ω m, and impelling strength is 3.34J/cm
2, frictional coefficient is 0.060.
The Material for Pantograph Slide of the present invention's preparation not only is confined to make the pantograph pan of electric locomotive, also can be used for making the product that used by electric slide block and other current collections of trolley bus.
Claims (2)
1, a kind of Materials for Electric Locomotive Pantograph Slide Plate contains copper, carbonaceous material, carbon fiber and additive, it is characterized in that the quality percentage composition as the copper powder of substrate aggregate is 62～86wt%, and the copper powder size range is 43～89 μ m; Quality percentage composition as the copper coated graphite powder of antifriction, anti-wear agent is 10～24wt%, and the granularity of Graphite Powder 99 is 43～89 μ m, and the quality percentage composition of copper is 19～39wt% in the copper coated graphite powder; Quality percentage composition as the copper facing polyacrylonitrile type carbon fiber of toughener is 1～6wt%, and the purity of used polyacrylonitrile type carbon fiber is greater than 99%, diameter 6～7 μ m, and the quality percentage composition of copper is 4～20wt% in the copper facing polyacrylonitrile type carbon fiber; Quality percentage composition as the lead powder of additive is 2～8wt%, and the quality percentage composition of iron powder is 0.02～0.04wt%, and the quality percentage composition of chromium powder is 0.008～0.02wt%, and the quality percentage composition of lanthanum powder is 0.002～0.01wt%.
2, a kind of preparation method of Materials for Electric Locomotive Pantograph Slide Plate, it is characterized in that with the quality percentage composition being that copper powder, the quality percentage composition of 62～86wt% is that 10～24wt% copper coated graphite powder, quality percentage composition are that 1～6wt% copper facing polyacrylonitrile type carbon fiber and quality percentage composition are that the lead powder of 2～8wt%, the iron powder that the quality percentage composition is 0.02～0.04wt%, the chromium powder that the quality percentage composition is 0.008～0.02wt%, the lanthanum powder of quality percentage composition 0.002～0.01wt% mix, mixing time is 0.5～4h; To mix uniform material again and put among the mould, and compression moulding, pressing pressure is 200～400MPa, the dwell time is 1～10min; The sample of being suppressed is carried out sintering processes, and sintering temperature is 800 ℃～950 ℃, and soaking time is 3～8h, can obtain Materials for Electric Locomotive Pantograph Slide Plate; Be that the Graphite Powder 99 surface is taked electroless copper, polyacrylonitrile type carbon fiber surface is taked the copper-plated concrete grammar of electrochemistry below:
The Graphite Powder 99 copper coating: preparation quality percentage composition is the salts solution of the copper of 3～10wt%, adding the quality percentage composition in this solution is the Graphite Powder 99 of the processing of 2～10wt%, and stirred solution adds the zinc powder that the quality percentage composition is 0.5～4.3wt% again after 2～6 minutes; Then dodecyl sodium soap and sodium-acetate are joined among the salts solution of copper, the quality percentage composition of adding is 0.1～0.2wt%, stirs afterwards 3～8 minutes; Clean up with deionized water after the Graphite Powder 99 copper facing, and be that the benzotriazole solution of 0.013～0.105wt% carries out Passivation Treatment with the quality percentage composition; At last the copper coated graphite powder after the Passivation Treatment is placed in the vacuum drying oven and dries;
Polyacrylonitrile type carbon fiber copper coating: with the Cu for preparing
2P
2O
7And K
4P
2O
7Mixed solution pour in the electrolytic plating pool Cu wherein into
2P
2O
7The quality percentage composition be 5～12wt%, K
4P
2O
7The quality percentage composition be 30～45wt%; The pH value of then regulating plating bath is 8～9, is additive with ammonium citrate, tin anhydride and OP-21, and the quality percentage composition of adding is 0.004～0.01wt%; Regulate the voltage of direct supply, making strength of current is 0.8～1.8A; Electroplate and finish the back, be placed in the vacuum drying oven and dry with washed with de-ionized water copper facing polyacrylonitrile type carbon fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101367659A CN100342054C (en) | 2005-12-30 | 2005-12-30 | Pantograph slip plate for electric locomotive and mfg. method thereof |
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| CN102059339B (en) * | 2010-12-09 | 2012-07-11 | 北京科技大学 | Method for preparing copper based pantograph pan material |
| CN103159495B (en) * | 2011-12-08 | 2014-09-24 | 苏州东南碳制品有限公司 | Carbon fiber reinforced pantograph carbon slide plate material and manufacturing method thereof |
| CN103469123A (en) * | 2013-09-26 | 2013-12-25 | 长春工业大学 | Manufacturing method of carbon fiber-reinforced copper-based pantograph slide plate material |
| CN104195477B (en) * | 2014-09-12 | 2016-01-06 | 四川理工学院 | A kind of preparation technology of high impact toughness carbon-carbon/carbon-copper composite material |
| CN104494447A (en) * | 2014-10-20 | 2015-04-08 | 赵飞 | Method for preparing pantograph slide plate composite carbon core of electric locomotive (including high-speed train) by using cold isostatic pressing process |
| CN104384515B (en) * | 2014-10-22 | 2016-10-19 | 福建国福中亚电气机械有限公司 | A kind of preparation method of pantograph graphite-based slide plate |
| CN107326347B (en) * | 2017-07-04 | 2019-09-20 | 西北工业大学 | Hard PMI foam integrated waveguide surface chemical plating copper method |
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| CN109014216A (en) * | 2018-09-03 | 2018-12-18 | 大同新成新材料股份有限公司 | A kind of pantograph pan preparation process based on copper coated graphite powder |
| CN110238381B (en) * | 2019-06-24 | 2020-08-25 | 东北大学 | Graphene copper pantograph sliding plate material for high-speed train and preparation method |
| US20210262076A1 (en) * | 2019-06-24 | 2021-08-26 | Northeastern University | Graphene copper pantograph pan material for high-speed trains and preparation method thereof |
| CN111360243B (en) * | 2020-04-24 | 2022-04-01 | 长沙迈特锐新材料有限公司 | High-performance self-lubricating copper-based pantograph slide plate material and preparation method thereof |
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