CN100340168C - Pesticiding fragrant composition and ernulsion for preparing the same and preparing process - Google Patents
Pesticiding fragrant composition and ernulsion for preparing the same and preparing process Download PDFInfo
- Publication number
- CN100340168C CN100340168C CNB2004100330099A CN200410033009A CN100340168C CN 100340168 C CN100340168 C CN 100340168C CN B2004100330099 A CNB2004100330099 A CN B2004100330099A CN 200410033009 A CN200410033009 A CN 200410033009A CN 100340168 C CN100340168 C CN 100340168C
- Authority
- CN
- China
- Prior art keywords
- composition
- stacte
- desinsection
- weight
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 77
- 238000000034 method Methods 0.000 title abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000011575 calcium Substances 0.000 claims abstract description 18
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 18
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 4
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 34
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 16
- -1 methoxyl group Chemical group 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 9
- 230000000749 insecticidal effect Effects 0.000 abstract description 5
- 239000000839 emulsion Substances 0.000 abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
- 150000005215 alkyl ethers Chemical class 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 9
- 241000255925 Diptera Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000723353 Chrysanthemum Species 0.000 description 3
- 235000007516 Chrysanthemum Nutrition 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- UZILCZKGXMQEQR-UHFFFAOYSA-N decyl-Benzene Chemical compound CCCCCCCCCCC1=CC=CC=C1 UZILCZKGXMQEQR-UHFFFAOYSA-N 0.000 description 2
- 238000003197 gene knockdown Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000144210 Culex pipiens pallens Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000006579 Tsuji-Trost allylation reaction Methods 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
- XBEADGFTLHRJRB-UHFFFAOYSA-N undecylbenzene Chemical compound CCCCCCCCCCCC1=CC=CC=C1 XBEADGFTLHRJRB-UHFFFAOYSA-N 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
This insecticidal incense stick comprises an insecticidal incense stick base containing a compound of formula (1) (wherein R is hydrogen atom, methyl group, methoxy group or methoxymethyl group; and X and Y are each independently chlorine atom, methyl group or hydrogen atom), a calcium alkylbenzensulfonate and a polyoxyalkylene alkyl ether. An emulsion and a method for manufacturing the insecticidal incense stick are also provided.
Description
Technical field
The present invention relates to a kind of desinsection stacte composition, and be used to prepare the missible oil (being called EC hereinafter) of said composition and prepare the method for said composition.
Background technology
The compound of formula (1) expression:
Wherein R is a hydrogen atom, methyl, methoxyl group or methoxyl methyl, X and Y respectively do for oneself chlorine atom, methyl or hydrogen atom.This compound has been disclosed in USP-6 as a kind of insecticidal constituent, and 225,495, USP-6,294,576, USP-4, in 889,872 documents such as grade.
At USP-6, also put down in writing this compound in 225,495 and USP-6,294,576 and can be processed into stacte composition (mosquito repellent coil disc).
Yet under some situation, above-mentioned desinsection stacte composition still can not obtain enough good effect.Thereby, need a kind of desinsection stacte composition that can show better effect of exploitation.
Summary of the invention
An object of the present invention is to provide a kind of desinsection stacte composition with excellent effect.
Other purpose of the present invention and advantage of the present invention will make those skilled in the art high-visible by following description.
The inventor finds that the effect of desinsection stacte composition can be improved by following measure: remove active component, be outside the compound of following formula (1) expression, by in desinsection stacte matrix, alkylbenzene mixture sulfoacid calcium and polyoxyalkylene alkyl, thus finish the present invention.
That is to say, the invention provides:
1. desinsection stacte composition wherein comprises the compound of formula (1) expression:
Wherein R is a hydrogen atom, methyl, methoxyl group or methoxyl methyl, X and the Y chlorine atom of respectively doing for oneself, methyl or hydrogen atom (hereinafter, being called compound (1));
Alkyl benzene calcium sulfonate; Polyoxyalkylene alkyl; With desinsection stacte matrix;
2. according to above-mentioned 1 composition,, comprise the compound (1) of 0.002 to 0.05 weight %, the polyoxyalkylene alkyl of the alkyl benzene calcium sulfonate of 0.002 to 0.05 weight % and 0.002 to 0.05 weight % wherein in composition;
3. according to above-mentioned 1 composition, wherein further comprise alkylbenzene;
4. according to above-mentioned 3 composition,, comprise the alkylbenzene of 0.03 to 0.8 weight % wherein in composition;
5. according to above-mentioned 1 composition, it is strip;
6. according to above-mentioned 1 composition, it is the coil shape;
7. missible oil that is used to prepare desinsection stacte composition, this missible oil inclusion compound (1), alkyl benzene calcium sulfonate, polyoxyalkylene alkyl, and alkylbenzene;
8. one kind prepares desinsection stacte method for compositions, comprises the steps:
To be used to prepare the diluted missible oil and the mixing of desinsection stacte matrix of desinsection stacte composition, this missible oil inclusion compound (1), alkyl benzene calcium sulfonate, polyoxyalkylene alkyl, and alkylbenzene; Moulding and dry gained mixture then; With
9. the desinsection stacte composition that obtains according to above-mentioned 8 method.
Detailed description of the preferred embodiment
Among the present invention, the example of compound (1) comprises 2,3,5,6-tetrafluoro-4-methyl-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxy benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, 2,3,5,6-tetrafluoro-4-methoxy-benzyl 3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester and 2,3,5,6-ptfe benzyl 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.These compounds are known, perhaps can prepare by known method.
The desinsection stacte matrix of using among the present invention can be conventional substrate, and this matrix is made up of combustion adjuvant (organic filler) and adhesive usually.
The example of combustion adjuvant comprises dry plant meal or powder such as wood powder, Dalmatian chrysanthemum slag, the epidermis meal of citrus fruit, palm shell powder, coconut shell powder, walnut parting etc., and powdered carbon such as charcoal powder, activated carbon powder, coal dust etc.They can be separately or two or more mix and use.
The example of adhesive comprises tabu-no-ki tree (red nanmu) powder, starch (as tapioca, corn starch, wheaten starch), casein, Siam glue, methylcellulose, carboxymethyl cellulose, high-molecular weight compounds such as polyvinyl alcohol etc.They can be separately or two or more mix and use.
Usually, the alkyl benzene calcium sulfonate that uses in the present invention is (C
8-C
14) alkyl benzene calcium sulfonate.Polyoxyalkylene alkyl, for example, polyoxygenated (C
2-C
3) allylic alkylation ether such as polyoxyethylene (C
12-C
18) alkyl ether.
Desinsection stacte composition of the present invention is the insecticidal matrix by inclusion compound (1), and alkyl benzene calcium sulfonate and polyoxyalkylene alkyl are formed.
Usually, desinsection stacte composition of the present invention comprises the compound (1) of 0.002 to 0.05 weight %, the polyoxyalkylene alkyl of the alkyl benzene calcium sulfonate of 0.002 to 0.05 weight % and 0.002 to 0.05 weight % in composition.
Desinsection stacte composition of the present invention can further comprise alkylbenzene.The example of alkylbenzene comprises C
10-C
14The benzene that alkyl replaces.Particularly, alkylbenzene is a decyl benzene for example, undecyl benzene, detergent alkylate and tridane.When desinsection stacte composition of the present invention comprised alkylbenzene, its content was normally in composition, 0.03 to 0.8 weight %.
If necessary, desinsection stacte composition can further comprise colouring agent, preservative etc.The example of colouring agent comprises organic pigment such as peacock green etc.The example of preservative comprises acid as benzoic acid, sorbic acid, dehydroactic acid, P-hydroxybenzoic acid, o-phenyl phenol etc., and the salt of above-mentioned substance and ester.Desinsection stacte composition of the present invention can comprise above-mentioned each compound of 1 weight % or less amount.
Desinsection stacte composition of the present invention can prepare like this, for example the EC and the desinsection stacte matrix (combustion adjuvant, adhesive etc.) of dilution is mixed, this is used to prepare the EC inclusion compound (1) of desinsection stacte composition, alkyl benzene calcium sulfonate, polyoxyalkylene alkyl, and alkylbenzene; And if required, further add entry.After kneading, with mould such as pressing machinery, extruder, embossing machine, stamping machine etc. are made suitable shape such as strip with the moulding of gained mixture, coil shape etc., and the subsequent drying forming mixture obtains desinsection stacte composition of the present invention.
The EC that is used to prepare the dilution of desinsection stacte composition is preparation like this, and dilute with water is used to prepare the EC of desinsection stacte composition of the present invention, described EC inclusion compound (1), alkyl benzene calcium sulfonate, polyoxyalkylene alkyl and alkylbenzene.Usually, emulsion of the present invention is the water dilution of the EC of per 1 weight portion with 10 to 1000 weight portions.
In order to prepare desinsection stacte composition of the present invention, usually, with mixing with the desinsection stacte matrix of 1 weight portion of 0.1 to 1.2 weight portion through dilution EC.
Be used to prepare the EC inclusion compound (1) of desinsection stacte composition of the present invention, alkyl benzene calcium sulfonate, polyoxyalkylene alkyl and alkylbenzene.
Usually, above-mentioned EC comprises the compound (1) of 2.5 to 20 weight %, the alkyl benzene calcium sulfonate of 2.5 to 20 weight %, the alkylbenzene of the polyoxyalkylene alkyl of 2.5 to 20 weight % and 40 to 92.5 weight %.For example, the preparation of EC can be by the compound (1) with specified rate; The emulsifier mixture that comprises the polyoxyalkylene alkyl of the alkyl benzene calcium sulfonate of specified rate and specified rate; And the alkylbenzene of specified rate mixes.
Obtaining desinsection stacte composition of the present invention thus can use according to conventional methods.That is to say that desinsection stacte composition of the present invention can produce smog in the habitat of insect (as mosquito, fly etc.) or in its vicinity as place such as in the room.When burning during this desinsection stacte composition, volatilization and diffusion activity composition, i.e. compound (1), thereby Pest Control.
Following preparation embodiment, comparing embodiment and test implementation example further describe the present invention, but should not be considered to limit the scope of the invention.In the following embodiments, except as otherwise noted, all " parts " are by weight.
Preparation embodiment
(1) EC (being called latex A hereinafter) that is used to prepare desinsection stacte composition is by mixing 5 part 2,3,5,6-tetrafluoro-4-methoxy benzyl (1R)-trans-3-(1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester (the geometric isomer ratio of 1-acrylic: Z/E=about 8/1); 4.5 part alkyl benzene calcium sulfonate, 4.5 parts of polyoxyalkylene alkyl and 6 parts of arsols are (by Takemoto Oil ﹠amp; The Newkalgen155A/Takemoto Oil ﹠amp that Fat Co., Ltd makes; The mixture of the Newkalgen155F=2/1 that Fat Co., Ltd makes) mixture; Obtain with 80 parts of alkylbenzenes (the Mitsubishi Soft Alkylbenzene SAB-G that makes by Mitsubishi Chemical Corporation).
(2) by 0.1 part of EC A and 49.9 parts of water being mixed with the EC of the dilution that is used to produce desinsection stacte composition.The EC of 50 parts of dilutions is mixed with 15 parts of Dalmatian chrysanthemum slags, 15 parts of wood powders, 20 parts of red bucket tree powder and 10 parts of water.The gained mixture is fully mediated, subsequently by moulding and drying (40 ℃, 6 hours) to obtain required desinsection stacte composition (being called the present composition 1 hereinafter).
Comparing embodiment
A kind of desinsection stacte composition (being called comparative composition hereinafter) is to obtain like this, with 2,3,5,6-tetrafluoro-4-methoxy benzyl (1R)-anti--3-(1-acrylic)-2,10mL0.05% (w/v) acetone soln of 2-dimethyl cyclopropane carboxylic acid ester (the geometric isomer ratio of 1-acrylic: Z/E=about 8/1), 15g Dalmatian chrysanthemum slag, 15g wood powder, 20gSiam glue and 60mL water mix, fully mediate the gained mixture, with aftershaping and drying (40 ℃, 6 hours).
The test implementation example
The effect of desinsection stacte composition of the present invention will be described by following test implementation example.
10 female northern houses (Culex pipiens pallens) adult is put into 4cm internal diameter and the long glass tube of 12cm.Seal with the nylon wire of 16 sieves at the two ends of pipe.
On the other hand, on the high stainless cylinder of 20cm internal diameter and 80cm, lay the transparent cylinder of the high plastics of a 20cm internal diameter and 30cm.The above-mentioned glass tube of introducing mosquito places in the plastic cylinder, makes the lower end of glass tube and the lower end of plastic cylinder reach substantial same level.Then, the composition to be tested with smooth combustion places stainless cylinder bottom center.
After placing composition to be tested in the stainless cylinder, count the quantity of knocking down mosquito at any time, and knock down 50% mosquito (KT according to result's statistics
50) required time and knock down 90% mosquito (KT
90) required time.
The results are shown in table 1.
Table 1
| Composition | KT 90(minute) | KT 90(minute) |
| Composition 1 of the present invention | 5.2 | 6.2 |
| Comparative composition | 6.8 | 8.9 |
As shown in table 1, composition 1 of the present invention was knocked down 90% mosquito in about 6 minutes.On the other hand, even comparative composition was only knocked down 50% mosquito after about 7 minutes.
Therefore, the excellent effect that it is evident that desinsection stacte compositions display of the present invention.
Claims (5)
1. desinsection stacte composition wherein comprises the compound of formula (1) expression:
Wherein R is a hydrogen atom, methyl, methoxyl group or methoxyl methyl, X and the Y chlorine atom of respectively doing for oneself, methyl or hydrogen atom;
Alkyl benzene calcium sulfonate; Polyoxyalkylene alkyl; With desinsection stacte matrix;
Wherein in composition, described composition comprises formula (1) compound of 0.002 to 0.05 weight %, the polyoxyalkylene alkyl of the alkyl benzene calcium sulfonate of 0.002 to 0.05 weight % and 0.002 to 0.05 weight %.
2. according to the composition of claim 1, wherein further comprise alkylbenzene.
3. according to the composition of claim 2,, comprise the alkylbenzene of 0.03 to 0.8 weight % wherein in composition.
4. according to the composition of claim 1, it is strip.
5. according to the composition of claim 1, it is the coil shape.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003042173A JP4423863B2 (en) | 2003-02-20 | 2003-02-20 | Insecticide |
| JP42173/2003 | 2003-02-20 | ||
| JP42173/03 | 2003-02-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1533694A CN1533694A (en) | 2004-10-06 |
| CN100340168C true CN100340168C (en) | 2007-10-03 |
Family
ID=33025523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100330099A Expired - Lifetime CN100340168C (en) | 2003-02-20 | 2004-02-20 | Pesticiding fragrant composition and ernulsion for preparing the same and preparing process |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP4423863B2 (en) |
| CN (1) | CN100340168C (en) |
| AR (1) | AR043245A1 (en) |
| BR (1) | BRPI0400141B1 (en) |
| MX (1) | MXPA04001492A (en) |
| MY (1) | MY143831A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0715137B8 (en) * | 2006-08-10 | 2021-10-19 | Nippon Soda Co | Agrochemical composition containing an agrochemically active ingredient having a restricted wetting capacity |
| JP5262352B2 (en) | 2008-06-30 | 2013-08-14 | 住友化学株式会社 | Aqueous preparations containing pyrethroid compounds |
| JP5733810B2 (en) * | 2008-09-25 | 2015-06-10 | 大日本除蟲菊株式会社 | Mosquito coil for infectious disease control mosquito control |
| CN101524084B (en) * | 2009-04-30 | 2012-11-07 | 江苏扬农化工股份有限公司 | Muscicide incense and preparation method and application thereof |
| JP5589712B2 (en) * | 2009-10-30 | 2014-09-17 | 住友化学株式会社 | Pest control composition and pest control method |
| UY33443A (en) * | 2010-06-19 | 2012-01-31 | Bayer Animal Health Gmbh | PREPARATION CONTAINING ECTOPARASITICIDE FOR THE FORMATION OF SPONTANEOUS EMULSION |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041863A (en) * | 1989-03-31 | 1990-05-09 | 南开大学 | A kind of chrysanthemum ester class mosquitocide |
| CN1229791A (en) * | 1998-02-26 | 1999-09-29 | 住友化学工业株式会社 | Ester compounds |
| CN1254507A (en) * | 1998-11-20 | 2000-05-31 | 住友化学工业株式会社 | Pyrethroid compound and composition containing said compound for preventing and killing pests |
-
2003
- 2003-02-20 JP JP2003042173A patent/JP4423863B2/en not_active Expired - Lifetime
-
2004
- 2004-02-09 MY MYPI20040380 patent/MY143831A/en unknown
- 2004-02-12 BR BRPI0400141 patent/BRPI0400141B1/en active IP Right Grant
- 2004-02-17 MX MXPA04001492 patent/MXPA04001492A/en active IP Right Grant
- 2004-02-20 AR ARP040100535 patent/AR043245A1/en active IP Right Grant
- 2004-02-20 CN CNB2004100330099A patent/CN100340168C/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041863A (en) * | 1989-03-31 | 1990-05-09 | 南开大学 | A kind of chrysanthemum ester class mosquitocide |
| CN1229791A (en) * | 1998-02-26 | 1999-09-29 | 住友化学工业株式会社 | Ester compounds |
| CN1254507A (en) * | 1998-11-20 | 2000-05-31 | 住友化学工业株式会社 | Pyrethroid compound and composition containing said compound for preventing and killing pests |
Also Published As
| Publication number | Publication date |
|---|---|
| MY143831A (en) | 2011-07-15 |
| AR043245A1 (en) | 2005-07-20 |
| JP4423863B2 (en) | 2010-03-03 |
| BRPI0400141A (en) | 2005-06-28 |
| JP2004250371A (en) | 2004-09-09 |
| CN1533694A (en) | 2004-10-06 |
| BRPI0400141B1 (en) | 2014-03-25 |
| MXPA04001492A (en) | 2004-12-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1669429A (en) | Insect disinfestation composition | |
| CN100340168C (en) | Pesticiding fragrant composition and ernulsion for preparing the same and preparing process | |
| CN1152252A (en) | Fungicidal composition and method of controlling fungus infestation | |
| US10959427B2 (en) | Attractant of ladybugs, aphid's natural enemy | |
| CN110973154A (en) | Composite insecticidal and acaricidal nano water agent containing fenpropathrin and emamectin benzoate and application thereof | |
| CN1870889A (en) | Formulation of a synergistic insecticidal composition as a cyclodextrin-complex | |
| JP2012524819A (en) | Insecticide and its production method and use | |
| CN101617650B (en) | Aqueous pesticidal composition | |
| CN101061798A (en) | Yunnan pine caterpillar sexual attractant core and the method of producing the same | |
| CN101669469A (en) | Sex attractant for isoceras sibirica | |
| CN1833495A (en) | Insect killing line fragrnant | |
| CN1049087C (en) | Solid agrochemical composition | |
| CN1295959C (en) | Sex attractant for moth of hippophae rhamnoides | |
| CN1667064A (en) | Latex paint with insect repelling function and method for preparing same | |
| CN1669419A (en) | Incense stick for insect disinfestation | |
| CN1833506B (en) | Insect killing composition | |
| CN1430888A (en) | Fly-repellent incense and its preparation method | |
| CN101637180A (en) | Insecticidal incense | |
| CN1276712C (en) | Miticide for preventing and killing indoor mite | |
| CN85101418A (en) | Fumigant formulation | |
| CN100409750C (en) | Pesticide compound | |
| CN1669423A (en) | Insecticide acaricide composition containing methylamino avermectin | |
| CN1491559A (en) | Fly expelling line incense | |
| CN1209973C (en) | Oil solution of insecticide Bacillus thuringiensis | |
| CN111328801A (en) | Diatomite-pine moth cytoplasmic polyhedrosis virus wettable powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20071003 |