CL2022003448A1 - Process for recovery of lithium from brine - Google Patents

Process for recovery of lithium from brine

Info

Publication number
CL2022003448A1
CL2022003448A1 CL2022003448A CL2022003448A CL2022003448A1 CL 2022003448 A1 CL2022003448 A1 CL 2022003448A1 CL 2022003448 A CL2022003448 A CL 2022003448A CL 2022003448 A CL2022003448 A CL 2022003448A CL 2022003448 A1 CL2022003448 A1 CL 2022003448A1
Authority
CL
Chile
Prior art keywords
lithium
lithium ion
recovery
brine
ion sieve
Prior art date
Application number
CL2022003448A
Other languages
Spanish (es)
Inventor
Johnstone Brown Craig
Original Assignee
Standard Lithium Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/895,783 external-priority patent/US11583830B2/en
Application filed by Standard Lithium Ltd filed Critical Standard Lithium Ltd
Publication of CL2022003448A1 publication Critical patent/CL2022003448A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/16—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the conditioning of the fluid carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
    • B01D15/361—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/02—Loose filtering material, e.g. loose fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0221—Group 4 or 5 metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/145—Purification by solid ion-exchangers or solid chelating agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/16—Purification by precipitation or adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/12—Addition of chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/18—Details relating to membrane separation process operations and control pH control
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/25—Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2315/00—Details relating to the membrane module operation
    • B01D2315/06—Submerged-type; Immersion type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Abstract

Un proceso para la recuperación de iones de litio de una salmuera que contiene litio que incluye poner en contacto la salmuera que contiene litio con un tamiz de iones de litio (donde ese LIS incluye un óxido de titanio o niobio) en un primer reactor agitado para formar un complejo de iones de litio con el tamiz de iones de litio, y descomplexar el ion de litio del tamiz de iones de litio en un segundo reactor agitado para formar el tamiz de iones de litio y un eluato de sal de litio ácido.A process for the recovery of lithium ions from a lithium-containing brine including contacting the lithium-containing brine with a lithium ion sieve (where that LIS includes an oxide of titanium or niobium) in a first stirred reactor to form a lithium ion complex with the lithium ion sieve, and decomplexing the lithium ion from the lithium ion sieve in a second stirred reactor to form the lithium ion sieve and an el acid lithium salt uate.

CL2022003448A 2020-06-08 2022-12-06 Process for recovery of lithium from brine CL2022003448A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16/895,783 US11583830B2 (en) 2017-12-27 2020-06-08 Process for recovery of lithium from brine

Publications (1)

Publication Number Publication Date
CL2022003448A1 true CL2022003448A1 (en) 2023-06-02

Family

ID=78846864

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2022003448A CL2022003448A1 (en) 2020-06-08 2022-12-06 Process for recovery of lithium from brine

Country Status (10)

Country Link
EP (1) EP4161875A1 (en)
JP (1) JP2023529407A (en)
KR (1) KR20230051148A (en)
CN (1) CN115916701A (en)
AU (1) AU2020452303A1 (en)
BR (1) BR112022025082A2 (en)
CA (1) CA3184777A1 (en)
CL (1) CL2022003448A1 (en)
MX (1) MX2022015540A (en)
WO (1) WO2021248221A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3087356B1 (en) * 2018-10-18 2021-04-23 Geolith INSTALLATION AND PROCEDURE FOR SEPARATING AT LEAST ONE IONIC SPECIES FROM A SOLUTION INCLUDING AT LEAST THE SAID IONIC SPECIES AND LITHIUM
CN115301196B (en) * 2022-04-27 2023-06-16 南京工业大学 Titanium-doped modified manganese-series lithium ion sieve and preparation method thereof
WO2023225245A1 (en) * 2022-05-20 2023-11-23 Schlumberger Technology Corporation Lithium recovery from precipitated solids
CN115069209A (en) * 2022-06-27 2022-09-20 天津科技大学 Titanium-based lithium ion sieve inorganic composite adsorption lithium extraction material and preparation method thereof
KR102656376B1 (en) 2023-08-18 2024-04-11 (주)유에스티21 Monitoring system and method for lithium mine using satellite images

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101047986B1 (en) * 2010-11-26 2011-07-13 한국지질자원연구원 Adsorption and desorption device of litium ion using counter current decantation process and method using the same
CN102774860B (en) * 2012-08-22 2014-07-16 东莞市广华化工有限公司 Method for preparing lithium carbonate by brine
WO2015096549A1 (en) * 2013-12-26 2015-07-02 江苏久吾高科技股份有限公司 Process and apparatus for extracting battery grade lithium from brine
AR105626A1 (en) * 2015-08-06 2017-10-25 Inneovation Pty Ltd SALMUERA LITHIUM EXTRACTION
CN106435220A (en) * 2016-09-06 2017-02-22 南京工业大学 Method for reducing magnesium-lithium ratio of salt lake brine
WO2018089932A1 (en) * 2016-11-14 2018-05-17 Lilac Solutions, Inc. Lithium extraction with coated ion exchange particles
WO2018145141A1 (en) * 2017-02-08 2018-08-16 Inneovation Pty Ltd Combined processing method for lithium containing solutions
WO2019000095A1 (en) * 2017-06-27 2019-01-03 Purlucid Treatment Solutions (Canada) Inc. Method and apparatus for the treatment of water with the recovery of metals
US11534748B2 (en) * 2017-12-27 2022-12-27 Standard Lithium Ltd. Process for recovery of lithium from brine
US10648090B2 (en) * 2018-02-17 2020-05-12 Lilac Solutions, Inc. Integrated system for lithium extraction and conversion
CA3123943A1 (en) * 2018-12-18 2020-06-25 Craig Johnstone Brown Process for recovery of lithium from brine with addition of alkali

Also Published As

Publication number Publication date
KR20230051148A (en) 2023-04-17
CA3184777A1 (en) 2021-12-16
JP2023529407A (en) 2023-07-10
MX2022015540A (en) 2023-01-18
BR112022025082A2 (en) 2022-12-27
AU2020452303A1 (en) 2023-01-05
WO2021248221A1 (en) 2021-12-16
EP4161875A1 (en) 2023-04-12
CN115916701A (en) 2023-04-04

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