CH683185A5 - A water-binding agent. - Google Patents
A water-binding agent. Download PDFInfo
- Publication number
- CH683185A5 CH683185A5 CH2307/91A CH230791A CH683185A5 CH 683185 A5 CH683185 A5 CH 683185A5 CH 2307/91 A CH2307/91 A CH 2307/91A CH 230791 A CH230791 A CH 230791A CH 683185 A5 CH683185 A5 CH 683185A5
- Authority
- CH
- Switzerland
- Prior art keywords
- oil
- resin
- vegetable
- binder according
- milk casein
- Prior art date
Links
- 239000011230 binding agent Substances 0.000 title claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 7
- 239000011347 resin Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 24
- 239000003921 oil Substances 0.000 claims description 14
- 235000019198 oils Nutrition 0.000 claims description 12
- 235000013311 vegetables Nutrition 0.000 claims description 11
- 239000005018 casein Substances 0.000 claims description 10
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 10
- 235000021240 caseins Nutrition 0.000 claims description 10
- 235000013336 milk Nutrition 0.000 claims description 10
- 239000008267 milk Substances 0.000 claims description 10
- 210000004080 milk Anatomy 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 235000021388 linseed oil Nutrition 0.000 claims description 4
- 239000000944 linseed oil Substances 0.000 claims description 4
- 240000000972 Agathis dammara Species 0.000 claims description 3
- 229920002871 Dammar gum Polymers 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 239000007884 disintegrant Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000004854 plant resin Substances 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 239000008399 tap water Substances 0.000 claims 1
- 235000020679 tap water Nutrition 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005445 natural material Substances 0.000 description 2
- 241001127819 Commiphora gileadensis Species 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/30—Proteins; Protein hydrolysates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
- C08L89/005—Casein
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
Description
5 5
10 10th
15 15
20 20th
25 25th
30 30th
35 35
40 40
45 45
50 50
55 55
60 60
CH 683 185 A5 CH 683 185 A5
Beschreibung description
Die Erfindung betrifft ein wasserverdiinnbares Bindemittel, bestehend aus einer flüssigen Komponente pflanzlichen Ursprungs, z.B. einem Pflanzenöl, homogen vermischt mit einem festen Harz, insbesondere zur Venwendung bei Farben, Lacken, Klebern und dgl. The invention relates to a water-thinnable binder consisting of a liquid component of vegetable origin, e.g. a vegetable oil, homogeneously mixed with a solid resin, especially for use in paints, varnishes, adhesives and the like.
Für die Herstellung derartiger Bindemittel müssen feste Harze, die den Grundbestandteil dieser Bindemittel darstellen, in der Weise gelöst werden, dass das entstehende Bindemittel wasserverdünnbar wird. For the production of such binders, solid resins, which are the basic constituent of these binders, must be dissolved in such a way that the resulting binder becomes water-dilutable.
Es ist bekannt, dass feste Harze in Lösemitteln wie z.B. Balsamterpentinöl oder Testbenzin und dgl. gelöst werden können oder über aufwendige chemische Verfahren so aufbereitet werden, bis die Harze in Wasser in Lösung gehen. It is known that solid resins in solvents such as e.g. Balsam turpentine or white spirit and the like can be dissolved or processed using complex chemical processes until the resins dissolve in water.
Nachteilig an Bindemitteln, die auf diese Weise hergestellt werden, ist, dass bei der Verwendung von Farben, Lacken oder Klebstoffen, die diese Bindemitteln aufweisen, gesundheits- oder umweltschädliche oder störende Emmissionen bzw. Gerüche freigesetzt werden können, bzw. auf synthetische Produkte als Lösevermittler zurückgegriffen werden muss. Weiterhin ist es von Nachteil, dass bei der Beseitigung von Gegenständen, welche mit derartigen Farben, Lacken oder Klebstoffen beschichtet sind, eine hohe Umweltbelastung auftritt, die durch die für das Bindemittel verwendeten umweltschädlichen Lösungsmittel bedingt ist. A disadvantage of binders which are produced in this way is that when paints, varnishes or adhesives containing these binders are used, emissions or smells which are harmful to health or the environment or are disruptive, or synthetic products as solubilizers must be used. It is also disadvantageous that when objects which are coated with such paints, varnishes or adhesives are removed, there is a high environmental impact which is caused by the environmentally harmful solvents used for the binder.
Aufgabe der Erfindung ist es nun, ein wasserverdünnbares Bindemittel für die Herstellung von Farben, Lacken oder Klebstoffen zu schaffen, das keine schädlichen oder störenden Emmissionen freisetzt, umweltfreundlich entsorgt und mit geringem Aufwand hergestellt werden kann. The object of the invention is now to provide a water-dilutable binder for the production of paints, varnishes or adhesives which does not release any harmful or disruptive emissions, can be disposed of in an environmentally friendly manner and can be produced with little effort.
Erfindungsgemäss wird diese Aufgabe dadurch gelöst, dass als festes Harz ein Pflanzenharz oder ein verkochtes Pflanzenharz oder Pflanzenöl oder die Seife aus einem Pflanzenharz oder Pflanzenöl mit Alkali- oder Erdalkaliionen vorliegt. According to the invention, this object is achieved in that a vegetable resin or a boiled vegetable resin or vegetable oil or the soap from a vegetable resin or vegetable oil with alkali or alkaline earth metal ions is present as the solid resin.
Auf diese Weise können die bisher üblichen gesundheits- und umweltschädlichen Lösemittel durch die unschädliche, aus natürlichen Stoffen bestehende Milchkasein-Lösung ersetzt werden. Die eigen-schaften von Farben, Lacken und Klebstoffen werden durch die Verwendung des erfindungsgemässen Bindemittels nicht nachteilig beeinfllusst. In this way, the hitherto common solvents that are harmful to health and the environment can be replaced by the innocuous milk casein solution made from natural substances. The properties of paints, varnishes and adhesives are not adversely affected by the use of the binder according to the invention.
Durch die Venwendung dieser natürlichen Stoffe ergibt sich eine besondere gute Umwelt- und Gesundheitsverträglichkeit. The use of these natural substances results in a particularly good environmental and health compatibility.
Bei einem bevorzugten Verfahren zur Herstellung eines erfindungsgemässen Bindemittels wird das Harz mit dem Öl zuerst homogen vermischt und anschliessend die als Emulgator wirkende, die Trennung von Harz, Öl und Wasser verhindernde Milchkasein-Lösung zugegeben. Die Vermischung von Harz und Öl erfolgt entweder durch Schmelzen und anschliessendem Vermischen des erhitzten Harzes mit dem Öl oder durch die Dispergierung des Harzes in Öl mittels Dissolvers oder eines Rührwerks. In a preferred method for producing a binder according to the invention, the resin is first homogeneously mixed with the oil and then the milk casein solution, which acts as an emulsifier and prevents the separation of resin, oil and water, is added. The resin and oil are mixed either by melting and then mixing the heated resin with the oil, or by dispersing the resin in oil using a dissolver or a stirrer.
Im folgenden ist ein konkretes Beispiel für ein erfindungsgemäss realisiertes Bindemittel angegeben: A specific example of a binder realized according to the invention is given below:
Als ein in festen Stücken vorliegendes Pflanzenharz wird z.B. Dammar zu gleichen Teilen, also 1:1, mittels Dissolver in einer flüssigen pflanzlichen Komponente z.B. Leinöl so lange gemischt, bis eine flüssige, homogene Mischung entsteht. As a vegetable resin present in solid pieces, e.g. Dammar in equal parts, i.e. 1: 1, using a dissolver in a liquid vegetable component e.g. Linseed oil mixed until a liquid, homogeneous mixture is created.
In dieser Mischung wird eine der Harz-Öl-Lösung entsprechende Menge Milchkasein-Lösung eingerührt, bis die Harz-Öl-Mischung vollständig emulgiert ist. Die Milchkasein-Lösung besteht aus Milchkasein, Borsäure und einem alkalischen Aufschlussmittel, z.B. Borax, im Verhältnis 2:1:1, sowie Wasser zur Verdünnung. A quantity of milk casein solution corresponding to the resin-oil solution is stirred into this mixture until the resin-oil mixture is completely emulsified. The milk casein solution consists of milk casein, boric acid and an alkaline disintegrant, e.g. Borax, in a ratio of 2: 1: 1, and water for dilution.
Aus der Beschreibung des Verfahrens können sich folgende Gewichtsprozente für 100% einer was-serverdünnbaren Harzemulsion ergeben: From the description of the method, the following weight percentages for 100% of a resin emulsion that can be thinned with water can result:
z.B. e.g.
Dammar 20 + Leinöl 20 Dammar 20 + linseed oil 20
= 40 = 40
Teile Parts
Milchkasein 2 + Borax 1 + Borsäure 1 + Wasser 36 Milk casein 2 + borax 1 + boric acid 1 + water 36
= 40 = 40
Teile Parts
+ zur Verdünnung Wasser 20 + for dilution water 20
= 20 = 20
Teile Parts
= 1ÖÖ = 1ÖÖ
Teile Parts
Die Anteile sind variationsfähig und abhängig von den Produkteigenschaften. The proportions are variable and depend on the product properties.
Claims (9)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4024925A DE4024925A1 (en) | 1990-08-06 | 1990-08-06 | Binder of vegetable oil and resin emulsified with milk casein soln. - for use in paint, lacquer, adhesive etc. which is environmentally friendly |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH683185A5 true CH683185A5 (en) | 1994-01-31 |
Family
ID=6411735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH2307/91A CH683185A5 (en) | 1990-08-06 | 1991-08-02 | A water-binding agent. |
Country Status (3)
| Country | Link |
|---|---|
| AT (1) | ATA155491A (en) |
| CH (1) | CH683185A5 (en) |
| DE (1) | DE4024925A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4338110A1 (en) * | 1993-11-08 | 1995-05-11 | Auro Pflanzenchemie Gmbh | Water-thinnable, glazing or covering paint |
| ITBO950462A1 (en) * | 1995-09-29 | 1997-03-29 | Bernacchia Ida | PAINTING AND ITS USE |
| US6706107B2 (en) | 2001-04-05 | 2004-03-16 | Whitney A. Walker | Paints and methods of making same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1168000B (en) * | 1964-04-16 | Hans Pichlmayr Dr Ing | Process for the production of shellac preparations which are soluble in cold water | |
| DE571299C (en) * | 1928-02-18 | 1933-02-27 | Bruno Wieger Dr | Process for the preparation of resin dispersions |
| DE849463C (en) * | 1950-04-23 | 1952-09-15 | Ernst Kalkhof Fa | Process for the production of shellac products which are colloidally soluble in water |
| CA1107910A (en) * | 1977-04-25 | 1981-09-01 | Richard W. Greiner | Aqueous fortified rosin dispersions |
| AT362848B (en) * | 1979-02-13 | 1981-06-25 | Janke Uwe | CASEIN COLOR AND METHOD FOR THE PRODUCTION THEREOF |
-
1990
- 1990-08-06 DE DE4024925A patent/DE4024925A1/en not_active Withdrawn
-
1991
- 1991-08-02 CH CH2307/91A patent/CH683185A5/en not_active IP Right Cessation
- 1991-08-05 AT AT0155491A patent/ATA155491A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE4024925A1 (en) | 1992-02-13 |
| ATA155491A (en) | 2000-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3046214C2 (en) | ||
| AT394676B (en) | WOOD PROTECTIVE PAINT, PREFERABLY WOOD PROTECTIVE PAINT | |
| DE2613494A1 (en) | BINDERS FOR VARNISHES AND PAINTS | |
| CH683185A5 (en) | A water-binding agent. | |
| DE4200678C2 (en) | Mixing component in the production of colorants and paints with egg components | |
| EP0037996B1 (en) | Process for the manufacture of amine oxides, and their use as surface active agents | |
| DE2201496A1 (en) | Metal fastener, process for its manufacture and coating compound for it | |
| DE2304663C3 (en) | Terpolymers based on vinyl chloride and processes for their preparation | |
| EP0037055B1 (en) | Hydrophobic agent for flat cellulosic substrate, process for its manufacture and its use | |
| EP0652270A2 (en) | Water dilutable, translucent or opaque coating compostion | |
| DE748379C (en) | Emulsifying agents | |
| DE2517112A1 (en) | TOPPING COMPOSITIONS | |
| DE3938063A1 (en) | AQUEOUS POLYMER DISPERSIONS, A METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR THE PRODUCTION OF COATING AGENTS | |
| DE1920972A1 (en) | Hardenable coating compositions based on mixtures of acidic polyesters and epoxy compounds | |
| AT220746B (en) | Process for the manufacture of a self-emulsifying nitrocellulose product | |
| DE747419C (en) | Process for the production of paint binders | |
| DE4332832A1 (en) | Coating material and process for its preparation | |
| DE139582C (en) | ||
| DE1222671B (en) | Process for the preparation of dispersions from hydrocarbon resins | |
| DE319199C (en) | Coating compound for ship floors u. like | |
| DE907564C (en) | Color pastes | |
| DE801737C (en) | Paints with drying binders | |
| DE143777C (en) | ||
| DE751603C (en) | Process for the production of polyvinyl ethers | |
| DE812572C (en) | Process for the production of emulsion binders |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |