CH493342A - Coating chemical appts. - with impregnated graphite or carbon belts/fabrics - Google Patents
Coating chemical appts. - with impregnated graphite or carbon belts/fabricsInfo
- Publication number
- CH493342A CH493342A CH1663367A CH1663367A CH493342A CH 493342 A CH493342 A CH 493342A CH 1663367 A CH1663367 A CH 1663367A CH 1663367 A CH1663367 A CH 1663367A CH 493342 A CH493342 A CH 493342A
- Authority
- CH
- Switzerland
- Prior art keywords
- dependent
- coated
- iii
- carbon
- chemical
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000000126 substance Substances 0.000 title claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 15
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 14
- 239000010439 graphite Substances 0.000 title claims abstract description 14
- 239000004744 fabric Substances 0.000 title claims abstract description 9
- 239000011248 coating agent Substances 0.000 title claims abstract description 7
- 238000000576 coating method Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 28
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 20
- 239000000057 synthetic resin Substances 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims 18
- 239000003245 coal Substances 0.000 claims 1
- 238000011417 postcuring Methods 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001913 cellulose Substances 0.000 abstract description 2
- 229920002239 polyacrylonitrile Polymers 0.000 abstract description 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/14—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/0017—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor characterised by the choice of the material
- B29C63/0021—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor characterised by the choice of the material with coherent impregnated reinforcing layers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/16—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from products of vegetable origin or derivatives thereof, e.g. from cellulose acetate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
- B01J2219/0227—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0809—Fabrics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0854—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2707/00—Use of elements other than metals for preformed parts, e.g. for inserts
- B29K2707/04—Carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Method for coating chemical apparatus utilises synthetic resin-impregnated flat articles, esp. felts or fabrics, composed of carbon or graphite. The flat article is placed on the surface of the chemical apparatus, and cured, either at normal temp. or elevated temp. The flat article can have reactive groups capable of reacting with the synthetic resin during curing. The coated chemical apparatus has good resistance to chemicals and high temps., and the coating is dense and firmly bonded. The carbon or graphite felts/fabrics are formed by carbonising felts/fabrics composed of wool, cellulose, polyamide or polyacrylonitrile fibres. The resin can be an epoxy, phenolic, furane, polyester or polyurethane resin.
Description
Verfahren zur Beschichtung von chemischen Apparaten und Apparateteilen mit kunstharz imprägnierten, aus Kohlenstoff- bzw. Graphitfasern bestehenden Flächengebilden
Aus dem Patent Nr. 475104 ist ein Verfahren zur Beschichtung von chemischen Apparaten und Apparateteilen mit kunstharzimprägnierten, aus Kohlenstoff- bzw.
Graphitfasern bestehenden Flächengebilden bekannt, welches dadurch gekennzeichnet ist, dass man das Flächengebilde zuschneidet, mit einem langsam kalthärtenden Kunstharz blasenfrei imprägniert, die so imprägnierte Folie auf die vorbereitete Oberfläche des Apparates bzw. Apparateteils aufbringt, bei Normaltemperatur erhärten lässt, die Stossfugen mit einem Kunstharz nachverfugt und bei höherer Temperatur nachhärtet.
Als Flächengebilde kommen z. B. Kohlenstoff- bzw.
Graphit-Filz oder -Gewebe in Frage. Es ist möglich, die Oberfläche eines Apparates bzw. Apparateteils aus Eisen durch Sandstrahlen und Vorgrundieren vorzubereiten. Die imprägnierte Folie kann, z. B. mit einer Gummirolle, auf die zu beschichtende Oberfläche aufgerollt werden. Man kann z. B. im Ofen, vorzugsweise im Druckofen, oder auch durch Anheizen des beschichteten Teils in einer schwach sauren Flüssigkeit nachhärten.
Das Verfahren eignet sich auch zur Reparatur von Reaktionsgefässen, die mit Graphit oder Hartbrandkohle ausgekleidet sind.
Es hat sich nun gezeigt, dass man bei diesem Verfahren auch heisshärtende Kunstharze verwenden kann und/oder auf das Nachverfugen verzichten kann.
Ausserdem wurde gefunden, dass die freien Valenzen von in geeigneter Weise hergestellten, z. B. beim Abkühlen nach dem Verkohlen in eine feuchte sauerstoffhaltige Atmosphäre eingebrachten Flächengebilden aus Kohlenstoff-Fasern offenbar mit den funktionellen Gruppen von gewissen Kunstharzen beim Härten zu reagieren vermögen. Das Produkt, nämlich kunstharzimprägniertes Kohlenstoff-Fasermaterial, zeigt im Vergleich zum entsprechenden Kunstharz allein eine erhöhte chemische und thermische Beständigkeit.
Es ist bekannt, dass elementarer mikrokistalliner Kohlenstoff auf der Oberfläche des kovalent verknüpften Atomverbandes freie Valenzen aufweist, die, z. B.
durch Sauerstoff, abgesättigt werden können. Es ist auch bekannt, dass die Oberfläche von mikrokirstallinem Kohlenstoff im allgemeinen saure sauerstoffhaltige Gruppen, z. B. Carboxylgruppen oder phenolische Hydroxylgruppen, trägt, welche je nach ihrer Stellung unterschiedliche Acidität zeigen.
Man kann nun annehmen, dass bei in geeigneter Weise gewählten Imprägnierharzen bei der Härtung eine Verknüpfung zwischen derartigen Gruppen und den funktionellen Gruppen des Kunstharzes zustande kommt; so können z. B. phenolische Hydroxylgruppen mit den entsprechenden Gruppen eines Phenol-Formaldehydharzes in Gegenwart von Protonen reagieren.
Dass in der Tat eine Umsetzung eintritt, zeigt folgender Versuch: Behandelt man einerseits das Kunstharz, z. B. ein Phenol-Formaldehydharz, für sich (Probe A), anderseits ein mit dem Kunstharz imprägniertes Flächengebilde der oben definierten Art (Probe B) und schliesslich ein Gemisch aus Glasfasern und dem Kunstharz (Probe C) nach dem Härten mit einem Mittel, welches das Harz löst oder abbaut, z. B. heisse Lauge, so löst sich Probe A ohne weiteres; aus Probe C wird das Kunstharz langsamer gelöst; Probe B aber wird nach Entfernung des nicht gebundenen Anteils des Harzes gewichtskonstant, d. h. das gebundene Harz hat eine andere Löslichkeit als das Harz für sich allein.
Das Verfahren gemäss der Erfindung zur Beschichtung von chemischen Apparaten und Apparateteilen ist dadurch gekennzeichnet, dass man mit Kunstharz imprägnierte, aus Kohlenstoff- bzw. Graphitfasern bestehende Flächngebilde auf die Oberfläche des Apparates bzw. Apparateteils aufbringt und härtet.
Vorzugsweise verwendet man ein Flächengebilde, das reaktionsfähige Gruppen enthält, die mit dem verwendeten Kunstharz bei der Härtung zu reagieren vermögen. Wenn man kalthärtende Kunstharze verwendet, kann man bei Normaltemperatur erhärten lassen und gegebenenfalls bei höherer Temperatur nachhärten, wäh rend bei Verwendung heisshärtender Kunstharze bei er höhter Temperatur gehärtet werden muss. Die Härtung bzw. Nachhärtung bei erhöhter Temperatur kann z. B.
im Ofen, vorzugsweise im Druckofen, oder durch Anheizen des beschichteten Teils erfolgen.
Die auf diese Weise erhaltenen beschichteten Apparate oder Apparateteile sind mit einem aus Kohlenstoffbzw. Graphitfasern bestehenden Flächengebilde, insbesondere einem Kohlenstoff- bzw. Graphit-Filz oder -Gewebe, beschichtet, wobei das Flächengebilde gehärtetes Kunstharz enthält, das vorzugsweise chemisch an das Flächengebilde gebunden ist.
Als aus Kohlenstoff- bzw. Graphitfasern bestehende Flächengebilde kommen solche in Frage, die durch Verkohlen bzw. Graphitieren von tierischen Fasern, z. B.
Wolle, pflanzlichen Fasern, z. B. Cellulose, oder Kunstfasern, z. B. Superpolyamide oder Polyacrylnitril, hergestellt sind, oder Pyrokohlenstoff-Fasem, die z. B.
durch Pyrolyse von Kohlenwasserstoffen erhältlich sind.
Derartige Flächengebilde werden z. B. von der Firma SIGRI Elektrographit GmbH, Meitingen bei Augsburg (Deutschland), hergestellt.
Als Kunstharze eignen sich z. B. unmodifizierte oder modifizierte Epoxydharze, unmodifizierte oder modifizierte Phenolharze, unmodifizierte oder modifizierte Furanharze, Polyester und Polyurethane.
Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers
Patent No. 475104 describes a process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated carbon or
Graphite fibers are known, which is characterized by the fact that the sheet is cut to size, impregnated with a slowly cold-curing synthetic resin without bubbles, the film impregnated in this way is applied to the prepared surface of the apparatus or part of the apparatus, allowed to harden at normal temperature, the butt joints are grouted with a synthetic resin and post-cures at a higher temperature.
As fabrics come z. B. carbon or
Graphite felt or fabric in question. It is possible to prepare the surface of a device or device part made of iron by sandblasting and pre-priming. The impregnated film can, for. B. with a rubber roller, rolled onto the surface to be coated. You can z. B. post-cure in an oven, preferably in a pressure oven, or by heating the coated part in a weakly acidic liquid.
The process is also suitable for repairing reaction vessels lined with graphite or hard charcoal.
It has now been shown that hot-curing synthetic resins can also be used in this process and / or post-grouting can be dispensed with.
It has also been found that the free valences of suitably prepared, e.g. B. when cooling after charring in a moist oxygen-containing atmosphere introduced flat structures made of carbon fibers are apparently able to react with the functional groups of certain synthetic resins during curing. The product, namely synthetic resin-impregnated carbon fiber material, shows increased chemical and thermal resistance compared to the corresponding synthetic resin alone.
It is known that elementary micro-crystalline carbon on the surface of the covalently linked atomic lattice has free valences which, for. B.
can be saturated by oxygen. It is also known that the surface of microcrystalline carbon generally contains acidic oxygen-containing groups, e.g. B. carboxyl groups or phenolic hydroxyl groups, which show different acidity depending on their position.
It can now be assumed that when impregnating resins are suitably selected, a link between such groups and the functional groups of the synthetic resin occurs during curing; so can z. B. phenolic hydroxyl groups react with the corresponding groups of a phenol-formaldehyde resin in the presence of protons.
The following experiment shows that there is indeed a conversion: If one treats the synthetic resin, e.g. B. a phenol-formaldehyde resin, for itself (sample A), on the other hand a sheet of the type defined above impregnated with the synthetic resin (sample B) and finally a mixture of glass fibers and the synthetic resin (sample C) after curing with an agent which the resin dissolves or degrades, e.g. B. hot lye, sample A dissolves easily; from sample C the resin dissolves more slowly; Sample B, however, becomes constant in weight after removing the unbound portion of the resin, i.e. H. the bound resin has a different solubility than the resin on its own.
The method according to the invention for coating chemical apparatus and apparatus parts is characterized in that sheet-like structures consisting of carbon or graphite fibers and impregnated with synthetic resin are applied to the surface of the apparatus or apparatus part and cured.
A flat structure is preferably used which contains reactive groups which are able to react with the synthetic resin used during curing. If you use cold-curing synthetic resins, you can harden at normal temperature and, if necessary, post-cure at a higher temperature, while when using hot-curing synthetic resins it must be cured at a higher temperature. The hardening or post-hardening at elevated temperature can, for. B.
in an oven, preferably in a pressure oven, or by heating the coated part.
The coated apparatuses or apparatus parts obtained in this way are coated with a carbon or Flat structure consisting of graphite fibers, in particular a carbon or graphite felt or fabric, coated, the flat structure containing hardened synthetic resin which is preferably chemically bonded to the flat structure.
As sheet-like structures made of carbon or graphite fibers, those that are produced by charring or graphitizing animal fibers, e.g. B.
Wool, vegetable fibers, e.g. B. cellulose, or synthetic fibers, e.g. B. superpolyamides or polyacrylonitrile, or pyrocarbon fibers, which z. B.
can be obtained by pyrolysis of hydrocarbons.
Such fabrics are z. B. by the company SIGRI Elektrographit GmbH, Meitingen near Augsburg (Germany).
Suitable synthetic resins are, for. B. unmodified or modified epoxy resins, unmodified or modified phenolic resins, unmodified or modified furan resins, polyesters and polyurethanes.
Claims (1)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH856867A CH475104A (en) | 1967-06-16 | 1967-06-16 | Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers. |
FR115880A FR1545665A (en) | 1967-06-16 | 1967-07-27 | Process for coating apparatus and parts of chemical apparatus with a coating material consisting of carbon or graphite fibers impregnated with synthetic resin |
CH1663367A CH493342A (en) | 1967-06-16 | 1967-11-27 | Coating chemical appts. - with impregnated graphite or carbon belts/fabrics |
DE1771579A DE1771579C3 (en) | 1967-06-16 | 1968-06-11 | Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers |
NL6808453A NL6808453A (en) | 1967-06-16 | 1968-06-14 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH856867A CH475104A (en) | 1967-06-16 | 1967-06-16 | Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers. |
CH1663367A CH493342A (en) | 1967-06-16 | 1967-11-27 | Coating chemical appts. - with impregnated graphite or carbon belts/fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
CH493342A true CH493342A (en) | 1970-07-15 |
Family
ID=25703483
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH856867A CH475104A (en) | 1967-06-16 | 1967-06-16 | Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers. |
CH1663367A CH493342A (en) | 1967-06-16 | 1967-11-27 | Coating chemical appts. - with impregnated graphite or carbon belts/fabrics |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH856867A CH475104A (en) | 1967-06-16 | 1967-06-16 | Process for coating chemical apparatus and apparatus parts with synthetic resin-impregnated flat structures made of carbon or graphite fibers. |
Country Status (3)
Country | Link |
---|---|
CH (2) | CH475104A (en) |
DE (1) | DE1771579C3 (en) |
NL (1) | NL6808453A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2212788A1 (en) * | 1971-03-19 | 1972-09-28 | Commissariat Energie Atomique | Process for the manufacture of synthetic resin-carbon fiber composite materials |
-
1967
- 1967-06-16 CH CH856867A patent/CH475104A/en not_active IP Right Cessation
- 1967-11-27 CH CH1663367A patent/CH493342A/en not_active IP Right Cessation
-
1968
- 1968-06-11 DE DE1771579A patent/DE1771579C3/en not_active Expired
- 1968-06-14 NL NL6808453A patent/NL6808453A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2212788A1 (en) * | 1971-03-19 | 1972-09-28 | Commissariat Energie Atomique | Process for the manufacture of synthetic resin-carbon fiber composite materials |
Also Published As
Publication number | Publication date |
---|---|
DE1771579B2 (en) | 1974-07-18 |
CH475104A (en) | 1969-07-15 |
DE1771579A1 (en) | 1972-03-09 |
NL6808453A (en) | 1968-12-17 |
DE1771579C3 (en) | 1975-03-06 |
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Legal Events
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PL | Patent ceased |