CH455753A - Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis - Google Patents

Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis

Info

Publication number
CH455753A
CH455753A CH1135463A CH1135463A CH455753A CH 455753 A CH455753 A CH 455753A CH 1135463 A CH1135463 A CH 1135463A CH 1135463 A CH1135463 A CH 1135463A CH 455753 A CH455753 A CH 455753A
Authority
CH
Switzerland
Prior art keywords
monooxymethyl
cyclic
compounds
preparation
ester
Prior art date
Application number
CH1135463A
Other languages
German (de)
Inventor
Clau Dr Ing Chem Berther
Sailer Richard
Original Assignee
Inventa Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inventa Ag filed Critical Inventa Ag
Priority to CH1135463A priority Critical patent/CH455753A/en
Priority to DK351964AA priority patent/DK104886C/en
Priority to FR984873A priority patent/FR1404182A/en
Priority to BE652299D priority patent/BE652299A/xx
Priority to GB35954/64A priority patent/GB1070246A/en
Priority to NL6410310A priority patent/NL6410310A/
Priority to ES303990A priority patent/ES303990A1/en
Publication of CH455753A publication Critical patent/CH455753A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Hydroxymethylcycloalkanes are prepared by heating a cycloalkene with carbon monoxide and hydrogen under pressure in the presence of a cobalt compound using an alcohol or ester as solvent, e.g. ethanol, butanol, or an ethyl or butyl ester. Preferably the cycloakane has from 5 to 12 carbon atoms in the ring and the action is carried out at a temperature of between 125-170 DEG C., and at a gauge pressure of between 50 and 300 atmospheres. The cobalt compound may be dissolved in the alcohol ester and heated under pressure with carbon monoxide and hydrogen before the cycloalkene is introduced. Examples show the production of hydroxy-methycyclo-pentane, -hexane, -octane, -do-decane from the corresponding cycloalkenes.
CH1135463A 1963-09-13 1963-09-13 Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis CH455753A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CH1135463A CH455753A (en) 1963-09-13 1963-09-13 Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis
DK351964AA DK104886C (en) 1963-09-13 1964-07-15 Process for the preparation of saturated cyclic monohydroxymethyl compounds by oxosynthesis.
FR984873A FR1404182A (en) 1963-09-13 1964-08-11 Process for obtaining cyclic monooxymethyl compounds by oxo-synthesis
BE652299D BE652299A (en) 1963-09-13 1964-08-26
GB35954/64A GB1070246A (en) 1963-09-13 1964-09-02 Process for the production of cycloalkane derivatives
NL6410310A NL6410310A (en) 1963-09-13 1964-09-04
ES303990A ES303990A1 (en) 1963-09-13 1964-09-12 Procedure for the preparation of monooximethical compounds cyclic (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1135463A CH455753A (en) 1963-09-13 1963-09-13 Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis

Publications (1)

Publication Number Publication Date
CH455753A true CH455753A (en) 1968-05-15

Family

ID=4372676

Family Applications (1)

Application Number Title Priority Date Filing Date
CH1135463A CH455753A (en) 1963-09-13 1963-09-13 Process for the preparation of cyclic monooxymethyl compounds by oxo synthesis

Country Status (6)

Country Link
BE (1) BE652299A (en)
CH (1) CH455753A (en)
DK (1) DK104886C (en)
ES (1) ES303990A1 (en)
GB (1) GB1070246A (en)
NL (1) NL6410310A (en)

Also Published As

Publication number Publication date
ES303990A1 (en) 1964-11-01
BE652299A (en) 1964-12-16
GB1070246A (en) 1967-06-01
NL6410310A (en) 1965-03-15
DK104886C (en) 1966-07-18

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