CH272269A - Process for obtaining a smooth friction surface on a metal support. - Google Patents

Process for obtaining a smooth friction surface on a metal support.

Info

Publication number
CH272269A
CH272269A CH272269DA CH272269A CH 272269 A CH272269 A CH 272269A CH 272269D A CH272269D A CH 272269DA CH 272269 A CH272269 A CH 272269A
Authority
CH
Switzerland
Prior art keywords
intermediate layer
support
spraying
heating
metal
Prior art date
Application number
Other languages
French (fr)
Inventor
Edras Societe Anonyme
Original Assignee
Edras Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Edras Sa filed Critical Edras Sa
Publication of CH272269A publication Critical patent/CH272269A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Coating By Spraying Or Casting (AREA)

Description

  

  Procédé pour l'obtention d'une surface de frottement lisse sur un support métallique.    La présente invention concerne l'obtention,  sur un support métallique, d'une surface de  frottement lisse et, plus particulièrement,  l'obtention de couches     clé    métal antifriction  sur des     coussinets    et autres pièces analogues.  



  On a déjà proposé, pour obtenir une telle  couche, de déposer sur le support à     reeouvrii-,     le métal. on alliage destiné à former cette  couche, par le procédé dit  de métallisation >,  c'est-à-dire en projetant, notamment à l'aide       du    dispositif connu sous le     soin    de pistolet  métalliseur, au moyen d'un jet de gaz sous       pression,    une dispersion de fines gouttelettes  dudit     métal    ou alliage à l'état. fondu.  



  Or, il arrive que, lorsqu'on     cherelie    à re  couvrir un support d'une couche de métal, par  le procédé susmentionné, on éprouve de sé  rieuses difficultés à faire adhérer sur ledit  support le métal ou l'alliage pulvérisé. C'est  notamment le cas lorsque le support est cons  titué par un bloc d'acier que l'on désire     reeou-          vrir    d'une mince couche d'un     alliage    de  bronze au plomb.  



  La présente invention a pour objet un  procédé qui permet     d'assurer    une adhérence  parfaite de la     couche    projetée sur le support  à recouvrir. Ce. procédé est caractérisé en ce  que, préalablement à la formation, par pro  jection, de la couche de     revëteinent    désirée,  l'on recouvre le support d'une couche inter  médiaire d'au moins un métal susceptible  d'adhérer aussi bien audit support qu'à la<B>,</B>  couche (le revêtement définitive, et en ce que,    après avoir projeté cette dernière, on soumet  l'ensemble à un traitement par chauffage à  haute température dans un milieu susceptible  de protéger la     couelie    projetée contre l'oxy  dation.  



  La couche métallique intermédiaire peut  avantageusement être obtenue     elle-même    par .  pulvérisation (le son ou ses constituants sur le  support à recouvrir. Elle     petit    également, être  formée par     trempage    on autre procédé ana  logue. Cette couche peut, dans le cas d'un.  revêtement au bronze au     plomb,    par     exemple,     être constituée par du cuivre ou par un  bronze à l'étain. On peut également, utiliser  du zinc ou (le l'étain.

   Pour augmenter     encore     l'adhérence des couches de revêtement, la sur  face du support peut être amenée à un état  propice préalable, par exemple par     gratte-          bossage,        parkerisation    ou sablage     ait    sable fin  ou à la grenaille d'acier.  



  Le traitement     tbermique    est réalisé par       eliauffage        ï),    une température de préférence  supérieure à 700" C, par exemple dans une  atmosphère réductrice, ou dans un milieu dès  oxydant, tel que     l'ttnbydi icle    borique. On.     petit,     par exemple, chauffer pendant quelques mi  nutes le support recouvert, puis le refroidir       immédiatement        après    à la température ordi  naire, notamment par trempe à,     l'eau.    froide       pure    ou additionnée d'un     antioxy    gène qui sera  de préférence un réducteur.  



  On peut     également    chauffer ledit     support     pendant quelques heures, le chauffage étant           suivi    d'un refroidissement lent en atmosphère  réductrice jusqu'à la température ordinaire.  



  Il se peut, que, malgré la disposition d'une  couche intermédiaire, et après le traitement       thermique,,    la; couche déposée- présente des  irrégularités quant à sa compacité. Cette der  nière peut alors être égalisée et augmentée par  compression à l'aide d'outils appropriés, à  froid, ou tout au moins à une température  inférieure à celle de fusion du métal ou alliage  d'apport, et sous une pression pouvant aller       jusqu'à    300 kg par     cmd.     



  A titre d'exemple, pour garnir un coussi  net en acier doux avec un revêtement antifric  tion     constitué    par un alliage de cuivre et de  plomb, on projette tout d'abord, à l'aide d'un  pistolet     métallisateur,    sur la surface de tra  vail du coussinet préalablement sablée, une       couche        de        bronze    à     l'étain    à 6     %        d'étain,        d'une     épaisseur comprise entre     1/10o    et     1/1o    de mm.

    On projette ensuite, sur la couche intermé  diaire ainsi obtenue, une couche d'environ  de mm d'un     alliage    de     cuivre    et de plomb à       30        %        de        plomb.        Cette        projection        est        égale-          ment    opérée à l'aide d'un pistolet     métallisa-          teur    alimenté à l'aide d'un fil     compound    com  portant une enveloppe de     cuivre    et une âme  en plomb,

   le rapport des sections de l'enve  loppe et de l'âme étant le même que celui dé  siré pour le cuivre et le plomb dans l'alliage  antifriction. Après dépôt de la couche finale,  l'ensemble est porté à une température supé  rieure à 700  C, dans     une    atmosphère réduc  trice pendant quelques minutes, puis trempé  à l'eau froide. Enfin, le revêtement antifric  tion est soumis à une pression comprise entre  200 et 300 kg par     cm2.     



  On obtient ainsi, sur le coussinet, un revê  tement parfaitement adhérent et homogène.



  Process for obtaining a smooth friction surface on a metal support. The present invention relates to obtaining, on a metal support, a smooth friction surface and, more particularly, obtaining key metal anti-friction layers on bearings and other similar parts.



  It has already been proposed, in order to obtain such a layer, to deposit the metal on the support to be re-worked. an alloy intended to form this layer, by the so-called metallization process>, that is to say by projecting, in particular using the device known as the metallizer gun, by means of a gas jet under pressure, a dispersion of fine droplets of said metal or alloy in the state. molten.



  However, it happens that, when trying to re-cover a support with a layer of metal, by the aforementioned process, serious difficulties are experienced in making the sprayed metal or alloy adhere to said support. This is particularly the case when the support is constituted by a block of steel which it is desired to reopen with a thin layer of a lead bronze alloy.



  The present invention relates to a method which makes it possible to ensure perfect adhesion of the sprayed layer on the support to be covered. This. method is characterized in that, prior to the formation, by projection, of the desired coating layer, the support is covered with an intermediate layer of at least one metal capable of adhering both to said support that 'to the <B>, </B> layer (the final coating, and in that, after having sprayed the latter, the whole is subjected to a treatment by heating at high temperature in a medium capable of protecting the projected coating against oxidation.



  The intermediate metal layer can advantageously be obtained itself by. spraying (the bran or its constituents on the support to be covered. It can also be formed by dipping or another similar process. This layer can, in the case of a lead bronze coating, for example, be constituted by copper or a tin bronze.You can also use zinc or (tin.

   To further increase the adhesion of the coating layers, the surface of the support can be brought to a prior favorable state, for example by scraper-boss, parkerization or sandblasting with fine sand or steel grit.



  The thermal treatment is carried out by heating ï), a temperature preferably above 700 ° C., for example in a reducing atmosphere, or in an oxidizing medium, such as boric hydrochloride. the coated support for a few minutes, then cool it immediately afterwards to the ordinary temperature, in particular by quenching with pure cold water or with the addition of an antioxidant which will preferably be a reducing agent.



  Said support can also be heated for a few hours, the heating being followed by slow cooling in a reducing atmosphere to room temperature.



  It may be that, despite the provision of an intermediate layer, and after the heat treatment ,, the; deposited layer - exhibits irregularities as to its compactness. The latter can then be equalized and increased by compression using appropriate tools, cold, or at least at a temperature lower than that of melting of the metal or filler alloy, and under a pressure which can go up to 'to 300 kg per cmd.



  By way of example, to cover a clean mild steel pad with an anti-rust coating consisting of an alloy of copper and lead, it is first projected, using a metallizer gun, on the surface of work of the pad previously sandblasted, a layer of tin bronze with 6% tin, with a thickness between 1 / 10o and 1 / 1o of mm.

    A layer of approximately mm of an alloy of copper and lead containing 30% lead is then projected onto the intermediate layer thus obtained. This spraying is also carried out using a metallizing gun supplied with a com compound wire carrying a copper casing and a lead core,

   the ratio of the sections of the casing and the core being the same as that desired for copper and lead in the anti-friction alloy. After depositing the final layer, the assembly is brought to a temperature above 700 ° C., in a reducing atmosphere for a few minutes, then soaked in cold water. Finally, the anti-scar coating is subjected to a pressure of between 200 and 300 kg per cm 2.



  A perfectly adherent and homogeneous coating is thus obtained on the pad.

 

Claims (1)

REVENDICATION: Procédé pour l'obtention d'une surface de frottement lisse sur un support métallique, par pulvérisation et projection sur ce support, d'au moins un métal antifriction, caractérisé en ce que, préalablement à la formation, par, projection, de la couche de revêtement désirée, l'on recouvre le support d'une couche intermé diaire d'au moins un métal susceptible d'ad hérer aussi bien audit support qu'à la couche de revêtement définitive, et en ce que, après avoir projeté cette dernière, on soumet l'en semble à tin traitement par chauffage à haute température dans un milieu susceptible de protéger la couche projetée contre l'oxyda tion. CLAIM: Process for obtaining a smooth friction surface on a metal support, by spraying and spraying on this support, at least one anti-friction metal, characterized in that, prior to the formation, by, projection, of the desired coating layer, the support is covered with an intermediate layer of at least one metal capable of adhering both to said support and to the final coating layer, and in that, after spraying the latter, the whole is subjected to a treatment by heating at high temperature in a medium capable of protecting the sprayed layer against oxidation. SOUS-REVENDICATIONS 1. Procédé selon la revendication, carac térisé en ce que la couche intermédiaire est formée par projection. 2. Procédé selon la revendication, caracté risé en ce que la couche intermédiaire est constituée par du cuivre. 3. Procédé selon la revendication, carac térisé en ce que la couche intermédiaire est constituée par du zinc. 4. Procédé selon la revendication, carac térisé en ce, que la couche intermédiaire est constituée par de l'étain. 5. Procédé selon la revendication, carac térisé en ce que la couche intermédiaire est constituée par un bronze à l'étain. 6. Procédé selon la revendication, carac térisé en ce que le traitement thermique est réalisé par chauffage à une température supé rieure à 700 C. 7. SUB-CLAIMS 1. Method according to claim, characterized in that the intermediate layer is formed by spraying. 2. Method according to claim, character ized in that the intermediate layer consists of copper. 3. Method according to claim, charac terized in that the intermediate layer consists of zinc. 4. Method according to claim, charac terized in that the intermediate layer consists of tin. 5. Method according to claim, charac terized in that the intermediate layer consists of a tin bronze. 6. Method according to claim, charac terized in that the heat treatment is carried out by heating to a temperature above 700 C. 7. Procédé selon la revendication et la sous-revendication 6, caractérisé en ce que le chauffage est opéré pendant quelques minutes et est suivi .d'un refroidissement brusque. 8. Procédé selon la revendication et la. sous-revendication 6, caractérisé en ce que le chauffage; est opéré pendant quelques heures et suivi d'un refroidissement lent en atmo sphère réductrice. 9. Procédé selon la revendication, carac térisé en ce que le traitement thermique est suivi d'une compression de la couche de revê tement, à une température inférieure au point de fusion de cette dernière. Process according to claim and sub-claim 6, characterized in that the heating is carried out for a few minutes and is followed by a sudden cooling. 8. Method according to claim and. Sub-claim 6, characterized in that the heating; is operated for a few hours and followed by slow cooling in a reducing atmosphere. 9. Method according to claim, characterized in that the heat treatment is followed by compression of the covering layer, at a temperature below the melting point of the latter.
CH272269D 1942-10-29 1947-12-27 Process for obtaining a smooth friction surface on a metal support. CH272269A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR272269X 1942-10-29
FR210743X 1943-07-21

Publications (1)

Publication Number Publication Date
CH272269A true CH272269A (en) 1950-12-15

Family

ID=26214137

Family Applications (1)

Application Number Title Priority Date Filing Date
CH272269D CH272269A (en) 1942-10-29 1947-12-27 Process for obtaining a smooth friction surface on a metal support.

Country Status (1)

Country Link
CH (1) CH272269A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2510926A1 (en) * 1981-08-05 1983-02-11 Lucas Ind Plc PROCESS FOR MANUFACTURING BEARING BODIES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2510926A1 (en) * 1981-08-05 1983-02-11 Lucas Ind Plc PROCESS FOR MANUFACTURING BEARING BODIES

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