CH272269A - Process for obtaining a smooth friction surface on a metal support. - Google Patents
Process for obtaining a smooth friction surface on a metal support.Info
- Publication number
- CH272269A CH272269A CH272269DA CH272269A CH 272269 A CH272269 A CH 272269A CH 272269D A CH272269D A CH 272269DA CH 272269 A CH272269 A CH 272269A
- Authority
- CH
- Switzerland
- Prior art keywords
- intermediate layer
- support
- spraying
- heating
- metal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Coating By Spraying Or Casting (AREA)
Description
Procédé pour l'obtention d'une surface de frottement lisse sur un support métallique. La présente invention concerne l'obtention, sur un support métallique, d'une surface de frottement lisse et, plus particulièrement, l'obtention de couches clé métal antifriction sur des coussinets et autres pièces analogues.
On a déjà proposé, pour obtenir une telle couche, de déposer sur le support à reeouvrii-, le métal. on alliage destiné à former cette couche, par le procédé dit de métallisation >, c'est-à-dire en projetant, notamment à l'aide du dispositif connu sous le soin de pistolet métalliseur, au moyen d'un jet de gaz sous pression, une dispersion de fines gouttelettes dudit métal ou alliage à l'état. fondu.
Or, il arrive que, lorsqu'on cherelie à re couvrir un support d'une couche de métal, par le procédé susmentionné, on éprouve de sé rieuses difficultés à faire adhérer sur ledit support le métal ou l'alliage pulvérisé. C'est notamment le cas lorsque le support est cons titué par un bloc d'acier que l'on désire reeou- vrir d'une mince couche d'un alliage de bronze au plomb.
La présente invention a pour objet un procédé qui permet d'assurer une adhérence parfaite de la couche projetée sur le support à recouvrir. Ce. procédé est caractérisé en ce que, préalablement à la formation, par pro jection, de la couche de revëteinent désirée, l'on recouvre le support d'une couche inter médiaire d'au moins un métal susceptible d'adhérer aussi bien audit support qu'à la<B>,</B> couche (le revêtement définitive, et en ce que, après avoir projeté cette dernière, on soumet l'ensemble à un traitement par chauffage à haute température dans un milieu susceptible de protéger la couelie projetée contre l'oxy dation.
La couche métallique intermédiaire peut avantageusement être obtenue elle-même par . pulvérisation (le son ou ses constituants sur le support à recouvrir. Elle petit également, être formée par trempage on autre procédé ana logue. Cette couche peut, dans le cas d'un. revêtement au bronze au plomb, par exemple, être constituée par du cuivre ou par un bronze à l'étain. On peut également, utiliser du zinc ou (le l'étain.
Pour augmenter encore l'adhérence des couches de revêtement, la sur face du support peut être amenée à un état propice préalable, par exemple par gratte- bossage, parkerisation ou sablage ait sable fin ou à la grenaille d'acier.
Le traitement tbermique est réalisé par eliauffage ï), une température de préférence supérieure à 700" C, par exemple dans une atmosphère réductrice, ou dans un milieu dès oxydant, tel que l'ttnbydi icle borique. On. petit, par exemple, chauffer pendant quelques mi nutes le support recouvert, puis le refroidir immédiatement après à la température ordi naire, notamment par trempe à, l'eau. froide pure ou additionnée d'un antioxy gène qui sera de préférence un réducteur.
On peut également chauffer ledit support pendant quelques heures, le chauffage étant suivi d'un refroidissement lent en atmosphère réductrice jusqu'à la température ordinaire.
Il se peut, que, malgré la disposition d'une couche intermédiaire, et après le traitement thermique,, la; couche déposée- présente des irrégularités quant à sa compacité. Cette der nière peut alors être égalisée et augmentée par compression à l'aide d'outils appropriés, à froid, ou tout au moins à une température inférieure à celle de fusion du métal ou alliage d'apport, et sous une pression pouvant aller jusqu'à 300 kg par cmd.
A titre d'exemple, pour garnir un coussi net en acier doux avec un revêtement antifric tion constitué par un alliage de cuivre et de plomb, on projette tout d'abord, à l'aide d'un pistolet métallisateur, sur la surface de tra vail du coussinet préalablement sablée, une couche de bronze à l'étain à 6 % d'étain, d'une épaisseur comprise entre 1/10o et 1/1o de mm.
On projette ensuite, sur la couche intermé diaire ainsi obtenue, une couche d'environ de mm d'un alliage de cuivre et de plomb à 30 % de plomb. Cette projection est égale- ment opérée à l'aide d'un pistolet métallisa- teur alimenté à l'aide d'un fil compound com portant une enveloppe de cuivre et une âme en plomb,
le rapport des sections de l'enve loppe et de l'âme étant le même que celui dé siré pour le cuivre et le plomb dans l'alliage antifriction. Après dépôt de la couche finale, l'ensemble est porté à une température supé rieure à 700 C, dans une atmosphère réduc trice pendant quelques minutes, puis trempé à l'eau froide. Enfin, le revêtement antifric tion est soumis à une pression comprise entre 200 et 300 kg par cm2.
On obtient ainsi, sur le coussinet, un revê tement parfaitement adhérent et homogène.
Process for obtaining a smooth friction surface on a metal support. The present invention relates to obtaining, on a metal support, a smooth friction surface and, more particularly, obtaining key metal anti-friction layers on bearings and other similar parts.
It has already been proposed, in order to obtain such a layer, to deposit the metal on the support to be re-worked. an alloy intended to form this layer, by the so-called metallization process>, that is to say by projecting, in particular using the device known as the metallizer gun, by means of a gas jet under pressure, a dispersion of fine droplets of said metal or alloy in the state. molten.
However, it happens that, when trying to re-cover a support with a layer of metal, by the aforementioned process, serious difficulties are experienced in making the sprayed metal or alloy adhere to said support. This is particularly the case when the support is constituted by a block of steel which it is desired to reopen with a thin layer of a lead bronze alloy.
The present invention relates to a method which makes it possible to ensure perfect adhesion of the sprayed layer on the support to be covered. This. method is characterized in that, prior to the formation, by projection, of the desired coating layer, the support is covered with an intermediate layer of at least one metal capable of adhering both to said support that 'to the <B>, </B> layer (the final coating, and in that, after having sprayed the latter, the whole is subjected to a treatment by heating at high temperature in a medium capable of protecting the projected coating against oxidation.
The intermediate metal layer can advantageously be obtained itself by. spraying (the bran or its constituents on the support to be covered. It can also be formed by dipping or another similar process. This layer can, in the case of a lead bronze coating, for example, be constituted by copper or a tin bronze.You can also use zinc or (tin.
To further increase the adhesion of the coating layers, the surface of the support can be brought to a prior favorable state, for example by scraper-boss, parkerization or sandblasting with fine sand or steel grit.
The thermal treatment is carried out by heating ï), a temperature preferably above 700 ° C., for example in a reducing atmosphere, or in an oxidizing medium, such as boric hydrochloride. the coated support for a few minutes, then cool it immediately afterwards to the ordinary temperature, in particular by quenching with pure cold water or with the addition of an antioxidant which will preferably be a reducing agent.
Said support can also be heated for a few hours, the heating being followed by slow cooling in a reducing atmosphere to room temperature.
It may be that, despite the provision of an intermediate layer, and after the heat treatment ,, the; deposited layer - exhibits irregularities as to its compactness. The latter can then be equalized and increased by compression using appropriate tools, cold, or at least at a temperature lower than that of melting of the metal or filler alloy, and under a pressure which can go up to 'to 300 kg per cmd.
By way of example, to cover a clean mild steel pad with an anti-rust coating consisting of an alloy of copper and lead, it is first projected, using a metallizer gun, on the surface of work of the pad previously sandblasted, a layer of tin bronze with 6% tin, with a thickness between 1 / 10o and 1 / 1o of mm.
A layer of approximately mm of an alloy of copper and lead containing 30% lead is then projected onto the intermediate layer thus obtained. This spraying is also carried out using a metallizing gun supplied with a com compound wire carrying a copper casing and a lead core,
the ratio of the sections of the casing and the core being the same as that desired for copper and lead in the anti-friction alloy. After depositing the final layer, the assembly is brought to a temperature above 700 ° C., in a reducing atmosphere for a few minutes, then soaked in cold water. Finally, the anti-scar coating is subjected to a pressure of between 200 and 300 kg per cm 2.
A perfectly adherent and homogeneous coating is thus obtained on the pad.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR272269X | 1942-10-29 | ||
FR210743X | 1943-07-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH272269A true CH272269A (en) | 1950-12-15 |
Family
ID=26214137
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH272269D CH272269A (en) | 1942-10-29 | 1947-12-27 | Process for obtaining a smooth friction surface on a metal support. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH272269A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2510926A1 (en) * | 1981-08-05 | 1983-02-11 | Lucas Ind Plc | PROCESS FOR MANUFACTURING BEARING BODIES |
-
1947
- 1947-12-27 CH CH272269D patent/CH272269A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2510926A1 (en) * | 1981-08-05 | 1983-02-11 | Lucas Ind Plc | PROCESS FOR MANUFACTURING BEARING BODIES |
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