CH219342A - Process for the production of metal coatings. - Google Patents
Process for the production of metal coatings.Info
- Publication number
- CH219342A CH219342A CH219342DA CH219342A CH 219342 A CH219342 A CH 219342A CH 219342D A CH219342D A CH 219342DA CH 219342 A CH219342 A CH 219342A
- Authority
- CH
- Switzerland
- Prior art keywords
- metal
- production
- nitrogen
- metal coatings
- pressure medium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
- B05B7/22—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc
- B05B7/222—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc using an arc
- B05B7/224—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc using an arc the material having originally the shape of a wire, rod or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Description
Verfahren zur Herstellung von Metallüberzügen. Das Verfahren zur Herstellung von Me tallüberzügen mittels eines im elektrischen Lichtbogen geschmolzenen und durch ein Druckmittel zerstäubten Metallee nach dem Hauptpatent ist dadurch gekennzeichnet, dass die Enden von zwei stromführenden Metall drähten zur Berührung unter gurzschluss ge bracht werden, so dass zwischen den Draht enden ein Lichtbogen erzeugt wird, welcher ein gleichmässiges Abschmelzen der Metall- drähte bewirkt.
Dabei kann folgende Erschei nung festgestellt werden Bei der am Lichtbogenort vorhandenen hohen Temperatur von mindestens 4000 C geht der Luftstickstoff in den hochaktiven Zustand über, und das hat bei der enormen Reaktionsoberfläche des die Luft durchdrin genden Metallstrahlkegels zur Folge, dass ein Nitrierungsprozess eingeleitet wird, welchem in theoretischer und praktischer Hinsicht ein erhebliches Interesse zukommt. Die erwähnte Wirkung wird verstärkt,
wenn gemäss vor liegender Erfindung als Druckmittel zur Zer- stäubung des geschmolzenen Metallee min- destens zum Teil Stickstoff, unter Ausschluss von Sauerstoff, also z.
B. Stickstoff und Was serstoff oder reiner Stickstoff, verwendet wird. Der Druck des Stickstoffes kann innerhalb weiter Grenzen veränderlich sein; 3-4 Atm. sind genügend, jedoch sind nach den bis jetzt vorliegenden Beobachtungen und Ergebnissen 8-10 Atm. vorzuziehen. Je höher der Druck, desto geringer ist die Streuung des Strahl kegele, was in den meisten Fällen er wünscht ist.
Zur Durchführung des Verfahrens dient zweckmässig eine Vorrichtung, bei der Press luft lediglich zum Antrieb einer den Vor schub der Metalldrähte bewirkenden Turbine Verwendung findet, während für den Zerstäu- bungsprozess des im elektrischen Lichtbogen geschmolzenen Metallee eine separate Zu leitung für reinen Stickstoff vorgesehen wird. Es ist auch möglich, dem Schmelzort der stromführenden Metalldrähte zusätzliche Me talle zuzuführen,
welche in Gegenwart des Lichtbogens in den gasförmigen Aggregat zustand übergehen. Ferner ist die Verwen. dung einer zusätzlichen - Kohlenelektrode möglich, um am Schmelzort eine Metall-C- Legierung sich bilden zu lassen.
Interessant ist die Beobachtung, dass ein nach dem erfindungsgemässen Verfahren her gestellter nitrierter Eisen- oder Stahlüberzug nicht rostet und gegenüber dem Ausgangs material eine Härtezunahme von 150 bis 200 % aufweist.
Process for the production of metal coatings. The process for the production of metal coatings by means of a metal that is melted in an electric arc and atomized by a pressure medium according to the main patent is characterized in that the ends of two current-carrying metal wires are short-circuited so that an arc ends between the wires which causes the metal wires to melt evenly.
The following phenomenon can be determined: At the high temperature of at least 4000 C at the arc location, the nitrogen in the air changes to the highly active state, and with the enormous reaction surface of the metal jet cone penetrating the air, this has the consequence that a nitration process is initiated there is considerable theoretical and practical interest. The mentioned effect is intensified,
if, according to the present invention, the pressure medium for atomizing the molten metal is at least partly nitrogen, with the exclusion of oxygen, e.g.
B. nitrogen and what hydrogen or pure nitrogen is used. The pressure of the nitrogen can vary within wide limits; 3-4 atm. are sufficient, however, according to the observations and results available so far, 8-10 atm. preferable. The higher the pressure, the lower the scattering of the jet cone, which in most cases it is desirable.
To carry out the method, a device is expediently used in which compressed air is only used to drive a turbine that pushes the metal wires forward, while a separate feed line for pure nitrogen is provided for the atomization process of the metal melted in the electric arc. It is also possible to add additional metals to the melting point of the current-carrying metal wires,
which pass into the gaseous aggregate state in the presence of the arc. Furthermore, the use is An additional carbon electrode is possible to allow a metal-C alloy to form at the melting point.
It is interesting to note that a nitrided iron or steel coating produced by the process according to the invention does not rust and has an increase in hardness of 150 to 200% compared to the starting material.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH219342T | 1940-12-05 | ||
CH213068T | 1941-09-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH219342A true CH219342A (en) | 1942-01-31 |
Family
ID=25725368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH219342D CH219342A (en) | 1940-12-05 | 1940-12-05 | Process for the production of metal coatings. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH219342A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE942484C (en) * | 1942-10-31 | 1956-05-03 | Hans Biel | Process for the production of metal layers by sputtering |
-
1940
- 1940-12-05 CH CH219342D patent/CH219342A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE942484C (en) * | 1942-10-31 | 1956-05-03 | Hans Biel | Process for the production of metal layers by sputtering |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE2431448A1 (en) | METHOD OF COATING A SUBSTRATE | |
DE2263210A1 (en) | WEAR PART MADE OF CARBIDE, ESPECIALLY FOR TOOLS | |
CH268905A (en) | Heat-resistant, ferritic alloy. | |
DE102016115550A1 (en) | Process for producing a fuel distributor | |
CH219342A (en) | Process for the production of metal coatings. | |
DE811899C (en) | Device for spraying metallic and non-metallic materials | |
DE685576C (en) | Process for the production of metal powder from liquid metal | |
DE420689C (en) | Sintered hard metal alloy and process for their manufacture | |
DE528500C (en) | Extraction of sulfur from sulphurous masses | |
DE728165C (en) | Process for the production of graphite-containing metal bodies | |
CH692201A5 (en) | Cobalt binder metal alloy for carbide tools and carbide tools with this alloy | |
DE692080C (en) | Process for casting metal objects in gas or vapor form | |
DE1060147B (en) | Process for the production of pure manganese | |
DE942484C (en) | Process for the production of metal layers by sputtering | |
DE876788C (en) | Process for spraying firmly adhering metallic coatings | |
DE835303C (en) | Process for the production of high-quality cast iron types in a coke-operated cupola furnace | |
DE952586C (en) | Process for the production of brittle metal powders | |
DE900457C (en) | Melting a cast iron suitable for the production of permanent molds in a foundry shaft furnace | |
DE582270C (en) | Process for the accelerated production of nitrided hardening layers on objects made of iron and its alloys | |
AT141832B (en) | Multi-stage process for the production of titanium carbide. | |
DE969312C (en) | Process for the production of a cast iron in which the graphite is present exclusively as spheroidal graphite | |
DE818368C (en) | Production of very low-inclusion steels in a basic electric furnace | |
DE974350C (en) | Process for cracking oils, tars or similar hydrocarbons in the gas phase | |
DE880491C (en) | Process for the gaseous reduction of metal oxides | |
DE1868909U (en) | HOLLOW CYLINDRICAL CARBON OR GRAPHITANODE FOR THERMIONIC TUBES AND MERCURY ARC RECTIFIERS. |