CA3228700A1 - Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication - Google Patents
Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication Download PDFInfo
- Publication number
- CA3228700A1 CA3228700A1 CA3228700A CA3228700A CA3228700A1 CA 3228700 A1 CA3228700 A1 CA 3228700A1 CA 3228700 A CA3228700 A CA 3228700A CA 3228700 A CA3228700 A CA 3228700A CA 3228700 A1 CA3228700 A1 CA 3228700A1
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- Prior art keywords
- foam
- blowing agent
- cells
- density
- foams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 117
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- 238000000034 method Methods 0.000 title description 74
- 210000004027 cell Anatomy 0.000 claims abstract description 286
- -1 polyethylene furanoate Polymers 0.000 claims abstract description 89
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 60
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 39
- OSHGZBCZUPGLPU-UHFFFAOYSA-N ethene furan-2-carboxylic acid Chemical group C=C.OC(=O)C1=CC=CO1 OSHGZBCZUPGLPU-UHFFFAOYSA-N 0.000 claims description 39
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
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- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 abstract description 2
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- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 4
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- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- 239000005022 packaging material Substances 0.000 description 4
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 4
- 239000012815 thermoplastic material Substances 0.000 description 4
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 3
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000012358 sourcing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 108010039189 tripeptidyl-peptidase 2 Proteins 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Mousses thermoplastiques à faible densité comprenant : (a) des cellules polymères thermoplastiques comprenant des parois cellulaires comprenant du polyéthylène furanoate, au moins environ 50 % en volume des cellules étant des cellules fermées ; et (b) au moins de l'HFO-1234ze(E) contenu dans lesdites cellules fermées.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
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US202163233720P | 2021-08-16 | 2021-08-16 | |
US63/233,720 | 2021-08-16 | ||
US202163252110P | 2021-10-04 | 2021-10-04 | |
US63/252,110 | 2021-10-04 | ||
US202163278497P | 2021-11-12 | 2021-11-12 | |
US63/278,497 | 2021-11-12 | ||
PCT/US2022/040504 WO2023023085A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procédés de fabrication |
Publications (1)
Publication Number | Publication Date |
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CA3228700A1 true CA3228700A1 (fr) | 2023-02-23 |
Family
ID=85239689
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3228703A Pending CA3228703A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
CA3228700A Pending CA3228700A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
CA3228702A Pending CA3228702A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
CA3228701A Pending CA3228701A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
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CA3228703A Pending CA3228703A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
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CA3228702A Pending CA3228702A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
CA3228701A Pending CA3228701A1 (fr) | 2021-08-16 | 2022-08-16 | Compositions thermoplastiques expansibles, mousses thermoplastiques et leurs procedes de fabrication |
Country Status (4)
Country | Link |
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KR (4) | KR20240046755A (fr) |
CA (4) | CA3228703A1 (fr) |
GB (4) | GB2624991A (fr) |
WO (4) | WO2023023088A1 (fr) |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2023225372A1 (fr) * | 2022-05-19 | 2023-11-23 | Honeywell International Inc. | Mousses thermoplastiques et utilisations dans des applications nécessitant une résistance et un poids léger |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
US20110144216A1 (en) * | 2009-12-16 | 2011-06-16 | Honeywell International Inc. | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene |
ES2645472T3 (es) * | 2012-07-19 | 2017-12-05 | Honeywell International Inc. | Agentes de soplado para espuma de poliestireno extruida y espuma de poliestireno extruida, y métodos de espumación |
EP3231836A1 (fr) * | 2016-04-13 | 2017-10-18 | Autoneum Management AG | Procede de preparation d'une mousse thermoplastique à alvéoles ouvertes |
WO2017192550A1 (fr) * | 2016-05-06 | 2017-11-09 | The Chemours Company Fc, Llc | Agent gonflant z-hfo-1336mzz pour l'expansion d'un polymère comprenant du polystyrène |
US20180327565A1 (en) * | 2017-05-10 | 2018-11-15 | The Chemours Company Fc, Llc | Z-hfo-1336mzz blowing agent blends for foaming thermoplastic polymer comprising polystyrene |
WO2018224461A1 (fr) * | 2017-06-07 | 2018-12-13 | Sabic Global Technologies B.V. | Copolymère de polyester thermoplastique expansible |
CN111263780B (zh) * | 2017-11-01 | 2022-04-05 | Agc株式会社 | 硬质发泡合成树脂的制造方法 |
GB2591301B (en) * | 2020-01-27 | 2022-11-09 | Kingspan Holdings Irl Ltd | Phenolic foam and method of manufacture thereof |
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2022
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- 2022-08-16 WO PCT/US2022/040507 patent/WO2023023088A1/fr active Application Filing
- 2022-08-16 CA CA3228700A patent/CA3228700A1/fr active Pending
- 2022-08-16 KR KR1020247008082A patent/KR20240046755A/ko unknown
- 2022-08-16 GB GB2402492.9A patent/GB2624991A/en active Pending
- 2022-08-16 GB GB2402636.1A patent/GB2624573A/en active Pending
- 2022-08-16 CA CA3228702A patent/CA3228702A1/fr active Pending
- 2022-08-16 GB GB2402635.3A patent/GB2624572A/en active Pending
- 2022-08-16 WO PCT/US2022/040504 patent/WO2023023085A1/fr active Application Filing
- 2022-08-16 KR KR1020247008081A patent/KR20240046754A/ko unknown
- 2022-08-16 WO PCT/US2022/040506 patent/WO2023023087A1/fr active Application Filing
- 2022-08-16 KR KR1020247008084A patent/KR20240046757A/ko unknown
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- 2022-08-16 CA CA3228701A patent/CA3228701A1/fr active Pending
- 2022-08-16 KR KR1020247008083A patent/KR20240046756A/ko unknown
- 2022-08-16 GB GB2402411.9A patent/GB2624565A/en active Pending
Also Published As
Publication number | Publication date |
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CA3228702A1 (fr) | 2023-02-23 |
WO2023023086A1 (fr) | 2023-02-23 |
WO2023023087A1 (fr) | 2023-02-23 |
CA3228701A1 (fr) | 2023-02-23 |
WO2023023088A1 (fr) | 2023-02-23 |
GB2624991A (en) | 2024-06-05 |
GB202402492D0 (en) | 2024-04-10 |
GB2624572A (en) | 2024-05-22 |
KR20240046757A (ko) | 2024-04-09 |
GB202402636D0 (en) | 2024-04-10 |
KR20240046756A (ko) | 2024-04-09 |
GB2624573A (en) | 2024-05-22 |
KR20240046755A (ko) | 2024-04-09 |
GB202402635D0 (en) | 2024-04-10 |
GB2624565A (en) | 2024-05-22 |
KR20240046754A (ko) | 2024-04-09 |
CA3228703A1 (fr) | 2023-02-23 |
WO2023023085A1 (fr) | 2023-02-23 |
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