CA3208839A1 - Milieu poreux pour separations de liquides de gaz naturel - Google Patents
Milieu poreux pour separations de liquides de gaz naturelInfo
- Publication number
- CA3208839A1 CA3208839A1 CA3208839A CA3208839A CA3208839A1 CA 3208839 A1 CA3208839 A1 CA 3208839A1 CA 3208839 A CA3208839 A CA 3208839A CA 3208839 A CA3208839 A CA 3208839A CA 3208839 A1 CA3208839 A1 CA 3208839A1
- Authority
- CA
- Canada
- Prior art keywords
- methane
- ethane
- stream
- porous material
- uptake
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011148 porous material Substances 0.000 title claims abstract description 145
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract description 373
- 238000000926 separation method Methods 0.000 title abstract description 67
- 239000003345 natural gas Substances 0.000 title abstract description 49
- 239000007788 liquid Substances 0.000 title description 13
- 239000007789 gas Substances 0.000 claims abstract description 109
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 88
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 85
- 239000003463 adsorbent Substances 0.000 claims abstract description 80
- 238000001179 sorption measurement Methods 0.000 claims abstract description 54
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 180
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 97
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 90
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 60
- 238000004519 manufacturing process Methods 0.000 claims description 39
- 239000004215 Carbon black (E152) Substances 0.000 claims description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 239000001569 carbon dioxide Substances 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 239000011593 sulfur Chemical group 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 125000005842 heteroatom Chemical group 0.000 claims description 9
- 239000006227 byproduct Substances 0.000 claims description 3
- 239000003575 carbonaceous material Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 79
- 239000000047 product Substances 0.000 description 122
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 110
- 239000001294 propane Substances 0.000 description 53
- 238000011084 recovery Methods 0.000 description 46
- 239000012229 microporous material Substances 0.000 description 42
- 238000010992 reflux Methods 0.000 description 38
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 30
- 239000000463 material Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 23
- 239000001273 butane Substances 0.000 description 18
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 18
- 239000007783 nanoporous material Substances 0.000 description 17
- 229920002239 polyacrylonitrile Polymers 0.000 description 11
- 238000012545 processing Methods 0.000 description 9
- 239000012621 metal-organic framework Substances 0.000 description 8
- 241000894007 species Species 0.000 description 8
- 239000010426 asphalt Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000000446 fuel Substances 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000005057 refrigeration Methods 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- -1 methane and ethane Chemical class 0.000 description 4
- 239000002808 molecular sieve Substances 0.000 description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- CKMDHPABJFNEGF-UHFFFAOYSA-N ethane methane propane Chemical compound C.CC.CCC CKMDHPABJFNEGF-UHFFFAOYSA-N 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000012620 biological material Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000128 polypyrrole Polymers 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- DXHVIYMLEMDHQW-UHFFFAOYSA-N [S].[C].[N].[O] Chemical compound [S].[C].[N].[O] DXHVIYMLEMDHQW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000002429 nitrogen sorption measurement Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Separation Of Gases By Adsorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/460,580 US10646817B2 (en) | 2017-11-09 | 2019-07-02 | Porous materials for natural gas liquids separations |
| US16/460,580 | 2019-07-02 | ||
| CA3078066A CA3078066C (fr) | 2019-07-02 | 2020-04-28 | Milieu poreux pour separations de liquides de gaz naturel |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3078066A Division CA3078066C (fr) | 2019-07-02 | 2020-04-28 | Milieu poreux pour separations de liquides de gaz naturel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA3208839A1 true CA3208839A1 (fr) | 2021-01-02 |
Family
ID=74036754
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3078066A Active CA3078066C (fr) | 2019-07-02 | 2020-04-28 | Milieu poreux pour separations de liquides de gaz naturel |
| CA3208839A Pending CA3208839A1 (fr) | 2019-07-02 | 2020-04-28 | Milieu poreux pour separations de liquides de gaz naturel |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3078066A Active CA3078066C (fr) | 2019-07-02 | 2020-04-28 | Milieu poreux pour separations de liquides de gaz naturel |
Country Status (1)
| Country | Link |
|---|---|
| CA (2) | CA3078066C (fr) |
-
2020
- 2020-04-28 CA CA3078066A patent/CA3078066C/fr active Active
- 2020-04-28 CA CA3208839A patent/CA3208839A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA3078066C (fr) | 2023-10-10 |
| CA3078066A1 (fr) | 2021-01-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20230809 |
|
| EEER | Examination request |
Effective date: 20230809 |
|
| EEER | Examination request |
Effective date: 20230809 |
|
| EEER | Examination request |
Effective date: 20230809 |