CA3180975A1 - Oxydation catalytique de gaz d'echappement de noir de carbone - Google Patents
Oxydation catalytique de gaz d'echappement de noir de carbone Download PDFInfo
- Publication number
- CA3180975A1 CA3180975A1 CA3180975A CA3180975A CA3180975A1 CA 3180975 A1 CA3180975 A1 CA 3180975A1 CA 3180975 A CA3180975 A CA 3180975A CA 3180975 A CA3180975 A CA 3180975A CA 3180975 A1 CA3180975 A1 CA 3180975A1
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- CA
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- Prior art keywords
- carbon black
- tail gas
- gas
- oxidized
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000006229 carbon black Substances 0.000 title claims abstract description 118
- 238000007254 oxidation reaction Methods 0.000 title claims description 54
- 230000003647 oxidation Effects 0.000 title claims description 53
- 230000003197 catalytic effect Effects 0.000 title claims description 30
- 239000007789 gas Substances 0.000 claims abstract description 213
- 238000000034 method Methods 0.000 claims abstract description 85
- 229910052815 sulfur oxide Inorganic materials 0.000 claims abstract description 30
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000013618 particulate matter Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims description 53
- 230000008569 process Effects 0.000 claims description 46
- 238000010438 heat treatment Methods 0.000 claims description 35
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 29
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 24
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 23
- 239000011149 active material Substances 0.000 claims description 19
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 19
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 14
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 230000001590 oxidative effect Effects 0.000 claims description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000003344 environmental pollutant Substances 0.000 claims description 6
- 231100000719 pollutant Toxicity 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 229910000510 noble metal Inorganic materials 0.000 claims description 5
- 239000011800 void material Substances 0.000 claims description 5
- 239000005909 Kieselgur Substances 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 125000000101 thioether group Chemical group 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229940000425 combination drug Drugs 0.000 claims description 2
- 229910052878 cordierite Inorganic materials 0.000 claims description 2
- -1 diatomaceous earth Chemical compound 0.000 claims description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002638 heterogeneous catalyst Substances 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 239000003365 glass fiber Substances 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 36
- 229940105289 carbon black Drugs 0.000 description 101
- 235000019241 carbon black Nutrition 0.000 description 101
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 238000002485 combustion reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000011282 treatment Methods 0.000 description 11
- 229910001868 water Inorganic materials 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 150000002431 hydrogen Chemical class 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000010531 catalytic reduction reaction Methods 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 229960000510 ammonia Drugs 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012717 electrostatic precipitator Substances 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
L'invention concerne un procédé de production de noir de carbone dans lequel un gaz résiduaire de noir de carbone est oxydé catalytiquement pour produire un gaz résiduaire oxydé. Le gaz résiduaire de noir de carbone peut également être traité pour éliminer la matière particulaire, les oxydes de soufre, le cas échéant, et les oxydes d'azote, le cas échéant.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202063037991P | 2020-06-11 | 2020-06-11 | |
US63/037,991 | 2020-06-11 | ||
PCT/EP2021/065593 WO2021250161A1 (fr) | 2020-06-11 | 2021-06-10 | Oxydation catalytique de gaz d'échappement de noir de carbone |
Publications (1)
Publication Number | Publication Date |
---|---|
CA3180975A1 true CA3180975A1 (fr) | 2021-12-16 |
Family
ID=76522934
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3180975A Pending CA3180975A1 (fr) | 2020-06-11 | 2021-06-10 | Oxydation catalytique de gaz d'echappement de noir de carbone |
Country Status (6)
Country | Link |
---|---|
US (1) | US20230226489A1 (fr) |
EP (1) | EP4164774A1 (fr) |
CN (1) | CN115734815A (fr) |
BR (1) | BR112022025282A2 (fr) |
CA (1) | CA3180975A1 (fr) |
WO (1) | WO2021250161A1 (fr) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4242105A (en) * | 1979-10-10 | 1980-12-30 | Union Carbide Corporation | Process for producing methane from gas streams containing carbon monoxide and hydrogen |
DK167910B1 (da) * | 1991-05-24 | 1994-01-03 | Topsoe Haldor As | Fremgangsmaade til fjernelse af svovloxider fra afgasser |
WO2012064734A1 (fr) | 2010-11-12 | 2012-05-18 | Cabot Corporation | Procédé et appareil pour la réduction des émissions de nox lors de l'incinération de gaz résiduaire |
CN104936679B (zh) | 2013-02-14 | 2017-08-18 | 托普索公司 | 用于从烟道气或废气中同时除去一氧化碳和氮氧化物的方法和催化剂 |
WO2015082351A1 (fr) * | 2013-12-02 | 2015-06-11 | Haldor Topsøe A/S | Oxydation catalytique d'un gaz contenant du sulfure d'hydrogène |
EP3285913B1 (fr) | 2015-04-21 | 2021-07-14 | Haldor Topsøe A/S | Procédé d'élimination de suie d'un flux gazeux sulfureux |
BR112018002339B1 (pt) * | 2015-08-14 | 2022-10-25 | Orion Engineered Carbons Gmbh | Método e sistema para reduzir matéria particulada em um gás de escape |
CN107949435A (zh) * | 2015-09-28 | 2018-04-20 | 托普索公司 | 用于炭黑生产中的能量回收的方法 |
WO2018138200A1 (fr) * | 2017-01-25 | 2018-08-02 | Haldor Topsøe A/S | Procédé de traitement de l'effluent gazeux d'une installation de production noir de carbone pour récupérer du soufre |
-
2021
- 2021-06-10 CN CN202180040051.5A patent/CN115734815A/zh active Pending
- 2021-06-10 EP EP21733394.7A patent/EP4164774A1/fr active Pending
- 2021-06-10 CA CA3180975A patent/CA3180975A1/fr active Pending
- 2021-06-10 US US18/000,971 patent/US20230226489A1/en active Pending
- 2021-06-10 BR BR112022025282A patent/BR112022025282A2/pt unknown
- 2021-06-10 WO PCT/EP2021/065593 patent/WO2021250161A1/fr unknown
Also Published As
Publication number | Publication date |
---|---|
EP4164774A1 (fr) | 2023-04-19 |
US20230226489A1 (en) | 2023-07-20 |
BR112022025282A2 (pt) | 2023-01-03 |
CN115734815A (zh) | 2023-03-03 |
WO2021250161A1 (fr) | 2021-12-16 |
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