CA3068993A1 - Stabilized polyolefin compositions comprising benzofuranones and hindered amine light stabilizers - Google Patents

Stabilized polyolefin compositions comprising benzofuranones and hindered amine light stabilizers Download PDF

Info

Publication number
CA3068993A1
CA3068993A1 CA3068993A CA3068993A CA3068993A1 CA 3068993 A1 CA3068993 A1 CA 3068993A1 CA 3068993 A CA3068993 A CA 3068993A CA 3068993 A CA3068993 A CA 3068993A CA 3068993 A1 CA3068993 A1 CA 3068993A1
Authority
CA
Canada
Prior art keywords
alkyl
bis
ppm
triazine
subformulae
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3068993A
Other languages
English (en)
French (fr)
Inventor
Iii King Roswell E.
Werner Hoelzl
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority claimed from PCT/US2018/040709 external-priority patent/WO2019010176A1/en
Publication of CA3068993A1 publication Critical patent/CA3068993A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
    • C07F9/65517—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring condensed with carbocyclic rings or carbocyclic ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/529—Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CA3068993A 2017-07-06 2018-07-03 Stabilized polyolefin compositions comprising benzofuranones and hindered amine light stabilizers Pending CA3068993A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP17180079.0 2017-07-06
EP17180079 2017-07-06
US201862691211P 2018-06-28 2018-06-28
US62/691,211 2018-06-28
PCT/US2018/040709 WO2019010176A1 (en) 2017-07-06 2018-07-03 STABILIZED POLYOLEFIN COMPOSITIONS COMPRISING BENZOFURANONES AND COATED AMINOUS AMOUNT PHOTOSTABILIZERS

Publications (1)

Publication Number Publication Date
CA3068993A1 true CA3068993A1 (en) 2019-01-10

Family

ID=67702078

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3068993A Pending CA3068993A1 (en) 2017-07-06 2018-07-03 Stabilized polyolefin compositions comprising benzofuranones and hindered amine light stabilizers

Country Status (11)

Country Link
US (2) US11623979B2 (https=)
EP (1) EP3649137A4 (https=)
JP (1) JP2020526607A (https=)
KR (1) KR20200026272A (https=)
CN (1) CN111448201A (https=)
AU (2) AU2018297119B2 (https=)
BR (1) BR112020000136A2 (https=)
CA (1) CA3068993A1 (https=)
MX (1) MX2020000237A (https=)
TW (1) TW201920426A (https=)
ZA (1) ZA202000589B (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112617441B (zh) * 2020-12-28 2024-09-10 安徽工业大学 一种便于取挂放衣物的智能衣柜及其取挂放衣物方法
EP4249388B1 (en) * 2022-03-23 2024-06-19 Borealis AG Living hinge of an alpha-nucleated propylene copolymer
CN114874528B (zh) * 2022-06-07 2023-07-28 苏州旭光聚合物有限公司 一种汽车头枕骨架用改性hdpe复合材料及其制备方法
CN114957860B (zh) * 2022-06-28 2024-01-26 江苏万纳普新材料科技有限公司 一种聚丙烯专用耐热氧老化改性功能母粒及其制备方法
CN115122528B (zh) * 2022-06-30 2024-11-12 安徽省天助纺织科技集团股份有限公司 一种利用废旧纺织品制造环保包装袋的方法
CN120867094A (zh) * 2025-09-26 2025-10-31 苏州大学 一种丝绸修复加固方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4746692A (en) * 1986-05-05 1988-05-24 Shell Oil Company Polyolefin compositions for use with water systems
US5308901A (en) 1988-07-25 1994-05-03 General Electric Company 3-9-diphosphaspiroundecane-stabilized polymer compositions
ES2134083B1 (es) * 1994-12-09 2000-05-01 Sumitomo Chemical Co Pelicula de resina de poliolefinas de cubrimiento y metodo para cultivo de plantas.
JPH09324081A (ja) * 1996-04-02 1997-12-16 Furukawa Electric Co Ltd:The 架橋ポリエチレンパイプ
US6521681B1 (en) 1996-07-05 2003-02-18 Ciba Specialty Chemicals Corporation Phenol-free stabilization of polyolefin fibres
JP2001081250A (ja) 1999-07-14 2001-03-27 Mitsui Chemicals Inc ポリオレフィン樹脂組成物
GB0004436D0 (en) * 2000-02-25 2000-04-12 Clariant Int Ltd Synergistic stabilizer compositions for thermoplastic polymers in prolonged contact with water
US6566672B1 (en) 2000-09-29 2003-05-20 Heidelberger Druckmaschinen Ag Light sensor for sheet products
EP1470183B1 (en) * 2002-01-31 2006-11-15 Ciba SC Holding AG Stabilization of polyolefins in permanent contact with chlorinated water
WO2004024810A2 (en) * 2002-09-11 2004-03-25 Ciba, Specialty Chemicals Holding Inc. Stabillization of organic materials
CA2498975A1 (en) * 2002-10-03 2004-04-15 Ciba Specialty Chemicals Holding Inc. Flame retardant compositions
US7109260B2 (en) 2002-10-17 2006-09-19 Ciba Specialty Chemicals Corporation Flame retardant compositions
US7291669B2 (en) 2004-03-16 2007-11-06 Ciba Specialty Chemicals Corporation Stabilized polyolefin compositions
CA2615555C (en) * 2005-07-21 2014-01-07 Ciba Specialty Chemicals Holding Inc. Stabilization of polyolefins with liquid tris-(mono-alkyl)phenyl phosphites
GB0515602D0 (en) * 2005-07-29 2005-09-07 Great Lakes Chemical Europ Colour stabilised polyolefins
CA2544891A1 (en) * 2006-04-26 2007-10-26 Nova Chemicals Corporation Pipe coating composition
EP1967548B1 (en) 2007-03-07 2010-06-02 Sumitomo Chemical Company, Limited Polypropylene Composition
EP2361951A1 (en) * 2010-02-18 2011-08-31 Borealis AG Stabilized polypropylene composition with improved lifetime and ageing properties
CN103146028B (zh) * 2013-03-08 2014-12-17 江西吉祥新材料有限公司 聚烯烃用的添加剂组合物及其应用和聚烯烃组合物
US9518176B2 (en) * 2013-06-05 2016-12-13 Gse Environmental, Llc High temperature geomembrane liners and master batch compositions
TR201901553T4 (tr) 2013-10-17 2019-02-21 Basf Se Triazin, piperidin ve pirolidin ve prolidin bazlı engellenmiş amin ışık dengeleyicileri.
EP3107959B1 (en) 2014-02-17 2018-07-25 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers
MA39529B1 (fr) * 2014-05-15 2018-11-30 Basf Se Agent stabilisant hautement efficace
WO2016020322A1 (en) * 2014-08-05 2016-02-11 Basf Se 3-phenyl-benzofuran-2-one diphosphite derivatives as stabilizers
WO2017025431A1 (en) * 2015-08-10 2017-02-16 Basf Se 3-phenyl-benzofuran-2-one derivatives containing phosphorus as stabilizers
US12421379B2 (en) 2017-07-06 2025-09-23 Basf Se Polyethylene pipe

Also Published As

Publication number Publication date
JP2020526607A (ja) 2020-08-31
ZA202000589B (en) 2021-07-28
CN111448201A (zh) 2020-07-24
TW201920426A (zh) 2019-06-01
EP3649137A4 (en) 2021-05-05
AU2022224796A1 (en) 2022-09-22
US11623979B2 (en) 2023-04-11
AU2018297119A1 (en) 2020-01-30
AU2018297119B2 (en) 2022-06-16
KR20200026272A (ko) 2020-03-10
EP3649137A1 (en) 2020-05-13
MX2020000237A (es) 2020-08-17
US20200216638A1 (en) 2020-07-09
AU2018297119A8 (en) 2020-02-13
BR112020000136A2 (pt) 2020-07-07
US20220259405A1 (en) 2022-08-18

Similar Documents

Publication Publication Date Title
US10934423B2 (en) Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers
US11623979B2 (en) Stabilized polyolefin compositions comprising benzofuranones and hindered amine light stabilizers
US20220145053A1 (en) Stabilized Polyolefin Compositions Comprising Benzofuranones and Hindered Phenolic Antioxidants
AU2022203873A1 (en) Stabilized polyolefin compositions comprising benzofuranones and organophosphorus stabilizers
AU2018298025B2 (en) Stabilized polyolefin compositions comprising benzofuranones and acid scavengers