CA3059006A1 - Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines - Google Patents
Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines Download PDFInfo
- Publication number
- CA3059006A1 CA3059006A1 CA3059006A CA3059006A CA3059006A1 CA 3059006 A1 CA3059006 A1 CA 3059006A1 CA 3059006 A CA3059006 A CA 3059006A CA 3059006 A CA3059006 A CA 3059006A CA 3059006 A1 CA3059006 A1 CA 3059006A1
- Authority
- CA
- Canada
- Prior art keywords
- microemulsion
- terpene
- emulsion
- surfactant
- freezing point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 93
- 238000000034 method Methods 0.000 title claims abstract description 75
- 239000000203 mixture Substances 0.000 title claims abstract description 62
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 29
- 230000004936 stimulating effect Effects 0.000 title claims abstract description 14
- 238000005755 formation reaction Methods 0.000 title abstract description 88
- 229930195733 hydrocarbon Natural products 0.000 title abstract description 27
- 150000002430 hydrocarbons Chemical class 0.000 title abstract description 27
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 194
- 150000003505 terpenes Chemical class 0.000 claims abstract description 160
- 235000007586 terpenes Nutrition 0.000 claims abstract description 154
- 239000004094 surface-active agent Substances 0.000 claims abstract description 113
- 239000000839 emulsion Substances 0.000 claims abstract description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000003921 oil Substances 0.000 claims abstract description 50
- 239000012530 fluid Substances 0.000 claims description 63
- 238000006073 displacement reaction Methods 0.000 claims description 51
- 230000008014 freezing Effects 0.000 claims description 44
- 238000007710 freezing Methods 0.000 claims description 44
- 238000011282 treatment Methods 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- -1 alkylene glycol Chemical compound 0.000 claims description 39
- 239000012071 phase Substances 0.000 claims description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 239000012267 brine Substances 0.000 claims description 18
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 18
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 14
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 11
- ROKSAUSPJGWCSM-UHFFFAOYSA-N 2-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol Chemical compound C1C2C(C)(C)C1CC=C2CCO ROKSAUSPJGWCSM-UHFFFAOYSA-N 0.000 claims description 11
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- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 8
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 7
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 7
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 7
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 7
- 239000005792 Geraniol Substances 0.000 claims description 7
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- 238000002347 injection Methods 0.000 claims description 7
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- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims description 6
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229930007503 menthone Natural products 0.000 claims description 6
- 229920000151 polyglycol Polymers 0.000 claims description 5
- 239000010695 polyglycol Substances 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
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- 239000002563 ionic surfactant Substances 0.000 claims 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims 1
- 239000010779 crude oil Substances 0.000 abstract description 41
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- 239000002904 solvent Substances 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 20
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 18
- 239000002253 acid Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 17
- 125000003118 aryl group Chemical group 0.000 description 17
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 14
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- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 12
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 239000004927 clay Substances 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
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- 150000001298 alcohols Chemical class 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical group CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 229920001400 block copolymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
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- 239000010452 phosphate Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 125000000547 substituted alkyl group Chemical group 0.000 description 5
- 239000003180 well treatment fluid Substances 0.000 description 5
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
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- 229940123973 Oxygen scavenger Drugs 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 125000003158 alcohol group Chemical group 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 125000000304 alkynyl group Chemical group 0.000 description 4
- 239000003139 biocide Substances 0.000 description 4
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- 239000003638 chemical reducing agent Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
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- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
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- 239000012535 impurity Substances 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
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- 238000013507 mapping Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical class COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
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- 125000002950 monocyclic group Chemical group 0.000 description 2
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- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
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- 239000001739 pinus spp. Substances 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
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- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- 238000010008 shearing Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
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- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 150000003508 terpinolene derivatives Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- YIEDHPBKGZGLIK-UHFFFAOYSA-L tetrakis(hydroxymethyl)phosphanium;sulfate Chemical compound [O-]S([O-])(=O)=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO YIEDHPBKGZGLIK-UHFFFAOYSA-L 0.000 description 1
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- 150000003626 triacylglycerols Chemical class 0.000 description 1
- AKUNSPZHHSNFFX-UHFFFAOYSA-M tributyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC AKUNSPZHHSNFFX-UHFFFAOYSA-M 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Colloid Chemistry (AREA)
- Medicinal Preparation (AREA)
Abstract
Des procédés et compositions sont décrits pour la stimulation de la production d'hydrocarbures (par exemple, du pétrole brut de formation et/ou du gaz de formation) à partir de formations souterraines. Selon certains modes de réalisation, les compositions sont des émulsions ou des microémulsions, qui peuvent inclure de l'eau, un terpène, et un agent de surface. Selon certains modes de réalisation, des procédés de sélection d'une composition pour le traitement d'un puits de pétrole ou de gaz sont décrits.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/829,495 US9428683B2 (en) | 2013-03-14 | 2013-03-14 | Methods and compositions for stimulating the production of hydrocarbons from subterranean formations |
US13/829,434 US9068108B2 (en) | 2013-03-14 | 2013-03-14 | Methods and compositions for stimulating the production of hydrocarbons from subterranean formations |
US13/829,434 | 2013-03-14 | ||
US13/829,495 | 2013-03-14 | ||
CA2906047A CA2906047C (fr) | 2013-03-14 | 2014-03-14 | Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CA2906047A Division CA2906047C (fr) | 2013-03-14 | 2014-03-14 | Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines |
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CA3059006A Active CA3059006C (fr) | 2013-03-14 | 2014-03-14 | Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines |
CA2906047A Active CA2906047C (fr) | 2013-03-14 | 2014-03-14 | Procedes et compositions pour la stimulation de la production d'hydrocarbures a partir de formations souterraines |
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EP (1) | EP2970750A4 (fr) |
CN (1) | CN104755582B (fr) |
AU (1) | AU2014236331B2 (fr) |
CA (2) | CA3059006C (fr) |
WO (1) | WO2014153078A1 (fr) |
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CA2904733C (fr) * | 2015-03-11 | 2021-10-19 | Cesi Chemical, Inc. | Methodes et compositions destinees aux puits de petrole et de gaz |
CN105419761B (zh) * | 2015-12-09 | 2018-06-01 | 中国石油天然气股份有限公司 | 一种阻止钙卤结垢的改性剂 |
CN107859507A (zh) * | 2016-09-22 | 2018-03-30 | 中国石油化工股份有限公司 | 提高油井单井产能的增产方法 |
US11473004B2 (en) | 2016-12-02 | 2022-10-18 | University Of Wyoming | Microemulsions and uses thereof to displace oil in heterogeneous porous media |
CN116144338B (zh) * | 2023-04-19 | 2023-07-07 | 太原理工大学 | 一种提高煤层气抽采效率的柠檬烯溶浸液 |
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US4472291A (en) * | 1983-03-07 | 1984-09-18 | Rosano Henri L | High viscosity microemulsions |
WO2003074833A2 (fr) * | 2002-03-01 | 2003-09-12 | Cesi Chemical, A Flotek Company | Composition et procede pour nettoyer un puits |
US20080287324A1 (en) * | 2002-03-01 | 2008-11-20 | Cesi Chemical, Inc., A Flotek Company | Process for well cleaning |
US8272442B2 (en) * | 2007-09-20 | 2012-09-25 | Green Source Energy Llc | In situ extraction of hydrocarbons from hydrocarbon-containing materials |
JP2010540694A (ja) * | 2007-09-20 | 2010-12-24 | グリーン・ソース・エナジー・リミテッド・ライアビリティ・カンパニー | 炭化水素含有材料からの炭化水素抽出 |
US7989404B2 (en) * | 2008-02-11 | 2011-08-02 | Clearwater International, Llc | Compositions and methods for gas well treatment |
US7893010B2 (en) * | 2008-05-08 | 2011-02-22 | Schlumberger Technology Corporation | Composition and method for fluid recovery from well |
US8865632B1 (en) * | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
JP2012520374A (ja) * | 2009-03-13 | 2012-09-06 | グリーン・ソース・エナジー・リミテッド・ライアビリティ・カンパニー | 炭化水素含有材料からの炭化水素抽出および/または炭化水素含有材料の処理 |
US9102860B2 (en) * | 2011-06-16 | 2015-08-11 | Baker Hughes Incorporated | Method of inhibiting or controlling release of well treatment agent |
US10000693B2 (en) * | 2013-03-14 | 2018-06-19 | Flotek Chemistry, Llc | Methods and compositions for use in oil and/or gas wells |
AU2014278002B2 (en) * | 2013-06-14 | 2017-08-17 | Flotek Chemistry, Llc | Methods and compositions for stimulating the production of hydrocarbons from subterranean formations |
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- 2014-03-14 WO PCT/US2014/028970 patent/WO2014153078A1/fr active Application Filing
- 2014-03-14 CN CN201480002624.5A patent/CN104755582B/zh active Active
- 2014-03-14 EP EP14769583.7A patent/EP2970750A4/fr not_active Withdrawn
- 2014-03-14 CA CA3059006A patent/CA3059006C/fr active Active
- 2014-03-14 CA CA2906047A patent/CA2906047C/fr active Active
Also Published As
Publication number | Publication date |
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CA3059006C (fr) | 2021-08-31 |
CN104755582A (zh) | 2015-07-01 |
CA2906047C (fr) | 2019-11-12 |
EP2970750A4 (fr) | 2017-04-19 |
AU2014236331A1 (en) | 2015-10-29 |
CA2906047A1 (fr) | 2014-09-25 |
CN104755582B (zh) | 2019-04-12 |
WO2014153078A1 (fr) | 2014-09-25 |
EP2970750A1 (fr) | 2016-01-20 |
AU2014236331B2 (en) | 2017-08-31 |
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