CA3048069A1 - Method for producing fibres and non-woven fabrics by solution-blow spinning and non-woven fabric produced thereby - Google Patents
Method for producing fibres and non-woven fabrics by solution-blow spinning and non-woven fabric produced thereby Download PDFInfo
- Publication number
- CA3048069A1 CA3048069A1 CA3048069A CA3048069A CA3048069A1 CA 3048069 A1 CA3048069 A1 CA 3048069A1 CA 3048069 A CA3048069 A CA 3048069A CA 3048069 A CA3048069 A CA 3048069A CA 3048069 A1 CA3048069 A1 CA 3048069A1
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- Prior art keywords
- parent solution
- parent
- lambda
- solution
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000004745 nonwoven fabric Substances 0.000 title abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 38
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims description 86
- 239000000835 fiber Substances 0.000 claims description 67
- 230000008569 process Effects 0.000 claims description 53
- 208000012886 Vertigo Diseases 0.000 claims description 27
- 239000007787 solid Substances 0.000 claims description 7
- 229920001410 Microfiber Polymers 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000003658 microfiber Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 239000002121 nanofiber Substances 0.000 claims description 3
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 abstract description 10
- 239000000243 solution Substances 0.000 description 95
- 239000007789 gas Substances 0.000 description 43
- 239000000203 mixture Substances 0.000 description 27
- 150000002191 fatty alcohols Chemical class 0.000 description 16
- 239000007788 liquid Substances 0.000 description 12
- -1 alkyl ether carboxylates Chemical class 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 238000010041 electrostatic spinning Methods 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 150000003871 sulfonates Chemical class 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 5
- 229940068984 polyvinyl alcohol Drugs 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002307 Dextran Polymers 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000000306 component Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229960004592 isopropanol Drugs 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- IEQAICDLOKRSRL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO IEQAICDLOKRSRL-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001612 Hydroxyethyl starch Polymers 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- NWGKJDSIEKMTRX-BFWOXRRGSA-N [(2r)-2-[(3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)C1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-BFWOXRRGSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical class CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001341 hydroxy propyl starch Substances 0.000 description 1
- 229940050526 hydroxyethylstarch Drugs 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000013828 hydroxypropyl starch Nutrition 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920001308 poly(aminoacid) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229940113165 trimethylolpropane Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/14—Stretch-spinning methods with flowing liquid or gaseous stretching media, e.g. solution-blowing
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/724—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged forming webs during fibre formation, e.g. flash-spinning
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to the use of a parent solution (A) in the method for producing fibres for a nonwoven fabric by means of solution blow spinning. Water is used as the solvent for the parent solution (A). At least one water-soluble polymer and preferably precisely one water-soluble polymer is dissolved in the water of the parent solution (A). The parent solution (A) also includes at least one surfactant and optionally a plasticizer for the at least one polymer used. Using this parent solution (A) it is possible to produce fibres (24) by solution blow spinning.
Description
prrn Method for producing fibers and non-woven fabrics by solu-tion-blow spinning and non-woven fabric produced thereby [0001] The invention relates to the use of a parent solu-tion for producing fibers, particularly microfibers or sub-microfibers or nanofibers by solution blow spinning as well as such a spinning method for producing fibers and a non-woven fabric produced by the method. The solution blow spin-ning is a spinning method, in which a parent solution exits from at least one output nozzle and is conveyed to a collec-tor, in doing so solid fibers are formed. Accordingly, the fibers are synthetic fibers.
[0002] Different methods exist for producing fibers. For example methods are known during which fibers are produced by pressing of a liquid or semi-liquid mass through openings.
Such methods are referenced as melt or wet or dry spinning methods, depending on how the respective mass was produced or liquefied.
Such methods are referenced as melt or wet or dry spinning methods, depending on how the respective mass was produced or liquefied.
[0003] If particularly fine fibers shall be produced, i.e.
fibers with a small fiber diameter, centrifugal spinning methods as well as the electrostatic spinning or the solution blow spinning are particularly suitable. Such fibers are par-ticularly necessary for manufacturing of filters. The draw-back of the current methods is that usually solutions are used for production of the fibers that are detrimental to the environment and/or incriminating for the health of the work-ing personnel. Also such solutions are often costly. There-fore, for environmental and cost reasons, water is increas-ingly provided as solution (i.e. the use of aqueous solutions of water-soluble polymers) in the afore-mentioned methods.
Water is environmental friendly, non-toxic and cheap.
fibers with a small fiber diameter, centrifugal spinning methods as well as the electrostatic spinning or the solution blow spinning are particularly suitable. Such fibers are par-ticularly necessary for manufacturing of filters. The draw-back of the current methods is that usually solutions are used for production of the fibers that are detrimental to the environment and/or incriminating for the health of the work-ing personnel. Also such solutions are often costly. There-fore, for environmental and cost reasons, water is increas-ingly provided as solution (i.e. the use of aqueous solutions of water-soluble polymers) in the afore-mentioned methods.
Water is environmental friendly, non-toxic and cheap.
[0004] The use of water as solution for spinning methods is already known. For example JP 2010-150712 A shows a method for producing of fibers by electrostatic spinning, in which aqueous solutions of water-soluble polymers are used.
[0005] The electrostatic spinning has a comparable low productivity for principle reasons. As a consequence, the fi-ber production by electrostatic spinning is very expensive.
The electrostatic spinning can be economically used only for the production of fibers that are used in very upscale prod-ucts.
The electrostatic spinning can be economically used only for the production of fibers that are used in very upscale prod-ucts.
[0006] US 8 641 960 Bl describes a solution blow spinning, in which solutions of respective polymers are transferred by means of a process gas stream in solid fibers for producing of very fine polymer fibers. Such a solution blow spinning is of advantage compared with electrostatic spinning, because it allows a productivity that is a hundred to a thousand times higher. However, so far producing fibers with a sufficient or high quality from environmental friendly aqueous solutions by solution blow spinning failed.
[0007] It can be considered as object of the present in-vention to produce fibers and particularly high-grade fibers environmental friendly and efficiently.
[0008] This object is solved by the use of a parent solu-tion in the solution blow spinning with features of claim 1 as well as a method with the features of claim 16.
[0009] According to the invention, the production of fi-bers by means of solution blow spinning uses a parent solu-tion, in which water is used as solvent. At least the portion of water as solvent is in the range of 30% to 99%, preferably 50% to 95% and further preferably 60% to 90%. At least one and preferably exactly one water-soluble polymer is dissolved in the solvent. Additionally the parent solution comprises at least one tenside. The tenside is a surface-active substance that can also be referred to as surfactant.
[0010] It has turned out that due to the use of the de-scribed parent solution, the production of qualitative good and/or high-grade fibers having a substantially constant fi-ber diameter can be achieved. The fibers can be produced as microfibers, sub-microfibers or nanofibers, i.e. with a fiber diameter in the micrometer range or sub-micrometer range or nanometer range by solution blow spinning. Thereby the se-quence in which the added agents are dissolved in the solvent is not of particular importance. The composition of the par-ent solution is significant.
[0011] During solution blow spinning one or more fluid jets are created without atomizing the liquid into spray. The liquid jets exit through a nozzle and are stretched by a pro-cess gas, particularly pressurized air. In doing so, fibers are created. The liquid jets are preferably substantially orientated parallel with each other.
[0012] The created fibers are comprised preferably a ratio of length to a mean thickness of at least 100:1, preferably at least 500:1, preferably at least 1000:1 and further pref-erably at least 10000:1. Preferably the fibers have a length of at least 1 mm, preferably of at least 3 ram and further preferably of at least 5 mm.
[0013] It is advantageous, if exclusively water is used as solvent in the parent solution. The at least one water-soluble polymer and the at least one surfactant respectively are not considered as solvents.
[0014] It is advantageous, if the parent solution compris-es exclusively water-soluble polymers. Other polymers that are not water-soluble are contained in the parent solution.
At least one of the contained water-soluble polymers in the parent solution can be polyvinyl alcohol and/or polyvinyl me-thyl ether and/or polyethylene oxide and/or polyvinyl pyrrol-idone and/or polyethylene glycol and/or polyacrylic acid and/or polyacrylamide.
At least one of the contained water-soluble polymers in the parent solution can be polyvinyl alcohol and/or polyvinyl me-thyl ether and/or polyethylene oxide and/or polyvinyl pyrrol-idone and/or polyethylene glycol and/or polyacrylic acid and/or polyacrylamide.
[0015] It is advantageous, if the concentration of water in the parent solution is in the range of 30 wt-% to 99 wt-%, preferably from 50 wt-% to 95 wt-% further preferably from 60 wt-% to 90 wt-%.
[0016] The at least one water-soluble polymer can be se-lected from known polymers or polymer groups. The following list contains a non-exclusive listing of usable water-soluble polymers:
- cellulose derivatives, like methyl cellulose, sodium carboxymethyl cellulose, hydroxymethyl cellulose, hy-droxypropyl cellulose, hydroxypropylmethyl cellulose;
- natural rubbers like gelatin, metal alginates (Na, K, Ca, Zn, Al), Agar;
- starch derivatives like hydroxyethyl starch ether, hydroxypropyl starch;
- dextran, hydroxyalkyl dextran, carboxyl lower alkyl dextran;
- water-soluble polysaccharides like xanthan, pullulan, ulvan;
- polyamino acids with a free carboxyl group like as-partic acid or glutamic acid;
- polyalkylene glycol like polyethylene glycol and pol-ypropylene glycol;
- synthetic derivatives of polyethylene oxide, polyvi-nyl alcohol, polyvinyl methyl ether, polyvinyl pyr-rolidone, polyallyl- and diallylamines, polydimethyl-aminoethyl dimethacrylat, polyacylic acid, polysty-rene sulfonates, polyacrylamide, neutralized carbopol rubber and copolymers and mixtures of the named poly-mers.
- cellulose derivatives, like methyl cellulose, sodium carboxymethyl cellulose, hydroxymethyl cellulose, hy-droxypropyl cellulose, hydroxypropylmethyl cellulose;
- natural rubbers like gelatin, metal alginates (Na, K, Ca, Zn, Al), Agar;
- starch derivatives like hydroxyethyl starch ether, hydroxypropyl starch;
- dextran, hydroxyalkyl dextran, carboxyl lower alkyl dextran;
- water-soluble polysaccharides like xanthan, pullulan, ulvan;
- polyamino acids with a free carboxyl group like as-partic acid or glutamic acid;
- polyalkylene glycol like polyethylene glycol and pol-ypropylene glycol;
- synthetic derivatives of polyethylene oxide, polyvi-nyl alcohol, polyvinyl methyl ether, polyvinyl pyr-rolidone, polyallyl- and diallylamines, polydimethyl-aminoethyl dimethacrylat, polyacylic acid, polysty-rene sulfonates, polyacrylamide, neutralized carbopol rubber and copolymers and mixtures of the named poly-mers.
[0017] In the parent solution can be contained exactly one or more of the named polymers.
[0018] Also copolymers or mixtures of the above-mentioned polymers can be used.
[0019] In the parent solution plasticizers can be con-tained for the present at least one polymer, like for example polyethylene glycol, polypropylene glycol, glycerine, trime-thylolpropane, di-/tripropylene glycol or chemical composi-tions related therewith. When the concentration in the parent solution is determined, the plasticizers are added to the polymer portion and not to the solvent portion or the surfac-tant.
[0020] The concentration of the at least one water-soluble polymer in the parent solution is preferably in the range of 1 wt-% to 70 wt-%, preferably in the range of 5 wt-% to 50 wt-% and further preferably in the range of 10 wt-% to 40 wt-% including an optionally present plasticizer. The indicated concentration applies, if only one water-soluble polymer is present in the parent solution as well as for parent solu-tions with a plurality of water-soluble polymers.
[0021] In a preferred embodiment the parent solution com-prises exactly one water-soluble polymer that can be complet-ed with a suitable plasticizer for the used polymer.
[0022] It is further preferred, if the concentration of the at least one surfactant in the parent solution is in the range of 0.001 wt-% to 50 wt-% and further preferably in the range of 0,01 wt-% to 5 wt-% and further preferably in the range of 0.1 wt-% to 1.5 wt-%. It is preferred, if exactly one surfactant is contained in the parent solution.
[0023] It is preferred, if a tenside is used that evapo-rates during the solution blow spinning substantially or com-pletely. Thus, no or only minor residuals of the surfactant remain in the produced fibers. In doing so, it is avoided that residuals of the surfactant lead to a negative impact of the mechanical properties and/or the chemical resistance of the produced fibers. Further, surfactant residuals can be disadvantageous for medical applications.
[0024] For the parent solution A any surfactant can be used that is indicated in the table below. In the table the trade name of the surfactant and indications of its composi-tion are indicated respectively.
Name of surfactant Composition Abil Silicone-based surfactants Aerosol Mostly sulfosuccinates Aerosol OT (AOT) Sodium dioctylsulfosuccinate Akypo Mostly alkyl ether carboxylates Alkamide Alkanolamides Amiet Ethoxylated amines and amides Ammonyx Amine oxides Ampholak Amphoterics Arlacel Fatty acid esters and ethoxylated fatty acid esters Arlatone Ethoxylated fatty acid esters Armeen Fatty amines Atlas Mostly ethoxylated compositions Atlox Surfactants and surfactant mixtures for pesticide formulations Berol Various, mostly ethoxylated compositions Biodac Ethoxylated C10 alcohol Brij Ethoxylated fatty alcohols Britex Ethoxylated fatty alcohols Calgene Various ester surfactants Chemal Ethoxylated fatty alcohols Chemax Various ethoxylated compositions Chimipal Alkanolamides and various ethoxylated com-positions Cithrol A, ML, MO Ethoxylated fatty acids und MS
Cithrol, others Glycol and glycerol ethers Crodamine Amine oxides Crodet Ethoxylated fatty acids Dehydol Ethoxylated fatty alcohols Dehydrophen Ethoxylated alkylphenols Dehypon Ethoxylated fatty alcohols, special, e.g.
end-blocked Dobanol Ethoxylated fatty alcohols Dowfax Diphenyloxide-based sulfonates Elfan Various sulfates and sulfonates Emal Sulfates of alcohols and ethoxylated alco-hols Emcol Various contents Empicol Sulfates of alcohols and ethoxylated alco-hols, alkyl ether carboxylates Empilan Alkanolamides and various ethoxylated com-positions Empimin Sulfates and sulfosuccinates Emulan Various ethoxylated compositions Emulgante Ethoxylated C16-C18 alcohols Emulson Various contents Ethylan Mostly ethoxylated compositions Eumulgin Various ethoxylated compositions Findet Various ethoxylated compositions Fluorad Fluorocarbon-based surfactants Genapol Ethoxylated fatty alcohols Geropon Mostly sulfosuccinates and taurates Glucopon Sugar-based surfactants Hamposyl N-Acylsarcosinates Hostapur Alpha olefin sulfonates and petroleum sul-fonates Iconol Various ethoxylated compositions Igepal Various ethoxylated compositions Imbentin Ethoxylated alkylphenols Lialet Ethoxylated fatty alcohols Lipolan Alpha olefin sulfonates Lorodac Ethoxylated fatty alcohols Lutensol Various ethoxylated compositions Mackam Amphoterics Macol Various ethoxylated compositions Manro Sulfates, sulfonates and alkanolamides Marlipal Ethoxylated fatty alcohols Marlophen NP Ethoxylated nonylphenol Miranol Imidazolines Mirataine Betaines Monamid Alkanolamides Montane Sorbitan derivatives Myverol Monoglycerides Neodol Ethoxylated fatty alcohols Newcol Various contents Nikkol Various contents Ninol Alkanolamides Nissan Nonion Various ethoxylated compositions Trydet Ethoxylated fatty acids and ester Trylon Ethoxylated fatty alcohols and oils Tween Ethoxylated sorbitan Ufarol Alkylbenzene sulfonates and sulfates of fatty alcohols and ethoxylated fatty alco-hols Ufaryl Alkylbenzene sulfonates Ufasan Alkylbenzene sulfonates Ungerol Sulfates of ethoxylated fatty alcohols Varamide Alkanolamides Variquat Quaternary ammonium surfactants Volpo Ethoxylated fatty alcohols Witcamide Alkanolamides Witconate Alkylaryl sulfonates Witconol Glycol and glycerol esters Ninol Alkanolamides Nissan Nonion Various ethoxylated compositions
Name of surfactant Composition Abil Silicone-based surfactants Aerosol Mostly sulfosuccinates Aerosol OT (AOT) Sodium dioctylsulfosuccinate Akypo Mostly alkyl ether carboxylates Alkamide Alkanolamides Amiet Ethoxylated amines and amides Ammonyx Amine oxides Ampholak Amphoterics Arlacel Fatty acid esters and ethoxylated fatty acid esters Arlatone Ethoxylated fatty acid esters Armeen Fatty amines Atlas Mostly ethoxylated compositions Atlox Surfactants and surfactant mixtures for pesticide formulations Berol Various, mostly ethoxylated compositions Biodac Ethoxylated C10 alcohol Brij Ethoxylated fatty alcohols Britex Ethoxylated fatty alcohols Calgene Various ester surfactants Chemal Ethoxylated fatty alcohols Chemax Various ethoxylated compositions Chimipal Alkanolamides and various ethoxylated com-positions Cithrol A, ML, MO Ethoxylated fatty acids und MS
Cithrol, others Glycol and glycerol ethers Crodamine Amine oxides Crodet Ethoxylated fatty acids Dehydol Ethoxylated fatty alcohols Dehydrophen Ethoxylated alkylphenols Dehypon Ethoxylated fatty alcohols, special, e.g.
end-blocked Dobanol Ethoxylated fatty alcohols Dowfax Diphenyloxide-based sulfonates Elfan Various sulfates and sulfonates Emal Sulfates of alcohols and ethoxylated alco-hols Emcol Various contents Empicol Sulfates of alcohols and ethoxylated alco-hols, alkyl ether carboxylates Empilan Alkanolamides and various ethoxylated com-positions Empimin Sulfates and sulfosuccinates Emulan Various ethoxylated compositions Emulgante Ethoxylated C16-C18 alcohols Emulson Various contents Ethylan Mostly ethoxylated compositions Eumulgin Various ethoxylated compositions Findet Various ethoxylated compositions Fluorad Fluorocarbon-based surfactants Genapol Ethoxylated fatty alcohols Geropon Mostly sulfosuccinates and taurates Glucopon Sugar-based surfactants Hamposyl N-Acylsarcosinates Hostapur Alpha olefin sulfonates and petroleum sul-fonates Iconol Various ethoxylated compositions Igepal Various ethoxylated compositions Imbentin Ethoxylated alkylphenols Lialet Ethoxylated fatty alcohols Lipolan Alpha olefin sulfonates Lorodac Ethoxylated fatty alcohols Lutensol Various ethoxylated compositions Mackam Amphoterics Macol Various ethoxylated compositions Manro Sulfates, sulfonates and alkanolamides Marlipal Ethoxylated fatty alcohols Marlophen NP Ethoxylated nonylphenol Miranol Imidazolines Mirataine Betaines Monamid Alkanolamides Montane Sorbitan derivatives Myverol Monoglycerides Neodol Ethoxylated fatty alcohols Newcol Various contents Nikkol Various contents Ninol Alkanolamides Nissan Nonion Various ethoxylated compositions Trydet Ethoxylated fatty acids and ester Trylon Ethoxylated fatty alcohols and oils Tween Ethoxylated sorbitan Ufarol Alkylbenzene sulfonates and sulfates of fatty alcohols and ethoxylated fatty alco-hols Ufaryl Alkylbenzene sulfonates Ufasan Alkylbenzene sulfonates Ungerol Sulfates of ethoxylated fatty alcohols Varamide Alkanolamides Variquat Quaternary ammonium surfactants Volpo Ethoxylated fatty alcohols Witcamide Alkanolamides Witconate Alkylaryl sulfonates Witconol Glycol and glycerol esters Ninol Alkanolamides Nissan Nonion Various ethoxylated compositions
[0025] In one embodiment the parent solution can contain solid particles, e.g. organic and/or inorganic solid parti-cles like SiO2 TiO2, ZrO2, CuO, ZnO or Ag, preferably with particle diameters that are smaller than the mean fiber diam-eter.
[0026] Preferably the parent solution no additional compo-nents to the solvent, to the at least one polymer, to the surfactant and to an optionally present plasticizer and to optionally present solid particles.
[0027] During solution blow spinning the parent solution emanates from at least one first output nozzle of a device.
Concurrently a process gas emanates from at least one second output nozzle. At least one second output nozzle is assigned to each first output nozzle. The emanating process gas exits with high velocity. In doing so, the parent solution exiting the first output opening is taken or carried by the process gas.
Concurrently a process gas emanates from at least one second output nozzle. At least one second output nozzle is assigned to each first output nozzle. The emanating process gas exits with high velocity. In doing so, the parent solution exiting the first output opening is taken or carried by the process gas.
[0028] Preferably the process gas is supplied under a pressure of 0.1 to 1000 psi, preferably from 5 to 80 psi and further preferably 10 to 60 psi to the at least one second output nozzle.
[0029] In one embodiment air or pressurized air can be used as process gas. The air can be supplied under a pressure of 10 to 80 psi to the at least one second output nozzle.
[0030] The parent solution can be supplied to the at least one first output nozzle by a pump device. A metering pump, e.g. a gear pump, an eccentric spiral pump, a reciprocating piston pump, a hose pump, a diaphragm pump or another dis-placement pump can be used as pump device.
[0031] Exactly one second output nozzle can be assigned to each first output nozzle. In such an embodiment the second output nozzle can surround the first output nozzle partly or completely, preferably ring-shaped. In a different embodiment at least two second output nozzles are assigned to each first output nozzle. The second output nozzles can be arranged uni-formly distributed around the parameter of the first output nozzles. Also linear arrangements of the output nozzles can he used.
[0032] The output direction that is defined by the at least one first output nozzle and the output direction that is defined by the assigned at least one second output nozzle can be orientated parallel to each other. Alternatively, it is also possible that the output direction of the at least one second output nozzle is inclined relative to the output direction of the assigned at least one first output nozzle.
[0033] Due to the exiting process gas, a liquid jet of the parent solution is formed at least in a distance of some mil-limeters, e.g. of 0 to 100 mm or 0.5 to 20 mm or 1 to 5 mm.
This liquid jet is carried or transported by the process gas.
During the transport of the parent solution in the direction toward a collector, a contained solvent and/or the contained surfactant vaporizes preferably substantially completely, at least to 85% or at least to 90% or at least to 95% or at least to 99%. In doing so, the polymer contained in the par-ent solution solidifies, that is no longer dissolved in the solvent. Solvent fibers created thereby are collected on the collector.
This liquid jet is carried or transported by the process gas.
During the transport of the parent solution in the direction toward a collector, a contained solvent and/or the contained surfactant vaporizes preferably substantially completely, at least to 85% or at least to 90% or at least to 95% or at least to 99%. In doing so, the polymer contained in the par-ent solution solidifies, that is no longer dissolved in the solvent. Solvent fibers created thereby are collected on the collector.
[0034] The nozzle collector distance of the at least one output nozzle to the collector has preferably an amount of at least 20 cm and further preferably of at least 25 cm. In one embodiment the nozzle collector distance can have an amount of about 30 to 70 cm. Preferably, the nozzle collector dis-tance is smaller than 200 cm and further preferably smaller than 100 cm.
[0035] It is preferred that the boiling point of the sol-vent and/or the surfactant is thus small that the solvent and/or the surfactant evaporates after exiting from the at least one first nozzle.
[0036] The process gas may have a focusing and/or concen-trating effect onto the exiting solution. The formation of a fluid jet of the exiting parent solution can be influenced by selection of process parameters, e.g. the composition of the parent solution and/or the temperature of the parent solution and/or the temperature of the process gas and/or the environ-ment temperature and/or the temperature of the output nozzle arrangement and/or the velocity of the process gas and/or the chemical composition of the used process gas and/or a suction power of a suction device arranged at the collector.
[0037] The fiber diameter of the produced fibers has typi-cally an amount of one twentieth to one thousandth of the opening diameter of the at least one first output opening.
The fiber diameter is smaller than the diameter of the fluid jet exiting the at least one first output opening. A reduc-tion of the fiber diameter relative to the diameter of the exiting fluid jet can be achieved and set by process parame-ters, e.g. the velocity of the exiting process gas. If, for example, the exiting velocity of the process gas is in-creased, the liquid jet is so to speak stretched along its path such that its diameter is reduced. Additionally, the solvent and/or surfactant is evaporated such that the liquid volume is reduced after exiting from the at least one first output nozzle.
The fiber diameter is smaller than the diameter of the fluid jet exiting the at least one first output opening. A reduc-tion of the fiber diameter relative to the diameter of the exiting fluid jet can be achieved and set by process parame-ters, e.g. the velocity of the exiting process gas. If, for example, the exiting velocity of the process gas is in-creased, the liquid jet is so to speak stretched along its path such that its diameter is reduced. Additionally, the solvent and/or surfactant is evaporated such that the liquid volume is reduced after exiting from the at least one first output nozzle.
[0038] Using the solution blow spinning it is for example possible to produce fibers in the micrometer or sub-micrometer or nanometer range with diameters of the at least one first output nozzle of, e.g. 0.2 to 1 mm. In one embodi-ment the produced fibers have a mean diameter of about 50 na-nometers to 3 micrometers.
[0039] The process gas can be supplied to the at least one second output nozzle (21) with a temperature of 0 C to 100 C, preferably 10 C to 90 C and further preferably 20 C to 80 C.
[0040] After the production of the fibers it can be advan-tageous, if a post-treatment of the fibers is performed, e.g.
by irradiation with an energy ridge radiation like UV light and/or a heat treatment and/or a plasma/corona treatment and/or a chemical treatment and/or another treatment for cross-linking. Due to such a post-treatment, it is possible to obtain fibers that are not water-soluble. Such a post-treatment can be performed simply and cheaply.
by irradiation with an energy ridge radiation like UV light and/or a heat treatment and/or a plasma/corona treatment and/or a chemical treatment and/or another treatment for cross-linking. Due to such a post-treatment, it is possible to obtain fibers that are not water-soluble. Such a post-treatment can be performed simply and cheaply.
[0041] All of the ranges indicated in the description ("from_ to _") have to be apprehended as including the indi-cated range limit as long as not indicated otherwise.
[0042] Preferred embodiments of the invention result from the dependent claims, the description and the drawings. In the following preferred embodiments of the invention are ex-plained in detail with reference to the attached drawings.
The drawings show:
The drawings show:
[0043] Figure 1 a schematic diagram-like illustration of a device for producing fibers by solution blow spinning,
[0044] Figures 2 and 3 a schematic principle illustration of different output nozzle arrangements respectively, each having a first output nozzle and at least one assigned second output nozzle in a top view on the output nozzles,
[0045] Figures 4 and 5 a schematic principle illustration of different linear output nozzle arrangements of a plurality of first and second output nozzles in a top view onto the output nozzles,
[0046] Figures 6 and 7 a schematic cross-section view of an embodiment of an output nozzle arrangement, each having at least one first output nozzle and at least one assigned sec-ond output nozzle respectively and
[0047] Figure 8 a highly schematic illustration of an em-bodiment of a produced fiber.
[0048] Figure 1 shows a device 10 for the execution of a solution blow spinning method. The device 10 has a reservoir 11 for providing a parent solution A. A parent solution A is conveyed by a pump device 12 to a solution fluid connection 13 of a spin nozzle device 14.
[0049] Additionally, the spin nozzle device 14 comprises a process gas connection 15 by means of which a pressurized process gas G is supplied to the spin nozzle device 14. The process gas G can be formed by air or pressurized air for ex-ample. It can be extracted from a pressure reservoir 16. Al-ternatively, instead of the pressure reservoir 16 a compres-sor or the like can be present in order to draw air from the environment and to provide pressurized air as process gas G.
The process gas G can also be a different gas, like nitrogen, helium or hydrogen.
The process gas G can also be a different gas, like nitrogen, helium or hydrogen.
[0050] The spin nozzle device 14 has at least one first output nozzle 20. At least one second output nozzle 21 is as-signed to each first output nozzle 20. If a plurality of first output nozzles 20 is present, they can have exit or emission directions that are orientated differently, as sche-matically illustrated in figure 1.
[0051] The at least one first output nozzle 20 is fluidi-cally connected with the solution fluid connection 13. The at least one second output nozzle 21 is fluidically connected with the process gas connection 15. Thus, the parent solution A exits through the at least one first output nozzle 20 and the process gas G exits through the at least one second out-put nozzle 21.
[0052] The process gas G exiting concurrently with the parent solution A carries the parent solution A and conveys it from the spin nozzle device 14 away in direction toward a collector 22. Due to the high velocity of the process gas G, one or more liquid jets 23 of the parent solution A are formed above the mouth of the respective first output nozzle 20. During the further path toward the collector 22, a sol-vent contained in the parent solution A and where applicable additional liquid components of the parent solution A evapo-rate, such that solid fibers 24 are formed that are collected at the collector 22.
[0053] The collector 22 can have moveable parts, e.g. a moving conveyor that is moved via drive rolls 25. In a modi-fication compared with the illustrated embodiment, the col-lector 22 can also be formed immovably, statically.
[0054] The collector 22 is preferably gas permeable and can be formed, for example, by a grid or mesh-shaped carrier like a fine-meshed net. At the side opposite the spin nozzle device 14 of the collector 22 a suction device 26 can be pre-sent. The suction device 26 can be configured to move the fi-bers 24 forming between the spin nozzle device 14 and the collector 22 toward the collector 22 by drawing of an air stream.
[0055] The nozzle collector distance z between the at least one first output nozzle 20 and the collector 22 and/or between the at least one second output nozzle 21 and the col-lector 22 has an amount of 20 cm or 25 cm. In the illustrated embodiment the nozzle collector distance z can have an amount of about 30 to 70 cm. Preferably the nozzle collector dis-tance z is smaller than 200 cm and further preferably smaller than 100 cm.
[0056] In Figures 2 to 7 different embodiments of an out-put nozzle arrangement 30 of the spin nozzle device 14 are schematically illustrated as an example respectively. The spin nozzle device 14 can comprise one or more of the illus-trated output nozzle arrangements 30. These can be arranged or orientated parallel or inclined with each other at the spin nozzle device 14. Each output nozzle arrangement 30 com-prises at least one and, for example, exactly one first out-put nozzle 20 for the parent solution A and at least one as-signed second output nozzle 21 for the process gas G.
[0057] In the embodiment illustrated in figure 2 the noz-zle arrangement 30 contains exactly one first output nozzle 20 and exactly one assigned second output nozzle 21. The first output nozzle 20 is arranged in the center of a com-pletely ring-shaped second output nozzle 21 that surrounds the first output nozzle 20 coaxially completely in the embod-iment.
[0058] In the embodiment shown in figure 3 the output noz-zle group 30 comprises exactly one first output nozzle 20 and a plurality of assigned second output nozzles 21 arranged ad-jacent thereto, e.g. four second output nozzles 21. The num-ber of the second output nozzles 21 can vary, wherein at least two second output nozzles 21 are present. The second output nozzles 21 are preferably uniformly distributed in the peripheral direction around the first output nozzle 20. The second output nozzles can also have a curved slit form and partly surround the first output nozzle 20 in its peripheral direction.
[0059] In general a cross-section form of the output noz-zles 20, 21 can be selected arbitrarily. According to the em-bodiment, circular or circular ring-shaped cross-sections are illustrated respectively. Also other polygonal or slit-like straight or curved cross-section contours can be provided, particularly for the at least one second output nozzle 21 of each output nozzle group 30.
[0060] Figures 4 and 5 show only by way of example that the output nozzles 20, 21 can be arranged in one or more rows side-by-side in a linear arrangement.
[0061] Figures 6 and 7 illustrate that the dashed dotted illustrated center length axis of the output nozzles 20, 21 of one output nozzle group 30 can be orientated parallel with each other (figure 6) or alternatively can be orientated in-clined with regard to each other (figure 7). In the embodi-ment that is schematically shown in figure 7, the exit direc-tion for the process gas G of the at least one second output nozzle 21 is inclined compared with the exit direction of the parent solution A, according to the example, such that the process gas G is orientated obliquely to the center length axis or the exit direction of the first output nozzle 20 at several circumferential locations.
[0062] The mouth of the at least one first output nozzle 20 is arranged with distance and preferably downstream of the process gas stream from the mouth of the at least one as-signed second output nozzle 21. The distance can have an amount of, e.g. 0.5 to 20 mm or 1 to 10 mm or 1 to 5 mm or 2 to 3 mm.
[0063] The orientations of the exit directions according to figures 6 and 7 can be provided for the output nozzle group 30 of figure 2 as well as for the output nozzle group 30 of figure 3.
[0064] For formation of the parent solution A at least one and preferably exactly one water-soluble polymer from which the fibers 24 shall be formed, is dissolved in a solvent and according to the example in water. The parent solution addi-tionally contains at least one surfactant. Also for the at least one polymer of the parent solution A a plasticizer can be contained in the parent solution A. The polymer can be dissolved in solid form, e.g. as powder, in form of small balls or pellets or the like in the water of the parent solu-tion A that serves as solvent.
[0065] The concentration of the at least one water-soluble polymer in the parent solution A can have an amount of 1 wt-%
to 70 wt-%, preferably 5 wt-% to 50 wt-%, further preferably wt-% to 40 wt-%. If a plasticizer is used for the at least one polymer, the values of the concentration refer to the to-tal sum of the at least one polymer including the plasticiz-er.
to 70 wt-%, preferably 5 wt-% to 50 wt-%, further preferably wt-% to 40 wt-%. If a plasticizer is used for the at least one polymer, the values of the concentration refer to the to-tal sum of the at least one polymer including the plasticiz-er.
[0066] In preferred embodiments the concentration of the water and the parent solution has an amount of 30 wt-% to 99 wt-%, preferably 50 wt-% to 95 wt-% and further preferably 60 wt-% to 90 wt-%.
[0067] In the embodiment the concentration of the surfac-tant in the parent solution A has an amount of 0.001 wt-% to 50 wt-%, preferably 0.01% to 5 wt-% and further preferably 0.1 wt-% to 1.5 wt-%.
[0068] The process gas G can be supplied at the process gas connection 13 with a pressure of up to 1000 psi, prefera-bly with a pressure of 5 to 80 psi. If air is used as process gas G, the pressure can be in the range of 10 to 60 psi. The process gas G has a temperature in the range of 0 C to 100 C, preferably 10 C to 90 C and further preferably of 20 C to 80 C when supplied to the spin nozzle device 14. According to the example, the process gas temperature of the process gas G
during supply to the spin nozzle device 14 is higher than the environment temperature, e.g. a room temperature, and can be in the range of 35 C to 70 C.
during supply to the spin nozzle device 14 is higher than the environment temperature, e.g. a room temperature, and can be in the range of 35 C to 70 C.
[0069] The fibers 24 formed by polymer chains are obtained in the method, because the solvent, here water, and/or the at least one surfactant evaporates completely or at least partly on the way between the spin nozzle device 14 and the collec-tor 22. That is the solvent and/or the surfactant evaporate by at least 85% or at least by 90% or at least by 95% or at least by 99%.
[0070] During the method by use of the device 10, the fi-bers 24 are formed. A fiber fleece of fibers 24 is created on the collector 22, wherein preferably the fiber diameter is in the micrometer range, in the sub-micrometer range or in the nanometer range. The fibers 24 consist substantially of the polymer present in the parent solution A optionally addition-ally of the plasticizer used for the at least one polymer.
[0071] The created fibers 24 have preferably a ratio of a length L to a mean thickness D of at least 100:1, preferably at least 500:1, further preferably at least 1000:1 and yet further preferably at least 10000:1. Preferably the fibers 24 have a length L of at least 1 mm, preferably of at least 3 mm and further preferably of at least 5 mm.
[0072] Subsequently, examples 1 to 4 are indicated that describe a possible composition of a parent solution A and features of the device 10.
Example 1:
Example 1:
[0073] For producing the polymer solution 10 wt-% of poly-vinyl alcohol powder (with a molecular weight of 130000 u) are dissolved in distilled water (88 wt-%) and 2 wt-% of the surfactant pdlyoxyethylen(23)1auryl ether (known under the trade name Brij-35) are added. From the polymer solution fine fibers 24 are produced by the solution blow spinning method.
The method is executed by using pressurized air as process gas G that is supplied with a pressure of 10 psi to the at least one second output nozzle 21. The at least one first output nozzle 20 has a diameter of 0.6 mm (at the exit open-ing). The distance between the at least one first output noz-zle 20 and the collector 22 has an amount of 65 cm. The fi-bers produced with this method have a fiber diameter with a diameter in the range of 50 to 400 nm. The mean value of the diameter of the created fibers 24 is at 200 nm.
Example 2:
The method is executed by using pressurized air as process gas G that is supplied with a pressure of 10 psi to the at least one second output nozzle 21. The at least one first output nozzle 20 has a diameter of 0.6 mm (at the exit open-ing). The distance between the at least one first output noz-zle 20 and the collector 22 has an amount of 65 cm. The fi-bers produced with this method have a fiber diameter with a diameter in the range of 50 to 400 nm. The mean value of the diameter of the created fibers 24 is at 200 nm.
Example 2:
[0074] The polymer solution is produced of 12 wt-% polyvi-nyl alcohol (molecular weight 130000 u) that is dissolved in distilled water that is present in the parent solution A with 87 wt-%. The parent solution A comprises 1 wt-% isopropanol.
The method is executed under use of pressurized air as pro-cess gas G that is supplied to the at least one second output nozzle 21 under a pressure of 20 psi. The at least one first output nozzle 20 has a diameter of 0.6 mm (at the exit open-ing). The distance between the at least one first output noz-zle 20 and the collector 22 has an amount of 65 cm. The fi-bers 24 produced with this method have a fiber diameter with a range of 100 to 450 nm. The mean value of the diameter of the created fibers 24 is at 240 nm.
Example 3:
The method is executed under use of pressurized air as pro-cess gas G that is supplied to the at least one second output nozzle 21 under a pressure of 20 psi. The at least one first output nozzle 20 has a diameter of 0.6 mm (at the exit open-ing). The distance between the at least one first output noz-zle 20 and the collector 22 has an amount of 65 cm. The fi-bers 24 produced with this method have a fiber diameter with a range of 100 to 450 nm. The mean value of the diameter of the created fibers 24 is at 240 nm.
Example 3:
[0075] 10 wt-% polyvinyl alcohol (molecular weight 130000 u) and 2 wt--% polyvinyl methyl ether are dissolved in 87 wt-%
water. The parent solution A also contains 1 wt-% isopropa-nol. The method is executed under use of pressurized air as process gas G that is supplied with a pressure of 20 psi to the at least one second output nozzle 21. The at least one first output nozzle 20 has a diameter of 0.8 mm (at the exit opening). The distance between the at least one first output nozzle 20 and the collector 22 has an amount of 65 cm. The fibers 24 produced with this method have a fiber diameter in the range of 100 to 500 nm. The mean value of the diameter of the created fibers 24 is at 250 nm.
Example 4:
water. The parent solution A also contains 1 wt-% isopropa-nol. The method is executed under use of pressurized air as process gas G that is supplied with a pressure of 20 psi to the at least one second output nozzle 21. The at least one first output nozzle 20 has a diameter of 0.8 mm (at the exit opening). The distance between the at least one first output nozzle 20 and the collector 22 has an amount of 65 cm. The fibers 24 produced with this method have a fiber diameter in the range of 100 to 500 nm. The mean value of the diameter of the created fibers 24 is at 250 nm.
Example 4:
[0076] 3 wt-% of polyethylene oxide (molecular weight 600.000 u) are dissolved in 96 wt-% of distilled water. The parent solution A also contains 2 wt-% isopropanol. The meth-od is executed under use of pressurized air as process gas G
that is supplied under a pressure of 40 psi to the at least one second output nozzle 21. The at least one first output nozzle has a diameter of 0.6 mm. The distance between the at least one first output nozzle 20 and the collector 22 has an amount of 65 cm. The fibers 24 produced with this method have a fiber diameter in the range of 100 to 500 nm. The mean val-ue of the diameter of the created fibers 24 is at 250 nm.
that is supplied under a pressure of 40 psi to the at least one second output nozzle 21. The at least one first output nozzle has a diameter of 0.6 mm. The distance between the at least one first output nozzle 20 and the collector 22 has an amount of 65 cm. The fibers 24 produced with this method have a fiber diameter in the range of 100 to 500 nm. The mean val-ue of the diameter of the created fibers 24 is at 250 nm.
[0077] The four examples above or in general the spinning method according to the invention can be further optimized by the use of additional and/or alternative surfactants. For ex-ample, each surfactant and/or polymer can be used that is contained in the tables indicated at the beginning of the de-scription.
[0078] Further specific examples result particularly from the selection of the composition of the components of the parent solution A in the ranges, as indicated in the descrip-tion.
[0079] The features of the device 10 indicated in the ex-amples 1 to 4 can also be used for other compositions of the parent solution A respectively.
[0080] The invention refers to the use of a parent solu-tion A during a method for producing fibers for a fiber fleece by a so-called solution blow spinning. Water is used as solvent for the parent solution A. At least one water-soluble polymer and preferably exactly one water-soluble pol-ymer is dissolved in the water of the parent solution A. The parent solution A additionally contains at least one surfac-tant and optionally plasticizer for the used at least one polymer respectively. By means of a parent solution A it is possible to produce fibers 24 by solution blow spinning envi-ronmental friendly.
Reference list:
device 11 reservoir 12 pump device 13 solution fluid connection 14 spin nozzle device process gas connection 16 pressure reservoir first output nozzle 21 second output nozzle 22 collector 23 liquid jet 24 fiber drive roll 26 suction device output nozzle group A parent solution = thickness of the fiber = process gas length of the fiber = nozzle collector distance
Reference list:
device 11 reservoir 12 pump device 13 solution fluid connection 14 spin nozzle device process gas connection 16 pressure reservoir first output nozzle 21 second output nozzle 22 collector 23 liquid jet 24 fiber drive roll 26 suction device output nozzle group A parent solution = thickness of the fiber = process gas length of the fiber = nozzle collector distance
Claims (25)
1. Use of a parent solution (.lambda.) in a method for producing of fibers and fleece materials (24) by solution blow spin-ning, wherein water is used as solvent for the parent solution (.lambda.), wherein at least one water-soluble polymer is dissolved in the parent solution (.lambda.), and wherein the parent solution (.lambda.) comprises at least one surfactant.
2. Use of the parent solution according to claim 1, charac-terized in that the parent solution (.lambda.) contains exclusively water as solvent.
3. Use of the parent solution according to claim 1 or 2, characterized in that the parent solution (.lambda.) contains exclu-sively polymers that are water-soluble.
4. Use of the parent solution according to any of the pre-ceding claims, characterized in that at least one water-soluble polymer is polyvinyl alcohol and/or polyvinyl methyl ether and/or polyethylene oxide and/or polyvinyl pyrrolidone and/or polyethylene glycol and/or polyacrylic acid and/or polyacrylamide.
5. Use of the parent solution according to any of the pre-ceding claims, characterized in that the concentration of the water in the parent solution (.lambda.) has an amount of 30 wt-% to 99 wt-%.
6. Use of the parent solution according to claim 5, char-acterized in that the concentration of the water in the par-ent solution (.lambda.) has an amount of 50 wt-% to 95 wt-%.
7. Use of the parent solution according to claim 6, charac-terized in that the concentration of water in the parent so-lution (.lambda.) has an amount of 60 wt-% to 90 wt-%.
8. Use of the parent solution according to any of the pre-ceding claims, characterized in that the concentration of the at least one water-soluble polymer in the parent solution (.lambda.) has an amount of 1 wt-% to 70 wt-%.
9. Use of the parent solution according to claim 8, charac-terized in that the concentration of the at least one water-soluble polymer in the parent solution (.lambda.) has an amount of 5 wt-% to 50 wt-%.
10. Use of the parent solution according to claim 8, charac-terized in that the concentration of the at least one water-soluble polymer in the parent solution (.lambda.) has an amount of wt-% to 40 wt-%.
11. Use of the parent solution according to any of the pre-ceding claims, characterized in that the concentration of the at least one surfactant in the parent solution (.lambda.) has an amount of 0.001 wt-% to 50 wt-%.
12. Use of the parent solution according to claim 11, char-acterized in that the concentration of the at least one sur-factant in the parent solution (.lambda.) has an amount of 0.01 wt-%
to 5 wt-%.
to 5 wt-%.
13. Use of the parent solution according to claim 12, char-acterized in that the concentration of the at least one sur-factant in the parent solution (.lambda.) has an amount of 0.1 wt-%
to 1.5 wt-%.
to 1.5 wt-%.
14. Use of the parent solution according to any of the pre-ceding claims, characterized in that the at least one surfac-tant has the characteristic to at least partly evaporate dur-ing the solution blow spinning.
15. Use of the parent solution according to any of the pre-ceding claims, characterized in that the parent solution com-prises solid particles.
16. Method for producing fibers (24) by solution blow spin-ning under use of a parent solution according to any of the preceding claims comprising the following steps:
- Emanating the parent solution (.lambda.) from at least one first output nozzle (20), - Emanating a process gas (G) from at least one second output nozzle (21) that is arranged adjacent to the at least one first output nozzle (20), concurrently with the emanation of the parent solution (.lambda.).
- Emanating the parent solution (.lambda.) from at least one first output nozzle (20), - Emanating a process gas (G) from at least one second output nozzle (21) that is arranged adjacent to the at least one first output nozzle (20), concurrently with the emanation of the parent solution (.lambda.).
17. Method according to claim 16, characterized in that the method is used for producing microfibers and/or sub-microfibers and/or nanofibers and fleece materials formed thereof.
18. Method according to claim 16 or 17, characterized in that the process gas (G) is supplied to the at least one sec-ond output nozzle (21) under a pressure of 0.1 to 100 psi.
19. Method according to claim 18, characterized in that the process gas (G) is supplied to the at least one second output nozzle (21) under a pressure of 5 to 80 psi.
20. Method according to claim 19, characterized in that the process gas (G) is supplied to the at least one second output nozzle (21) under a pressure of 10 to 60 psi.
21. Method according to any of the claims 16 to 20, charac-terized in that the process gas (G) is supplied to the at least one second output nozzle (21), wherein the process gas (G) has a temperature of 0°C to 100°C.
22. Method according to claim 21, characterized in that the process gas is supplied to the at least one second output nozzle (21), wherein the process gas (G) has a temperature of 10°C to 90°C.
23. Method according to claim 21, characterized in that the process gas (C) is supplied to the at least one second output nozzle (21), wherein the process gas (G) has a temperature of 20°C to 80°C.
24. Method according to any of the claims 16 to 23, charac-terized in that the solvent in the parent solution (A) evapo-rates at least partly or mainly after exiting from the at least one first output nozzle (20).
25. Fleece material produced by a method according to any of the claims 16-24.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE102016125182.8 | 2016-12-21 | ||
DE102016125182.8A DE102016125182A1 (en) | 2016-12-21 | 2016-12-21 | Process for producing fibers and nonwovens by solution blow spinning and nonwoven fabric made therewith |
PCT/EP2017/082973 WO2018114645A1 (en) | 2016-12-21 | 2017-12-15 | Method for producing fibres and nonwoven fabrics by solution blow spinning and nonwoven fabric produced thereby |
Publications (1)
Publication Number | Publication Date |
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CA3048069A1 true CA3048069A1 (en) | 2018-06-28 |
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CA3048069A Abandoned CA3048069A1 (en) | 2016-12-21 | 2017-12-15 | Method for producing fibres and non-woven fabrics by solution-blow spinning and non-woven fabric produced thereby |
Country Status (8)
Country | Link |
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US (1) | US20200095706A1 (en) |
EP (1) | EP3559323A1 (en) |
JP (1) | JP2020502383A (en) |
KR (1) | KR20190092568A (en) |
CN (1) | CN110325674A (en) |
CA (1) | CA3048069A1 (en) |
DE (1) | DE102016125182A1 (en) |
WO (1) | WO2018114645A1 (en) |
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CN109537068B (en) * | 2018-12-19 | 2021-08-06 | 上海固甲新材料科技有限公司 | Liquid jet spinning device |
CN110656402A (en) * | 2019-01-21 | 2020-01-07 | 深圳维度新材料有限公司 | Preparation method and equipment of inorganic nano-fiber |
EP3954811A1 (en) | 2020-08-13 | 2022-02-16 | Gelatex Technologies OÜ | Device and method for producing polymer fibers and its uses thereof |
CN112316567B (en) * | 2020-10-19 | 2022-07-22 | 江苏大学 | Nanofiber filter membrane and preparation method and device thereof |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1044615A (en) * | 1974-01-30 | 1978-12-19 | Minnesota Mining And Manufacturing Company | Low pressure drop filter medium |
JPS61231210A (en) * | 1985-04-01 | 1986-10-15 | Toa Nenryo Kogyo Kk | Production of fibrous material of water-soluble resin |
CA2070589C (en) * | 1991-12-19 | 2000-11-28 | Kimberly-Clark Corporation | Method of preparing a nonwoven web of poly (vinyl alcohol) fibers |
US5411693A (en) * | 1994-01-05 | 1995-05-02 | Hercules Incorporated | High speed spinning of multi-component fibers with high hole surface density spinnerettes and high velocity quench |
WO1997009472A1 (en) * | 1995-09-05 | 1997-03-13 | Kuraray Co., Ltd. | Polyvinyl alcohol fibers excellent in resistance to boiling water and process for the production thereof |
DE19609143C1 (en) * | 1996-03-08 | 1997-11-13 | Rhodia Ag Rhone Poulenc | Melt-blown fleece, process for its production and its uses |
CN1170018C (en) * | 2002-01-21 | 2004-10-06 | 中国科学院山西煤炭化学研究所 | Method for preparing aluminium oxide-silicon oxide fibre |
DE50312125D1 (en) * | 2002-04-24 | 2009-12-31 | Polyamide High Performance Gmb | High-strength yarn with profiled filaments |
JP4619947B2 (en) * | 2003-04-22 | 2011-01-26 | 旭化成せんい株式会社 | High strength nonwoven fabric |
US7846374B2 (en) * | 2004-11-05 | 2010-12-07 | E. I. Du Pont De Nemours And Company | Blowing gases in electroblowing process |
JP2006323914A (en) * | 2005-05-18 | 2006-11-30 | Fujifilm Holdings Corp | Manufacturing method of optical information recording medium, and optical information recording medium |
DE102005040000B4 (en) * | 2005-08-23 | 2010-04-01 | Lenzing Ag | Multi-spinneret arrangement and methods with suction and blowing |
ES2787501T3 (en) * | 2005-12-02 | 2020-10-16 | Sunstar Suisse Sa | Biocompatible material featuring a non-woven nano- or microfiber fabric produced by electrospinning process |
CN101235592A (en) * | 2008-03-07 | 2008-08-06 | 吴江市良燕纺织助剂厂 | Terylene FDY nano spinning oil and preparation method thereof |
US20090270566A1 (en) * | 2008-04-23 | 2009-10-29 | Fina Technology, Inc. | Olefin Polymerization Processes and Catalysts for Use Therein |
JP5186671B2 (en) | 2008-12-25 | 2013-04-17 | 国立大学法人信州大学 | Silk protein nanofiber and method for producing the same, silk protein composite nanofiber and method for producing the same |
US8641960B1 (en) | 2009-09-29 | 2014-02-04 | The United States Of America, As Represented By The Secretary Of Agriculture | Solution blow spinning |
WO2012003349A2 (en) * | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Dissolvable fibrous web structure article comprising active agents |
EP2612959B1 (en) * | 2010-08-30 | 2020-01-15 | National University Corporation Okayama University | Nanofiber exerting excellent biodegradability and biocompatibility, and method for producing said nanofiber |
CN102465358B (en) * | 2010-11-19 | 2014-02-19 | 山东鲁阳股份有限公司 | Method for preparing polycrystal mullite fibers |
WO2012109251A2 (en) * | 2011-02-07 | 2012-08-16 | Fiberio Technology Corporation | Apparatuses and methods for the deposition of microfibers and nanofibers on a substrate |
US20120302119A1 (en) * | 2011-04-07 | 2012-11-29 | Eastman Chemical Company | Short cut microfibers |
CN104246047A (en) * | 2012-04-23 | 2014-12-24 | 宝洁公司 | Fibrous structures and methods for making same |
CN102943319A (en) * | 2012-11-27 | 2013-02-27 | 天津工业大学 | Method for preparing silicon carbide and precursor composite fibers |
CN103015039B (en) * | 2012-12-04 | 2015-02-18 | 江苏六鑫洁净新材料有限公司 | Two-component melt-blown automatic mixing system |
ES2541203B1 (en) * | 2014-01-15 | 2016-05-13 | Consejo Superior De Investigaciones Científicas (Csic) | PROCEDURE FOR PROTECTION OF BIOLOGICAL MATERIAL AND THERMOLABABLE COMPOUNDS FOR POSSIBLE INDUSTRIAL APPLICATIONS |
JP6362226B2 (en) * | 2014-04-22 | 2018-07-25 | ザ プロクター アンド ギャンブル カンパニー | Composition in the form of a soluble solid structure |
CN105239186B (en) * | 2015-10-28 | 2017-06-06 | 东华大学 | A kind of water-soluble polyvinyl alcohol fibers and preparation method thereof |
-
2016
- 2016-12-21 DE DE102016125182.8A patent/DE102016125182A1/en not_active Ceased
-
2017
- 2017-12-15 EP EP17835818.0A patent/EP3559323A1/en not_active Withdrawn
- 2017-12-15 WO PCT/EP2017/082973 patent/WO2018114645A1/en active Search and Examination
- 2017-12-15 CN CN201780079125.XA patent/CN110325674A/en active Pending
- 2017-12-15 CA CA3048069A patent/CA3048069A1/en not_active Abandoned
- 2017-12-15 JP JP2019532775A patent/JP2020502383A/en active Pending
- 2017-12-15 KR KR1020197020862A patent/KR20190092568A/en not_active Application Discontinuation
- 2017-12-15 US US16/472,081 patent/US20200095706A1/en not_active Abandoned
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US20200095706A1 (en) | 2020-03-26 |
WO2018114645A1 (en) | 2018-06-28 |
EP3559323A1 (en) | 2019-10-30 |
KR20190092568A (en) | 2019-08-07 |
DE102016125182A1 (en) | 2018-06-21 |
CN110325674A (en) | 2019-10-11 |
JP2020502383A (en) | 2020-01-23 |
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