CA3021696C - In-situ monitoring of flue gas contaminants for fuel cell systems - Google Patents

In-situ monitoring of flue gas contaminants for fuel cell systems Download PDF

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Publication number
CA3021696C
CA3021696C CA3021696A CA3021696A CA3021696C CA 3021696 C CA3021696 C CA 3021696C CA 3021696 A CA3021696 A CA 3021696A CA 3021696 A CA3021696 A CA 3021696A CA 3021696 C CA3021696 C CA 3021696C
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Canada
Prior art keywords
flue gas
fuel cell
contaminants
power production
amount
Prior art date
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Application number
CA3021696A
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English (en)
French (fr)
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CA3021696A1 (en
Inventor
Hossein Ghezel-Ayagh
Stephen Jolly
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Fuelcell Energy Inc
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Fuelcell Energy Inc
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Publication of CA3021696A1 publication Critical patent/CA3021696A1/en
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/30—Controlling by gas-analysis apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444—Concentration; Density
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04664—Failure or abnormal function
    • H01M8/04686—Failure or abnormal function of auxiliary devices, e.g. batteries, capacitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04858—Electric variables
    • H01M8/04895—Current
    • H01M8/0491—Current of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04955—Shut-off or shut-down of fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04992—Processes for controlling fuel cells or fuel cell systems characterised by the implementation of mathematical or computational algorithms, e.g. feedback control loops, fuzzy logic, neural networks or artificial intelligence
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0637—Direct internal reforming at the anode of the fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/14—Fuel cells with fused electrolytes
    • H01M8/144—Fuel cells with fused electrolytes characterised by the electrolyte material
    • H01M8/145—Fuel cells with fused electrolytes characterised by the electrolyte material comprising carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/14—Fuel cells with fused electrolytes
    • H01M2008/147—Fuel cells with molten carbonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/32—Direct CO2 mitigation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Artificial Intelligence (AREA)
  • Computing Systems (AREA)
  • Evolutionary Computation (AREA)
  • Fuzzy Systems (AREA)
  • Medical Informatics (AREA)
  • Software Systems (AREA)
  • Theoretical Computer Science (AREA)
  • Automation & Control Theory (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Fuel Cell (AREA)
CA3021696A 2016-04-22 2017-04-21 In-situ monitoring of flue gas contaminants for fuel cell systems Active CA3021696C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662326505P 2016-04-22 2016-04-22
US62/326,505 2016-04-22
PCT/US2017/028844 WO2017184983A1 (en) 2016-04-22 2017-04-21 In-situ monitoring of flue gas contaminants for fuel cell systems

Publications (2)

Publication Number Publication Date
CA3021696A1 CA3021696A1 (en) 2017-10-26
CA3021696C true CA3021696C (en) 2021-06-15

Family

ID=60117028

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3021696A Active CA3021696C (en) 2016-04-22 2017-04-21 In-situ monitoring of flue gas contaminants for fuel cell systems

Country Status (7)

Country Link
US (1) US11362360B2 (zh)
EP (1) EP3446348B1 (zh)
JP (1) JP6758407B2 (zh)
KR (1) KR102204609B1 (zh)
CN (1) CN109314259B (zh)
CA (1) CA3021696C (zh)
WO (1) WO2017184983A1 (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180335205A1 (en) * 2017-05-17 2018-11-22 Gas Technology Institute Pressurized fluidized bed combustor with fuel cell co2 capture
CN114307569B (zh) * 2021-12-17 2022-09-16 山东国舜建设集团有限公司 一种烟气治理智能运行优化控制系统及方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5505766A (en) * 1994-07-12 1996-04-09 Electric Power Research, Inc. Method for removing pollutants from a combustor flue gas and system for same
US7060382B2 (en) 2003-05-15 2006-06-13 Fuelcell Energy, Inc. Fuel cell system with recycle of anode exhaust gas
US20050123810A1 (en) * 2003-12-09 2005-06-09 Chellappa Balan System and method for co-production of hydrogen and electrical energy
US7396603B2 (en) * 2004-06-03 2008-07-08 Fuelcell Energy, Inc. Integrated high efficiency fossil fuel power plant/fuel cell system with CO2 emissions abatement
WO2006043494A1 (ja) * 2004-10-19 2006-04-27 Central Research Institute Of Electric Power Industry 複合発電設備
US20090214902A1 (en) * 2005-06-15 2009-08-27 Pelman Aaron M Adsorptive Bulk Separation for Upgrading Gas Streams
JP4916138B2 (ja) 2005-07-08 2012-04-11 中国電力株式会社 発電システム
FR2897154B1 (fr) * 2006-02-08 2008-03-07 Airbus France Sas Dispositif pour construire et securiser une trajectoire de vol a basse altitude destinee a etre suivie par un aeronef.
JP2007269615A (ja) 2006-03-31 2007-10-18 Miura Co Ltd 水素生成機およびこれを用いた燃料電池システム
US20070243108A1 (en) * 2006-04-13 2007-10-18 Siemens Power Generation, Inc. Sulfur detector for gaseous fuels
KR100803669B1 (ko) 2007-03-27 2008-02-19 한국과학기술연구원 에탄올을 직접 내부 개질하는 용융탄산염 연료전지용연료극, 그 제조방법, 및 그 연료극을 포함하는 용융탄산염연료전지의 직접 내부 개질 방법
US8999590B2 (en) * 2007-07-25 2015-04-07 Fuelcell Energy, Inc. On-line monitoring assembly for detection of sulfur breakthrough in a desulfurizer assembly and sulfur breakthrough detection method
US7766997B2 (en) 2007-12-21 2010-08-03 Alstom Technology Ltd Method of reducing an amount of mercury in a flue gas
JP5047032B2 (ja) 2008-03-31 2012-10-10 中国電力株式会社 排ガス脱硫方法、排ガス脱硫装置及びこの装置を具備した二酸化炭素回収型燃料電池発電システム
JP5177653B2 (ja) 2008-07-03 2013-04-03 株式会社メガチップス 節電システム
US20130014484A1 (en) 2009-12-21 2013-01-17 Luciano Caprile System and method for separating co2 from combustion exhaust gas by means of mcfc multistacks
US10283793B2 (en) 2011-12-30 2019-05-07 DOOSAN Heavy Industries Construction Co., LTD Combined generation system and method for collecting carbon dioxide for combined generation system
KR101438109B1 (ko) * 2012-12-27 2014-09-04 두산중공업 주식회사 복합발전시스템 및 복합발전시스템의 이산화탄소 포집방법
EP2833455A4 (en) 2012-03-29 2015-04-01 Panasonic Corp FUEL CELL SYSTEM
US20140079615A1 (en) * 2012-09-14 2014-03-20 Mitsubishi Heavy Industries, Ltd. Exhaust gas treatment system and a method of treating exhaust gas
US20140272615A1 (en) 2013-03-15 2014-09-18 Exxonmobil Research And Engineering Company Integrated power generation and carbon capture using fuel cells

Also Published As

Publication number Publication date
JP6758407B2 (ja) 2020-09-23
EP3446348A1 (en) 2019-02-27
CN109314259B (zh) 2021-12-10
EP3446348A4 (en) 2019-05-22
KR102204609B1 (ko) 2021-01-18
US20190157696A1 (en) 2019-05-23
KR20190002533A (ko) 2019-01-08
CN109314259A (zh) 2019-02-05
CA3021696A1 (en) 2017-10-26
WO2017184983A1 (en) 2017-10-26
EP3446348B1 (en) 2023-06-07
US11362360B2 (en) 2022-06-14
JP2019516221A (ja) 2019-06-13

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Effective date: 20181019