CA2879991C - Fiber blends, yarns, fabrics, and garments for arc and flame protection - Google Patents
Fiber blends, yarns, fabrics, and garments for arc and flame protection Download PDFInfo
- Publication number
- CA2879991C CA2879991C CA2879991A CA2879991A CA2879991C CA 2879991 C CA2879991 C CA 2879991C CA 2879991 A CA2879991 A CA 2879991A CA 2879991 A CA2879991 A CA 2879991A CA 2879991 C CA2879991 C CA 2879991C
- Authority
- CA
- Canada
- Prior art keywords
- fiber
- weight percent
- fabric
- aramid
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000835 fiber Substances 0.000 title claims abstract description 179
- 239000004744 fabric Substances 0.000 title claims abstract description 126
- 239000000203 mixture Substances 0.000 title claims abstract description 64
- -1 yarns Substances 0.000 title abstract description 26
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 51
- 229920000297 Rayon Polymers 0.000 claims abstract description 49
- 229920002821 Modacrylic Polymers 0.000 claims abstract description 48
- 239000002964 rayon Substances 0.000 claims abstract description 48
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 16
- 239000001301 oxygen Substances 0.000 claims abstract description 16
- 229920003235 aromatic polyamide Polymers 0.000 claims description 32
- 239000004760 aramid Substances 0.000 claims description 26
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 claims description 4
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 description 21
- 238000000034 method Methods 0.000 description 21
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 17
- 229910052787 antimony Inorganic materials 0.000 description 13
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 12
- 230000001681 protective effect Effects 0.000 description 12
- 229920000433 Lyocell Polymers 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 238000009987 spinning Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229920003043 Cellulose fiber Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000007655 standard test method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 239000002759 woven fabric Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229920000784 Nomex Polymers 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000010042 air jet spinning Methods 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 229910000410 antimony oxide Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000004763 nomex Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000004985 diamines Chemical group 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- 238000005079 FT-Raman Methods 0.000 description 1
- 229920006309 Invista Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000012901 Milli-Q water Substances 0.000 description 1
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 238000003841 Raman measurement Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001462 antimony Chemical class 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QGGZBXOADPVUPN-UHFFFAOYSA-N beta-phenylpropiophenone Natural products C=1C=CC=CC=1C(=O)CCC1=CC=CC=C1 QGGZBXOADPVUPN-UHFFFAOYSA-N 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 231100000647 material safety data sheet Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 1
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000007378 ring spinning Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B17/00—Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
- A62B17/003—Fire-resistant or fire-fighters' clothes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
- D10B2321/101—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Woven Fabrics (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/559,966 | 2012-07-27 | ||
| US13/559,966 US20140026303A1 (en) | 2012-07-27 | 2012-07-27 | Fiber blends, yarns, fabrics, and garments for arc and flame protection |
| PCT/US2013/051921 WO2014018697A1 (en) | 2012-07-27 | 2013-07-25 | Fiber blends, yarns, fabrics, and garments for arc and flame protection |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2879991A1 CA2879991A1 (en) | 2014-01-30 |
| CA2879991C true CA2879991C (en) | 2021-01-12 |
Family
ID=48953447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2879991A Active CA2879991C (en) | 2012-07-27 | 2013-07-25 | Fiber blends, yarns, fabrics, and garments for arc and flame protection |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20140026303A1 (enExample) |
| EP (1) | EP2877620B1 (enExample) |
| JP (1) | JP6140285B2 (enExample) |
| KR (1) | KR102041835B1 (enExample) |
| CN (1) | CN104685118B (enExample) |
| CA (1) | CA2879991C (enExample) |
| WO (1) | WO2014018697A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008027454A1 (en) * | 2006-08-31 | 2008-03-06 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
| JP6158602B2 (ja) * | 2013-06-11 | 2017-07-05 | 帝人株式会社 | 伸縮性難燃布帛および繊維製品 |
| JP6159620B2 (ja) * | 2013-08-21 | 2017-07-05 | 日本ピラー工業株式会社 | グランドパッキン |
| JP6145359B2 (ja) * | 2013-08-21 | 2017-06-07 | 日本ピラー工業株式会社 | グランドパッキン |
| EP3186421B1 (en) * | 2014-08-29 | 2025-03-26 | Southern Mills, Inc. | Flame resistant fabrics having cellulosic filament yarns |
| CN105256444A (zh) * | 2015-09-10 | 2016-01-20 | 康帝雅高档面料（苏州）有限公司 | 阻燃防电弧面料及其制作的防护服 |
| CA2964708A1 (en) * | 2016-04-22 | 2017-10-22 | General Recycled | Protective fabric and process of manufacturing same |
| ES3022205T3 (en) | 2016-06-23 | 2025-05-28 | Southern Mills Inc | Flame resistant fabrics having fibers containing energy absorbing and/or reflecting additives |
| US10253437B2 (en) | 2016-09-01 | 2019-04-09 | E I Du Pont De Nemours And Company | Lightweight fabrics containing carbon-containing aramid fiber blend including modacrylic fiber |
| US9797070B1 (en) * | 2016-09-01 | 2017-10-24 | E I Du Pont De Nemours And Company | Intimate blends of carbon-containing and dyeable fibers |
| CN108166119A (zh) * | 2017-12-27 | 2018-06-15 | 南通谐好安全科技有限公司 | 舒适性防电弧阻燃共混物 |
| NZ766902A (en) * | 2018-02-08 | 2021-07-30 | Southern Mills Inc | Flame resistant fabrics for protection against molten metal splash |
| EP3540106A1 (en) * | 2018-03-14 | 2019-09-18 | Blue Star Denim LLC | Yarn and fabric comprising the yarn |
| JPWO2019194001A1 (ja) * | 2018-04-03 | 2021-03-25 | 帝人株式会社 | 布帛および繊維製品 |
| PT3623509T (pt) * | 2018-09-13 | 2021-07-09 | Chemiefaser Lenzing Ag | Tecido feito de fios retorcidos entrelaçados uns com os outros |
| KR102610650B1 (ko) | 2019-03-28 | 2023-12-05 | 써던 밀즈, 인코포레이티드 | 방염 직물 |
| WO2021085571A1 (ja) * | 2019-11-01 | 2021-05-06 | 旭化成アドバンス株式会社 | 難燃ストレッチ繊維構造物、難燃ストレッチ織編物、難燃ストレッチコアスパンヤーン、及びこれを用いた防護服 |
| US11946173B2 (en) * | 2020-05-20 | 2024-04-02 | Glen Raven, Inc. | Yarns and fabrics including modacrylic fibers |
| CA3190203C (en) | 2020-08-19 | 2024-06-11 | Cevin Brent Smith | Fabric material that is resistant to molten metals |
| US12104291B1 (en) | 2020-12-02 | 2024-10-01 | Kaneka Corporation | Flame-retardant fabric and protective clothing made of the same |
| CA3226759A1 (en) | 2021-08-10 | 2023-02-16 | Robert Self | Flame resistant fabrics |
| US12215442B2 (en) * | 2022-03-30 | 2025-02-04 | Ptw Holdings, Llc | Flame resistant fabric comprising a PTW fiber blend |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3094511A (en) | 1958-11-17 | 1963-06-18 | Du Pont | Wholly aromatic polyamides |
| US3193602A (en) | 1962-08-13 | 1965-07-06 | Monsanto Co | Process for the production of flame retarded acrylic fibers |
| US3354127A (en) | 1966-04-18 | 1967-11-21 | Du Pont | Aromatic copolyamides |
| US3819587A (en) | 1969-05-23 | 1974-06-25 | Du Pont | Wholly aromatic carbocyclic polycarbonamide fiber having orientation angle of less than about 45{20 |
| US3673143A (en) | 1970-06-24 | 1972-06-27 | Du Pont | Optically anisotropic spinning dopes of polycarbonamides |
| US3869429A (en) | 1971-08-17 | 1975-03-04 | Du Pont | High strength polyamide fibers and films |
| US3748302A (en) | 1971-11-17 | 1973-07-24 | Du Pont | Flame-retarded acrylonitrile fibers |
| US3803453A (en) | 1972-07-21 | 1974-04-09 | Du Pont | Synthetic filament having antistatic properties |
| JPS53294A (en) | 1976-06-23 | 1978-01-05 | Teijin Ltd | Preparation of aromatic polyamide with high degree of polymerization |
| US4246221A (en) | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
| US4612150A (en) | 1983-11-28 | 1986-09-16 | E. I. Du Pont De Nemours And Company | Process for combining and codrawing antistatic filaments with undrawn nylon filaments |
| US5208105A (en) | 1984-10-05 | 1993-05-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flame-retarded composite fiber |
| DE3587745T2 (de) | 1984-10-05 | 1994-05-19 | Kanegafuchi Chemical Ind | Flammverzögerndes Fasergemisch. |
| US4668234A (en) | 1985-08-15 | 1987-05-26 | E. I. Du Pont De Nemours And Company | Aromatic polyamide fibers and process for stabilizing such fibers with surfactants |
| US4755335A (en) | 1986-09-12 | 1988-07-05 | E. I. Du Pont De Nemours And Company | Method of improving impregnation of poly (meta-phenylene isophthalamide) fibers |
| US4883496A (en) | 1988-02-14 | 1989-11-28 | E. I. Du Pont De Nemours And Company | Process for dyeing crystalline aromatic polyamide fibers with water-insoluble dyes |
| US5096459A (en) | 1990-09-26 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Method of dyeing aromatic polyamide fibers with water-soluble dyes |
| US20050208855A1 (en) * | 2004-03-18 | 2005-09-22 | Reiyao Zhu | Modacrylic/cotton/aramid fiber blends for arc and flame protection |
| US7348059B2 (en) * | 2004-03-18 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection and reduced shrinkage |
| WO2008027454A1 (en) | 2006-08-31 | 2008-03-06 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
| WO2008114285A1 (en) * | 2007-03-16 | 2008-09-25 | Area 52 S.R.L. | Fire-proof fabric |
| US7744999B2 (en) * | 2008-07-11 | 2010-06-29 | E. I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and arc protection |
| US8069643B2 (en) * | 2009-06-02 | 2011-12-06 | E. I. Du Pont De Nemours And Company | Limited-antimony-content and antimony-free modacrylic / aramid blends for improved flash fire and arc protection |
| US8069642B2 (en) * | 2009-06-02 | 2011-12-06 | E.I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and superior arc protection |
| US8133584B2 (en) * | 2010-04-08 | 2012-03-13 | E.I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for flash fire and arc protection having improved comfort |
| CA2797859A1 (en) * | 2010-04-30 | 2011-11-03 | Drifire, Llc | Fiber blends for garments with high thermal, abrasion resistance, and moisture management properties |
| US20120003472A1 (en) * | 2010-06-30 | 2012-01-05 | Coats American Inc. | Flame-resistant yarn |
| CN101973148B (zh) * | 2010-08-20 | 2014-02-12 | 圣欧芳纶（江苏）股份有限公司 | 一种防电弧织物、制作方法及其应用 |
| US20120102632A1 (en) * | 2010-10-28 | 2012-05-03 | E.I. Du Pont De Nemours And Company | Arc resistant garment containing a multilayer fabric laminate and processes for making same |
| AT511288B1 (de) * | 2010-11-24 | 2013-01-15 | Chemiefaser Lenzing Ag | Flammbeständiger Stoff für Schutzkleidung |
| US9370212B2 (en) * | 2011-09-02 | 2016-06-21 | E I Du Pont De Nemours And Company | Article of thermal protective clothing |
-
2012
- 2012-07-27 US US13/559,966 patent/US20140026303A1/en not_active Abandoned
-
2013
- 2013-07-25 WO PCT/US2013/051921 patent/WO2014018697A1/en not_active Ceased
- 2013-07-25 CN CN201380050612.5A patent/CN104685118B/zh active Active
- 2013-07-25 JP JP2015524434A patent/JP6140285B2/ja active Active
- 2013-07-25 CA CA2879991A patent/CA2879991C/en active Active
- 2013-07-25 EP EP13747913.5A patent/EP2877620B1/en active Active
- 2013-07-25 KR KR1020157002052A patent/KR102041835B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2877620B1 (en) | 2019-05-01 |
| KR20150036204A (ko) | 2015-04-07 |
| US20140026303A1 (en) | 2014-01-30 |
| WO2014018697A1 (en) | 2014-01-30 |
| CN104685118A (zh) | 2015-06-03 |
| JP2015530485A (ja) | 2015-10-15 |
| KR102041835B1 (ko) | 2019-11-08 |
| CA2879991A1 (en) | 2014-01-30 |
| EP2877620A1 (en) | 2015-06-03 |
| JP6140285B2 (ja) | 2017-05-31 |
| CN104685118B (zh) | 2018-04-06 |
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| Date | Code | Title | Description |
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| EEER | Examination request |
Effective date: 20180615 |