CA2869659C - Method and apparatus for reduction of tar in gasification of carbonaceous materials - Google Patents

Method and apparatus for reduction of tar in gasification of carbonaceous materials Download PDF

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Publication number
CA2869659C
CA2869659C CA2869659A CA2869659A CA2869659C CA 2869659 C CA2869659 C CA 2869659C CA 2869659 A CA2869659 A CA 2869659A CA 2869659 A CA2869659 A CA 2869659A CA 2869659 C CA2869659 C CA 2869659C
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CA
Canada
Prior art keywords
char
ash
tar
stage
product gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2869659A
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English (en)
French (fr)
Other versions
CA2869659A1 (en
Inventor
Thomas J. Paskach
Jerod Smeenk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Frontline Bioenergy LLC
Original Assignee
Frontline Bioenergy LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Frontline Bioenergy LLC filed Critical Frontline Bioenergy LLC
Publication of CA2869659A1 publication Critical patent/CA2869659A1/en
Application granted granted Critical
Publication of CA2869659C publication Critical patent/CA2869659C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/08—Continuous processes with ash-removal in liquid state
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/005—Reducing the tar content by partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/008—Reducing the tar content by cracking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628—Ash post-treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628—Ash post-treatment
    • C10J2300/1634—Ash vitrification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2869659A 2012-04-03 2012-04-03 Method and apparatus for reduction of tar in gasification of carbonaceous materials Active CA2869659C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2012/000184 WO2013151522A1 (en) 2012-04-03 2012-04-03 Method and apparatus for reduction of tar in gasification of carbonaceous materials

Publications (2)

Publication Number Publication Date
CA2869659A1 CA2869659A1 (en) 2013-10-10
CA2869659C true CA2869659C (en) 2019-10-08

Family

ID=49300863

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2869659A Active CA2869659C (en) 2012-04-03 2012-04-03 Method and apparatus for reduction of tar in gasification of carbonaceous materials

Country Status (9)

Country Link
US (1) US9353321B2 (enFirst)
EP (1) EP2834328B1 (enFirst)
CN (1) CN104321414B (enFirst)
CA (1) CA2869659C (enFirst)
ES (1) ES2949733T3 (enFirst)
HU (1) HUE063086T2 (enFirst)
IN (1) IN2014MN02174A (enFirst)
PL (1) PL2834328T3 (enFirst)
WO (1) WO2013151522A1 (enFirst)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014152070A1 (en) * 2013-03-14 2014-09-25 Synthesis Energy Systems, Inc. Method and apparatus for recycling ash fines
US10011793B2 (en) * 2013-07-19 2018-07-03 V-GRID Energy Systems Coaxial gasifier for enhanced hydrogen production
AU2014366885B2 (en) * 2013-12-16 2019-05-23 Renergi Pty Ltd Process and apparatus for cleaning raw product gas
CN104711027A (zh) * 2015-03-13 2015-06-17 罗世学 预燃除焦油的煤气制备方法
CN105602623B (zh) * 2015-12-16 2018-08-28 上海理工大学 双级下吸式生物质气化炉
CN105542858B (zh) * 2015-12-21 2018-08-28 上海理工大学 一种低焦油生物质气化发电系统
EP3305876B1 (en) * 2016-10-07 2019-06-05 Meva Energy AB Improved gasification system and method
US11286436B2 (en) * 2019-02-04 2022-03-29 Eastman Chemical Company Feed location for gasification of plastics and solid fossil fuels
WO2021165986A1 (en) * 2020-02-19 2021-08-26 Perumal Raman A gasifier system for power generation from biomass
WO2025054529A1 (en) * 2023-09-07 2025-03-13 Reformed Energy, Inc. Downdraft plasma gasifier

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032305A (en) * 1974-10-07 1977-06-28 Squires Arthur M Treating carbonaceous matter with hot steam
US3971635A (en) * 1974-12-23 1976-07-27 Gulf Oil Corporation Coal gasifier having an elutriated feed stream
US4057402A (en) * 1976-06-28 1977-11-08 Institute Of Gas Technology Coal pretreatment and gasification process
US7955403B2 (en) * 2008-07-16 2011-06-07 Kellogg Brown & Root Llc Systems and methods for producing substitute natural gas
US8460410B2 (en) * 2008-08-15 2013-06-11 Phillips 66 Company Two stage entrained gasification system and process
BRPI1007232A2 (pt) * 2009-01-21 2016-02-16 Rentech Inc "sistemas para produção de gás de síntese de alta qualidade, e para reforma contínua a seco, e, métodos para produzir gás de síntase, para dessulfurização profunda de gás de síntese, e para reforma contínua a seco"
US8580019B2 (en) * 2010-05-14 2013-11-12 Frontline Bioenergy, Llc Apparatus and method of optimized acid gas and toxic metal control in gasifier produced gases
WO2011159352A2 (en) * 2010-06-16 2011-12-22 Frontline Bio Energy,Llc Producing low tar gases in a multi-stage gasifier
CN101906323B (zh) * 2010-08-05 2013-06-19 中国科学院广州能源研究所 一种生物质气化制取低焦油含量可燃气的方法及装置

Also Published As

Publication number Publication date
EP2834328B1 (en) 2023-06-07
CA2869659A1 (en) 2013-10-10
ES2949733T3 (es) 2023-10-02
EP2834328A4 (en) 2015-11-25
PL2834328T3 (pl) 2023-10-02
HUE063086T2 (hu) 2023-12-28
EP2834328A1 (en) 2015-02-11
WO2013151522A1 (en) 2013-10-10
EP2834328C0 (en) 2023-06-07
IN2014MN02174A (enFirst) 2015-08-28
CN104321414A (zh) 2015-01-28
US9353321B2 (en) 2016-05-31
CN104321414B (zh) 2017-10-20
US20150083971A1 (en) 2015-03-26

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