CA2794568C

CA2794568C - Method for forming a fire resistant cellulose product, and associated apparatus

Info

Publication number: CA2794568C
Application number: CA2794568A
Authority: CA
Inventors: Daniel Baroux
Original assignee: BLMH TECHNOLOGIES Inc
Current assignee: BLMH TECHNOLOGIES Inc
Priority date: 2010-03-26
Filing date: 2010-03-26
Publication date: 2014-06-10
Anticipated expiration: 2030-03-26
Also published as: EP2550397A4; CA2794568A1; WO2011116450A1; BR112012024113A2; EP2550397A1; US20130255900A1

Abstract

A method is provided for forming a fire resistant cellulose product. Such a method comprises processing cellulose fibers into a fiber mixture, and forming a slurry from the fiber mixture and a fire-retarding solution, wherein the slurry has the fire-retarding solution substantially uniformly distributed therethrough. The slurry is then formed into a cellulose product. An associated apparatus is also provided.

Description

METHOD FOR FORMING A FIRE RESISTANT CELLULOSE PRODUCT, AND ASSOCIATED A P P ARATUS

BACKGROUND OF THE DISCLOSURE
Field of the Disclosure Aspects of the present disclosure relate to methods for formin`, fire resistant products, and, more particul arrly, to a method for forming a fire resistant cellulose product, and associated apparatuses.

Description of Related Art It may sometimes be desirable for particular products to exhibit resistance to fire. For example, it maybe desirable for paperboard products used in building construction to cxl hit a certain degree of fire resistance. In the case of drywall, which generally comprises a gypsum core with paperboard facing sheets, it is the gypsun' core, and not the paperboard facing sheets, which is relied upon to provide some fire resistance capabilities. How ever, since di all is comprised of tv o different materials, it may be difficult and/or relatively expensive to produce.
Further, the fire resistance capabilities of drywall may not necessarily be enough to make a siuniticant difference in the overall construction of the building.
In some instances, a paperboard product may have a fire-retardant product applied thereto, post-formation, to provide some fire resistance capabilities for the paperboard product.
That is, an exemplary as-formed paperboard product may have a surface treatment, for example, a Iiquid fire retardant, applied thereto in order for the treated product to exhibit at least some fire resistance. In such instances, however, one possible limitation in the treatment of the as-formed paperboard product for fire resistance. particularly ~~ ith a liquid fire retardant, is achieving an even and consistent treatment of that product. ,More particularly, the result of some fire resistance treatment processes involvi ngr application of a liq uici fire-retardant to an as-formed paperboard product may be an uneven or otherwise inconsistent coverage of the fire retardant with respect to the product. In those cases, the uneven treatment may result in ark ing levels of fire resistance of the treated paperboard product which may, in turn, become a hazard in the event of a ti re %%hich the product is intended to retard or other%lise provide some resistance.
Further, such treatment Processes may not necessarily be efficient in terms of applying the fire retardant to the paperboard product, may not include provisions for capturing or recycling excess portions of the ti re retardant product, and may not have the capability for preventing or restricting losses of the fire retardant due, for instance, to ev aporativ e processes Thus, there exists a need for a process and associated apparatus for evenly and consistently applying a fire retardant, particularly a liquid fire retardant, to a cellulose product such as, for example, a paperboard product. In some instances, it may be desirable to form an integral cellulose product having the characteristics of an existing product having two or more discrete components (i e., drywall), while also providing an enhanced level of fire resistance. It may also be desirable, in some instances, to have a paperboard formation process with the capability of capturing excess fire retardant and recycling the captured excess in subsequent cellulose product manufacturing cycles, whether the excess is captured in a liquid form or in other forms, such as vapors.

BRIEF SUMMARY OF THE DISCLOSL RE
The above and other needs are met by aspects of the present disclosure, wherein one such aspect relates to a method of forming a fire resistant cellulose product. Such a method comprises processing; cellulose fibers into a fiber mixture, and forming a slurry from the fiber mixture and a fire-retarding solution, wherein the slur-r-y has the tire-retar-din;g solution substantially uniformly distributed therethrough. The slurry is then formed into a cellulose product.
Another aspect of the present disclosure relates to an apparatus for forming a fire I esistant cellulose product. Such an apparatus comprises a processing device configured process cellulose fibers into a fiber mixture, and a mixing- device configured to forrn a slurry from the fiber mixture and a fire-retarding solution, such that the fire-retarding solution is substantially uniformly distributed therethrough. A forming device is configured to then f'tbr-m the slurry into a cellulose product In particular aspects, the fire-retarding solution may be an aqueous fire-retarding solution. It may be preferred that the fire-retarding solution be nontoxic and/or have a neutral pH and/or be hypoallergenic and/or have any number of otherwise desirable properties. In some aspects, the fire-retarding solution may comprise any one of a boron compound, a borate, an inorganic hydrate, a bromine compound, aluminum hydroxide, magnesium hydroxide, hydromagnesite, antimony trioxide, a phosphonium salt, ammonium phosphate, and diammonium phosphate, or various combinations thereof.
In still further aspects, the processing device may be cone gur-ed to process waste paper and/or waste board, each comprising cellulose fibers, into the fiber mixture.
Further, the mixing device may be configured, for example, to add water to the cellulose fibers to form the slur7ry, and/or to au>itate the slurry so as to substantially uniformly distribute the fire-retarding solution therethrough.
In further aspects, the forming device may be configured to dewater the slurry and to dry the dewatered slurry to fors the cel l ulose product. In doing so, the slurry maybe compressed to forme a densified cellulose product and/or heated to form a dried cellulose product. The forming device may also be configured to dry the slurry to form a substantially planar cellulose product haul na one of a thickness of between about 0.125 inches and about 2 feet, and a width of between about I inch and about 8 feet.
In some instances, the forming device may be configured to engage the slurry with one of a negative die and a positive die, so as to form a cellulose product having a surface defining a negative impression of the one of the negative die and the positive die.
In yet other aspects, the apparatus may also comprise a recovery device configured to recover excess fire-retarding solution, in one of a liquid and a vapor form, upon the forming device forming the slurry into the cellulose product. Further, the recovery device maybe configured to direct the recovered excess fire-retarding solution to the mixing device, for example, in a closed-loop, fire-retarding solution recycling process.
Aspects of the present disclosure thus address the identified needs and provide other advantages as otherwise detailed herein, BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S) Having thus described the disclosure in general terms, reference zw ill now be made to the accompanying drawings., which are not necessarily drawn to scale. and wherein;
FIG. I schematically illustrates an apparatus for forming a fire resistant cellulose product, according; to one aspect of the disclosure; and FIG. 2 schematically illustrates a method of formina fire resistant cellulose product, accorcii n ~! to one aspect of the disclosure.

DETAILED DESCR IPTTON OF THE DISCLOSURE
The present disclosure now will be described more fully hereinafter with reference to the accompanying drawings, i n which some, but not all aspects of the disclosure are shown. Indeed, the disclosure may be embodied in mangy different ~orms and should not be construed as limited to the aspects set forth herein; rather, these aspects are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
Aspects of the present disclosure are generally directed to apparatuses and methods for forming a fire resistant cellulose product. As previously discussed, one possible limitation in the treatment of as-formed cellulose products, such as a paperboard product, for the resistance, particularly with a liquid fire retardant, is achieving an even and consistent treatment of that cellulose product. That is, the result of some fire resistance surface-treatment processes may be an uneven or otherwise inconsistent application of the fire Fetardant to the cellulose product. In those cases. such uneven surface treatment may result in varying levels of fire resistance of the treated cellulose product which may, in turn, become a hazard in the event of a fire which the product is intended to retard or otherwise provide some resistance.
As such, one aspect of the present disclosure involves an apparatus for forming a fire-resistant cellulose product, such an apparatus being= indicated as element 100 in FICA. 1. Such an apparatus 100 may comprise, for example, a processing device 200 configured to process cellulose fibers into a fiber mixture, a mixing de\ ice 500 configured to form a slurry from the fiber mixture and a Pre-retarding solution, such that the f re-retarding solution is substantially uniformly distributed therethrough, and a forming device 400 cont`ureci to form the slurry into a cellulose product.
The processing device 200 may be configured to process cellulose ti bers from one or more sources 150 into a fiber mixture. That is, though aspects of the present disclosure contemplate that the cellulose products may be comprised of recycled cellulose fibers (i.e., from waste paper, 'A aste board, waste paperboard, or any other suitable waste source of cells l ose fibers), one skilled in the art will appreciate that raw, original, or otherwise virgin cellulose fibers may also be used i Ti addition to, in combination ww ith, or instead of the recycled, %\ ante cellulose fibers -Further, in some aspects, the cellulose fibers may not necessarily be required to be free of contaminants, as long as those contaminants can be processed along ww ith the cellulose fibers to form the fiber mixture. For example, where the source of cellulose fibers includes waste pizza boxes, those ;w aste pizza boxes do not necessarily need to be free of pizza components, such as cheese, in order for those pizza boxes to be processed by the processing device 200. As such, a decontamination process may not necessarily be contemplated, but could be incl uded, should there be a need or desire for a contaminant-free cellulose product. In addition, the cellulose fibers do not necessarily need to be dry prior to being processed by the processing device 200.
That is, w:vaste sources of cellulose fibers may be, in some instances, in the form of bales, wherein the hales may often be exposed to the elements (i.e., rain or condensation) prior to being;
introduced to the processing device 200. In those instances, aspects of the present disclosure are also configured to process the "wet" source of cellulose fibers into the fiber rrrixture In this regard, the cellulose fibers may be processed by the processing device 200, regardless of the moisture level present therein, into the fiber nmi.xture. The extent of the processing of the cellulose fibers may vary considerably depending, for example, on the level of refinement (i.e., coarse/ fine) desired of the final cellulose product The processing device 200 maybe any machine suitable for deconstructing the waste cellulose fibers in the manner discussed, wherein one such exemplary machine may be manufactured by Metso Paper, Inc. of Helsinki, Finland.
Once the fiber mixture is produced in the desired state by the processing device 200, the fiber mixture may be directed to the mixing device 300, where the fiber mixture is mixed wwith a fire-retarding solution 250 to forni a slurry 275, and the slurry 275 is mixed such that the fire- solution is substantially uniformly distributed therethrouh In some instances, the 1 fixing device 300 may be configured to add water and/or other appropriate liquid or chemical to the fiber mixture in forming the slurry.

In particular- aspects, the fire-retarding solution 250 may be an aqueous tire-retarding;
solution. It may be preferred that the ti r e-retarding; solution be nontoxic and/or- have a neutral pH and/or be hypoallergenic and/or have any number of otherwise desirable properties affecting hun'an / animal and/or environmental safety, while maintaining the necessary efficacy, as implemented and upon exposure to heat and/or flame. in some aspects, the fi re-retarding solution 250 may comprise any one of a boron compound, a borate, an inorganic hydrate, a bromine compound, alriminum hydroxide, magnesium hydroxide, hydromaunesite, antimony trioxide, a phosphonium salt, ammonium phosphate, and dianimonium phosphate, or various combinations thereof. In this regard, one spilled in the art i\ I]] appreciate that various fire-retardiir or fire resistant substances, either currently known or later developed or discox eyed, may be applicable to the disclosed processes and apparatuses herein within the scope of the present disclosure.
One spilled in the art will further appreciate that the fire-retarding solution may be formed by adding a solid fire-retardant product to a liquid (i.e., water) or other chemical mixed with the fiber mixture such that the solid fire-retardant product forms a solution with the liquid or other chemical comprising the slurry with the fiber mixture. In some instances, the mixing device 300 may be confi Lured to agitate the slurry or pulp mixture, so as to substantially uniforrnl distribute the fire-retarding solution therethrough. The mi'ing device 300 may be any machine suitable for forming the slurry 275 from the fiber mixture and the fire-retardin solution, in the manner discussed, %\ herein one such exemplary machine may be manufactured by Metso Paper, Inc. of Helsinki, Finland.
The forming device 400 is configured to receive the slurry 275 from the mixing device 300 and to form the slurry into a cellulose product 600. In some instances, the forming device 400 may be configured to dewater the slurry, before drying the dewatered slurry to form the cellulose product. Such a dewatering process may be accomplished, for example, by a suitably modified Fourdrinier-type machine, or other appropriate process, as twill be appreciated by one skilled in the art. The slurry may also be dewatered, for instance, using a twin wire forming section and/or appropriate screening de-ices, In other instances, whether dewatered or not, the slurry may be compressed by the forming device 400 to forth a densifed cellulose product and/or heated by the forming device 400 to form a dried cellulose product.
Compression of the slurry may be accomplished, for instance, using a screw press or other suitable press device.
Heat may be applied to the slurry, for example, via heated air (i.e,, heated with combusted natural -as or other suitable fuel source), or through any of a variety of lieatin /dryin methods, such as, for example, microwave or infrared drying techniques, as will be appreciated by one skilled in the art.
One skilled in the art will also appreciate that the forming device 400 may be configured in many different manners. For example, a suitably-configured screen device may be configured to receive the slurry, wherein the screen device may include a number of perforations Once deposited in the screen device, the slurry may be engaged by an opposing platen, which may also be perforated. The perforations may serve to dewater the slurry, while the platen and/or the screen device maybe heated to provide for drying of the devvatered slurry Further, pressure may be applied to the screen device and/or the platen, for example, using a hydraulic or screw-type pressure dev ice, so as to compress the slurry while the slur-i-y is dewwatered and heated. In some desirable aspects, the forming device 400 may also be configured to form the slurry into a substantially planar cellulose product 600 having a thickness of between about 0.125 inches and about 2 feet, and/or a width of between about 1 inch and about 8 feet. One skilled in the art will appreciate, however, that the dimensions of the planar cellulose product may vary considerably.
In still other aspects, the cellulose product 600 may be formed as a sheet having a desired length, or as a continuous sheet that is later subdivided into segments of a desired length. In some instances, the forming device 400 may be configured to engage the slurry with one of a negative die and a positive ciie, so as to form a cellulose product having a surface defining a negative impression of the one of the negative die and the positive die. That is, for example, the screen device and/or the platen may be appropriately patterned ith a raised and/or depressed pattern such that the formed cellulose product \v ill have a corresponding surface defining a negative impression of the pattern. One skilled in the art will also appreciate that the capability of manipulating the slurry i ti this manner indicates that the final form of the cellulose product need not necessarily be in planar form, but may take many different shapes, contours, and sizes in addition to that disclosed herein.
In other aspects, the apparatus 100 may also comprise a recovery device 500 configured to recover excess fire-retarding solution, in one of a liquid and a vapor form, upon the forming device 400 forming the slurry into the cellulose product. In some instances, the recovery device 500 may also be configured to engage the mixing device 300 for accomplishing the recovery of the excess fire-retarding solution, Further, the recovery device 500 may be configured to direct the recovered excess ti re-retarding solution to the mixing device '300, for example, in a closed-loop, fire-retarding solution recycling process. Upon recovery of the excess portions, including iquids and vapors, by the recovery device 500, the recovered excess fire-retarding solution may be strained, filtered, or otherwise purified, and then reintroduced to the mixing device 300 to form subsequent cellulose products, such that the fire-retarding solution is substantially or entirely prevented from leaving the apparatus 100 as a waste product.
In addition, in sonic instances, the as-formed cellulose product may be further processed, for example, to planari ze certai n surfaces thereof, or to remove "broke" or otherwise planarize the edges of the cellulose product. In such instances, the apparatus 100 may also include a collection device (not shown), wherein the collection device may be configured to capture waste solids from the post-formation processing of the cellulose product. In those instances, the captured waste solids may be incorporated into other products (i.e., blown-in insulation) Mille providing fire-resistance properties therefor.
Many modifications and other aspects of the disclosures set forth herein will come to mind to one skilled in the art to which these disclosures pertain having the benefit of the teachings presented in the foregoing descriptions and the associated dram i n;s For example, one skilled in the art that the apparatuses disclosed herein readily lead to associated processes and methods for fonning a fire resistant cellulose product, as shown, for example, in FIG, 2. More particularly., such methods may comprise processing cellulose fibers into a fiber mixture (block 700), and torn' n; a slurry from the fiber mixture and a fire-retarding solution, wwherein the slurry has the fire-retarding solution substantially uniformly distributed therethrough (block 800), and then fonning the slurry into a cellulose product (block 9)0), Further, one skilled in the art will appreciate that, in some aspects, the slurry, clewwatered slurry, and/or cellulose product may be formed as a ggeneral cellulose element that can then be formed, molded, or otherwise manipulated into various end products such as, for example, boards, compounded roofing shingles, compounded roofing shakes, compounded sidewwall shingles, compounded Spanish style "red clay" type roof tiles, electrical outlet encasements, doors, interior wall plankin~, exterior sheathing, cabinetry cores. cupboards, compounded cabinet door faces, flooring, laminated flooring, veneered compounded flooring, or the like.
However, the exemplary end products presented herein are not intended to be limiting in any manner with respect to the wide variety of contemplated end products. Thus, the general cellulose element concept may be extend to instances where the end product may be produced in many different planners such as, for example, by molding, extrusion, pressin,,, stamping, or by any other suitable production method.
Moreover, the general cellulose element concept may be applicable where the general cellulose element is provided as a component or other portion of a further end assembly.
Particularly, as shown in such previous examples as laminated flooring and cored cabinetry, the general cellulose element incorporating the fire retarding solution forms a component of the end assembly. One skilled in the art pill thus appreciate that cellulose products in accordance with aspects of the present disclosure may be produced such that the tire.-retarding solution is dispersed at least partially, if not consistently and uniformly, throughout.
As such, the components of the end assembly comprising the fire-retarded cellulose product may likely be wholly resistant to fire and/or unable to ignite on a more permanent basis (i.e., since the fire-retarding solution is effectiv ely integrated into the cellulose produ(_--t).
as compared to simple surface treatments that may be easily renmoved., washed away, or sul:-) ect to deuradation over time.
Therefore, it is to be understood that the disclosures are not to be limited to the specific aspects disclosed and that modifications and other aspects are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation,

Claims

THAT WHICH IS CLAIMED:

1. A method of forming a fire resistant cellulose product, said method comprising:
processing cellulose fibers into a fiber mixture;
forming a slurry from the fiber mixture and a fire-retarding solution, the fire-retarding solution comprising a neutral pH liquid including one of an inorganic hydrate, a bromine compound, magnesium hydroxide, hydromagnesite, antimony trioxide, a phosphonium salt, ammonium phosphate, diammonium phosphate, and combinations thereof, the slurry having the fire-retarding solution substantially uniformly distributed therethrough; and forming the slurry into a cellulose product.

2. A method according to Claim 1, wherein processing cellulose fibers into the fiber mixture further comprises processing one of waste paper and waste board, each comprising cellulose fibers, into the fiber mixture.

3. A method according to Claim 1, wherein forming the slurry further comprises adding water to the fiber mixture.

4. A method according to Claim 1, further comprising agitating the slurry so as to substantially uniformly distribute the fire-retarding solution therethrough.

5. A method according to Claim 1, wherein forming the slurry into the cellulose product further comprises:
dewatering the slurry; and drying the dewatered slurry to form the cellulose product.

6. A method according to Claim 1, wherein forming the slurry into the cellulose product further comprises compressing the slurry to form a densified cellulose product.

7. A method according to Claim 1, wherein forming the slurry into the cellulose product further comprises heating the slurry to form a dried cellulose product.

8. A method according to Claim 1, wherein forming the slurry into the cellulose product further comprises drying the slurry to form a substantially planar cellulose product having one of a thickness of between about 0.125 inches and about 2 feet, and a width of between about 1 inch and about 8 feet.

9. A method according to Claim 1, wherein forming the slurry into the cellulose product further comprises engaging the slurry with one of a negative die and a positive die, so as to form the cellulose product having a surface defining a negative impression of the one of the negative die and the positive die.

10. A method according to Claim 1, further comprising recovering excess fire-retarding solution, in one of a liquid and a vapor form, upon forming the slurry into the cellulose product.

11. A method according to Claim 10, wherein forming the slurry further comprises adding the recovered excess fire-retarding solution to the slurry, prior to forming the slurry into the cellulose product.

12. A method according to Claim 1, forming the slurry further comprises forming the slurry from the fiber mixture and one of an aqueous fire-retarding solution and a nontoxic liquid fire-retarding solution.