CA2735920A1 - Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants - Google Patents
Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants Download PDFInfo
- Publication number
- CA2735920A1 CA2735920A1 CA2735920A CA2735920A CA2735920A1 CA 2735920 A1 CA2735920 A1 CA 2735920A1 CA 2735920 A CA2735920 A CA 2735920A CA 2735920 A CA2735920 A CA 2735920A CA 2735920 A1 CA2735920 A1 CA 2735920A1
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- Canada
- Prior art keywords
- liquid
- gas
- gas stream
- methane
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 149
- 239000000356 contaminant Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 61
- 239000007789 gas Substances 0.000 claims abstract description 120
- 239000007788 liquid Substances 0.000 claims abstract description 76
- 239000007792 gaseous phase Substances 0.000 claims abstract description 49
- 239000007791 liquid phase Substances 0.000 claims abstract description 25
- 238000001816 cooling Methods 0.000 claims abstract description 23
- 238000004821 distillation Methods 0.000 claims abstract description 22
- 239000012071 phase Substances 0.000 claims abstract description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 44
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 30
- 238000000926 separation method Methods 0.000 claims description 29
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 22
- 239000001294 propane Substances 0.000 claims description 22
- 239000001569 carbon dioxide Substances 0.000 claims description 15
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 15
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 14
- 239000003507 refrigerant Substances 0.000 claims description 14
- 239000003345 natural gas Substances 0.000 claims description 12
- 230000006835 compression Effects 0.000 claims description 8
- 238000007906 compression Methods 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 230000004323 axial length Effects 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000003949 liquefied natural gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- -1 zeolites Chemical compound 0.000 description 2
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 1
- GAPFINWZKMCSBG-UHFFFAOYSA-N 2-(2-sulfanylethyl)guanidine Chemical compound NC(=N)NCCS GAPFINWZKMCSBG-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 102100032373 Coiled-coil domain-containing protein 85B Human genes 0.000 description 1
- 101000868814 Homo sapiens Coiled-coil domain-containing protein 85B Proteins 0.000 description 1
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- IJCVBMSXIPFVLH-UHFFFAOYSA-N [C].S=O Chemical compound [C].S=O IJCVBMSXIPFVLH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
- F25J3/061—Natural gas or substitute natural gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/0635—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/067—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/04—Recovery of liquid products
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/66—Separating acid gases, e.g. CO2, SO2, H2S or RSH
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/80—Separating impurities from carbon dioxide, e.g. H2O or water-soluble contaminants
- F25J2220/82—Separating low boiling, i.e. more volatile components, e.g. He, H2, CO, Air gases, CH4
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/12—External refrigeration with liquid vaporising loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/60—Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/66—Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
The invention provides a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, the process comprising: 1) providing the feed gas stream (1); 2) cooling the feed gas stream to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase,- 3) separating the two phases obtained in step 2) by means of a gas/liquid separator (4); and 4) subjecting the methane enriched gaseous phase obtained in step 3) to a distillation treatment in a distillation section (10) thereby obtaining a bottom stream (12) rich in liquid phase con-taminant and lean in methane, and a top stream (11) rich in methane and lean in gaseous contaminant. The invention further con-cerns a device for carrying out the present process, the purified gas stream, and a process for liquefying a feed gas stream.
Description
PROCESS FOR REMOVING GASEOUS CONTAMINANTS FROM A FEED GAS
STREAM COMPRISING METHANE AND GASEOUS CONTAMINANTS
The present invention concerns a process for the removal of gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, in particular the removal of gaseous contaminants such as carbon dioxide and hydrogen sulphide from a natural gas.
Methane comprising gas streams produced from subsurface reservoirs, especially natural gas, associated gas and coal bed methane, usually contain contaminants as carbon dioxide, hydrogen sulphide, carbon oxysulphide, mercaptans, sulphides and aromatic sulphur containing compounds in varying amounts. For most of the applications of these gas streams, the contaminants need to be removed, either partly or almost completely, depending on the specific contaminant and the use. Often, the sulphur compounds need to be removed into the ppm level, carbon dioxide sometimes into the ppm level, e.g. LNG
applications, or down to 2 or 3 vol. percent, e.g. for use as heating gas. Higher hydrocarbons may be present, which, depending on the use, may be recovered.
Processes for the removal of carbon dioxide and sulphur compounds are know in the art. These processes include absorption processes using e.g. aqueous amine solutions or adsorption processes using e.g. molecular sieves. These processes are especially suitable for the removal of contaminants, especially carbon dioxide and hydrogen sulphide, that are present in relatively low amounts, e.g. up till several vol%.
In WO 2006/087332, a method has been described for removing contaminating gaseous components, such as carbon dioxide and hydrogen sulphide, from a natural gas stream.
In this method a contaminated natural gas stream is cooled in a first expander to obtain an expanded gas stream having a temperature and pressure at which the dewpointing conditions of the phases containing a preponderance of contaminating components, such a carbon dioxide and/or hydrogen sulphide are achieved. The expanded gas stream is then supplied to a first segmented centrifugal separator to establish the separation of a contaminants-enriched liquid phase and a contaminants-depleted gaseous phase. The contaminants-depleted gaseous phase is then passed via a recompressor, an interstage cooler, and a second expander into a second centrifugal separator. The interstage cooler which is utilising air, water and/or an internal cold process stream, e.g. cold gas and/or liquid obtained form step 3), and the second expander are used to cool the contaminants-depleted gaseous phase to such an extent that again a contaminants-enriched liquid phase and a further contaminants-depleted gaseous phase are obtained which are subsequently separated from each other by means of the second centrifugal separator. In such a method energy recovered from the first expansion step is used in the compression step.
A disadvantage of this known method is that there is still room for improving the removal of gaseous contaminants from the feed gas stream, ensuring that levels can be reached that are specified for pipeline transport of the feed gas stream or the production of liquefied natural gas. A further disadvantage of such a method is that there is still room to improve the hydrocarbon efficiency of such a method, which hydrocarbon efficiency is a measure of the fuel consumption and the hydrocarbon loss into the liquid phase contaminant streams during the process.
STREAM COMPRISING METHANE AND GASEOUS CONTAMINANTS
The present invention concerns a process for the removal of gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, in particular the removal of gaseous contaminants such as carbon dioxide and hydrogen sulphide from a natural gas.
Methane comprising gas streams produced from subsurface reservoirs, especially natural gas, associated gas and coal bed methane, usually contain contaminants as carbon dioxide, hydrogen sulphide, carbon oxysulphide, mercaptans, sulphides and aromatic sulphur containing compounds in varying amounts. For most of the applications of these gas streams, the contaminants need to be removed, either partly or almost completely, depending on the specific contaminant and the use. Often, the sulphur compounds need to be removed into the ppm level, carbon dioxide sometimes into the ppm level, e.g. LNG
applications, or down to 2 or 3 vol. percent, e.g. for use as heating gas. Higher hydrocarbons may be present, which, depending on the use, may be recovered.
Processes for the removal of carbon dioxide and sulphur compounds are know in the art. These processes include absorption processes using e.g. aqueous amine solutions or adsorption processes using e.g. molecular sieves. These processes are especially suitable for the removal of contaminants, especially carbon dioxide and hydrogen sulphide, that are present in relatively low amounts, e.g. up till several vol%.
In WO 2006/087332, a method has been described for removing contaminating gaseous components, such as carbon dioxide and hydrogen sulphide, from a natural gas stream.
In this method a contaminated natural gas stream is cooled in a first expander to obtain an expanded gas stream having a temperature and pressure at which the dewpointing conditions of the phases containing a preponderance of contaminating components, such a carbon dioxide and/or hydrogen sulphide are achieved. The expanded gas stream is then supplied to a first segmented centrifugal separator to establish the separation of a contaminants-enriched liquid phase and a contaminants-depleted gaseous phase. The contaminants-depleted gaseous phase is then passed via a recompressor, an interstage cooler, and a second expander into a second centrifugal separator. The interstage cooler which is utilising air, water and/or an internal cold process stream, e.g. cold gas and/or liquid obtained form step 3), and the second expander are used to cool the contaminants-depleted gaseous phase to such an extent that again a contaminants-enriched liquid phase and a further contaminants-depleted gaseous phase are obtained which are subsequently separated from each other by means of the second centrifugal separator. In such a method energy recovered from the first expansion step is used in the compression step.
A disadvantage of this known method is that there is still room for improving the removal of gaseous contaminants from the feed gas stream, ensuring that levels can be reached that are specified for pipeline transport of the feed gas stream or the production of liquefied natural gas. A further disadvantage of such a method is that there is still room to improve the hydrocarbon efficiency of such a method, which hydrocarbon efficiency is a measure of the fuel consumption and the hydrocarbon loss into the liquid phase contaminant streams during the process.
It has now been found that in an integrated process for removing gaseous contaminants improved levels of gaseous contaminants and an improved hydrocarbon efficiency can be obtained when after a gas/liquid separation the contaminants-depleted gaseous phase is subjected to a distillation treatment.
Thus, the present invention concerns a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, which process comprises:
1) providing the feed gas stream;
2) cooling the feed gas stream to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase;
3) separating the two phases obtained in step 2) by means of a gas/liquid separator; and 4) subjecting the methane enriched gaseous phase obtained in step 3) to a distillation treatment in a distillation section thereby obtaining a bottom stream rich in liquid phase contaminant and lean in methane, and a top stream rich in methane and and lean in gaseous contaminant.
Suitably, the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide. The natural gas stream suitably comprises between 0.1 and 60 vol% of hydrogen sulphide, preferably between 20 and 40 vol% of hydrogen sulphide. The natural gas stream suitably comprises between 1 and 90 vol%
of carbon dioxide, preferably between 5 and 80 vol% of carbon dioxide.
The feed gas stream to be used in accordance with the present invention comprises between 20 and 80 vol% of methane.
Suitably, the feed gas stream in step 1) has a temperature between -20 and 150 C, preferably between -10 and 70 C, and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
The raw feed gas stream may be pre-treated to partially or completely remove water and optionally some heavy hydrocarbons. This can for instance be done by means of a pre-cooling cycle, against an external cooling loop or a cold internal process stream. Water may also be removed by means of pre-treatment with molecular sieves, e.g. zeolites, or silica gel or alumina oxide or other drying agents such as glycol, MEG, DEG or TEG, or glycerol.
The amount of water in the gas feed stream is suitably less than 1 vol%, preferably less than 0.1 vol%, more preferably less than 0.0001 vol%.
The cooling in step 2) of the feed gas stream may be done by methods known in the art. For instance, cooling may be done against an internal or external cooling fluid. In the case that the pressure of the feed gas is sufficiently high, cooling may be obtained by expansion of the feed gas stream.
Combinations may also be possible. A suitable method to cool the feed gas stream is by nearly isentropic expansion, especially by means of an expander, preferably a turbo expander or laval nozzle. Another suitable method is to cool the feed gas stream by isenthalpic expansion, preferably isenthalpic expansion over an orifice or a valve, especially over a Joule-Thomson valve.
Preferably, the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied acidic contaminants have a certain droplet size distribution. In this way, the droplet size distribution can be controlled.
In a preferred embodiment the feed gas stream is pre-cooled before expansion. This may be done against an external cooling loop or against a cold internal process stream, e.g. liquid acidic contaminant. Preferably the gas stream is pre-cooled before expansion to a temperature between 15 and -35 C, preferably between 10 and -20 C.
Especially when the feed gas stream has been compressed, the temperature of the feed gas stream may be between 100 and 150 C. In that case air or water cooling may be used to decrease the temperature first, optionally followed by further cooling.
Another suitable cooling method is heat exchange against a cold fluidum, especially an external refrigerant, e.g. a propane cycle, an ethane/propane cascade or a mixed refrigerant cycle, optionally in combination with an internal process loop, suitably a contaminants stream (liquid or slurry), a cold methane enriched stream or washing fluid.
Suitably the feed gas stream is cooled in step 2) to a temperature between -30 and -80 C, preferably between -40 and -65 C. At these temperatures liquid phase contaminant will be formed.
In the present invention both liquid phase contaminant and gaseous contaminant will comprise carbon dioxide and/or hydrogen sulphide.
In step 4), the bottom temperature of the distillation device is suitably between 0 and 30 C, and preferably between 5 and 20 C, whereas the top temperature of the distillation device is between -20 and -90 C, preferably between -30 and -70 C.
In accordance with the present invention the distillation device can suitable be a distillation column or distillation vessel known in the art.
Suitably, the top stream in step 4) comprises between 1 and 75 mol% of the gaseous contaminants present in the feed gas stream. Preferably, the top stream in step 4) WO 2010/034628 _ 6 _ PCT/EP2009/061798 comprises between 2 and 50 mol% of the gaseous contaminants present in the feed gas stream.
Hence, it will be clear that with the relatively simple process according to the invention very low levels of gaseous contaminants can be established in the methane enriched gaseous phase, ensuring that levels can be reached that are specified for pipeline transport of the feed gas stream or the production of liquefied natural gas.
In accordance with the present invention the methane enriched gaseous phase obtained in step 3) can suitably be cooled in a cooling step to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, and the methane enriched gaseous phase so obtained is subjected to the distillation treatment in step 4).
The cooling between steps 3) and 4) can, e.g. be carried out by means of an internal process stream, e.g. a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
In accordance with the present invention the cooling of the methane enriched gaseous phase between steps 3) and 4) can suitably at least partly be done by means of an external refrigerant.
Preferably, the external refrigerant to be used has a higher molecular weight than the methane enriched gaseous phase to be cooled. Suitable examples of such cooling medium include ethane, propane and butane. Preferably, the cooling medium comprises ethane and/or propane.
More preferably, the external refrigerant to be used comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade. Such an ethane/propane cascade is described in more detail hereinbelow.
In a preferred embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is recompressed in one or more compression steps before the methane enriched gaseous phase is cooled by means of the internal and/or external refrigerant.
Suitably, the recompressed methane enriched gaseous phase obtained in the one or more compression steps is cooled in a cooling step to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, whereafter the methane enriched gaseous phase so obtained is subjected to the distillation treatment in step 4).
The cooling of the methane enriched gaseous phase between steps 3) and 4) can suitably be partly done by means of an external refrigerant and partly by means of an internal process stream such as a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
The cooling by means of the external refrigerant may be carried out in such a way that a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase. This stream can subsequently be subjected to the distillation treatment in step 4). In this way a further enriched methane-containing gaseous phase can be obtained containing a low level of gaseous contaminants, making the present process a relatively simple process that requires relatively simple equipment only, and at the same time improving the removal of gaseous contaminants from the feed gas stream.
In another embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is firstly cooled by means of an interstage cooler before the methane enriched gaseous phase obtained in step 3) is cooled to a temperature at which liquid phase contaminant in methane enriched phase is subsequently subjected to the distillation treatment in step 4).
In yet another embodiment of the present invention, the methane enriched gaseous phase obtained in step 3) is firstly recompressed in one or more compression steps, than cooled by means of an interstage cooler, and subsequently cooled to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, which methane enriched gaseous phase so obtained is then subjected to the distillation treatment in step 4).
Suitably, such an interstage cooler can be based on a internalprocess loop.
In the one or more compression steps suitably energy is used that is recovered in step 2) or 4).
In accordance with the present invention the methane enriched gaseous phase obtained in step 3) is cooled between steps 3) and 4) to a temperature between 30 and -90 C, preferably between -30 and -70 C, and the pressure is suitably between 20 and 80 bara, preferably between 30 and 60 bara.
Whereas in known separation processes for removing gaseous contaminants from a feed gas stream the cold of the methane enriched gaseous phase as obtained in step 3) is usually at least partly used to pre-cool the feed gas stream. In accordance with the present process preferably no part of the methane enriched gaseous phase is used as an internal loop to pre-cool the feed gas stream, but the entire cold of the methane enriched gaseous phase is maintained in the stream to be further processed in accordance with the present invention.
In the process according to the present invention a variety of gas/liquid separators can suitably be used in step 3), such as, for instance, rotating centrifuges or cyclones.
Suitable gas/liquid separators to be used in accordance with the present invention have, for instance, been described in WO 2008/082291, WO 2006/087332, WO
2005/118110, WO 97/44117, WO 2007/097621 and WO 94/23823, which documents are hereby incorporated by reference.
In one preferred embodiment, a gas/liquid separator is used comprising:
a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
b) tangentially arranged inlet means to introduce the mixture into the first separation section;
c) means to remove liquid from the first separation section;
d) means to remove liquid from the third separation section; and e) means to remove a gaseous stream, lean in liquid, from the third separation section.
In another preferred embodiment of the present invention, the gas/liquid separator vessel in step 3) comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
When using a vertical gas/liquid separator vessel, the process only needs a relatively small area.
According to a preferred embodiment, the gas/liquid inlet comprises an admittance with a supply and distribution assembly extending horizontally in the separator vessel. In its most simple form, the inlet is a simple pipe, having a closed end and a number of perforations evenly distributed over the length of the pipe. Optionally, the pipe may have a tapered or conical shape. One or more cross pipes may be present to create a grid system to distribute the gas-liquid mixture more evenly over the cross-section of the vessel. Preferably, the assembly includes a chamber, e.g. a longitudinal box-like structure, connected to the gas inlet and having at least one open vertical side with a grid of guide vanes disposed one behind each other, seen in the direction of the flow. By means of this supply and distribution assembly, the gas is evenly distributed by the guide vanes over the cross-section of the column, which brings about an additional improvement of the liquid separation in the coalescer/centrifugal separator combination. A further advantage is that the supply and distribution assembly separates from the gas any waves of liquid which may suddenly occur in the gas stream, the separation being effected by the liquid colliding with the guide vanes and falling down inside the column. Suitably, the box structure narrows down in the direction of the flow. After having been distributed by the vanes over the column cross-section, the gas flows up to the coalescer.
In a preferred embodiment the longitudinal chamber has two open vertical sides with a grid of guide vanes.
Suitable gas/liquid inlets are those described in e.g.
GB 1,119,699, US 6,942,720, EP 195,464, US 6,386,520 and US 6,537,458. A suitable, commercially available gas/liquid inlet is a Schoepentoeter.
There are numerous horizontal coalescers available, especially for vertical columns. A well-known example of a mist eliminator is the demister mat. All of these are relatively tenuous (large permeability) and have a relatively large specific (internal) surface area. Their operation is based on drop capture by collision of drops with internal surfaces, followed by drop growth on these surfaces, and finally by removal of the grown drop either by the gas or by gravity.
The horizontal coalescer can have many forms which are known per se and may, for example, consist of a bed of layers of gauze, especially metal or non-metal gauze, e.g.
organic polymer gauze, or a layer of vanes or a layer of structured packing. Also unstructured packings can be used and also one or more trays may be present. All these sorts of coalescers have the advantage of being commercially available and operating efficiently in the column according to the invention. See also Perry's Chemical Engineers' Handbook, Sixth edition, especially Chapter 18. See also EP 195464.
The centrifugal liquid separator in one of its most simple forms may comprise a horizontal plate and one or more vertical swirl tubes extending downwardly from the plate, each swirl tube having one or more liquid outlets below the horizontal plate at the upper end of the swirl tube. In another form, the centrifugal liquid separator comprises one or more vertical swirl tubes extending upwardly from the plate, each swirl tube having one or more liquid outlets at the upper end. The plate is provided with a downcomer, preferably a downcomer that extends to the lower end of the separator vessel.
In a preferred embodiment of the invention, the centrifugal liquid separator comprises two horizontal trays between which vertical open-ended swirl tubes extend, each from an opening in the lower tray to some distance below a coaxial opening in the upper tray, means for the discharge of secondary gas and of liquid from the space between the trays outside the swirl tubes, and means provided in the lower part of the swirl tubes to impart to the gas/liquid a rotary movement around the vertical axis.
The liquid separator is also preferably provided with vertical tube pieces which project down from the coaxial openings in the upper tray into the swirl tubes and have a smaller diameter than these latter. This arrangement enhances the separation between primary gas on the one hand and secondary gas and liquid on the other hand, since these latter cannot get from the swirl tubes into the openings in the upper tray for primary gas.
According to a preferred embodiment, the means for discharging the secondary gas from the space between the trays consist of vertical tubelets through the upper tray, and the means for discharging liquid from the space between the trays consist of one or more vertical discharge pipes which extend from this space to the bottom of the column.
This arrangement has the advantage that the secondary gas, after having been separated from liquid in the said space between the trays, is immediately returned to the primary gas, and the liquid is added to the liquid at the bottom of the column after coming from the coalescer, so that the secondary gas and the liquid removed in the centrifugal separator do not require separate treatment.
In order to improve even further the liquid separation in the centrifugal separator, openings are preferably provided in accordance with the invention at the top of the swirl tubes for discharging liquid to the space between the trays outside the swirl tubes. This has the advantage that less secondary gas is carried to the space between the trays. A suitable, commercially available centrifugal separator is a Shell Swirltube deck.
In a preferred embodiment, the separation vessel comprises a second normally horizontal liquid coalescer above the centrifugal liquid separator and over the whole cross-section of the vessel. This has the advantage that any droplets still present in the gas stream are removed.
See for a further description hereinabove. Preferably, the second coalescer is a bed of one or more layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze. In another preferred embodiment, the second normally horizontal liquid coalescer is situated above the secondary gas outlets, for instance in the way as described in EP
83811, especially as depicted in Figure 4.
In another preferred embodiment of the present invention the gas/liquid separator in step 3) comprises a centrifugal separator which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube.
Suitably, the centrifugal separator is spinned by introducing a swirling gas stream into the spinning tube.
Preferably, the centrifugal separator to be used in accordance with the present invention comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body or upstream and downstream of the separating body, wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
It will be appreciated that the discs can be easily created by drilling or cutting a plurality of perforations into the relatively thin discs. By attaching several discs together these discs form a separating body. By aligning the perforations ducts are obtained.
It is now also very easy to attach the discs such that the perforations are not completely aligned. By varying the number and nature of the non-alignment of the perforations the resulting ducts can be given any desired shape. In such cases not only ducts are obtainable that are not completely parallel to the central axis of rotation, but also ducts that form a helix shape around the axis of rotation. So, in this way very easily the preferred embodiment of having non-parallel ducts can be obtained. Hence it is preferred that the perforations of the discs have been arranged such that the ducts are not parallel to the central axis of rotation or form a helix shape around the axis of rotation.
Further, it will be appreciated that it is relatively easy to increase or decrease the diameter of the perforations. Thereby the skilled person has an easy manner at his disposal to adapt the (hydraulic) diameter of the ducts, and thereby the Reynolds number, so that he can easy ascertain that the flow in the ducts is laminar or turbulent, just as he pleases. The use of these discs also enables the skilled person to vary the diameter of the duct along the axis of the housing. The varying diameter can be selected such that the separated liquid or solid contaminants that are collected against the wall of the duct will not clog up the duct completely, which would hamper the operation of the apparatus.
The skilled person is also now enabled to maximise the porosity of the separating body. The easy construction of the discs allows the skilled person to meticulously provide the disc with as many perforations as he likes. He may also select the shape of the perforations. These may have a circular cross-section, but also square, pentagon, hexagon, octagon or oval cross-sections are possible. He may therefore minimise the wall thickness of the separating body and the wall thicknesses of the ducts. He is able to select the wall thicknesses and the shape of the ducts such that the surface area that is contributed to the cross-section of the separating body by the walls is minimal.
That means that the pressure drop over the separating body can be minimised.
The apparatus can have a small or large number of ducts. Just as explained in the prior art apparatuses the number of ducts suitably ranges from 100 to 1,000,000, preferably from 500 to 500,000. The diameter of the cross-section of the ducts can be varied in accordance with the amount of gas and amounts and nature, e.g., droplet size distribution, of contaminants and the desired contaminants removal efficiency. Suitably, the diameter is from 0.05 to 50 mm, preferably from 0.1 to 20 mm, and more preferably from 0.1 to 5 mm. By diameter is understood twice the radius in case of circular cross-sections or the largest diagonal in case of any other shape.
The size of the apparatus and in particular of the separating body may vary in accordance with the amount of gas to be treated. In EP-B 286 160 it is indicated that separating bodies with a peripheral diameter of 1 m and an axial length of 1.5 m are feasible. The separating body according to the present invention may suitably have a radial length ranging from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length ranges conveniently from 0.1 to 10 m, preferably, from 0.2 to 5 m.
The number of discs may also vary over a large number.
It is possible to have only two discs if a simple separation is needed and/or when the perforations can be easily made. Other considerations may be whether parallel ducts are desired, or whether a uniform diameter is wanted.
Suitably the number of discs varies from 3 to 1000, preferably from 4 to 500, more preferably from 4 to 40.
When more discs, are used the skilled person will find it easier to gradually vary the diameter of the ducts and/or to construct non-parallel ducts. Moreover, by increasing or decreasing the number of discs the skilled person may vary the duct length. So, when the conditions or the composition of the gas changes, the skilled person may adapt the duct length easily to provide the most optimal conditions for the apparatus of the present invention. The size of the discs is selected such that the radial diameter suitably ranges from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length of the discs may be varied in accordance with construction possibilities, desire for varying the shape etc. Suitably, the axial length of each disc ranges from 0.001 to 0.5 m, preferably from 0.002 to 0.2 m, more preferably from 0.005 to 0.1 m.
Although the discs may be manufactured from a variety of materials, including paper, cardboard, and foil, it is preferred to manufacture the discs from metal or ceramics.
Metals discs have the advantage that they can be easily perforated and be combined to firm sturdy separating bodies. Dependent on the material that needs to be purified a suitable metal can be selected. For some applications carbon steel is suitable whereas for other applications, in particular when corrosive materials are to be separated, stainless steel may be preferred. Ceramics have the advantage that they can be extruded into the desired form such as in honeycomb structures with protruding ducts.
Typically, the ceramics precursor material is chosen to form a dense or low-porosity ceramic. Thereby the solid or liquid contaminants are forced to flow along the wall of the ducts and not, or hardly, through the ceramic material of the walls. Examples of ceramic materials are silica, alumina, zirconia, optionally with different types and concentrations of modifiers to adapt its physical and/or chemical properties to the gas and the contaminants.
The discs may be combined to a separating body in a variety of ways. The skilled person will appreciate that such may depend on the material from which the discs have been manufactured. A convenient manner is to attach the discs to a shaft that provides the axis of rotation.
Suitable ways of combining the discs include clamping the discs together, but also gluing them or welding them together can be done. Alternatively, the discs may be stacked in a cylindrical sleeve. This sleeve may also at least partly replace the shaft. This could be convenient for extruded discs since no central opening for the shaft would be required. It is preferred to have metal discs that are welded together.
In a preferred embodiment of the invention, the methane enriched gaseous phase obtained in accordance with the present invention is further purified, e.g. by extraction of remaining acidic components with a chemical solvent, e.g. an aqueous amine solution, especially aqueous ethanolamines, such as DIPA, DMA, MDEA, etc., or with a physical solvent, e.g. cold methanol, DEPG, NMP, etc.
The contaminated gas stream is continuously provided, continuously cooled and continuously separated.
The present invention also relates to a device (plant) for carrying out the process as described above, as well as the purified gas stream obtained by the present process. In addition, the present invention concerns a process for liquefying a feed gas stream comprising purifying the feed gas stream by means of the present process, followed by liquifying the purified feed gas stream by methods known in the art.
The invention will be further illustrated by means of the following Figures.
Referring to Figure 1, natural gas via a conduit 1 is passed through an expansion means 2, whereby a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase. The stream flows via a conduit 3 into a gas/liquid separator 4 wherein the two phases are separated from each other. The liquid phase contaminant is recovered via a conduit 5, whereas the methane enriched gaseous phase is passed via a conduit 6 into a heat exchanger 7. In heat exchanger 7 ethane is used an external refrigerant whereby ethane is cooled by means of an ethane/propane cascade 8 as depicted in more detail in Figure 2. The cooling in heat exchanger 7 is such that a liquid phase contaminant and a methane enriched gaseous phase are formed. The stream which comprises these two phases is then passed via a conduit 9 into a distillation column 10 from which a further enriched methane enriched gaseous phase is recovered via a conduit 11 and liquid phase contaminant is recovered via a conduit 12.
In Figure 2 a suitable heat exchanger 7 is shown which is based on an ethane/propane cascade which comprises an ethane loop and a propane loop. In the ethane loop an ethane stream is passed via a conduit 13 into an expander 14 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled ethane stream so obtained is passed via a conduit 15 into the heat exchanger 7. A stream of warm ethane is then passed from the heat exchanger 7 to a recompressor 16 via a conduit 17 to increase the pressure of the ethane stream. The compressed stream of ethane obtained from recompressor 16 is then passed via a conduit 18 into heat exchanger 19 wherein the ethane stream is cooled and at least partly condensed. Via the conduit 13 the ethane stream is then recycled to the expander 14. In the propane loop a propane stream is passed via a conduit 20 into an expander 21 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled propane stream so obtained is passed via a conduit 22 into the heat exchanger 19 of the ethane loop. A stream of warm propane is then passed from the heat exchanger 19 via a conduit 23 into a recompressor 24 to increase the pressure of the propane stream. The compressed stream of propane obtained from recompressor 24 is then passed via a conduit 25 into a heat exchanger 26 wherein the propane stream is cooled and at least partly condensed by means of water or air. Via the conduit 20 the propane stream is then recycled to the expander 21.
In Figure 3 a preferred gas/liquid separator is shown for carrying out step 3) of the present process. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 into the gas/liquid separator 4 via supply and distribution assembly 27. Most of the liquid will flow down to the lower end of the separator and leave the separator via the liquid outlet 5. The gaseous stream comprising larger and smaller droplets will flow upwards via liquid coalescer 28, centrifugal separator 29 and a second liquid coalescer 30 to the top of the separator vessel, and leave the separator vessel via gas outlet 6.
In Figure 4 another preferred gas/liquid separator is shown for carrying out step 3) of the present process. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 to a gas inlet 31 in a housing 32 of the gas/liquid separator 4.
The housing 32 further comprises a separating body 33 which shows a large number of ducts 34 which are arranged around a shaft 35, which provides an axis of rotation. Separating body 33 has been composed of six discs 33a, 33b, 33c, 33d, 33e and 33f that have been combined by welding or gluing.
In the rotating separating body droplets of carbon dioxide and/or hydrogen sulphide are separated from the natural gas. The separated contaminants are discharged from the housing via a contaminants outlet 36 which has been arranged downstream of the separating body 33, and via the discharge conduit 5. Purified natural gas leaves housing 32 via the gas outlet 6 arranged at the opposite end of the housing 32.
Thus, the present invention concerns a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, which process comprises:
1) providing the feed gas stream;
2) cooling the feed gas stream to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase;
3) separating the two phases obtained in step 2) by means of a gas/liquid separator; and 4) subjecting the methane enriched gaseous phase obtained in step 3) to a distillation treatment in a distillation section thereby obtaining a bottom stream rich in liquid phase contaminant and lean in methane, and a top stream rich in methane and and lean in gaseous contaminant.
Suitably, the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide. The natural gas stream suitably comprises between 0.1 and 60 vol% of hydrogen sulphide, preferably between 20 and 40 vol% of hydrogen sulphide. The natural gas stream suitably comprises between 1 and 90 vol%
of carbon dioxide, preferably between 5 and 80 vol% of carbon dioxide.
The feed gas stream to be used in accordance with the present invention comprises between 20 and 80 vol% of methane.
Suitably, the feed gas stream in step 1) has a temperature between -20 and 150 C, preferably between -10 and 70 C, and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
The raw feed gas stream may be pre-treated to partially or completely remove water and optionally some heavy hydrocarbons. This can for instance be done by means of a pre-cooling cycle, against an external cooling loop or a cold internal process stream. Water may also be removed by means of pre-treatment with molecular sieves, e.g. zeolites, or silica gel or alumina oxide or other drying agents such as glycol, MEG, DEG or TEG, or glycerol.
The amount of water in the gas feed stream is suitably less than 1 vol%, preferably less than 0.1 vol%, more preferably less than 0.0001 vol%.
The cooling in step 2) of the feed gas stream may be done by methods known in the art. For instance, cooling may be done against an internal or external cooling fluid. In the case that the pressure of the feed gas is sufficiently high, cooling may be obtained by expansion of the feed gas stream.
Combinations may also be possible. A suitable method to cool the feed gas stream is by nearly isentropic expansion, especially by means of an expander, preferably a turbo expander or laval nozzle. Another suitable method is to cool the feed gas stream by isenthalpic expansion, preferably isenthalpic expansion over an orifice or a valve, especially over a Joule-Thomson valve.
Preferably, the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied acidic contaminants have a certain droplet size distribution. In this way, the droplet size distribution can be controlled.
In a preferred embodiment the feed gas stream is pre-cooled before expansion. This may be done against an external cooling loop or against a cold internal process stream, e.g. liquid acidic contaminant. Preferably the gas stream is pre-cooled before expansion to a temperature between 15 and -35 C, preferably between 10 and -20 C.
Especially when the feed gas stream has been compressed, the temperature of the feed gas stream may be between 100 and 150 C. In that case air or water cooling may be used to decrease the temperature first, optionally followed by further cooling.
Another suitable cooling method is heat exchange against a cold fluidum, especially an external refrigerant, e.g. a propane cycle, an ethane/propane cascade or a mixed refrigerant cycle, optionally in combination with an internal process loop, suitably a contaminants stream (liquid or slurry), a cold methane enriched stream or washing fluid.
Suitably the feed gas stream is cooled in step 2) to a temperature between -30 and -80 C, preferably between -40 and -65 C. At these temperatures liquid phase contaminant will be formed.
In the present invention both liquid phase contaminant and gaseous contaminant will comprise carbon dioxide and/or hydrogen sulphide.
In step 4), the bottom temperature of the distillation device is suitably between 0 and 30 C, and preferably between 5 and 20 C, whereas the top temperature of the distillation device is between -20 and -90 C, preferably between -30 and -70 C.
In accordance with the present invention the distillation device can suitable be a distillation column or distillation vessel known in the art.
Suitably, the top stream in step 4) comprises between 1 and 75 mol% of the gaseous contaminants present in the feed gas stream. Preferably, the top stream in step 4) WO 2010/034628 _ 6 _ PCT/EP2009/061798 comprises between 2 and 50 mol% of the gaseous contaminants present in the feed gas stream.
Hence, it will be clear that with the relatively simple process according to the invention very low levels of gaseous contaminants can be established in the methane enriched gaseous phase, ensuring that levels can be reached that are specified for pipeline transport of the feed gas stream or the production of liquefied natural gas.
In accordance with the present invention the methane enriched gaseous phase obtained in step 3) can suitably be cooled in a cooling step to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, and the methane enriched gaseous phase so obtained is subjected to the distillation treatment in step 4).
The cooling between steps 3) and 4) can, e.g. be carried out by means of an internal process stream, e.g. a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
In accordance with the present invention the cooling of the methane enriched gaseous phase between steps 3) and 4) can suitably at least partly be done by means of an external refrigerant.
Preferably, the external refrigerant to be used has a higher molecular weight than the methane enriched gaseous phase to be cooled. Suitable examples of such cooling medium include ethane, propane and butane. Preferably, the cooling medium comprises ethane and/or propane.
More preferably, the external refrigerant to be used comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade. Such an ethane/propane cascade is described in more detail hereinbelow.
In a preferred embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is recompressed in one or more compression steps before the methane enriched gaseous phase is cooled by means of the internal and/or external refrigerant.
Suitably, the recompressed methane enriched gaseous phase obtained in the one or more compression steps is cooled in a cooling step to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, whereafter the methane enriched gaseous phase so obtained is subjected to the distillation treatment in step 4).
The cooling of the methane enriched gaseous phase between steps 3) and 4) can suitably be partly done by means of an external refrigerant and partly by means of an internal process stream such as a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
The cooling by means of the external refrigerant may be carried out in such a way that a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase. This stream can subsequently be subjected to the distillation treatment in step 4). In this way a further enriched methane-containing gaseous phase can be obtained containing a low level of gaseous contaminants, making the present process a relatively simple process that requires relatively simple equipment only, and at the same time improving the removal of gaseous contaminants from the feed gas stream.
In another embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is firstly cooled by means of an interstage cooler before the methane enriched gaseous phase obtained in step 3) is cooled to a temperature at which liquid phase contaminant in methane enriched phase is subsequently subjected to the distillation treatment in step 4).
In yet another embodiment of the present invention, the methane enriched gaseous phase obtained in step 3) is firstly recompressed in one or more compression steps, than cooled by means of an interstage cooler, and subsequently cooled to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, which methane enriched gaseous phase so obtained is then subjected to the distillation treatment in step 4).
Suitably, such an interstage cooler can be based on a internalprocess loop.
In the one or more compression steps suitably energy is used that is recovered in step 2) or 4).
In accordance with the present invention the methane enriched gaseous phase obtained in step 3) is cooled between steps 3) and 4) to a temperature between 30 and -90 C, preferably between -30 and -70 C, and the pressure is suitably between 20 and 80 bara, preferably between 30 and 60 bara.
Whereas in known separation processes for removing gaseous contaminants from a feed gas stream the cold of the methane enriched gaseous phase as obtained in step 3) is usually at least partly used to pre-cool the feed gas stream. In accordance with the present process preferably no part of the methane enriched gaseous phase is used as an internal loop to pre-cool the feed gas stream, but the entire cold of the methane enriched gaseous phase is maintained in the stream to be further processed in accordance with the present invention.
In the process according to the present invention a variety of gas/liquid separators can suitably be used in step 3), such as, for instance, rotating centrifuges or cyclones.
Suitable gas/liquid separators to be used in accordance with the present invention have, for instance, been described in WO 2008/082291, WO 2006/087332, WO
2005/118110, WO 97/44117, WO 2007/097621 and WO 94/23823, which documents are hereby incorporated by reference.
In one preferred embodiment, a gas/liquid separator is used comprising:
a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
b) tangentially arranged inlet means to introduce the mixture into the first separation section;
c) means to remove liquid from the first separation section;
d) means to remove liquid from the third separation section; and e) means to remove a gaseous stream, lean in liquid, from the third separation section.
In another preferred embodiment of the present invention, the gas/liquid separator vessel in step 3) comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
When using a vertical gas/liquid separator vessel, the process only needs a relatively small area.
According to a preferred embodiment, the gas/liquid inlet comprises an admittance with a supply and distribution assembly extending horizontally in the separator vessel. In its most simple form, the inlet is a simple pipe, having a closed end and a number of perforations evenly distributed over the length of the pipe. Optionally, the pipe may have a tapered or conical shape. One or more cross pipes may be present to create a grid system to distribute the gas-liquid mixture more evenly over the cross-section of the vessel. Preferably, the assembly includes a chamber, e.g. a longitudinal box-like structure, connected to the gas inlet and having at least one open vertical side with a grid of guide vanes disposed one behind each other, seen in the direction of the flow. By means of this supply and distribution assembly, the gas is evenly distributed by the guide vanes over the cross-section of the column, which brings about an additional improvement of the liquid separation in the coalescer/centrifugal separator combination. A further advantage is that the supply and distribution assembly separates from the gas any waves of liquid which may suddenly occur in the gas stream, the separation being effected by the liquid colliding with the guide vanes and falling down inside the column. Suitably, the box structure narrows down in the direction of the flow. After having been distributed by the vanes over the column cross-section, the gas flows up to the coalescer.
In a preferred embodiment the longitudinal chamber has two open vertical sides with a grid of guide vanes.
Suitable gas/liquid inlets are those described in e.g.
GB 1,119,699, US 6,942,720, EP 195,464, US 6,386,520 and US 6,537,458. A suitable, commercially available gas/liquid inlet is a Schoepentoeter.
There are numerous horizontal coalescers available, especially for vertical columns. A well-known example of a mist eliminator is the demister mat. All of these are relatively tenuous (large permeability) and have a relatively large specific (internal) surface area. Their operation is based on drop capture by collision of drops with internal surfaces, followed by drop growth on these surfaces, and finally by removal of the grown drop either by the gas or by gravity.
The horizontal coalescer can have many forms which are known per se and may, for example, consist of a bed of layers of gauze, especially metal or non-metal gauze, e.g.
organic polymer gauze, or a layer of vanes or a layer of structured packing. Also unstructured packings can be used and also one or more trays may be present. All these sorts of coalescers have the advantage of being commercially available and operating efficiently in the column according to the invention. See also Perry's Chemical Engineers' Handbook, Sixth edition, especially Chapter 18. See also EP 195464.
The centrifugal liquid separator in one of its most simple forms may comprise a horizontal plate and one or more vertical swirl tubes extending downwardly from the plate, each swirl tube having one or more liquid outlets below the horizontal plate at the upper end of the swirl tube. In another form, the centrifugal liquid separator comprises one or more vertical swirl tubes extending upwardly from the plate, each swirl tube having one or more liquid outlets at the upper end. The plate is provided with a downcomer, preferably a downcomer that extends to the lower end of the separator vessel.
In a preferred embodiment of the invention, the centrifugal liquid separator comprises two horizontal trays between which vertical open-ended swirl tubes extend, each from an opening in the lower tray to some distance below a coaxial opening in the upper tray, means for the discharge of secondary gas and of liquid from the space between the trays outside the swirl tubes, and means provided in the lower part of the swirl tubes to impart to the gas/liquid a rotary movement around the vertical axis.
The liquid separator is also preferably provided with vertical tube pieces which project down from the coaxial openings in the upper tray into the swirl tubes and have a smaller diameter than these latter. This arrangement enhances the separation between primary gas on the one hand and secondary gas and liquid on the other hand, since these latter cannot get from the swirl tubes into the openings in the upper tray for primary gas.
According to a preferred embodiment, the means for discharging the secondary gas from the space between the trays consist of vertical tubelets through the upper tray, and the means for discharging liquid from the space between the trays consist of one or more vertical discharge pipes which extend from this space to the bottom of the column.
This arrangement has the advantage that the secondary gas, after having been separated from liquid in the said space between the trays, is immediately returned to the primary gas, and the liquid is added to the liquid at the bottom of the column after coming from the coalescer, so that the secondary gas and the liquid removed in the centrifugal separator do not require separate treatment.
In order to improve even further the liquid separation in the centrifugal separator, openings are preferably provided in accordance with the invention at the top of the swirl tubes for discharging liquid to the space between the trays outside the swirl tubes. This has the advantage that less secondary gas is carried to the space between the trays. A suitable, commercially available centrifugal separator is a Shell Swirltube deck.
In a preferred embodiment, the separation vessel comprises a second normally horizontal liquid coalescer above the centrifugal liquid separator and over the whole cross-section of the vessel. This has the advantage that any droplets still present in the gas stream are removed.
See for a further description hereinabove. Preferably, the second coalescer is a bed of one or more layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze. In another preferred embodiment, the second normally horizontal liquid coalescer is situated above the secondary gas outlets, for instance in the way as described in EP
83811, especially as depicted in Figure 4.
In another preferred embodiment of the present invention the gas/liquid separator in step 3) comprises a centrifugal separator which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube.
Suitably, the centrifugal separator is spinned by introducing a swirling gas stream into the spinning tube.
Preferably, the centrifugal separator to be used in accordance with the present invention comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body or upstream and downstream of the separating body, wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
It will be appreciated that the discs can be easily created by drilling or cutting a plurality of perforations into the relatively thin discs. By attaching several discs together these discs form a separating body. By aligning the perforations ducts are obtained.
It is now also very easy to attach the discs such that the perforations are not completely aligned. By varying the number and nature of the non-alignment of the perforations the resulting ducts can be given any desired shape. In such cases not only ducts are obtainable that are not completely parallel to the central axis of rotation, but also ducts that form a helix shape around the axis of rotation. So, in this way very easily the preferred embodiment of having non-parallel ducts can be obtained. Hence it is preferred that the perforations of the discs have been arranged such that the ducts are not parallel to the central axis of rotation or form a helix shape around the axis of rotation.
Further, it will be appreciated that it is relatively easy to increase or decrease the diameter of the perforations. Thereby the skilled person has an easy manner at his disposal to adapt the (hydraulic) diameter of the ducts, and thereby the Reynolds number, so that he can easy ascertain that the flow in the ducts is laminar or turbulent, just as he pleases. The use of these discs also enables the skilled person to vary the diameter of the duct along the axis of the housing. The varying diameter can be selected such that the separated liquid or solid contaminants that are collected against the wall of the duct will not clog up the duct completely, which would hamper the operation of the apparatus.
The skilled person is also now enabled to maximise the porosity of the separating body. The easy construction of the discs allows the skilled person to meticulously provide the disc with as many perforations as he likes. He may also select the shape of the perforations. These may have a circular cross-section, but also square, pentagon, hexagon, octagon or oval cross-sections are possible. He may therefore minimise the wall thickness of the separating body and the wall thicknesses of the ducts. He is able to select the wall thicknesses and the shape of the ducts such that the surface area that is contributed to the cross-section of the separating body by the walls is minimal.
That means that the pressure drop over the separating body can be minimised.
The apparatus can have a small or large number of ducts. Just as explained in the prior art apparatuses the number of ducts suitably ranges from 100 to 1,000,000, preferably from 500 to 500,000. The diameter of the cross-section of the ducts can be varied in accordance with the amount of gas and amounts and nature, e.g., droplet size distribution, of contaminants and the desired contaminants removal efficiency. Suitably, the diameter is from 0.05 to 50 mm, preferably from 0.1 to 20 mm, and more preferably from 0.1 to 5 mm. By diameter is understood twice the radius in case of circular cross-sections or the largest diagonal in case of any other shape.
The size of the apparatus and in particular of the separating body may vary in accordance with the amount of gas to be treated. In EP-B 286 160 it is indicated that separating bodies with a peripheral diameter of 1 m and an axial length of 1.5 m are feasible. The separating body according to the present invention may suitably have a radial length ranging from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length ranges conveniently from 0.1 to 10 m, preferably, from 0.2 to 5 m.
The number of discs may also vary over a large number.
It is possible to have only two discs if a simple separation is needed and/or when the perforations can be easily made. Other considerations may be whether parallel ducts are desired, or whether a uniform diameter is wanted.
Suitably the number of discs varies from 3 to 1000, preferably from 4 to 500, more preferably from 4 to 40.
When more discs, are used the skilled person will find it easier to gradually vary the diameter of the ducts and/or to construct non-parallel ducts. Moreover, by increasing or decreasing the number of discs the skilled person may vary the duct length. So, when the conditions or the composition of the gas changes, the skilled person may adapt the duct length easily to provide the most optimal conditions for the apparatus of the present invention. The size of the discs is selected such that the radial diameter suitably ranges from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length of the discs may be varied in accordance with construction possibilities, desire for varying the shape etc. Suitably, the axial length of each disc ranges from 0.001 to 0.5 m, preferably from 0.002 to 0.2 m, more preferably from 0.005 to 0.1 m.
Although the discs may be manufactured from a variety of materials, including paper, cardboard, and foil, it is preferred to manufacture the discs from metal or ceramics.
Metals discs have the advantage that they can be easily perforated and be combined to firm sturdy separating bodies. Dependent on the material that needs to be purified a suitable metal can be selected. For some applications carbon steel is suitable whereas for other applications, in particular when corrosive materials are to be separated, stainless steel may be preferred. Ceramics have the advantage that they can be extruded into the desired form such as in honeycomb structures with protruding ducts.
Typically, the ceramics precursor material is chosen to form a dense or low-porosity ceramic. Thereby the solid or liquid contaminants are forced to flow along the wall of the ducts and not, or hardly, through the ceramic material of the walls. Examples of ceramic materials are silica, alumina, zirconia, optionally with different types and concentrations of modifiers to adapt its physical and/or chemical properties to the gas and the contaminants.
The discs may be combined to a separating body in a variety of ways. The skilled person will appreciate that such may depend on the material from which the discs have been manufactured. A convenient manner is to attach the discs to a shaft that provides the axis of rotation.
Suitable ways of combining the discs include clamping the discs together, but also gluing them or welding them together can be done. Alternatively, the discs may be stacked in a cylindrical sleeve. This sleeve may also at least partly replace the shaft. This could be convenient for extruded discs since no central opening for the shaft would be required. It is preferred to have metal discs that are welded together.
In a preferred embodiment of the invention, the methane enriched gaseous phase obtained in accordance with the present invention is further purified, e.g. by extraction of remaining acidic components with a chemical solvent, e.g. an aqueous amine solution, especially aqueous ethanolamines, such as DIPA, DMA, MDEA, etc., or with a physical solvent, e.g. cold methanol, DEPG, NMP, etc.
The contaminated gas stream is continuously provided, continuously cooled and continuously separated.
The present invention also relates to a device (plant) for carrying out the process as described above, as well as the purified gas stream obtained by the present process. In addition, the present invention concerns a process for liquefying a feed gas stream comprising purifying the feed gas stream by means of the present process, followed by liquifying the purified feed gas stream by methods known in the art.
The invention will be further illustrated by means of the following Figures.
Referring to Figure 1, natural gas via a conduit 1 is passed through an expansion means 2, whereby a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase. The stream flows via a conduit 3 into a gas/liquid separator 4 wherein the two phases are separated from each other. The liquid phase contaminant is recovered via a conduit 5, whereas the methane enriched gaseous phase is passed via a conduit 6 into a heat exchanger 7. In heat exchanger 7 ethane is used an external refrigerant whereby ethane is cooled by means of an ethane/propane cascade 8 as depicted in more detail in Figure 2. The cooling in heat exchanger 7 is such that a liquid phase contaminant and a methane enriched gaseous phase are formed. The stream which comprises these two phases is then passed via a conduit 9 into a distillation column 10 from which a further enriched methane enriched gaseous phase is recovered via a conduit 11 and liquid phase contaminant is recovered via a conduit 12.
In Figure 2 a suitable heat exchanger 7 is shown which is based on an ethane/propane cascade which comprises an ethane loop and a propane loop. In the ethane loop an ethane stream is passed via a conduit 13 into an expander 14 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled ethane stream so obtained is passed via a conduit 15 into the heat exchanger 7. A stream of warm ethane is then passed from the heat exchanger 7 to a recompressor 16 via a conduit 17 to increase the pressure of the ethane stream. The compressed stream of ethane obtained from recompressor 16 is then passed via a conduit 18 into heat exchanger 19 wherein the ethane stream is cooled and at least partly condensed. Via the conduit 13 the ethane stream is then recycled to the expander 14. In the propane loop a propane stream is passed via a conduit 20 into an expander 21 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled propane stream so obtained is passed via a conduit 22 into the heat exchanger 19 of the ethane loop. A stream of warm propane is then passed from the heat exchanger 19 via a conduit 23 into a recompressor 24 to increase the pressure of the propane stream. The compressed stream of propane obtained from recompressor 24 is then passed via a conduit 25 into a heat exchanger 26 wherein the propane stream is cooled and at least partly condensed by means of water or air. Via the conduit 20 the propane stream is then recycled to the expander 21.
In Figure 3 a preferred gas/liquid separator is shown for carrying out step 3) of the present process. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 into the gas/liquid separator 4 via supply and distribution assembly 27. Most of the liquid will flow down to the lower end of the separator and leave the separator via the liquid outlet 5. The gaseous stream comprising larger and smaller droplets will flow upwards via liquid coalescer 28, centrifugal separator 29 and a second liquid coalescer 30 to the top of the separator vessel, and leave the separator vessel via gas outlet 6.
In Figure 4 another preferred gas/liquid separator is shown for carrying out step 3) of the present process. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 to a gas inlet 31 in a housing 32 of the gas/liquid separator 4.
The housing 32 further comprises a separating body 33 which shows a large number of ducts 34 which are arranged around a shaft 35, which provides an axis of rotation. Separating body 33 has been composed of six discs 33a, 33b, 33c, 33d, 33e and 33f that have been combined by welding or gluing.
In the rotating separating body droplets of carbon dioxide and/or hydrogen sulphide are separated from the natural gas. The separated contaminants are discharged from the housing via a contaminants outlet 36 which has been arranged downstream of the separating body 33, and via the discharge conduit 5. Purified natural gas leaves housing 32 via the gas outlet 6 arranged at the opposite end of the housing 32.
Claims (15)
1. A process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, the process comprising:
1) providing the feed gas stream;
1) providing the feed gas stream;
2) cooling the feed gas stream to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase;
3) separating the two phases obtained in step 2) by means of a gas/liquid separator; and
4) subjecting the methane enriched gaseous phase obtained in step 3) to a distillation treatment in a distillation device thereby obtaining a bottom stream rich in liquid phase contaminant and lean in methane, and a top stream rich in methane and lean in gaseous contaminant.
2. A process according to claim 1, in which the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide, preferably in which the natural gas stream comprises between 1 and 90 vol% of carbon dioxide, preferably between 5 and 80 vol% of carbon dioxide and/or wherein the natural gas stream comprises between 0.1 and 60 vol% of hydrogen sulphide, preferably between 20 and 40 vol% of hydrogen sulphide.
3. A process according to claim 1 or 2, in which the feed gas stream comprises between 20 and 80 vol% of methane.
4. A process according to any one of claims 1 to3, in which the feed gas stream in step 1) has a temperature between -20 and 150°C, preferably between -10 and 70°C, and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
2. A process according to claim 1, in which the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide, preferably in which the natural gas stream comprises between 1 and 90 vol% of carbon dioxide, preferably between 5 and 80 vol% of carbon dioxide and/or wherein the natural gas stream comprises between 0.1 and 60 vol% of hydrogen sulphide, preferably between 20 and 40 vol% of hydrogen sulphide.
3. A process according to claim 1 or 2, in which the feed gas stream comprises between 20 and 80 vol% of methane.
4. A process according to any one of claims 1 to3, in which the feed gas stream in step 1) has a temperature between -20 and 150°C, preferably between -10 and 70°C, and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
5. A process according to any one of claims 1 to 4, in which the cooling in step 2) is done by isenthalpic expansion, preferably isenthalpic expansion over an orifice or a valve, especially a Joule-Thomson valve, or in which the cooling is done by nearly isentropic expansion, especially by means of an expander, preferably a turbo expander or a laval nozzle, preferably in which the feed gas stream is pre-cooled to a temperature between 15 and -35°C, preferably between 10 and -20°C, before expansion.
6. A process according to claim 5, wherein the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied acidic contaminants have a certain droplet size distribution.
7. A process according to any one of claims 1 to6, in which the feed gas stream is cooled in step 2) to a temperature between -30 and -80°C, preferably between -40 and -65°C.
8. A process according to any one of claims 1 to 7, in which the methane enriched gaseous phase obtained in step 3) is recompressed in one more compression steps before it is subjected to the distillation treatment in step 4), preferably in which energy that is recovered in step 2) is used for one or more compression steps.
9. A process according to any one of claims 1 to 8, in which the methane enriched gaseous phase obtained in step 3) or the recompressed methane enriched gaseous phase obtained in the one or more compression steps is cooled in a cooling step to a temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase, and the methane enriched gaseous phase so obtained is subjected to the distillation treatment in step 4).10.
A process according to claim 9, in which the cooling between steps 3) and 4) is at least partly done by means of an external refrigerant preferably in which the external refrigerant has a higher molecular weight than the methane enriched gaseous phase to be cooled, more preferably in which the external refrigerant comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade.
A process according to claim 9, in which the cooling between steps 3) and 4) is at least partly done by means of an external refrigerant preferably in which the external refrigerant has a higher molecular weight than the methane enriched gaseous phase to be cooled, more preferably in which the external refrigerant comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade.
10. A process according to any one of claims 1 to 10, in which the bottom temperature of the distillation section is between 0 and 30°C, or in which the top temperature of the distillation section is between -20 and -90°C.
11. A process according to any one of claims 1 to 11, in which the gas/liquid separator in step 3) comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
12. A process according to any one of claims 1 to 11, in which the gas/liquid separator in step 3) comprises a centrifugal separator which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube, preferably in which the centrifugal separator is spinned by introducing a swirling gas stream into the spinning tube.
13. A process according to any one of claims 1 to 13, in which the gas/liquid separator in step 3) comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body or upstream and downstream of the separating body, wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
14. A process according to any one of claims 1 to 14, wherein a gas/liquid separator is used comprising:
a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
b) tangentially arranged inlet means to introduce the mixture into the first separation section;
c) means to remove liquid from the first separation section;
d) means to remove liquid from the third separation section; and e) means to remove a gaseous stream, lean in liquid, from the third separation section
a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
b) tangentially arranged inlet means to introduce the mixture into the first separation section;
c) means to remove liquid from the first separation section;
d) means to remove liquid from the third separation section; and e) means to remove a gaseous stream, lean in liquid, from the third separation section
15. A device for carrying out the process according to any one of claims 1-14.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08164886.7 | 2008-09-23 | ||
| EP08164886 | 2008-09-23 | ||
| PCT/EP2009/061798 WO2010034628A1 (en) | 2008-09-23 | 2009-09-11 | Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2735920A1 true CA2735920A1 (en) | 2010-04-01 |
Family
ID=40351798
Family Applications (1)
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|---|---|---|---|
| CA2735920A Abandoned CA2735920A1 (en) | 2008-09-23 | 2009-09-11 | Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants |
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| US (1) | US20110192192A1 (en) |
| CA (1) | CA2735920A1 (en) |
| EA (1) | EA201100521A1 (en) |
| WO (1) | WO2010034628A1 (en) |
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| US10330363B2 (en) | 2016-02-08 | 2019-06-25 | Trane International Inc. | Lubricant separator for a heating, ventilation, and air conditioning system |
| GB2548548B (en) * | 2016-02-23 | 2020-12-09 | Sagetech Medical Equipment Ltd | Improvements in the capture and elution of halocarbons by supercritical fluids |
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| USH825H (en) * | 1988-05-20 | 1990-10-02 | Exxon Production Research Company | Process for conditioning a high carbon dioxide content natural gas stream for gas sweetening |
| DE60002992T2 (en) * | 1999-03-05 | 2004-05-19 | Shell Internationale Research Maatschappij B.V. | DREIPHASENABSCHEIDER |
| FR2814378B1 (en) * | 2000-09-26 | 2002-10-31 | Inst Francais Du Petrole | PROCESS FOR PRETREATMENT OF A NATURAL GAS CONTAINING ACID GASES |
| US6836520B1 (en) * | 2000-11-10 | 2004-12-28 | Motorola, Inc. | Method and apparatus for establishing synchronization with a synchronization signal |
| ATE376866T1 (en) * | 2002-02-21 | 2007-11-15 | Shell Int Research | DEVICE AND METHOD FOR TREATING LIQUIDS |
| FR2848121B1 (en) * | 2002-12-04 | 2005-01-28 | Inst Francais Du Petrole | PROCESS FOR TREATING AN ACIDIC NATURAL GAS |
| FR2883769B1 (en) * | 2005-03-31 | 2007-06-08 | Inst Francais Du Petrole | PROCESS FOR PRETREATING AN ACIDIC GAS |
| NL2000292C2 (en) * | 2006-10-27 | 2008-04-29 | Romico Hold A V V | Method for separating a medium mixture into fractions. |
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- 2009-09-11 US US13/120,411 patent/US20110192192A1/en not_active Abandoned
- 2009-09-11 EA EA201100521A patent/EA201100521A1/en unknown
- 2009-09-11 WO PCT/EP2009/061798 patent/WO2010034628A1/en active Application Filing
- 2009-09-11 CA CA2735920A patent/CA2735920A1/en not_active Abandoned
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| WO2010034628A1 (en) | 2010-04-01 |
| EA201100521A1 (en) | 2011-08-30 |
| US20110192192A1 (en) | 2011-08-11 |
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| Date | Code | Title | Description |
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| FZDE | Discontinued |
Effective date: 20130911 |