US20110192190A1 - Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants - Google Patents

Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants Download PDF

Info

Publication number
US20110192190A1
US20110192190A1 US13/120,410 US200913120410A US2011192190A1 US 20110192190 A1 US20110192190 A1 US 20110192190A1 US 200913120410 A US200913120410 A US 200913120410A US 2011192190 A1 US2011192190 A1 US 2011192190A1
Authority
US
United States
Prior art keywords
gas
liquid
gas stream
stream
contaminants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/120,410
Inventor
Diki Andrian
Rick Van Der Vaart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell USA Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to SHELL OIL COMPANY reassignment SHELL OIL COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: VAN DER VAART, RICK, ANDRIAN, DIKI
Publication of US20110192190A1 publication Critical patent/US20110192190A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/067Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0605Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
    • F25J3/061Natural gas or substitute natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0635Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00Processes characterised by the type or other details of the product stream
    • F25J2215/04Recovery of liquid products
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/66Separating acid gases, e.g. CO2, SO2, H2S or RSH
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/12External refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/60Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/66Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Definitions

  • the present invention concerns a process for the removal of gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, in particular the removal of gaseous contaminants such as carbon dioxide and hydrogen sulphide from a natural gas.
  • Methane comprising gas streams produced from subsurface reservoirs, especially natural gas, associated gas and coal bed methane, usually contain contaminants as carbon dioxide, hydrogen sulphide, carbon oxysulphide, mercaptans, sulphides and aromatic sulphur containing compounds in varying amounts.
  • the contaminants needs to be removed, either partly or almost completely, depending on the specific contaminant and/or the use.
  • the sulphur compounds need to be removed into the ppm level, carbon dioxide sometimes into ppm level, e.g. LNG applications, or down to 2 or 3 vol. percent, e.g. for use as heating gas. Higher hydrocarbons may be present, which, depending on the use, may be recovered.
  • Processes for the removal of carbon dioxide and sulphur compounds are know in the art. These processes include absorption processes using e.g. aqueous amine solutions or adsorption processes using e.g. molecular sieves. These processes are especially suitable for the removal of contaminants, especially carbon dioxide and hydrogen sulphide, that are present in relatively low amounts, e.g. up till several vol %.
  • a method for removing contaminating gaseous components, such as carbon dioxide and hydrogen sulphide, from a natural gas stream.
  • a contaminated natural gas stream is cooled in a first expander to obtain an expanded gas stream having a temperature and pressure at which the dewpointing conditions of the phases containing a preponderance of contaminating components, such a carbon dioxide and/or hydrogen sulphide are achieved.
  • the expanded gas stream is then supplied to a first centrifugal separator to establish the separation of a contaminants-enriched liquid phase and a contaminants-depleted gaseous phase.
  • the contaminants-depleted gaseous phase is then passed via a recompressor, an interstage cooler, and a second expander into a second centrifugal separator.
  • the interstage cooler and the second expander are used to cool the contaminants-depleted gaseous phase to such an extent that again a contaminants-enriched liquid phase and a further contaminants-depleted gaseous phase are obtained which are subsequently separated from each other by means of the second centrifugal separator.
  • energy recovered from the first expansion step is used in the compression step, and air, water and/or an internal process stream is used in the interstage cooler.
  • a disadvantage of this known method is that the use of a recompressor, interstage cooler and an expander between the two centrifugal separators affects the hydrocarbon efficiency of the separation process, which hydrocarbon efficiency is a measure of the fuel gas consumption and the hydrocarbon loss in the liquid phase contaminant streams during the process.
  • the present invention concerns a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, which process comprises:
  • step 1) providing the feed gas stream; 2) cooling the feed gas stream to a first temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; 3) separating the two phases obtained in step 2) by means of a first gas/liquid separator; 4) cooling the methane enriched gaseous phase obtained in step 3) at least partly by means of an external refrigerant to a second temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; and 5) separating the two phases obtained in step 4) by means of a second gas/liquid separator.
  • the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide.
  • the natural gas stream suitably comprises between 1 and 90 vol % of carbon dioxide, preferably between 5 and 80 vol % of carbon dioxide.
  • the natural gas stream suitably comprises between 0.1 to 60 vol % of hydrogen sulphide, preferably between 20 and 40 vol % of hydrogen sulphide.
  • the feed gas stream to be used in accordance with the present invention comprises between 20 and 80 vol % of methane.
  • the feed gas stream in step 1) has a temperature between ⁇ 20 and 150° C., preferably between ⁇ 10 and 70° C., and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
  • the raw feed gas stream may be pre-treated to partially or completely remove water and optionally some heavy hydrocarbons. This can for instance be done by means of a pre-cooling cycle, against an external cooling loop or a cold internal process stream. Water may also be removed by means of pre-treatment with molecular sieves, e.g. zeolites, or silica gel or alumina oxide or other drying agents such as glycol, MEG, DEG or TEG, or glycerol.
  • the amount of water in the gas feed stream is suitably less than 1 vol %, preferably less than 0.1 vol %, more preferably less than 0.0001 vol %.
  • the cooling in step 2) of the feed gas stream may be done by methods known in the art. For instance, cooling may be done against an external cooling fluid. In the case that the pressure of the feed gas is sufficiently high, cooling may be obtained by expansion of the feed gas stream.
  • a suitable method to cool the feed gas stream is done by nearly isentropic expansion, especially by means of an expander, preferably a turbo expander or laval nozzle.
  • Another suitable method is to cool the feed gas stream by isenthalpic expansion, preferably isenthalpic expansion over an orifice or a valve, especially over a Joule-Thomson valve.
  • the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied contaminants in the cooled stream have a certain droplet size distribution.
  • the use of at least two expansion devices allows the control of the droplet size distribution of condensed contaminants.
  • the feed gas stream is pre-cooled before expansion. This may be done against an external cooling loop or against a cold process stream, e.g. liquid contaminant.
  • the gas stream is pre-cooled before expansion to a temperature between 15 and ⁇ 35° C., preferably between 10° C. and ⁇ 20° C. Pre-cooling may be done against internal process streams.
  • the temperature of the feed gas stream may be between 100 and 150° C. In that case air or water cooling may be used to decrease the temperature first, optionally followed by further cooling.
  • Another suitable cooling method is heat exchange against a cold fluidum, especially an external refrigerant, e.g. a propane cycle, an ethane/propane cascade or a mixed refrigerant cycle, optionally in combination with an internal process loop, suitably a carbon dioxide stream (liquid or slurry), a cold methane enriched stream or washing fluid.
  • an external refrigerant e.g. a propane cycle, an ethane/propane cascade or a mixed refrigerant cycle
  • an internal process loop suitably a carbon dioxide stream (liquid or slurry), a cold methane enriched stream or washing fluid.
  • the feed gas stream is cooled in steps 2) and 4) to a temperature between ⁇ 30 and ⁇ 80° C., preferably between ⁇ 40 and ⁇ 65° C. At these temperatures liquid phase contaminant will be formed.
  • the pressure applied in step 4) can be higher than the pressure applied in step 2).
  • the second temperature in step 4) is lower than the first temperature in step 2).
  • the second temperature in step 4) is up to 20° C. lower than the first temperature in step 2). More preferably, the second temperature is between 5 and 10° C. lower than the first temperature in step 2).
  • the cooling in step 4) can be carried out by means of an internal process stream such as a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
  • the cooling of the methane enriched gaseous phase in step 4) can suitably at least partly be done by means of an external refrigerant.
  • the external refrigerant to be used in step 4) has a higher molecular weight than the methane enriched gaseous phase to be cooled.
  • suitable examples of such cooling medium include ethane, propane and butane.
  • the cooling medium comprises ethane and/or propane.
  • the external refrigerant to be used comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade.
  • a propane cycle an ethane/propane mixed refrigerant or an ethane/propane cascade.
  • the cooling in step 4) can suitably be partly done by means of an external refrigerant and partly by means of an internal process stream, e.g. a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
  • step 4 as, for instance, done by use of an external refrigerant can very attractively replace the sequence of the recompressor, interstage cooler and the expander which is used between the two centrifugal separators as described in WO 2006/087332, improving the hydrocarbon efficiency of the separation process.
  • the methane enriched gaseous phase obtained in step 3) is recompressed in one or more compression steps before step 4) is carried out.
  • the methane enriched gaseous phase obtained in step 3) is firstly cooled by means of an interstage cooler before the cooling in step 4) is carried out.
  • the methane enriched gaseous phase obtained in step 3) is firstly recompressed in one or more compression steps, than cooled by means of an interstage cooler, and subsequently cooled in step 4).
  • such an interstage cooler will be based on a internal process stream and air or water cooling.
  • this cooler is designed in such a way that liquid is effectively removed form the cooling device without impairing heat transfer.
  • gas/liquid separators can suitably be used in steps 3) and 5), such as, for instance, rotating centrifuges or cyclones.
  • steps 3) and 5) use can be made of different types or similar types of gas/liquid separators.
  • steps 3) and 5) is made of similar types of gas/liquid separators.
  • Suitable gas/liquid separators to be used in accordance with the present invention have, for instance, been described in WO 2008/082291, WO 2006/087332, WO 2005/118110, WO 97/44117, WO 2007/097621 and WO 94/23823, which documents are hereby incorporated by reference.
  • the gas/liquid separator requirements in step 3) are more stringent than the requirements in step 5) since homogeneous droplet nucleation after expansion does produce smaller droplets than heterogeneous nucleation in a heat exchanger, cooled by an external process stream.
  • the first and/or second gas/liquid separator comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
  • the gas/liquid inlet comprises an admittance with a supply and distribution assembly extending horizontally in the separator vessel.
  • the inlet is a simple pipe, having a closed end and a number of perforations evenly distributed over the length of the pipe.
  • the pipe may have a tapered or conical shape.
  • One or more cross pipes may be present to create a grid system to distribute the gas-liquid mixture more evenly over the cross-section of the vessel.
  • the assembly includes a chamber, e.g. a longitudinal box-like structure, connected to the gas inlet and having at least one open vertical side with a grid of guide vanes disposed one behind each other, seen in the direction of the flow.
  • the gas is evenly distributed by the guide vanes over the cross-section of the column, which brings about an additional improvement of the liquid separation in the coalescer/centrifugal separator combination.
  • a further advantage is that the supply and distribution assembly separates from the gas any slugs of liquid which may suddenly occur in the gas stream, the separation being effected by the liquid colliding with the guide vanes and falling down inside the column.
  • the box structure narrows down in the direction of the flow. After having been distributed by the vanes over the column cross-section, the gas flows up to the coalescer.
  • the longitudinal chamber has two open vertical sides with a grid of guide vanes.
  • Suitable gas/liquid inlets are those described in e.g. GB 1,119,699, U.S. Pat. No. 6,942,720, EP 195,464, U.S. Pat. No. 6,386,520 and U.S. Pat. No. 6,537,458.
  • a suitable, commercially available gas/liquid inlet is a Schoepentoeter.
  • mist eliminator There are numerous horizontal coalescers available, especially for vertical columns.
  • demister mat A well-known example of a mist eliminator is the demister mat. All of these are relatively tenuous (large permeability) and have a relatively large specific (internal) surface area. Their operation is based on drop capture by collision of drops with internal surfaces, followed by drop growth on these surfaces, and finally by removal of the grown drop either by the gas or by gravity.
  • the horizontal coalescer can have many forms which are known per se and may, for example, consist of a bed of layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze, or a layer of vanes or a layer of structured packing. Also unstructured packings can be used and also one or more trays may be present. All these sorts of coalescers have the advantage of being commercially available and operating efficiently in the column according to the invention. See also Perry's Chemical Engineers' Handbook, Sixth edition, especially Chapter 18. See also EP 195464.
  • the centrifugal liquid separator in one of its most simple forms may comprise a horizontal plate and one or more vertical swirl tubes extending downwardly from the plate, each swirl tube having one or more liquid outlets below the horizontal plate at the upper end of the swirl tube.
  • the centrifugal liquid separator comprises one or more vertical swirl tubes extending upwardly from the plate, each swirl tube having one or more liquid outlets at the upper end.
  • the plate is provided with a downcomer, preferably a downcomer that extends to the lower end of the separator vessel.
  • the centrifugal liquid separator comprises two horizontal trays between which vertical open-ended swirl tubes extend, each from an opening in the lower tray to some distance below a coaxial opening in the upper tray, means for the discharge of secondary gas and of liquid from the space between the trays outside the swirl tubes, and means provided in the lower part of the swirl tubes to impart to the gas/liquid a rotary movement around the vertical axis.
  • the liquid separator is also preferably provided with vertical tube pieces which project down from the coaxial openings in the upper tray into the swirl tubes and have a smaller diameter than these latter. This arrangement enhances the separation between primary gas on the one hand and secondary gas and liquid on the other hand, since these latter cannot get from the swirl tubes into the openings in the upper tray for primary gas.
  • the means for discharging the secondary gas from the space between the trays consist of vertical tubelets through the upper tray, and the means for discharging liquid from the space between the trays consist of one or more vertical discharge pipes which extend from this space to the bottom of the column.
  • This arrangement has the advantage that the secondary gas, after having been separated from liquid in the said space between the trays, is immediately returned to the primary gas, and the liquid is added to the liquid at the bottom of the column after coming from the coalescer, so that the secondary gas and the liquid removed in the centrifugal separator do not require separate treatment.
  • openings are preferably provided in accordance with the invention at the top of the swirl tubes for discharging liquid to the space between the trays outside the swirl tubes. This has the advantage that less secondary gas is carried to the space between the trays.
  • a suitable, commercially available centrifugal separator is a Shell Swirltube deck.
  • the separation vessel comprises a second normally horizontal liquid coalescer above the centrifugal liquid separator and over the whole cross-section of the vessel.
  • the second coalescer is a bed of one or more layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze.
  • the second normally horizontal liquid coalescer is situated above the secondary gas outlets, for instance in the way as described in EP 83811, especially as depicted in FIG. 4 .
  • a first and/or second separator comprising:
  • a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element; b) tangentially arranged inlet means to introduce the mixture into the first separation section; c) means to remove liquid from the first separation section; d) means to remove liquid from the third separation section; and e) means to remove a gaseous stream, lean in liquid, from the third separation section.
  • the first and/or second gas/liquid separator may suitably comprise a centrifugal separator which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube.
  • the centrifugal separator is spinned by introducing a swirling gas stream into the spinning tube.
  • the centrifugal separator to be used in accordance with the present invention comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body or upstream and downstream of the separating body, wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
  • the discs can be easily created by drilling or cutting a plurality of perforations into the relatively thin discs. By attaching several discs to together these discs form a separating body. By aligning the perforations ducts are obtained.
  • the resulting ducts can be given any desired shape. In such cases not only ducts are obtainable that are not completely parallel to the central axis of rotation, but also ducts that form a helix shape around the axis of rotation. So, in this way very easily the preferred embodiment of having non-parallel ducts can be obtained.
  • the perforations of the discs have been arranged such that the ducts are not parallel to the central axis of rotation or form a helix shape around the axis of rotation.
  • the skilled person is also now enabled to maximise the porosity of the separating body.
  • the easy construction of the discs allows the skilled person to meticulously provide the disc with as many perforations as he likes. He may also select the shape of the perforations. These may have a circular cross-section, but also square, pentagon, hexagon, octagon or oval cross-sections are possible. He may therefore minimise the wall thickness of the separating body and the wall thicknesses of the ducts. He is able to select the wall thicknesses and the shape of the ducts such that the surface area that is contributed to the cross-section of the separating body by the walls is minimal. That means that the pressure drop over the separating body can be minimised.
  • the apparatus can have a small or large number of ducts.
  • the number of ducts suitably ranges from 100 to 1,000,000, preferably from 500 to 500,000.
  • the diameter of the cross-section of the ducts can be varied in accordance with the amount of gas and amounts and nature, e.g., droplet size distribution, of contaminants and the desired contaminants removal efficiency.
  • the diameter is from 0.05 to 50 mm, preferably from 0.1 to 20 mm, and more preferably from 0.1 to 5 mm.
  • diameter is understood twice the radius in case of circular cross-sections or the largest diagonal in case of any other shape.
  • the size of the apparatus and in particular of the separating body may vary in accordance with the amount of gas to be treated.
  • EP-B 286 160 it is indicated that separating bodies with a peripheral diameter of 1 m and an axial length of 1.5 m are feasible.
  • the separating body according to the present invention may suitably have a radial length ranging from 0.1 to 5 m, preferably from 0.2 to 2 m.
  • the axial length ranges conveniently from 0.1 to 10 m, preferably, from 0.2 to 5 m.
  • the number of discs may also vary over a large number. It is possible to have only two discs if a simple separation is needed and/or when the perforations can be easily made. Other considerations may be whether parallel ducts are desired, or whether a uniform diameter is wanted. Suitably the number of discs varies from 3 to 1000, preferably from 4 to 500, more preferably from 4 to 40. When more discs, are used the skilled person will find it easier to gradually vary the diameter of the ducts and/or to construct non-parallel ducts. Moreover, by increasing or decreasing the number of discs the skilled person may vary the duct length.
  • the size of the discs is selected such that the radial diameter suitably ranges from 0.1 to 5 m, preferably from 0.2 to 2 m.
  • the axial length of the discs may be varied in accordance with construction possibilities, desire for varying the shape etc.
  • the axial length of each disc ranges from 0.001 to 0.5 m, preferably from 0.002 to 0.2 m, more preferably from 0.005 to 0.1 m.
  • the discs may be manufactured from a variety of materials, including paper, cardboard, and foil, it is preferred to manufacture the discs from metal or ceramics.
  • Metals discs have the advantage that they can be easily perforated and be combined to firm sturdy separating bodies. Dependent on the material that needs to be purified a suitable metal can be selected. For some applications carbon steel is suitable whereas for other applications, in particular when corrosive materials are to be separated, stainless steel may be preferred. Ceramics have the advantage that they can be extruded into the desired form such as in honeycomb structures with protruding ducts.
  • the ceramics precursor material is chosen to form a dense or low-porosity ceramic.
  • the solid or liquid contaminants are forced to flow along the wall of the ducts and not, or hardly, through the ceramic material of the walls.
  • ceramic materials are silica, alumina, zirconia, optionally with different types and concentrations of modifiers to adapt its physical and/or chemical properties to the gas and the contaminants.
  • the discs may be combined to a separating body in a variety of ways. The skilled person will appreciate that such may depend on the material from which the discs have been manufactured. A convenient manner is to attach the discs to a shaft that provides the axis of rotation. Suitable ways of combining the discs include clamping the discs together, but also gluing them or welding them together can be done. Alternatively, the discs may be stacked in a cylindrical sleeve. This sleeve may also at least partly replace the shaft. This could be convenient for extruded discs since no central opening for the shaft would be required. It is preferred to have metal discs that are welded together.
  • the methane enriched gaseous phase obtained in accordance with the present invention is further purified, e.g. by extraction of remaining acidic components with a chemical solvent, e.g. an aqueous amine solution, especially aqueous ethanolamines, such as DIPA, DMA, MDEA, etc., or with a physical solvent, e.g. cold methanol, DEPG, NMP, etc.
  • a chemical solvent e.g. an aqueous amine solution, especially aqueous ethanolamines, such as DIPA, DMA, MDEA, etc.
  • a physical solvent e.g. cold methanol, DEPG, NMP, etc.
  • the contaminated gas stream is continuously provided, continuously cooled and continuously separated.
  • the present invention also relates to a device (plant) for carrying out the process as described above, as well as the purified gas stream obtained by the present process.
  • the present invention concerns a process for liquefying a feed gas stream comprising purifying the feed gas stream by means of the present process, followed by liquifying the purified feed gas stream by methods known in the art.
  • natural gas via a conduit 1 is passed through an expansion means 2 , whereby a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase.
  • the stream flows via a conduit 3 into a gas/liquid separator 4 wherein the two phases are separated from each other.
  • the liquid phase contaminant is recovered via a conduit 5
  • the methane enriched gaseous phase is passed via a conduit 6 into a heat exchanger 7 .
  • heat exchanger 7 ethane is used as an external refrigerant whereby the ethane is cooled by means of an ethane/propane cascade 8 as depicted in more detail in FIG. 2 .
  • the methane enriched gaseous phase is cooled in the heat exchanger 7 to a temperature whereby a liquid phase contaminant and an methane enriched gaseous phase are formed.
  • the stream which comprises these two phases is then passed via a conduit 9 into a gas/liquid separator 10 from which a further enriched methane enriched gaseous phase is recovered via a conduit 11 and liquid phase contaminant is recovered via a conduit 12 .
  • the heat exchanger 7 is shown using ethane that is cooled by means of an ethane/propane cascade which comprises an ethane loop and a propane loop.
  • an ethane stream is passed via a conduit 13 into an expander 14 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled ethane stream so obtained is passed via a conduit 15 into the heat exchanger 7 .
  • a stream of warm ethane is then passed from the heat exchanger 7 to a recompressor 16 via a conduit 17 to increase the pressure of the ethane stream.
  • the compressed stream of ethane obtained from recompressor 16 is then passed via a conduit 18 into a heat exchanger 19 wherein the ethane stream is cooled and at least partly condensed. Via the conduit 13 the ethane stream is then recycled to the expander 14 .
  • a propane stream is passed via a conduit 20 into an expander 21 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled propane stream so obtained is passed via a conduit 22 into the heat exchanger 19 of the ethane loop.
  • a stream of warm propane is then passed from the heat exchanger 19 via a conduit 23 into a recompressor 24 to increase the pressure of the propane stream.
  • the compressed stream of propane obtained from recompressor 24 is then passed via a conduit 25 into heat exchanger 26 wherein the propane stream is cooled and at least partly condensed by means of water or air. Via the conduit 20 the propane stream is then recycled to the expander 21 .
  • FIG. 3 a suitable gas/liquid separator is shown for use in steps 3) and 5) of the present process.
  • Both the gas/liquid separators 4 and 10 as shown in FIG. 1 can be of this type.
  • the stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 (or the conduit 9 ) into the gas/liquid separator 4 (or the gas/liquid separator 10 ) via supply and distribution assembly 27 . Most of the liquid will flow down to the lower end of the separator and leave the separator via the liquid outlet 5 .
  • the gaseous stream comprising larger and smaller droplets will flow upwards via liquid coalescer 28 , centrifugal separator 29 and a second liquid coalescer 30 to the top of the separator vessel, and leave the separator vessel via the gas outlet 6 .
  • FIG. 4 another suitable gas/liquid separator is shown for use in steps 3) and 5) of the present process.
  • Both the gas/liquid separators 4 and 10 as shown in FIG. 1 can be of this type.
  • the stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 (or the conduit 9 ) to a gas inlet 31 in a housing 32 of the gas/liquid separator 4 (or the gas/liquid separator 10 ).
  • the housing 32 further comprises a separating body 33 which shows a large number of ducts 34 which are arranged around a shaft 35 , which provides an axis of rotation.
  • Separating body 33 has been composed of six discs 33 a , 33 b , 33 c , 33 d , 33 e and 33 f that have been combined by welding or gluing.
  • droplets of carbon dioxide and/or hydrogen sulphide are separated from the natural gas.
  • the separated contaminants are discharged from the housing via a contaminants outlet 36 which has been arranged downstream of the separating body 33 , and via the discharge conduit 5 .
  • Purified natural gas leaves housing 32 via the gas outlet 6 arranged at the opposite end of the housing 32 .

Abstract

The invention provides a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, the process comprising: 1) providing the feed gas stream; 2) cooling the feed gas stream to a first temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; 3) separating the two phases obtained in step 2) by means of a first gas/liquid separator; 4) cooling the methane enriched gaseous phase obtained in step 3) at least party by means of an external refrigerant to a second temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; and 5) separating the two phases obtained in step 4) by means of a second gas/liquid separator. The invention further concerns a device for carrying out the present process, the purified gas stream, and a process for liquefying a feed gas stream.

Description

  • The present invention concerns a process for the removal of gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, in particular the removal of gaseous contaminants such as carbon dioxide and hydrogen sulphide from a natural gas.
  • Methane comprising gas streams produced from subsurface reservoirs, especially natural gas, associated gas and coal bed methane, usually contain contaminants as carbon dioxide, hydrogen sulphide, carbon oxysulphide, mercaptans, sulphides and aromatic sulphur containing compounds in varying amounts. For most of the applications of these gas streams, the contaminants needs to be removed, either partly or almost completely, depending on the specific contaminant and/or the use. Often, the sulphur compounds need to be removed into the ppm level, carbon dioxide sometimes into ppm level, e.g. LNG applications, or down to 2 or 3 vol. percent, e.g. for use as heating gas. Higher hydrocarbons may be present, which, depending on the use, may be recovered.
  • Processes for the removal of carbon dioxide and sulphur compounds are know in the art. These processes include absorption processes using e.g. aqueous amine solutions or adsorption processes using e.g. molecular sieves. These processes are especially suitable for the removal of contaminants, especially carbon dioxide and hydrogen sulphide, that are present in relatively low amounts, e.g. up till several vol %.
  • In WO 2006/087332, a method has been described for removing contaminating gaseous components, such as carbon dioxide and hydrogen sulphide, from a natural gas stream. In this method a contaminated natural gas stream is cooled in a first expander to obtain an expanded gas stream having a temperature and pressure at which the dewpointing conditions of the phases containing a preponderance of contaminating components, such a carbon dioxide and/or hydrogen sulphide are achieved. The expanded gas stream is then supplied to a first centrifugal separator to establish the separation of a contaminants-enriched liquid phase and a contaminants-depleted gaseous phase. The contaminants-depleted gaseous phase is then passed via a recompressor, an interstage cooler, and a second expander into a second centrifugal separator. The interstage cooler and the second expander are used to cool the contaminants-depleted gaseous phase to such an extent that again a contaminants-enriched liquid phase and a further contaminants-depleted gaseous phase are obtained which are subsequently separated from each other by means of the second centrifugal separator. In such a method energy recovered from the first expansion step is used in the compression step, and air, water and/or an internal process stream is used in the interstage cooler.
  • A disadvantage of this known method is that the use of a recompressor, interstage cooler and an expander between the two centrifugal separators affects the hydrocarbon efficiency of the separation process, which hydrocarbon efficiency is a measure of the fuel gas consumption and the hydrocarbon loss in the liquid phase contaminant streams during the process.
  • It has now been found that in an integrated process for removing gaseous contaminants from a gas stream the hydrocarbon efficiency can be considerably improved when between a first and a second gas/liquid separation the contaminants-depleted gaseous phase is at least partly cooled by means of an external refrigerant which allows an excellent separation of gaseous contaminants, whereas the use of an expander between the first and second gas/liquid separation can be avoided.
  • Thus, the present invention concerns a process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, which process comprises:
  • 1) providing the feed gas stream;
    2) cooling the feed gas stream to a first temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase;
    3) separating the two phases obtained in step 2) by means of a first gas/liquid separator;
    4) cooling the methane enriched gaseous phase obtained in step 3) at least partly by means of an external refrigerant to a second temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; and
    5) separating the two phases obtained in step 4) by means of a second gas/liquid separator.
  • Suitably, the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide.
  • The natural gas stream suitably comprises between 1 and 90 vol % of carbon dioxide, preferably between 5 and 80 vol % of carbon dioxide.
  • The natural gas stream suitably comprises between 0.1 to 60 vol % of hydrogen sulphide, preferably between 20 and 40 vol % of hydrogen sulphide.
  • The feed gas stream to be used in accordance with the present invention comprises between 20 and 80 vol % of methane.
  • Suitably, the feed gas stream in step 1) has a temperature between −20 and 150° C., preferably between −10 and 70° C., and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
  • The raw feed gas stream may be pre-treated to partially or completely remove water and optionally some heavy hydrocarbons. This can for instance be done by means of a pre-cooling cycle, against an external cooling loop or a cold internal process stream. Water may also be removed by means of pre-treatment with molecular sieves, e.g. zeolites, or silica gel or alumina oxide or other drying agents such as glycol, MEG, DEG or TEG, or glycerol. The amount of water in the gas feed stream is suitably less than 1 vol %, preferably less than 0.1 vol %, more preferably less than 0.0001 vol %.
  • The cooling in step 2) of the feed gas stream may be done by methods known in the art. For instance, cooling may be done against an external cooling fluid. In the case that the pressure of the feed gas is sufficiently high, cooling may be obtained by expansion of the feed gas stream.
  • Combinations may also be possible. A suitable method to cool the feed gas stream is done by nearly isentropic expansion, especially by means of an expander, preferably a turbo expander or laval nozzle. Another suitable method is to cool the feed gas stream by isenthalpic expansion, preferably isenthalpic expansion over an orifice or a valve, especially over a Joule-Thomson valve.
  • Preferably, the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied contaminants in the cooled stream have a certain droplet size distribution. The use of at least two expansion devices allows the control of the droplet size distribution of condensed contaminants.
  • In a preferred embodiment the feed gas stream is pre-cooled before expansion. This may be done against an external cooling loop or against a cold process stream, e.g. liquid contaminant. Preferably the gas stream is pre-cooled before expansion to a temperature between 15 and −35° C., preferably between 10° C. and −20° C. Pre-cooling may be done against internal process streams. Especially when the feed gas stream has been compressed, the temperature of the feed gas stream may be between 100 and 150° C. In that case air or water cooling may be used to decrease the temperature first, optionally followed by further cooling.
  • Another suitable cooling method is heat exchange against a cold fluidum, especially an external refrigerant, e.g. a propane cycle, an ethane/propane cascade or a mixed refrigerant cycle, optionally in combination with an internal process loop, suitably a carbon dioxide stream (liquid or slurry), a cold methane enriched stream or washing fluid.
  • Suitably the feed gas stream is cooled in steps 2) and 4) to a temperature between −30 and −80° C., preferably between −40 and −65° C. At these temperatures liquid phase contaminant will be formed.
  • Suitably, the pressure applied in step 4) can be higher than the pressure applied in step 2).
  • Preferably, the second temperature in step 4) is lower than the first temperature in step 2).
  • Preferably, the second temperature in step 4) is up to 20° C. lower than the first temperature in step 2). More preferably, the second temperature is between 5 and 10° C. lower than the first temperature in step 2).
  • The cooling in step 4) can be carried out by means of an internal process stream such as a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
  • In accordance with the present invention the cooling of the methane enriched gaseous phase in step 4) can suitably at least partly be done by means of an external refrigerant.
  • Preferably, the external refrigerant to be used in step 4) has a higher molecular weight than the methane enriched gaseous phase to be cooled. Suitable examples of such cooling medium include ethane, propane and butane. Preferably, the cooling medium comprises ethane and/or propane.
  • More preferably, the external refrigerant to be used comprises a propane cycle, an ethane/propane mixed refrigerant or an ethane/propane cascade. Such an ethane/propane cascade is described in more detail hereinbelow.
  • The cooling in step 4) can suitably be partly done by means of an external refrigerant and partly by means of an internal process stream, e.g. a stream of liquid phase contaminant which is separated from the methane enriched gaseous phase in step 3).
  • The cooling in step 4) as, for instance, done by use of an external refrigerant can very attractively replace the sequence of the recompressor, interstage cooler and the expander which is used between the two centrifugal separators as described in WO 2006/087332, improving the hydrocarbon efficiency of the separation process.
  • In another embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is recompressed in one or more compression steps before step 4) is carried out.
  • In another embodiment of the present invention the methane enriched gaseous phase obtained in step 3) is firstly cooled by means of an interstage cooler before the cooling in step 4) is carried out.
  • In yet another embodiment of the present invention, the methane enriched gaseous phase obtained in step 3) is firstly recompressed in one or more compression steps, than cooled by means of an interstage cooler, and subsequently cooled in step 4).
  • Suitably, such an interstage cooler will be based on a internal process stream and air or water cooling.
  • Suitably, in the case liquid is formed inside the cooler, this cooler is designed in such a way that liquid is effectively removed form the cooling device without impairing heat transfer.
  • In the one or more compression steps suitably energy is used that is recovered in step 2).
  • In the process according to the present invention a variety of gas/liquid separators can suitably be used in steps 3) and 5), such as, for instance, rotating centrifuges or cyclones.
  • In steps 3) and 5) use can be made of different types or similar types of gas/liquid separators. Suitably, in steps 3) and 5) is made of similar types of gas/liquid separators.
  • Suitable gas/liquid separators to be used in accordance with the present invention have, for instance, been described in WO 2008/082291, WO 2006/087332, WO 2005/118110, WO 97/44117, WO 2007/097621 and WO 94/23823, which documents are hereby incorporated by reference.
  • Typically, the gas/liquid separator requirements in step 3) are more stringent than the requirements in step 5) since homogeneous droplet nucleation after expansion does produce smaller droplets than heterogeneous nucleation in a heat exchanger, cooled by an external process stream.
  • In a preferred embodiment of the present invention, the first and/or second gas/liquid separator comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
  • When using a vertical gas/liquid separator vessel, the process only needs a relatively small area.
  • According to a preferred embodiment, the gas/liquid inlet comprises an admittance with a supply and distribution assembly extending horizontally in the separator vessel. In its most simple form, the inlet is a simple pipe, having a closed end and a number of perforations evenly distributed over the length of the pipe. Optionally, the pipe may have a tapered or conical shape. One or more cross pipes may be present to create a grid system to distribute the gas-liquid mixture more evenly over the cross-section of the vessel. Preferably, the assembly includes a chamber, e.g. a longitudinal box-like structure, connected to the gas inlet and having at least one open vertical side with a grid of guide vanes disposed one behind each other, seen in the direction of the flow. By means of this supply and distribution assembly, the gas is evenly distributed by the guide vanes over the cross-section of the column, which brings about an additional improvement of the liquid separation in the coalescer/centrifugal separator combination. A further advantage is that the supply and distribution assembly separates from the gas any slugs of liquid which may suddenly occur in the gas stream, the separation being effected by the liquid colliding with the guide vanes and falling down inside the column. Suitably, the box structure narrows down in the direction of the flow. After having been distributed by the vanes over the column cross-section, the gas flows up to the coalescer.
  • In a preferred embodiment the longitudinal chamber has two open vertical sides with a grid of guide vanes.
  • Suitable gas/liquid inlets are those described in e.g. GB 1,119,699, U.S. Pat. No. 6,942,720, EP 195,464, U.S. Pat. No. 6,386,520 and U.S. Pat. No. 6,537,458. A suitable, commercially available gas/liquid inlet is a Schoepentoeter.
  • There are numerous horizontal coalescers available, especially for vertical columns. A well-known example of a mist eliminator is the demister mat. All of these are relatively tenuous (large permeability) and have a relatively large specific (internal) surface area. Their operation is based on drop capture by collision of drops with internal surfaces, followed by drop growth on these surfaces, and finally by removal of the grown drop either by the gas or by gravity.
  • The horizontal coalescer can have many forms which are known per se and may, for example, consist of a bed of layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze, or a layer of vanes or a layer of structured packing. Also unstructured packings can be used and also one or more trays may be present. All these sorts of coalescers have the advantage of being commercially available and operating efficiently in the column according to the invention. See also Perry's Chemical Engineers' Handbook, Sixth edition, especially Chapter 18. See also EP 195464.
  • The centrifugal liquid separator in one of its most simple forms may comprise a horizontal plate and one or more vertical swirl tubes extending downwardly from the plate, each swirl tube having one or more liquid outlets below the horizontal plate at the upper end of the swirl tube. In another form, the centrifugal liquid separator comprises one or more vertical swirl tubes extending upwardly from the plate, each swirl tube having one or more liquid outlets at the upper end. The plate is provided with a downcomer, preferably a downcomer that extends to the lower end of the separator vessel.
  • In a preferred embodiment of the invention, the centrifugal liquid separator comprises two horizontal trays between which vertical open-ended swirl tubes extend, each from an opening in the lower tray to some distance below a coaxial opening in the upper tray, means for the discharge of secondary gas and of liquid from the space between the trays outside the swirl tubes, and means provided in the lower part of the swirl tubes to impart to the gas/liquid a rotary movement around the vertical axis.
  • The liquid separator is also preferably provided with vertical tube pieces which project down from the coaxial openings in the upper tray into the swirl tubes and have a smaller diameter than these latter. This arrangement enhances the separation between primary gas on the one hand and secondary gas and liquid on the other hand, since these latter cannot get from the swirl tubes into the openings in the upper tray for primary gas.
  • According to a preferred embodiment, the means for discharging the secondary gas from the space between the trays consist of vertical tubelets through the upper tray, and the means for discharging liquid from the space between the trays consist of one or more vertical discharge pipes which extend from this space to the bottom of the column. This arrangement has the advantage that the secondary gas, after having been separated from liquid in the said space between the trays, is immediately returned to the primary gas, and the liquid is added to the liquid at the bottom of the column after coming from the coalescer, so that the secondary gas and the liquid removed in the centrifugal separator do not require separate treatment.
  • In order to improve even further the liquid separation in the centrifugal separator, openings are preferably provided in accordance with the invention at the top of the swirl tubes for discharging liquid to the space between the trays outside the swirl tubes. This has the advantage that less secondary gas is carried to the space between the trays. A suitable, commercially available centrifugal separator is a Shell Swirltube deck.
  • In a preferred embodiment, the separation vessel comprises a second normally horizontal liquid coalescer above the centrifugal liquid separator and over the whole cross-section of the vessel. This has the advantage that any droplets still present in the gas stream are removed. See for a further description hereinabove. Preferably, the second coalescer is a bed of one or more layers of gauze, especially metal or non-metal gauze, e.g. organic polymer gauze. In another preferred embodiment, the second normally horizontal liquid coalescer is situated above the secondary gas outlets, for instance in the way as described in EP 83811, especially as depicted in FIG. 4.
  • In a most preferred embodiment, a first and/or second separator is used comprising:
  • a) a housing comprising a first, second and third separation section for separating liquid from the mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
    b) tangentially arranged inlet means to introduce the mixture into the first separation section;
    c) means to remove liquid from the first separation section;
    d) means to remove liquid from the third separation section; and
    e) means to remove a gaseous stream, lean in liquid, from the third separation section.
  • In the present invention the first and/or second gas/liquid separator may suitably comprise a centrifugal separator which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube.
  • Suitably, in the present process the centrifugal separator is spinned by introducing a swirling gas stream into the spinning tube.
  • Preferably, the centrifugal separator to be used in accordance with the present invention comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body or upstream and downstream of the separating body, wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
  • It will be appreciated that the discs can be easily created by drilling or cutting a plurality of perforations into the relatively thin discs. By attaching several discs to together these discs form a separating body. By aligning the perforations ducts are obtained.
  • It is now also very easy to attach the discs such that the perforations are not completely aligned. By varying the number and nature of the non-alignment of the perforations the resulting ducts can be given any desired shape. In such cases not only ducts are obtainable that are not completely parallel to the central axis of rotation, but also ducts that form a helix shape around the axis of rotation. So, in this way very easily the preferred embodiment of having non-parallel ducts can be obtained. Hence it is preferred that the perforations of the discs have been arranged such that the ducts are not parallel to the central axis of rotation or form a helix shape around the axis of rotation.
  • Further, it will be appreciated that it is relatively easy to increase or decrease the diameter of the perforations. Thereby the skilled person has an easy manner at his disposal to adapt the (hydraulic) diameter of the ducts, and thereby the Reynolds number, so that he can easy ascertain that the flow in the ducts is laminar or turbulent, just as he pleases. The use of these discs also enables the skilled person to vary the diameter of the duct along the axis of the housing. The varying diameter can be selected such that the separated liquid or solid contaminants that are collected against the wall of the duct will not clog up the duct completely, which would hamper the operation of the apparatus.
  • The skilled person is also now enabled to maximise the porosity of the separating body. The easy construction of the discs allows the skilled person to meticulously provide the disc with as many perforations as he likes. He may also select the shape of the perforations. These may have a circular cross-section, but also square, pentagon, hexagon, octagon or oval cross-sections are possible. He may therefore minimise the wall thickness of the separating body and the wall thicknesses of the ducts. He is able to select the wall thicknesses and the shape of the ducts such that the surface area that is contributed to the cross-section of the separating body by the walls is minimal. That means that the pressure drop over the separating body can be minimised.
  • The apparatus can have a small or large number of ducts. Just as explained in the prior art apparatuses the number of ducts suitably ranges from 100 to 1,000,000, preferably from 500 to 500,000. The diameter of the cross-section of the ducts can be varied in accordance with the amount of gas and amounts and nature, e.g., droplet size distribution, of contaminants and the desired contaminants removal efficiency. Suitably, the diameter is from 0.05 to 50 mm, preferably from 0.1 to 20 mm, and more preferably from 0.1 to 5 mm. By diameter is understood twice the radius in case of circular cross-sections or the largest diagonal in case of any other shape.
  • The size of the apparatus and in particular of the separating body may vary in accordance with the amount of gas to be treated. In EP-B 286 160 it is indicated that separating bodies with a peripheral diameter of 1 m and an axial length of 1.5 m are feasible. The separating body according to the present invention may suitably have a radial length ranging from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length ranges conveniently from 0.1 to 10 m, preferably, from 0.2 to 5 m.
  • The number of discs may also vary over a large number. It is possible to have only two discs if a simple separation is needed and/or when the perforations can be easily made. Other considerations may be whether parallel ducts are desired, or whether a uniform diameter is wanted. Suitably the number of discs varies from 3 to 1000, preferably from 4 to 500, more preferably from 4 to 40. When more discs, are used the skilled person will find it easier to gradually vary the diameter of the ducts and/or to construct non-parallel ducts. Moreover, by increasing or decreasing the number of discs the skilled person may vary the duct length. So, when the conditions or the composition of the gas changes, the skilled person may adapt the duct length easily to provide the most optimal conditions for the apparatus of the present invention. The size of the discs is selected such that the radial diameter suitably ranges from 0.1 to 5 m, preferably from 0.2 to 2 m. The axial length of the discs may be varied in accordance with construction possibilities, desire for varying the shape etc. Suitably, the axial length of each disc ranges from 0.001 to 0.5 m, preferably from 0.002 to 0.2 m, more preferably from 0.005 to 0.1 m.
  • Although the discs may be manufactured from a variety of materials, including paper, cardboard, and foil, it is preferred to manufacture the discs from metal or ceramics. Metals discs have the advantage that they can be easily perforated and be combined to firm sturdy separating bodies. Dependent on the material that needs to be purified a suitable metal can be selected. For some applications carbon steel is suitable whereas for other applications, in particular when corrosive materials are to be separated, stainless steel may be preferred. Ceramics have the advantage that they can be extruded into the desired form such as in honeycomb structures with protruding ducts.
  • Typically, the ceramics precursor material is chosen to form a dense or low-porosity ceramic. Thereby the solid or liquid contaminants are forced to flow along the wall of the ducts and not, or hardly, through the ceramic material of the walls. Examples of ceramic materials are silica, alumina, zirconia, optionally with different types and concentrations of modifiers to adapt its physical and/or chemical properties to the gas and the contaminants.
  • The discs may be combined to a separating body in a variety of ways. The skilled person will appreciate that such may depend on the material from which the discs have been manufactured. A convenient manner is to attach the discs to a shaft that provides the axis of rotation. Suitable ways of combining the discs include clamping the discs together, but also gluing them or welding them together can be done. Alternatively, the discs may be stacked in a cylindrical sleeve. This sleeve may also at least partly replace the shaft. This could be convenient for extruded discs since no central opening for the shaft would be required. It is preferred to have metal discs that are welded together.
  • In a preferred embodiment of the invention, the methane enriched gaseous phase obtained in accordance with the present invention is further purified, e.g. by extraction of remaining acidic components with a chemical solvent, e.g. an aqueous amine solution, especially aqueous ethanolamines, such as DIPA, DMA, MDEA, etc., or with a physical solvent, e.g. cold methanol, DEPG, NMP, etc.
  • The contaminated gas stream is continuously provided, continuously cooled and continuously separated.
  • The present invention also relates to a device (plant) for carrying out the process as described above, as well as the purified gas stream obtained by the present process. In addition, the present invention concerns a process for liquefying a feed gas stream comprising purifying the feed gas stream by means of the present process, followed by liquifying the purified feed gas stream by methods known in the art.
  • The invention will be further illustrated by means of the following Figures.
  • Referring to FIG. 1, natural gas via a conduit 1 is passed through an expansion means 2, whereby a stream is obtained comprising liquid phase contaminant and a methane enriched gaseous phase. The stream flows via a conduit 3 into a gas/liquid separator 4 wherein the two phases are separated from each other. The liquid phase contaminant is recovered via a conduit 5, whereas the methane enriched gaseous phase is passed via a conduit 6 into a heat exchanger 7. In heat exchanger 7 ethane is used as an external refrigerant whereby the ethane is cooled by means of an ethane/propane cascade 8 as depicted in more detail in FIG. 2. The methane enriched gaseous phase is cooled in the heat exchanger 7 to a temperature whereby a liquid phase contaminant and an methane enriched gaseous phase are formed. The stream which comprises these two phases is then passed via a conduit 9 into a gas/liquid separator 10 from which a further enriched methane enriched gaseous phase is recovered via a conduit 11 and liquid phase contaminant is recovered via a conduit 12.
  • In FIG. 2 the heat exchanger 7 is shown using ethane that is cooled by means of an ethane/propane cascade which comprises an ethane loop and a propane loop. In the ethane loop an ethane stream is passed via a conduit 13 into an expander 14 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled ethane stream so obtained is passed via a conduit 15 into the heat exchanger 7. A stream of warm ethane is then passed from the heat exchanger 7 to a recompressor 16 via a conduit 17 to increase the pressure of the ethane stream. The compressed stream of ethane obtained from recompressor 16 is then passed via a conduit 18 into a heat exchanger 19 wherein the ethane stream is cooled and at least partly condensed. Via the conduit 13 the ethane stream is then recycled to the expander 14. In the propane loop a propane stream is passed via a conduit 20 into an expander 21 (e.g. a turbine expander or a Joule-Thomson valve), and the cooled propane stream so obtained is passed via a conduit 22 into the heat exchanger 19 of the ethane loop. A stream of warm propane is then passed from the heat exchanger 19 via a conduit 23 into a recompressor 24 to increase the pressure of the propane stream. The compressed stream of propane obtained from recompressor 24 is then passed via a conduit 25 into heat exchanger 26 wherein the propane stream is cooled and at least partly condensed by means of water or air. Via the conduit 20 the propane stream is then recycled to the expander 21.
  • In FIG. 3 a suitable gas/liquid separator is shown for use in steps 3) and 5) of the present process. Both the gas/ liquid separators 4 and 10 as shown in FIG. 1 can be of this type. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 (or the conduit 9) into the gas/liquid separator 4 (or the gas/liquid separator 10) via supply and distribution assembly 27. Most of the liquid will flow down to the lower end of the separator and leave the separator via the liquid outlet 5. The gaseous stream comprising larger and smaller droplets will flow upwards via liquid coalescer 28, centrifugal separator 29 and a second liquid coalescer 30 to the top of the separator vessel, and leave the separator vessel via the gas outlet 6.
  • In FIG. 4 another suitable gas/liquid separator is shown for use in steps 3) and 5) of the present process. Both the gas/ liquid separators 4 and 10 as shown in FIG. 1 can be of this type. The stream comprising liquid phase contaminant and a methane enriched gaseous phase is passed via the conduit 3 (or the conduit 9) to a gas inlet 31 in a housing 32 of the gas/liquid separator 4 (or the gas/liquid separator 10). The housing 32 further comprises a separating body 33 which shows a large number of ducts 34 which are arranged around a shaft 35, which provides an axis of rotation. Separating body 33 has been composed of six discs 33 a, 33 b, 33 c, 33 d, 33 e and 33 f that have been combined by welding or gluing. In the rotating separating body droplets of carbon dioxide and/or hydrogen sulphide are separated from the natural gas. The separated contaminants are discharged from the housing via a contaminants outlet 36 which has been arranged downstream of the separating body 33, and via the discharge conduit 5. Purified natural gas leaves housing 32 via the gas outlet 6 arranged at the opposite end of the housing 32.

Claims (15)

1. A process for removing gaseous contaminants from a feed gas stream which comprises methane and gaseous contaminants, the process comprising:
1) providing the feed gas stream;
2) cooling the feed gas stream to a first temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase;
3) separating the two phases obtained in step 2) by means of a first gas/liquid separator;
4) cooling the methane enriched gaseous phase obtained in step 3) at least partly by means of an external refrigerant to a second temperature at which liquid phase contaminant is formed as well as a methane enriched gaseous phase; and
5) separating the two phases obtained in step 4) by means of a second gas/liquid separator.
2. A process according to claim 1, in which at least one of the first and second gas/liquid separators comprises a centrifugal which comprises a bundle of parallel channels that are arranged within a spinning tube parallel to an axis of rotation of the spinning tube.
3. A process according to claim 1, in which the first and/or second gas/liquid separator comprises a housing with a gas inlet for contaminated gas at one end of the vessel, a separating body, a gas outlet for purified gas at the opposite end of the housing and a contaminants outlet downstream of the separating body wherein the separating body comprises a plurality of ducts over a part of the length of the axis of the housing, which ducts have been arranged around a central axis of rotation, in which apparatus the separating body has been composed of a plurality of perforated discs wherein the perforations of the discs form the ducts.
4. A gas separation system, comprising:
a) a housing comprising a first, second and third separation section for separating liquid from a gas mixture, wherein the second separation section is arranged below the first separation section and above the third separation section, the respective separation sections are in communication with each other, and the second separation section comprises a rotating coalescer element;
b) tangentially arranged inlet means to introduce the mixture into the first separation section;
c) means to remove liquid from the first separation section;
d) means to remove liquid from the third separation section; and
e) means to remove a gaseous stream, lean in liquid, from the third separation section.
5. A process according claim 1, in which the feed gas stream is a natural gas stream in which the gaseous contaminants are carbon dioxide and/or hydrogen sulphide.
6. A process according to claim 5, in which the natural gas stream comprises between 1 and 90 vol % of carbon dioxide, and between 0.1 and 60 vol % of hydrogen sulphide.
7. A process claim 1, in which the feed gas stream comprises between 20 and 80 vol % of methane.
8. A process according to claim 1, in which the feed gas stream in step 1) has a temperature between −20 and 150° C., preferably between −10 and 70° C., and a pressure between 10 and 150 bara, preferably between 80 and 120 bara.
9. A process according to claim 1, in which the cooling in step 2) is done by isenthalpic expansion.
10. A process according to claim 9, wherein the expansion is done using at least two expansion devices and the operating parameters of the expansion devices are chosen such that the liquefied acidic contaminants have a certain droplet size distribution.
11. A process claim 1, in which the feed gas stream is cooled in steps 2) and 4) to a temperature between −30 and −80° C., preferably between −40 and −65° C.
12. A process claim 1, in which the pressure applied in step 4) is higher than the pressure applied in step 2), and in which the second temperature in step 4) is lower than the first temperature in step 2).
13. A process according claim 1, in which the external refrigerant has a higher molecular weight than the methane enriched gaseous phase to be cooled.
14. A process according to claim 1, in which the first and/or second gas/liquid separator comprises a gas/liquid inlet at an intermediate level, a liquid outlet arranged below the gas/liquid inlet and a gas outlet arranged above the gas/liquid inlet, in which vessel a normally horizontal coalescer is present above the gas/liquid inlet and over the whole cross-section of the vessel and in which vessel a centrifugal liquid separator is arranged above the coalescer and over the whole cross-section of the vessel, the liquid separator comprising one or more swirl tubes.
15. (canceled)
US13/120,410 2008-09-23 2009-09-11 Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants Abandoned US20110192190A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08164892.5 2008-09-23
EP08164892 2008-09-23
PCT/EP2009/061795 WO2010034627A1 (en) 2008-09-23 2009-09-11 Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants

Publications (1)

Publication Number Publication Date
US20110192190A1 true US20110192190A1 (en) 2011-08-11

Family

ID=40428001

Family Applications (1)

Application Number Title Priority Date Filing Date
US13/120,410 Abandoned US20110192190A1 (en) 2008-09-23 2009-09-11 Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants

Country Status (5)

Country Link
US (1) US20110192190A1 (en)
CN (1) CN102159298A (en)
CA (1) CA2735919A1 (en)
EA (1) EA201100522A1 (en)
WO (1) WO2010034627A1 (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103351896A (en) * 2013-06-07 2013-10-16 新地能源工程技术有限公司 Method and device for removing water and heavy hydrocarbons from shale gas
CN103351895A (en) * 2013-06-07 2013-10-16 新地能源工程技术有限公司 Method and device for removing water and heavy hydrocarbons from shale gas
US9562719B2 (en) 2013-12-06 2017-02-07 Exxonmobil Upstream Research Company Method of removing solids by modifying a liquid level in a distillation tower
US9752827B2 (en) 2013-12-06 2017-09-05 Exxonmobil Upstream Research Company Method and system of maintaining a liquid level in a distillation tower
US9803918B2 (en) 2013-12-06 2017-10-31 Exxonmobil Upstream Research Company Method and system of dehydrating a feed stream processed in a distillation tower
US9823016B2 (en) 2013-12-06 2017-11-21 Exxonmobil Upstream Research Company Method and system of modifying a liquid level during start-up operations
US9829247B2 (en) 2013-12-06 2017-11-28 Exxonmobil Upstream Reseach Company Method and device for separating a feed stream using radiation detectors
US9869511B2 (en) 2013-12-06 2018-01-16 Exxonmobil Upstream Research Company Method and device for separating hydrocarbons and contaminants with a spray assembly
US9874395B2 (en) 2013-12-06 2018-01-23 Exxonmobil Upstream Research Company Method and system for preventing accumulation of solids in a distillation tower
US9874396B2 (en) 2013-12-06 2018-01-23 Exxonmobil Upstream Research Company Method and device for separating hydrocarbons and contaminants with a heating mechanism to destabilize and/or prevent adhesion of solids
US9964352B2 (en) 2012-03-21 2018-05-08 Exxonmobil Upstream Research Company Separating carbon dioxide and ethane from a mixed stream
US10139158B2 (en) 2013-12-06 2018-11-27 Exxonmobil Upstream Research Company Method and system for separating a feed stream with a feed stream distribution mechanism
US10323495B2 (en) 2016-03-30 2019-06-18 Exxonmobil Upstream Research Company Self-sourced reservoir fluid for enhanced oil recovery
US10330363B2 (en) 2016-02-08 2019-06-25 Trane International Inc. Lubricant separator for a heating, ventilation, and air conditioning system
US10365037B2 (en) 2015-09-18 2019-07-30 Exxonmobil Upstream Research Company Heating component to reduce solidification in a cryogenic distillation system
US10495379B2 (en) 2015-02-27 2019-12-03 Exxonmobil Upstream Research Company Reducing refrigeration and dehydration load for a feed stream entering a cryogenic distillation process
US11255603B2 (en) 2015-09-24 2022-02-22 Exxonmobil Upstream Research Company Treatment plant for hydrocarbon gas having variable contaminant levels
US11306267B2 (en) 2018-06-29 2022-04-19 Exxonmobil Upstream Research Company Hybrid tray for introducing a low CO2 feed stream into a distillation tower
US11378332B2 (en) 2018-06-29 2022-07-05 Exxonmobil Upstream Research Company Mixing and heat integration of melt tray liquids in a cryogenic distillation tower

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8312738B2 (en) 2007-01-19 2012-11-20 Exxonmobil Upstream Research Company Integrated controlled freeze zone (CFZ) tower and dividing wall (DWC) for enhanced hydrocarbon recovery
AU2010239718B2 (en) 2009-04-20 2016-02-04 Exxonmobil Upstream Research Company Cryogenic system for removing acid gases from a hyrdrocarbon gas stream, and method of removing acid gases
MY161120A (en) 2009-09-09 2017-04-14 Exxonmobil Upstream Res Co Cryogenic system for removing acid gases from a hydrocarbon gas stream
MY161559A (en) 2010-01-22 2017-04-28 Exxonmobil Upstream Res Co Removal of acid gases from a gas stream, with co2 capture and sequestration
MX2012008667A (en) 2010-02-03 2012-08-23 Exxonmobil Upstream Res Co Systems and methods for using cold liquid to remove solidifiable gas components from process gas streams.
CA2805513C (en) 2010-07-30 2016-10-04 Exxonmobil Upstream Research Company Cryogenic systems for removing acid gases from a hydrocarbon gas stream using co-current separation devices
EP2540371A1 (en) 2011-06-29 2013-01-02 Shell Internationale Research Maatschappij B.V. Method of removing aromatic hydrocarbons from a feed gas stream being rich in aliphatic hydrocarbons
DE102012003741A1 (en) * 2012-02-28 2013-08-29 Thyssenkrupp Uhde Gmbh Process for the recovery of hydrocarbons from polyolefin plants and apparatus suitable therefor
CN103230737B (en) * 2013-05-13 2015-09-23 达州军华环保科技有限公司 Stench device for purifying and treating tail gas and treatment process thereof in gas production waste water
FR3023562A1 (en) 2014-07-08 2016-01-15 Total Sa PROCESS AND INSTALLATION FOR THE SEPARATION OF LIGHT CONSTITUENTS AND HEAVY CONSTITUENTS FROM NATURAL GAS
CN107376518A (en) * 2017-08-29 2017-11-24 浙江万好万家智能设备股份有限公司 A kind of NMP filters
CN114555208A (en) * 2019-06-25 2022-05-27 马来西亚国家石油公司 System and method for processing LNG

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5244479A (en) * 1993-03-15 1993-09-14 United Technologies Corporation Liquid/gas separator for soapy liquid
US5520249A (en) * 1993-12-23 1996-05-28 Institut Francais Du Petrole Process for the pretreatment of a natural gas containing hydrogen sulphide
US5983663A (en) * 1998-05-08 1999-11-16 Kvaerner Process Systems, Inc. Acid gas fractionation
US6386520B2 (en) * 2000-02-16 2002-05-14 Shell Oil Company Fluid inlet device
US20030000698A1 (en) * 2001-05-11 2003-01-02 Lecomte Fabrice Process for pretreating a natural gas containing acid compounds
US6537458B1 (en) * 1999-03-05 2003-03-25 Shell Oil Company Three-phase separator
US6942720B2 (en) * 2002-02-21 2005-09-13 Shell Oil Company Apparatus and method for treating a fluid
US20060112725A1 (en) * 2004-08-06 2006-06-01 Owen Ryan O Natural gas liquefaction process
WO2006087332A1 (en) * 2005-02-17 2006-08-24 Shell Internationale Research Maatschappij B.V. Method for removing contaminating gaseous components from a natural gas stream
US20070107465A1 (en) * 2001-05-04 2007-05-17 Battelle Energy Alliance, Llc Apparatus for the liquefaction of gas and methods relating to same
US20100005721A1 (en) * 2008-07-10 2010-01-14 Adriaan Pieter Houtekamer Process for the removal of acidic contaminants from a natural gas stream
US20100281916A1 (en) * 2008-01-11 2010-11-11 Rick Van Der Vaart Process for the purification of an hydrocarbon gas stream by freezing out and separating the solidified acidic contaminants
US20110083558A1 (en) * 2008-01-30 2011-04-14 Rick Van Der Vaart Apparatus for the separation of gas and solid and/or liquid contaminants

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USH825H (en) * 1988-05-20 1990-10-02 Exxon Production Research Company Process for conditioning a high carbon dioxide content natural gas stream for gas sweetening
KR20070114192A (en) * 2005-02-24 2007-11-29 트위스터 비.브이. Method and system for cooling a natural gas stream and separating the cooled stream into various fractions
NL2000292C2 (en) * 2006-10-27 2008-04-29 Romico Hold A V V Method for separating a medium mixture into fractions.

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5244479A (en) * 1993-03-15 1993-09-14 United Technologies Corporation Liquid/gas separator for soapy liquid
US5520249A (en) * 1993-12-23 1996-05-28 Institut Francais Du Petrole Process for the pretreatment of a natural gas containing hydrogen sulphide
US5983663A (en) * 1998-05-08 1999-11-16 Kvaerner Process Systems, Inc. Acid gas fractionation
US6537458B1 (en) * 1999-03-05 2003-03-25 Shell Oil Company Three-phase separator
US6386520B2 (en) * 2000-02-16 2002-05-14 Shell Oil Company Fluid inlet device
US20070107465A1 (en) * 2001-05-04 2007-05-17 Battelle Energy Alliance, Llc Apparatus for the liquefaction of gas and methods relating to same
US20030000698A1 (en) * 2001-05-11 2003-01-02 Lecomte Fabrice Process for pretreating a natural gas containing acid compounds
US6942720B2 (en) * 2002-02-21 2005-09-13 Shell Oil Company Apparatus and method for treating a fluid
US20060112725A1 (en) * 2004-08-06 2006-06-01 Owen Ryan O Natural gas liquefaction process
WO2006087332A1 (en) * 2005-02-17 2006-08-24 Shell Internationale Research Maatschappij B.V. Method for removing contaminating gaseous components from a natural gas stream
US20060225386A1 (en) * 2005-02-17 2006-10-12 Bert Brouwers Method for removing contaminating gaseous components from a natural gas stream
US20100281916A1 (en) * 2008-01-11 2010-11-11 Rick Van Der Vaart Process for the purification of an hydrocarbon gas stream by freezing out and separating the solidified acidic contaminants
US20110083558A1 (en) * 2008-01-30 2011-04-14 Rick Van Der Vaart Apparatus for the separation of gas and solid and/or liquid contaminants
US20100005721A1 (en) * 2008-07-10 2010-01-14 Adriaan Pieter Houtekamer Process for the removal of acidic contaminants from a natural gas stream

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10323879B2 (en) 2012-03-21 2019-06-18 Exxonmobil Upstream Research Company Separating carbon dioxide and ethane from a mixed stream
US9964352B2 (en) 2012-03-21 2018-05-08 Exxonmobil Upstream Research Company Separating carbon dioxide and ethane from a mixed stream
CN103351896A (en) * 2013-06-07 2013-10-16 新地能源工程技术有限公司 Method and device for removing water and heavy hydrocarbons from shale gas
CN103351895A (en) * 2013-06-07 2013-10-16 新地能源工程技术有限公司 Method and device for removing water and heavy hydrocarbons from shale gas
US9823016B2 (en) 2013-12-06 2017-11-21 Exxonmobil Upstream Research Company Method and system of modifying a liquid level during start-up operations
US10139158B2 (en) 2013-12-06 2018-11-27 Exxonmobil Upstream Research Company Method and system for separating a feed stream with a feed stream distribution mechanism
US9829247B2 (en) 2013-12-06 2017-11-28 Exxonmobil Upstream Reseach Company Method and device for separating a feed stream using radiation detectors
US9869511B2 (en) 2013-12-06 2018-01-16 Exxonmobil Upstream Research Company Method and device for separating hydrocarbons and contaminants with a spray assembly
US9874395B2 (en) 2013-12-06 2018-01-23 Exxonmobil Upstream Research Company Method and system for preventing accumulation of solids in a distillation tower
US9874396B2 (en) 2013-12-06 2018-01-23 Exxonmobil Upstream Research Company Method and device for separating hydrocarbons and contaminants with a heating mechanism to destabilize and/or prevent adhesion of solids
US9752827B2 (en) 2013-12-06 2017-09-05 Exxonmobil Upstream Research Company Method and system of maintaining a liquid level in a distillation tower
US9803918B2 (en) 2013-12-06 2017-10-31 Exxonmobil Upstream Research Company Method and system of dehydrating a feed stream processed in a distillation tower
US9562719B2 (en) 2013-12-06 2017-02-07 Exxonmobil Upstream Research Company Method of removing solids by modifying a liquid level in a distillation tower
US10495379B2 (en) 2015-02-27 2019-12-03 Exxonmobil Upstream Research Company Reducing refrigeration and dehydration load for a feed stream entering a cryogenic distillation process
US10365037B2 (en) 2015-09-18 2019-07-30 Exxonmobil Upstream Research Company Heating component to reduce solidification in a cryogenic distillation system
US11255603B2 (en) 2015-09-24 2022-02-22 Exxonmobil Upstream Research Company Treatment plant for hydrocarbon gas having variable contaminant levels
US10330363B2 (en) 2016-02-08 2019-06-25 Trane International Inc. Lubricant separator for a heating, ventilation, and air conditioning system
US10323495B2 (en) 2016-03-30 2019-06-18 Exxonmobil Upstream Research Company Self-sourced reservoir fluid for enhanced oil recovery
US11306267B2 (en) 2018-06-29 2022-04-19 Exxonmobil Upstream Research Company Hybrid tray for introducing a low CO2 feed stream into a distillation tower
US11378332B2 (en) 2018-06-29 2022-07-05 Exxonmobil Upstream Research Company Mixing and heat integration of melt tray liquids in a cryogenic distillation tower

Also Published As

Publication number Publication date
CN102159298A (en) 2011-08-17
WO2010034627A1 (en) 2010-04-01
CA2735919A1 (en) 2010-04-01
EA201100522A1 (en) 2011-08-30

Similar Documents

Publication Publication Date Title
US20110192190A1 (en) Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants
US20100107687A1 (en) Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants
US8790447B2 (en) Separation device for removing liquid from a mixture comprising a gas and liquid
WO2010052299A1 (en) Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants
US20110154856A1 (en) Process for removing a gaseous contaminant from a contaminated gas stream
RU2462295C2 (en) Hydrogen sulphide removal from natural gas flow
AU2016220515B2 (en) Inner surface features for co-current contactors
CA2978899C (en) Coalescer for co-current contactors
CN103201013A (en) Refining system and method for refining a feed gas stream
AU2018322435B2 (en) Integration of cold solvent and acid gas removal
CA3073038C (en) Integration of cold solvent and acid gas removal
US20100005721A1 (en) Process for the removal of acidic contaminants from a natural gas stream
US20110192192A1 (en) Process for removing gaseous contaminants from a feed gas stream comprising methane and gaseous contaminants
US20110083558A1 (en) Apparatus for the separation of gas and solid and/or liquid contaminants
US20120324941A1 (en) Process for producing a contaminant-depleted hydrocarbon gas stream with improved hydrocarbon recovery
EP2540371A1 (en) Method of removing aromatic hydrocarbons from a feed gas stream being rich in aliphatic hydrocarbons
Betting et al. Method and system for removing H 2 S from a natural gas stream

Legal Events

Date Code Title Description
AS Assignment

Owner name: SHELL OIL COMPANY, TEXAS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ANDRIAN, DIKI;VAN DER VAART, RICK;SIGNING DATES FROM 20110102 TO 20110131;REEL/FRAME:025999/0701

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION