CA2684952A1 - Hydrogen-catalyst reactor - Google Patents
Hydrogen-catalyst reactor Download PDFInfo
- Publication number
- CA2684952A1 CA2684952A1 CA002684952A CA2684952A CA2684952A1 CA 2684952 A1 CA2684952 A1 CA 2684952A1 CA 002684952 A CA002684952 A CA 002684952A CA 2684952 A CA2684952 A CA 2684952A CA 2684952 A1 CA2684952 A1 CA 2684952A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrogen
- catalyst
- source
- reaction
- nah
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 440
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 445
- 239000001257 hydrogen Substances 0.000 claims abstract description 423
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 388
- 238000006243 chemical reaction Methods 0.000 claims abstract description 356
- 150000004678 hydrides Chemical class 0.000 claims abstract description 177
- 239000011541 reaction mixture Substances 0.000 claims abstract description 155
- 239000000376 reactant Substances 0.000 claims abstract description 137
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 claims abstract description 123
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 111
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 72
- 239000000203 mixture Substances 0.000 claims abstract description 68
- 150000002431 hydrogen Chemical class 0.000 claims abstract 2
- 229910000104 sodium hydride Inorganic materials 0.000 claims description 222
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 207
- 239000011734 sodium Substances 0.000 claims description 162
- -1 another element Substances 0.000 claims description 156
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 135
- AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical compound [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 claims description 123
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 114
- 239000007868 Raney catalyst Substances 0.000 claims description 103
- 229910000564 Raney nickel Inorganic materials 0.000 claims description 103
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 claims description 102
- 150000001875 compounds Chemical class 0.000 claims description 101
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 83
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 79
- 229910052744 lithium Inorganic materials 0.000 claims description 78
- 239000007789 gas Substances 0.000 claims description 75
- 238000000034 method Methods 0.000 claims description 72
- 229910052751 metal Inorganic materials 0.000 claims description 69
- 239000002184 metal Substances 0.000 claims description 69
- 239000000047 product Substances 0.000 claims description 67
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 62
- 230000015572 biosynthetic process Effects 0.000 claims description 58
- 230000001965 increasing effect Effects 0.000 claims description 53
- 238000005755 formation reaction Methods 0.000 claims description 52
- 229910052700 potassium Inorganic materials 0.000 claims description 52
- 125000004429 atom Chemical group 0.000 claims description 51
- 239000003638 chemical reducing agent Substances 0.000 claims description 49
- 229910052708 sodium Inorganic materials 0.000 claims description 49
- 229910045601 alloy Inorganic materials 0.000 claims description 47
- 239000000956 alloy Substances 0.000 claims description 47
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 46
- 239000000463 material Substances 0.000 claims description 46
- 229910052697 platinum Inorganic materials 0.000 claims description 45
- 229910010408 Li2NH Inorganic materials 0.000 claims description 44
- 229910052792 caesium Inorganic materials 0.000 claims description 41
- 150000004820 halides Chemical class 0.000 claims description 41
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 41
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 claims description 40
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 39
- 150000002500 ions Chemical class 0.000 claims description 37
- 239000010936 titanium Substances 0.000 claims description 37
- 229910018954 NaNH2 Inorganic materials 0.000 claims description 34
- 229910052763 palladium Inorganic materials 0.000 claims description 34
- 239000003153 chemical reaction reagent Substances 0.000 claims description 33
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 31
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 29
- 230000008929 regeneration Effects 0.000 claims description 29
- 238000011069 regeneration method Methods 0.000 claims description 29
- 238000010438 heat treatment Methods 0.000 claims description 28
- 239000003513 alkali Substances 0.000 claims description 27
- 150000002602 lanthanoids Chemical class 0.000 claims description 25
- 238000004891 communication Methods 0.000 claims description 24
- 229910052593 corundum Inorganic materials 0.000 claims description 23
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 23
- 229910052723 transition metal Inorganic materials 0.000 claims description 22
- 150000003624 transition metals Chemical class 0.000 claims description 22
- 238000000354 decomposition reaction Methods 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 229910052987 metal hydride Inorganic materials 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 20
- 238000012546 transfer Methods 0.000 claims description 20
- 150000004681 metal hydrides Chemical class 0.000 claims description 19
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- 229910052783 alkali metal Inorganic materials 0.000 claims description 18
- 150000001340 alkali metals Chemical class 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 230000002441 reversible effect Effects 0.000 claims description 18
- 229910052712 strontium Inorganic materials 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 238000002844 melting Methods 0.000 claims description 17
- 230000008018 melting Effects 0.000 claims description 17
- 229910052718 tin Inorganic materials 0.000 claims description 17
- 230000007704 transition Effects 0.000 claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 150000002739 metals Chemical class 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 16
- 230000003197 catalytic effect Effects 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000010955 niobium Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- 238000004845 hydriding Methods 0.000 claims description 13
- 150000002484 inorganic compounds Chemical class 0.000 claims description 13
- 229910010272 inorganic material Inorganic materials 0.000 claims description 13
- 229910052707 ruthenium Inorganic materials 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 12
- 229910052758 niobium Inorganic materials 0.000 claims description 12
- 229910000510 noble metal Inorganic materials 0.000 claims description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 239000012448 Lithium borohydride Substances 0.000 claims description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910000733 Li alloy Inorganic materials 0.000 claims description 9
- 150000001793 charged compounds Chemical class 0.000 claims description 9
- 238000002485 combustion reaction Methods 0.000 claims description 9
- 230000002829 reductive effect Effects 0.000 claims description 9
- 229910052701 rubidium Inorganic materials 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 9
- 239000010937 tungsten Substances 0.000 claims description 9
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 8
- 229910052794 bromium Inorganic materials 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 230000007935 neutral effect Effects 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 235000017550 sodium carbonate Nutrition 0.000 claims description 8
- 239000010457 zeolite Substances 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- 229910052772 Samarium Inorganic materials 0.000 claims description 7
- 229910052740 iodine Inorganic materials 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 7
- 239000003870 refractory metal Substances 0.000 claims description 7
- 239000012279 sodium borohydride Substances 0.000 claims description 7
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 6
- 230000001172 regenerating effect Effects 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 230000005284 excitation Effects 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 230000035699 permeability Effects 0.000 claims description 5
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 238000007740 vapor deposition Methods 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052691 Erbium Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 229910052790 beryllium Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 230000005574 cross-species transmission Effects 0.000 claims description 4
- 238000007323 disproportionation reaction Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 229910052743 krypton Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000007873 sieving Methods 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 229910000311 lanthanide oxide Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 3
- VPZRWNZGLKXFOE-UHFFFAOYSA-M sodium phenylbutyrate Chemical compound [Na+].[O-]C(=O)CCCC1=CC=CC=C1 VPZRWNZGLKXFOE-UHFFFAOYSA-M 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims description 2
- 150000008046 alkali metal hydrides Chemical class 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 239000001989 lithium alloy Substances 0.000 claims description 2
- 230000002269 spontaneous effect Effects 0.000 claims 9
- 229910013698 LiNH2 Inorganic materials 0.000 claims 6
- IDBFBDSKYCUNPW-UHFFFAOYSA-N lithium nitride Chemical compound [Li]N([Li])[Li] IDBFBDSKYCUNPW-UHFFFAOYSA-N 0.000 claims 6
- 229910000054 lanthanide hydride Inorganic materials 0.000 claims 4
- 235000012239 silicon dioxide Nutrition 0.000 claims 4
- 229910010084 LiAlH4 Inorganic materials 0.000 claims 2
- 239000012280 lithium aluminium hydride Substances 0.000 claims 2
- 239000002105 nanoparticle Substances 0.000 claims 2
- 229910010199 LiAl Inorganic materials 0.000 claims 1
- 229910020828 NaAlH4 Inorganic materials 0.000 claims 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000000859 sublimation Methods 0.000 claims 1
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- 238000009834 vaporization Methods 0.000 claims 1
- 230000008016 vaporization Effects 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 134
- 229910000103 lithium hydride Inorganic materials 0.000 description 99
- 241000894007 species Species 0.000 description 97
- 210000002381 plasma Anatomy 0.000 description 75
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 50
- BHZCMUVGYXEBMY-UHFFFAOYSA-N trilithium;azanide Chemical compound [Li+].[Li+].[Li+].[NH2-] BHZCMUVGYXEBMY-UHFFFAOYSA-N 0.000 description 39
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 31
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- 238000001228 spectrum Methods 0.000 description 25
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 22
- 239000004449 solid propellant Substances 0.000 description 21
- 239000002904 solvent Substances 0.000 description 21
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- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 16
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- MXCPYJZDGPQDRA-UHFFFAOYSA-N dialuminum;2-acetyloxybenzoic acid;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].CC(=O)OC1=CC=CC=C1C(O)=O MXCPYJZDGPQDRA-UHFFFAOYSA-N 0.000 description 5
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- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 4
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- 229910001416 lithium ion Inorganic materials 0.000 description 4
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 4
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- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
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- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- MOOUSOJAOQPDEH-UHFFFAOYSA-K cerium(iii) bromide Chemical compound [Br-].[Br-].[Br-].[Ce+3] MOOUSOJAOQPDEH-UHFFFAOYSA-K 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
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- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 description 1
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- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
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- 239000011630 iodine Substances 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- HXGWMCJZLNWEBC-UHFFFAOYSA-K lithium citrate tetrahydrate Chemical compound [Li+].[Li+].[Li+].O.O.O.O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HXGWMCJZLNWEBC-UHFFFAOYSA-K 0.000 description 1
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- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
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- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XNQULTQRGBXLIA-UHFFFAOYSA-O phosphonic anhydride Chemical compound O[P+](O)=O XNQULTQRGBXLIA-UHFFFAOYSA-O 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 229910000105 potassium hydride Inorganic materials 0.000 description 1
- NTTOTNSKUYCDAV-UHFFFAOYSA-N potassium hydride Chemical compound [KH] NTTOTNSKUYCDAV-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910001419 rubidium ion Inorganic materials 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229910000046 scandium hydride Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 238000002460 vibrational spectroscopy Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910000047 yttrium hydride Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K13/00—General layout or general methods of operation of complete plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
Applications Claiming Priority (71)
| Application Number | Priority Date | Filing Date | Title |
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| WO2011016878A1 (en) * | 2009-08-07 | 2011-02-10 | Blacklight Power, Inc. | Heterogeneous hydrogen-catalyst power system |
| EP2702623A1 (en) * | 2011-04-05 | 2014-03-05 | Blacklight Power, Inc. | H20 - based electrochemical hydrogen - catalyst power system |
| JP5922372B2 (ja) * | 2011-10-24 | 2016-05-24 | 日揮触媒化成株式会社 | 水素化処理触媒及びその製造方法 |
| CN107195935A (zh) * | 2012-05-21 | 2017-09-22 | 辉光能源公司 | Ciht动力系统 |
| KR102681406B1 (ko) * | 2013-11-20 | 2024-07-03 | 브릴리언트 라이트 파워, 인크. | 발전 시스템 및 발전 방법 |
| SG10202008475UA (en) * | 2014-03-03 | 2020-09-29 | Brilliant Light Power Inc | Photovoltaic power generation systems and methods regarding same |
| CN109247031B (zh) * | 2016-01-19 | 2023-02-17 | 辉光能源公司 | 热光伏发电机 |
| KR102564577B1 (ko) * | 2016-08-16 | 2023-08-04 | 한화오션 주식회사 | 금속 연료 수소발생장치용 금속 연료 공급장치 |
| KR102564578B1 (ko) * | 2016-08-17 | 2023-08-04 | 한화오션 주식회사 | 금속 연료 수소 발생장치용 금속 연료 공급장치 |
| RU2019108040A (ru) * | 2016-08-31 | 2020-10-01 | Ван Сайнтифик, Инк. Сша | Системы, устройства и способы для получения электрической энергии посредством преобразования воды в водород и кислород |
| PL3533758T3 (pl) * | 2018-03-01 | 2021-06-14 | Hoppecke Batterien Gmbh & Co. Kg. | Rekombinator |
| JP6827254B2 (ja) * | 2019-01-04 | 2021-02-10 | ブリリアント ライト パワー インコーポレーティド | パワー発生システム及び同システムに関する方法 |
| JPWO2021049166A1 (enExample) * | 2019-09-09 | 2021-03-18 | ||
| US12005391B2 (en) | 2019-12-11 | 2024-06-11 | Brookhaven Science Associates, Llc | Method for trapping noble gas atoms and molecules in oxide nanocages |
| CN112037958B (zh) * | 2020-09-09 | 2022-09-23 | 中国工程物理研究院核物理与化学研究所 | 一种高浓氚水处理装置 |
| CN112117020B (zh) * | 2020-09-09 | 2022-11-22 | 中国工程物理研究院核物理与化学研究所 | 一种光热协同催化处理氚水的方法 |
| CN112723878B (zh) * | 2020-12-29 | 2022-09-23 | 苏州金宏气体股份有限公司 | 能量收集多孔陶瓷Pt-BaTiO3其制法及高效制氢 |
| CN113117675B (zh) * | 2021-04-10 | 2022-04-08 | 福州大学 | 一种铑铒复合金属光热催化剂及其制备方法和应用 |
| CN113479844B (zh) * | 2021-06-04 | 2022-11-01 | 中国原子能科学研究院 | 一种氚化水样品转化制备氢化钛的方法 |
| KR102368521B1 (ko) * | 2022-01-04 | 2022-02-25 | 순천대학교 산학협력단 | 액상 플라즈마 반응을 이용한 수소생성용 복합 금속산화물 촉매의 제조방법 및 복합 금속산화물 촉매 |
| CN117416929B (zh) * | 2022-07-11 | 2025-03-11 | 中国科学院物理研究所 | 一种金属氢化物材料及其制备方法 |
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| KR100398058B1 (ko) * | 2001-05-18 | 2003-09-19 | 주식회사 경동도시가스 | 수식된 θ-알루미나에 담지되어 이루어진 니켈계 개질촉매및 이를 이용한 천연가스로부터 합성가스의 제조방법 |
| KR100488726B1 (ko) * | 2002-12-13 | 2005-05-11 | 현대자동차주식회사 | 연료전지 시스템의 수소 공급장치 |
| JP2006524339A (ja) * | 2003-04-15 | 2006-10-26 | ブラックライト パワー インコーポレーティド | 低エネルギー水素種を生成するためのプラズマ反応炉およびプロセス |
| US7904065B2 (en) * | 2004-06-21 | 2011-03-08 | Varia Holdings Llc | Serving data/applications from a wireless mobile phone |
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- 2008-04-24 CN CN200880020310.2A patent/CN101679025B/zh not_active Expired - Fee Related
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117085726A (zh) * | 2023-09-21 | 2023-11-21 | 华东师范大学 | 一种丙烷脱氢制丙烯的钴基催化剂及其固相合成方法 |
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| WO2008134451A1 (en) | 2008-11-06 |
| JP2010532301A (ja) | 2010-10-07 |
| JP2018027888A (ja) | 2018-02-22 |
| KR101871950B1 (ko) | 2018-06-27 |
| KR20150116905A (ko) | 2015-10-16 |
| EA200901438A1 (ru) | 2010-06-30 |
| KR20100017342A (ko) | 2010-02-16 |
| CN101679025B (zh) | 2014-10-22 |
| HK1142055A1 (en) | 2010-11-26 |
| EP2185468A1 (en) | 2010-05-19 |
| IL201716A0 (en) | 2010-05-31 |
| AU2008245686B2 (en) | 2014-01-09 |
| IL238038A0 (en) | 2015-05-31 |
| EP2185468A4 (en) | 2012-02-01 |
| JP2015071536A (ja) | 2015-04-16 |
| IL249525A0 (en) | 2017-02-28 |
| CN101679025A (zh) | 2010-03-24 |
| AU2008245686A1 (en) | 2008-11-06 |
| MX2009011545A (es) | 2010-01-28 |
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