CA2653791A1 - Sizing of paper - Google Patents
Sizing of paper Download PDFInfo
- Publication number
- CA2653791A1 CA2653791A1 CA002653791A CA2653791A CA2653791A1 CA 2653791 A1 CA2653791 A1 CA 2653791A1 CA 002653791 A CA002653791 A CA 002653791A CA 2653791 A CA2653791 A CA 2653791A CA 2653791 A1 CA2653791 A1 CA 2653791A1
- Authority
- CA
- Canada
- Prior art keywords
- nitrogen
- containing organic
- organic compound
- process according
- sizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 83
- -1 nitrogen-containing organic compound Chemical class 0.000 claims abstract description 86
- 239000000725 suspension Substances 0.000 claims abstract description 57
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000006185 dispersion Substances 0.000 claims abstract description 20
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000003760 tallow Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 5
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical group C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims description 3
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 3
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 125000004018 acid anhydride group Chemical group 0.000 claims 1
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical group C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 claims 1
- 239000000123 paper Substances 0.000 description 37
- 125000002091 cationic group Chemical group 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 239000002270 dispersing agent Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 7
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 150000002894 organic compounds Chemical class 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 150000008065 acid anhydrides Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 150000002561 ketenes Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- 238000010561 standard procedure Methods 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000011121 hardwood Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000011087 paperboard Substances 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- 150000003335 secondary amines Chemical class 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000001399 aluminium compounds Chemical class 0.000 description 2
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ASUDFOJKTJLAIK-UHFFFAOYSA-N 2-methoxyethanamine Chemical compound COCCN ASUDFOJKTJLAIK-UHFFFAOYSA-N 0.000 description 1
- GPFVWKXABQQNEM-BMRADRMJSA-N 3-[(e)-16-methylheptadec-1-enyl]oxolane-2,5-dione Chemical compound CC(C)CCCCCCCCCCCCC\C=C\C1CC(=O)OC1=O GPFVWKXABQQNEM-BMRADRMJSA-N 0.000 description 1
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical class CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- QAJYCTCPYRVYMM-UHFFFAOYSA-N C=C.CCCCCCCCCCCCCCCCC(O)=O Chemical compound C=C.CCCCCCCCCCCCCCCCC(O)=O QAJYCTCPYRVYMM-UHFFFAOYSA-N 0.000 description 1
- JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical compound CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- CBSOFSBFHDQRLV-UHFFFAOYSA-N N-methylbenzylamine hydrochloride Chemical compound [Cl-].C[NH2+]CC1=CC=CC=C1 CBSOFSBFHDQRLV-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940106135 cellulose Drugs 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229940078672 didecyldimethylammonium Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- UAKOZKUVZRMOFN-JDVCJPALSA-M dimethyl-bis[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CCCCCCCC\C=C/CCCCCCCC UAKOZKUVZRMOFN-JDVCJPALSA-M 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229940014259 gelatin Drugs 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 150000005451 methyl sulfates Chemical class 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
- D21H17/45—Nitrogen-containing groups
- D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
- D21H23/765—Addition of all compounds to the pulp
Landscapes
- Paper (AREA)
Abstract
The present invention relates to a process for the production of paper which comprises: (a) providing an aqueous cellulosic suspension; (b) separately adding to the suspension: (i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper. The invention further relates to a process in which a nitrogen-containing organic compound having a molecular weight less than 1,000 is mixed with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix and which premix is added to the suspension.
Description
SIZING OF PAPER
Field of the Invention The present invention generally relates sizing of paper and paper board.
Background of the invention Cellulose-reactive sizing agents, such as those based on alkyl ketene dimer (AKD) and alkenyl succinic anhydride (ASA), are widely used in papermaking at neutral or slightly alkaline stock pH's in order to give paper and paper board some degree of resistance to wetting and penetration by aqueous liquids. Paper sizes based on cellulose-reactive sizing agents are generally provided in the form of dispersions containing an aqueous phase and finely divided particles or droplets of the sizing agent dispersed therein.
Cellulose-reactive sizing agents generally provide good sizing effect using low dosages of the sizing agent when added to the aqueous cellulosic suspension. The sizing effect starts to develop in the drying section of the paper machine. However, since most paper machines operate at maximum speed to optimize the paper production, the time in the drying section is often not long enough to produce sized paper on-machine. Instead the paper has to be allowed to cure for up to 24 hours before a fully sized product can be achieved. This slow development of the sizing effect creates a number of problems. Firstly, subsequent operations such as printing, coating, pasting, etc. may be difficult to handle. Secondly, many paper makers continuously overdose the sizing agents to make sure that a fully sized product is achieved. Consequently, problems in terms of deposits on machine components are usually created.
WO 9710387 discloses a paper sizing enhancer which is a polymerization reaction product of a quaternary diallylammonium monomer and a diallylammonium monomer. The polymerization product has a molecular weight of at least 10,000. WO 9710387 discloses that the paper sizing enhancer may be introduced into a paper furnish during the papermaking process in combination with the paper sizing agent, either separately or as an aqueous medium containing both components.
WO 02081587 discloses a sizing dispersion containing a sizing agent and a non-ionic surface active monoester of glycerol with a fatty acid.
Field of the Invention The present invention generally relates sizing of paper and paper board.
Background of the invention Cellulose-reactive sizing agents, such as those based on alkyl ketene dimer (AKD) and alkenyl succinic anhydride (ASA), are widely used in papermaking at neutral or slightly alkaline stock pH's in order to give paper and paper board some degree of resistance to wetting and penetration by aqueous liquids. Paper sizes based on cellulose-reactive sizing agents are generally provided in the form of dispersions containing an aqueous phase and finely divided particles or droplets of the sizing agent dispersed therein.
Cellulose-reactive sizing agents generally provide good sizing effect using low dosages of the sizing agent when added to the aqueous cellulosic suspension. The sizing effect starts to develop in the drying section of the paper machine. However, since most paper machines operate at maximum speed to optimize the paper production, the time in the drying section is often not long enough to produce sized paper on-machine. Instead the paper has to be allowed to cure for up to 24 hours before a fully sized product can be achieved. This slow development of the sizing effect creates a number of problems. Firstly, subsequent operations such as printing, coating, pasting, etc. may be difficult to handle. Secondly, many paper makers continuously overdose the sizing agents to make sure that a fully sized product is achieved. Consequently, problems in terms of deposits on machine components are usually created.
WO 9710387 discloses a paper sizing enhancer which is a polymerization reaction product of a quaternary diallylammonium monomer and a diallylammonium monomer. The polymerization product has a molecular weight of at least 10,000. WO 9710387 discloses that the paper sizing enhancer may be introduced into a paper furnish during the papermaking process in combination with the paper sizing agent, either separately or as an aqueous medium containing both components.
WO 02081587 discloses a sizing dispersion containing a sizing agent and a non-ionic surface active monoester of glycerol with a fatty acid.
It is an object of this invention to provide a process for the production of paper with improved initial sizing on-machine. It is also an object of the invention to provide faster curing times for sizing agent. Further objects will appear hereinafter.
Summary of the Invention The present invention concerns a process for the production of paper which comprises:
(a) providing an aqueous cellulosic suspension;
(b) separately adding to the suspension:
(i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper.
The present invention further concerns a process for the production of paper which comprises:
(a) providing a cellulosic suspension;
(b) mixing a nitrogen-containing organic compound having molecular weight less than 1,000 with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix;
(c) adding the pre-mix to the suspension; and (d) dewatering the obtained suspension to form paper.
Detailed Description of the Invention In accordance with the present invention it has surprisingly been found that improved initial sizing, i.e. faster development of the sizing effect or faster curing of paper, in papermaking can be achieved by separately adding to a cellulosic suspension a nitrogen-containing organic compound having a molecular weight of less than 1,000 and a cellulose-reactive sizing agent. It has also been found that improved initial sizing can be achieved by adding to the suspension a pre-mix of the nitrogen-containing organic compound and an aqueous dispersion of a cellulose-reactive sizing agent.
Faster curing provides faster feedback on sized products, minimizes the risk of overdosing the sizing agent which, in turn, may result in less deposits in the paper machine. Hereby improved runnability of the paper machine can be achieved. Due to faster curing times, less storage space for paper rolls to be cured will be required. The present invention thus offers substantial economical and technical benefits.
Summary of the Invention The present invention concerns a process for the production of paper which comprises:
(a) providing an aqueous cellulosic suspension;
(b) separately adding to the suspension:
(i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper.
The present invention further concerns a process for the production of paper which comprises:
(a) providing a cellulosic suspension;
(b) mixing a nitrogen-containing organic compound having molecular weight less than 1,000 with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix;
(c) adding the pre-mix to the suspension; and (d) dewatering the obtained suspension to form paper.
Detailed Description of the Invention In accordance with the present invention it has surprisingly been found that improved initial sizing, i.e. faster development of the sizing effect or faster curing of paper, in papermaking can be achieved by separately adding to a cellulosic suspension a nitrogen-containing organic compound having a molecular weight of less than 1,000 and a cellulose-reactive sizing agent. It has also been found that improved initial sizing can be achieved by adding to the suspension a pre-mix of the nitrogen-containing organic compound and an aqueous dispersion of a cellulose-reactive sizing agent.
Faster curing provides faster feedback on sized products, minimizes the risk of overdosing the sizing agent which, in turn, may result in less deposits in the paper machine. Hereby improved runnability of the paper machine can be achieved. Due to faster curing times, less storage space for paper rolls to be cured will be required. The present invention thus offers substantial economical and technical benefits.
The nitrogen-containing organic compound according to the invention can be selected from primary amines, secondary amines, tertiary amines, quaternary amines, which are also referred to as quaternary ammonium compounds. The nitrogen-containing compound is preferably water-soluble or water-dispersible and it can be aromatic, i.e.
containing one or more aromatic groups, or aliphatic; the aliphatic nitrogen-containing water-dispersible organic compounds usually being preferred. The nitrogen-containing organic compound can be uncharged or cationic. Suitable nitrogen-containing organic compounds include acid addition salts of primary, secondary and tertiary amines and, preferably, quaternary ammonium compounds. The nitrogen-containing organic compound may have one or more oxygen-containing substituents, for example with oxygen in the form of hydroxyl groups and/or alkyloxy groups. Examples of preferred substituents of this type include hydroxyl groups, e.g. ethanol groups, and methoxy and ethoxy groups.
The nitrogen-containing organic compounds may include one or more nitrogen atoms, preferably one or two. The nitrogen-containing organic compound has a molecular weight of less than 1,000, suitably less than 900 or 800 and preferably less than 750 or 600.
Usually, the molecular weight of the nitrogen-containing organic compound is at least 250, preferably at least 330.
Examples of suitable nitrogen-containing organic compounds include compounds prepared by reacting a primary, secondary or tertiary amine with methyl chloride, dimethyl sulphate and benzyl chloride. Examples of suitable quaternary ammonium compounds further include compounds having the general formula R4N+ X, wherein each R group is independently selected from (i) hydrogen; (ii) hydrocarbon groups, suitably aliphatic and preferably alkyl groups, having from 1 to about 30 carbon atoms, preferably from 1 to 22 carbon atoms; and (iii) hydrocarbon groups, suitably aliphatic and preferably alkyl groups, having up to about 30 carbon atoms, preferably from 4 to 22 carbon atoms, and being interrupted by one or more heteroatoms, e.g. oxygen or nitrogen, and/or groups containing a heteroatom, e.g. carbonyl and acyloxy groups; where at least one, suitably at least three and preferably all of said R
groups contain carbon atoms; suitably at least one and preferably at least two of said R
groups containing at least 7 carbon atoms, preferably at least 9 carbon atoms and most pre-ferably at least 12 carbon atoms; and wherein X- is an anion, typically a halide like chloride.
The nitrogen-containing organic compound of the invention is preferably substantially free from silica-based particles.
Examples of suitable primary amines, i.e. amines having one organic substituent, include alkylamines, e.g. propylamine, butylamine, cyclohexylamine, alkanolamines, e.g.
ethanolamine, and alkoxyalkylamines, e.g. 2-methoxyethylamine. Examples of suitable secondary amines, i.e. amines having two organic substituents, include dialkylamines, e.g. diethylamine, dipropylamine and di-isopropylamine, dialkanolamines, e.g.
diethanolamine, and pyrrolidine. Examples of suitable tertiary amines, i.e.
amines having three organic substituents, include trialkylamines, e.g. triethylamine, trialkanolamines, e.g. triethanolamine, N,N-dialkylalkanolamines, e.g. N,N-dimethylethanolamine.
Examples of suitable quaternary ammonium compounds include methyl bis[ethyl (tallowate)]
- 2- hydroxyethyl ammonium methyl sulphate, dioctyldimethylammonium chloride, didecyldi-methylammonium chloride, dicocodimethylammonium chloride, cocobenzyldimethylammo-nium chloride, coco(fractionated)benzyldimethylammonium chloride, octadecyl trimethyl-ammonium chloride, dioctadecyl dimethylammonium chloride, dihexadecyl dimethylammo-nium chloride, di(hydrogenated tallow)dimethylammonium chloride, di(hydrogenated tallow)-benzylmethylammonium chloride, di(hydrogenated tallow fatty acids-2-hydroxyethyl ester) dimethyl ammonium chloride, (hydrogenated tallow)benzyldimethylammonium chloride, dioleyldimethylammonium chloride, di(ethylene hexadecanecarboxylate)dimethylammonium chloride, (vegetableoil)benzyl-dimethylammonium chloride, (dodecyl)benzyl-dimethylammonium chloride and quaternised imidazole derivates. Examples of suitable diamines include aminoalkylalkanolamines, e.g. aminoethylethanolamine, piperazine and nitrogen-substituted piperazines having one or two lower alkyl groups of 1 to 4 carbon atoms. Example of suitable imidazoline derivates include quaternary imidazolinium compounds, e.g. 2-(C17 and C17 unsaturated alkyl)-1-[2-(C18 and C18-unsaturated amido) ethyl]-4,5-dihydro-l-methyl, methyl sulfates. Examples of preferred nitrogen-containing organic compounds include methyl bis[ethyl (tallowate)] - 2-hydroxyethyl ammonium methyl sulphate, di(hydrogenated tallow)dimethylammonium chloride, di(hydrogenated tallow fatty acids-2-hydroxyethyl ester) dimethyl ammonium chloride, didecyldimethylammonium chloride, (vegetableoil)benzyl-dimethylammonium chloride and (dodecyl)benzyl-dimethylammonium chloride.
The cellulose-reactive sizing agent can be selected from the group consisting of hydrophobic ketene dimers, ketene multimers, acid anhydrides, organic isocyanates and mixtures thereof, preferably ketene dimers, ketene multimers and acid anhydrides, most preferably ketene dimers. Suitable ketene dimers have the general formula (I) below, wherein R' and R2 represent saturated or unsaturated hydrocarbon groups, usually saturated hydrocarbons, the hydrocarbon groups suitably having from 8 to 36 carbon atoms, usually being straight or branched chain alkyl groups having 12 to 20 carbon atoms, such as hexadecyl and octadecyl groups. Suitable acid anhydrides can be characterized by the general formula (II) below, wherein R3 and R4 can be identical or different and represent saturated or unsaturated hydrocarbon groups suitably containing from 8 to 30 carbon atoms, or R3 and R4 together with the -C-O-C- moiety can form a 5 to 6 membered ring, optionally being further substituted with hydrocarbon groups containing up to 30 carbon atoms.
Examples of acid anhydrides which are used commercially include alkyl and alkenyl succinic anhydrides and particularly isooctadecenyl succinic anhydride.
containing one or more aromatic groups, or aliphatic; the aliphatic nitrogen-containing water-dispersible organic compounds usually being preferred. The nitrogen-containing organic compound can be uncharged or cationic. Suitable nitrogen-containing organic compounds include acid addition salts of primary, secondary and tertiary amines and, preferably, quaternary ammonium compounds. The nitrogen-containing organic compound may have one or more oxygen-containing substituents, for example with oxygen in the form of hydroxyl groups and/or alkyloxy groups. Examples of preferred substituents of this type include hydroxyl groups, e.g. ethanol groups, and methoxy and ethoxy groups.
The nitrogen-containing organic compounds may include one or more nitrogen atoms, preferably one or two. The nitrogen-containing organic compound has a molecular weight of less than 1,000, suitably less than 900 or 800 and preferably less than 750 or 600.
Usually, the molecular weight of the nitrogen-containing organic compound is at least 250, preferably at least 330.
Examples of suitable nitrogen-containing organic compounds include compounds prepared by reacting a primary, secondary or tertiary amine with methyl chloride, dimethyl sulphate and benzyl chloride. Examples of suitable quaternary ammonium compounds further include compounds having the general formula R4N+ X, wherein each R group is independently selected from (i) hydrogen; (ii) hydrocarbon groups, suitably aliphatic and preferably alkyl groups, having from 1 to about 30 carbon atoms, preferably from 1 to 22 carbon atoms; and (iii) hydrocarbon groups, suitably aliphatic and preferably alkyl groups, having up to about 30 carbon atoms, preferably from 4 to 22 carbon atoms, and being interrupted by one or more heteroatoms, e.g. oxygen or nitrogen, and/or groups containing a heteroatom, e.g. carbonyl and acyloxy groups; where at least one, suitably at least three and preferably all of said R
groups contain carbon atoms; suitably at least one and preferably at least two of said R
groups containing at least 7 carbon atoms, preferably at least 9 carbon atoms and most pre-ferably at least 12 carbon atoms; and wherein X- is an anion, typically a halide like chloride.
The nitrogen-containing organic compound of the invention is preferably substantially free from silica-based particles.
Examples of suitable primary amines, i.e. amines having one organic substituent, include alkylamines, e.g. propylamine, butylamine, cyclohexylamine, alkanolamines, e.g.
ethanolamine, and alkoxyalkylamines, e.g. 2-methoxyethylamine. Examples of suitable secondary amines, i.e. amines having two organic substituents, include dialkylamines, e.g. diethylamine, dipropylamine and di-isopropylamine, dialkanolamines, e.g.
diethanolamine, and pyrrolidine. Examples of suitable tertiary amines, i.e.
amines having three organic substituents, include trialkylamines, e.g. triethylamine, trialkanolamines, e.g. triethanolamine, N,N-dialkylalkanolamines, e.g. N,N-dimethylethanolamine.
Examples of suitable quaternary ammonium compounds include methyl bis[ethyl (tallowate)]
- 2- hydroxyethyl ammonium methyl sulphate, dioctyldimethylammonium chloride, didecyldi-methylammonium chloride, dicocodimethylammonium chloride, cocobenzyldimethylammo-nium chloride, coco(fractionated)benzyldimethylammonium chloride, octadecyl trimethyl-ammonium chloride, dioctadecyl dimethylammonium chloride, dihexadecyl dimethylammo-nium chloride, di(hydrogenated tallow)dimethylammonium chloride, di(hydrogenated tallow)-benzylmethylammonium chloride, di(hydrogenated tallow fatty acids-2-hydroxyethyl ester) dimethyl ammonium chloride, (hydrogenated tallow)benzyldimethylammonium chloride, dioleyldimethylammonium chloride, di(ethylene hexadecanecarboxylate)dimethylammonium chloride, (vegetableoil)benzyl-dimethylammonium chloride, (dodecyl)benzyl-dimethylammonium chloride and quaternised imidazole derivates. Examples of suitable diamines include aminoalkylalkanolamines, e.g. aminoethylethanolamine, piperazine and nitrogen-substituted piperazines having one or two lower alkyl groups of 1 to 4 carbon atoms. Example of suitable imidazoline derivates include quaternary imidazolinium compounds, e.g. 2-(C17 and C17 unsaturated alkyl)-1-[2-(C18 and C18-unsaturated amido) ethyl]-4,5-dihydro-l-methyl, methyl sulfates. Examples of preferred nitrogen-containing organic compounds include methyl bis[ethyl (tallowate)] - 2-hydroxyethyl ammonium methyl sulphate, di(hydrogenated tallow)dimethylammonium chloride, di(hydrogenated tallow fatty acids-2-hydroxyethyl ester) dimethyl ammonium chloride, didecyldimethylammonium chloride, (vegetableoil)benzyl-dimethylammonium chloride and (dodecyl)benzyl-dimethylammonium chloride.
The cellulose-reactive sizing agent can be selected from the group consisting of hydrophobic ketene dimers, ketene multimers, acid anhydrides, organic isocyanates and mixtures thereof, preferably ketene dimers, ketene multimers and acid anhydrides, most preferably ketene dimers. Suitable ketene dimers have the general formula (I) below, wherein R' and R2 represent saturated or unsaturated hydrocarbon groups, usually saturated hydrocarbons, the hydrocarbon groups suitably having from 8 to 36 carbon atoms, usually being straight or branched chain alkyl groups having 12 to 20 carbon atoms, such as hexadecyl and octadecyl groups. Suitable acid anhydrides can be characterized by the general formula (II) below, wherein R3 and R4 can be identical or different and represent saturated or unsaturated hydrocarbon groups suitably containing from 8 to 30 carbon atoms, or R3 and R4 together with the -C-O-C- moiety can form a 5 to 6 membered ring, optionally being further substituted with hydrocarbon groups containing up to 30 carbon atoms.
Examples of acid anhydrides which are used commercially include alkyl and alkenyl succinic anhydrides and particularly isooctadecenyl succinic anhydride.
(I) R'-CH=C-CH-R2 (II) 0 0 O-C=0 R3-C-O-C-R4 Suitable ketene dimers, acid anhydrides and organic isocyanates include the compounds disclosed in U.S. Pat. No. 4,522,686, which is hereby incorporated herein by reference.
The dispersions of this invention contain a dispersant or a dispersant system comprising one or more dispersing agents and protective colloids. The dispersing agents and protective colloids can be selected from anionic, non-ionic, cationic and amphoteric compounds which separately or together may function as dispersing agent or dispersant system for the cellulose-reactive sizing agent. The dispersions according to the invention can have contents of cellulose-reactive sizing agents from about 0.1 % by weight up to about 30% by weight. The content of cellulose-reactive sizing agent is suitably within the range of from 5 to 25% and preferably from 8 to 20% by weight.
The dispersing agents and protective colloids can be any of those conventionally used in the preparation of aqueous sizing dispersions or emulsions. They can for example be selected from saponified rosin derivatives, alkyl sulphates, alkylaryl sulphates, alkyl sulphonates, alkylaryl sulphonates, etc. Particularly suitable anionic dispersing agents are alkyl sulphates and alkyl sulphonates, e.g. sodium lauryl sulphate, as well as sodium lignosulphonate and sodium naphthalene sulphonate. Examples of suitable protective colloids include water-soluble cellulose-derivatives such as hydroxyethyl- and hydroxypropyl-, methyl-hydroxypropyl- and ethylhydroxyethylcellulose, methyl- and carboxymethylcellulose, gelatin, starch, guar gum, xanthan gum, polyvinyl alcohol, etc.. Examples of suitable non-ionic dispersing agents can for example be selected from fatty alcohols, ethoxylated fatty alcohols, fatty acids, alkyl phenols or fatty acid amides, ethoxylated or non-ethoxylated glycerol esters, sorbitan esters of fatty acids, etc.. Examples of suitable cationic dispersing agents and protective colloids include water-soluble nitrogen-containing epichlorohydrin resins and cationic starches, etc.. The dispersion may also contain other additives such as preservative agents. Suitably, the amount of dispersing agent is at least 0.5%
by weight, based on the amount of sizing agent. Normally, it is not necessary to use more than 10% by weight.
The dispersions of this invention contain a dispersant or a dispersant system comprising one or more dispersing agents and protective colloids. The dispersing agents and protective colloids can be selected from anionic, non-ionic, cationic and amphoteric compounds which separately or together may function as dispersing agent or dispersant system for the cellulose-reactive sizing agent. The dispersions according to the invention can have contents of cellulose-reactive sizing agents from about 0.1 % by weight up to about 30% by weight. The content of cellulose-reactive sizing agent is suitably within the range of from 5 to 25% and preferably from 8 to 20% by weight.
The dispersing agents and protective colloids can be any of those conventionally used in the preparation of aqueous sizing dispersions or emulsions. They can for example be selected from saponified rosin derivatives, alkyl sulphates, alkylaryl sulphates, alkyl sulphonates, alkylaryl sulphonates, etc. Particularly suitable anionic dispersing agents are alkyl sulphates and alkyl sulphonates, e.g. sodium lauryl sulphate, as well as sodium lignosulphonate and sodium naphthalene sulphonate. Examples of suitable protective colloids include water-soluble cellulose-derivatives such as hydroxyethyl- and hydroxypropyl-, methyl-hydroxypropyl- and ethylhydroxyethylcellulose, methyl- and carboxymethylcellulose, gelatin, starch, guar gum, xanthan gum, polyvinyl alcohol, etc.. Examples of suitable non-ionic dispersing agents can for example be selected from fatty alcohols, ethoxylated fatty alcohols, fatty acids, alkyl phenols or fatty acid amides, ethoxylated or non-ethoxylated glycerol esters, sorbitan esters of fatty acids, etc.. Examples of suitable cationic dispersing agents and protective colloids include water-soluble nitrogen-containing epichlorohydrin resins and cationic starches, etc.. The dispersion may also contain other additives such as preservative agents. Suitably, the amount of dispersing agent is at least 0.5%
by weight, based on the amount of sizing agent. Normally, it is not necessary to use more than 10% by weight.
The nitrogen-containing organic compound of the invention and the cellulose-reactive sizing agent can be separately added to the cellulosic suspension in any order. The nitrogen-containing organic compound can be separately added prior to, simultaneously with or after adding the cellulose-reactive sizing agent and preferably prior to adding the cellulose-reactive sizing agent.
The nitrogen-containing organic compound and the aqueous dispersion of cellulose-reactive sizing agent, herein also referred to as sizing dispersion, can also be added to the cellulosic suspension as a pre-mix. In this embodiment, the nitrogen-containing organic compound and the sizing dispersion are mixed to form a pre-mix before addition to the cellulosic suspension. The mixing can be done by bringing into contact some time before the addition the nitrogen-containing organic compound, suitably an aqueous phase thereof and preferably an aqueous stream thereof, and the sizing dispersion, preferably an aqueous stream thereof.
The obtained aqueous phase or stream is then introduced to the cellulosic suspension.
Preferably, the contact time, i.e. the time from mixing the nitrogen-containing organic compound and the sizing dispersion to adding the pre-mix so formed to the cellulosic suspension, is short. This period of time can be less than about 20 minutes, suitably less than 4 minutes and preferably less than 2 minutes.
The mixing of aqueous streams of the nitrogen-containing organic compound and the sizing dispersion can be effected by directing the separate streams to be mixed towards each other, allowing them to impinge on each other and introducing the pre-mix stream so formed into the cellulosic suspension. Suitably mixing is carried out under turbulent flow conditions, which promote more intensive and rapid mixing of the streams. The streams can be mixed by means of any mixing device having at least two inlets into which separate streams to be mixed are supplied and having at least one outlet through which the resulting pre-mix is passed and subsequently introduced to the cellulosic suspension. This stream mixing embodiment is advantageous from a practical point of view and confers operational benefits.
The nitrogen-containing organic compound and the cellulose-reactive sizing agent can be added to the cellulosic suspension at any position, e.g. anywhere between the machine chest and the headbox.
The nitrogen-containing organic compound and the cellulose-reactive sizing agent can be added to the cellulosic suspension in amounts that can vary within wide limits, where the dosage is mainly dependent on the quality of the pulp or paper to be sized, the cellulose-reactive sizing agent used and the level of sizing desired. The nitrogen-containing organic compound is suitably added to the cellulosic suspension in an amount of from 0.005 to 0.5%
by weight, preferably of from 0.01 to 0.3% by weight and most preferably of from 0.02 to 0.1 % by weight based on the dry weight of the cellulosic suspension. The cellulose-reactive sizing agent is suitably added to the cellulosic suspension in an amount of from 0.01 to 1.0%
by weight, preferably of from 0.05 to 0.5% by weight based on the dry weight of the cellulosic suspension.
The term "paper", as used herein, is meant to include not only paper but all types of cellu-lose-based products in sheet and web form, including, for example, board, paperboard and particularly liquid packaging board. The process according to the invention can be used in the production of paper from different types of cellulosic suspensions of cellulose-containing fibres and the suspensions should suitably contain at least 25% by weight and preferably at least 50% by weight of such fibres, based on dry substance. The suspension can be based on fibres from chemical pulp such as sulphate, sulphite and organosolv pulps, mechanical pulp such as thermomechanical pulp, chemo-thermomechanical pulp, refiner pulp and groundwood pulp, from both hardwood and softwood, and can also be based on recycled fibres, optionally from de-inked pulps, and mixtures thereof. The cellulosic suspension may optionally also contain mineral fillers. Examples of mineral fillers of conventional types include kaolin, china clay, titanium dioxide, gypsum, talc and natural and synthetic calcium carbonates such as chalk, ground marble and precipitated calcium carbonate.
The pH of the cellulosic suspension can be within the range of from about 3 to about 10. The pH is suitably above 3.5 and preferably within the range of from 4 to 9.
Chemicals conventionally added to the cellulosic suspension in papermaking such as retention aids, aluminium compounds, dyes, wet-strength resins, optical brightening agents, etc., can of course be used in conjunction with the present dispersions.
Examples of aluminium compounds include alum, aluminates and polyaluminium compounds, e.g.
polyaluminium chlorides and sulphates. Examples of suitable retention aids include cationic polymers, anionic inorganic materials in combination with organic polymers, e.g. bentonite in combination with cationic polymers, silica-based sols in combination with cationic polymers or cationic and anionic polymers. Particularly good internal sizing can be obtained when using the nitrogen-containing organic compound and the cellulose-reactive sizing agent as described above in combination with retention aids comprising cationic polymers. Suitable cationic polymers include cationic starch, guar gum, acrylate-based and acrylamide-based polymers, polyethyleneimine, dicyandiamide-formaldehyde resins, polyamines, polyamido-amines and poly(diallyldimethyl ammoniumchloride) and combinations thereof.
Cationic starch and cationic acrylamide-based polymers are preferably used, either alone or in combination with each other or with other materials.
The invention is further illustrated in the following examples, which, however, are not intended to limit the same.
Example 1 AKD sizing of liquid packaging board was performed on an experimental paper machine which comprised a machine chest, two separate pumping arrangements, defoamer, screen, headbox and a wire, where the cellulosic suspension was dewatered to form a sheet.
The nitrogen-containing organic compounds used in the following Examples are those described in Table 1.
Table 1 Nitrogen-containing Description Molecular weight Trade name organic compound A Di(hydrogenated 560 Arquad 2HT-75PG
tallow)dimethylammonium chloride B Didecyldimethylammonium 360 Arquad 2.10-50 chloride C (Vegetableoil)benzyl- 410 Arquad HTB-75 dimethylammonium chloride D (Dodecyl)benzyl- 420 Croda N-Dodecyl dimethylammonium chloride E Quaternary imidazolinium 744 Incrosoft CFI-90 PG
F polyDADMAC 350,000 Eka ATC 6340 G Di(hydrogenatedtallow fatty 702 Armosoft DEQ
acids-2-hydroxyethyl ester) dimethyl ammonium chloride The cellulosic suspension comprised 100% bleached CTMP. Two different nitrogen-containing organic compounds were used in the tests: A and E. The addition of the nitrogen containing compound to the cellulosic suspension took place after the machine chest. A
reference without addition of nitrogen-containing organic compound was also performed.
Cationic starch (Raisamyl 142) was dosed at two points; after the first pumping arrangement (P1) 2 kg/tonne and before the second pumping arrangement (P2) 3 kg/tonne. The AKD
(Eka DH 28HF) sizing agent was dosed before the P2 and a silica sol (Eka NP
442) was dosed after the P2 (3 kg/tonne as received). pH at the head box was 8Ø
Edge Wick (EW) tests with lactic acid (1 %) were performed on the final paper after 1 h and 24h, respectively. The results are presented in Table 2.
Table 2 Nitrogen-containing 1 h EW (LA 1 %) (kg/m ) 24h EW (LA 1 %) (kg/m ) organic compound AKD AKD AKD AKD
(2kg/tonne) (3kg/tonne) (2kg/tonne) (3kg/tonne) Reference 1.29 0.96 0.68 0.56 E (0.5 kg/tonne) 0.9 0.78 0.63 0.60 A (0.5 kg/tonne) 0.83 0.67 0.6 0.55 A (1.0 kg/tonne) 0.75 0.62 0.63 0.54 As can be seen from Table 2, the tests using nitrogen-containing organic compounds according to the present invention showed lower EW values after 1 hour compared to references which did not contain any nitrogen-containing organic compound. It can be concluded that the addition of nitrogen-containing organic compounds shorten the curing time. After 24 hours, all samples show about the same EW values.
Example 2 The papermaking conditions were the same as in Example 1. Two different dosages (0.25 kg/tonne and 0.5 kg/tonne) of the nitrogen-containing organic compounds were tested at two dosage levels of AKD (1 kg/tonne and 1.5 kg/tonne).
Sizing performance was tested as Cobb6o-value on the paper directly after it had come off the machine, after lh, 3h, and finally after 24h according to the standard method Tappi T441. The results are shown in Table 3.
Table 3 Cobb60 (g/m ) Nitrogen- AKD Nitrogen- Off 1 h 3h 24h containing (kg/tonne) containing Machine organic organic compound compound (kg/tonne) Reference 1.0 0 220 127 39 20 A 1.0 0.25 68 39 26 18 B 1.0 0.25 111 47 31 21 C 1.0 0.25 42 30 25 19 D 1.0 0.25 84 41 26 21 Reference 1.5 0 41 29 23 17 A 1.5 0.25 28 24 21 17 B 1.5 0.25 35 24 21 17 C 1.5 0.25 24 22 19 17 D 1.5 0.25 28 24 21 18 A 1.0 0.5 31 26 23 20 B 1.0 0.5 42 30 24 20 C 1.0 0.5 31 26 22 20 D 1.0 0.5 58 40 26 21 A 1.5 0.5 22 20 18 17 B 1.5 0.5 26 21 19 17 C 1.5 0.5 24 19 18 17 D 1.5 0.5 27 23 20 18 Cobb60-values off machine and after lh of the paper samples treated with a nitrogen-5 containing organic compound show lower Cobb6o-values compared to Cobb60-values of the reference. After 24h, all the samples have reached approximately the same sizing degree.
From the results of Table 3 it can also be concluded that it is possible to decrease the AKD
dosage when a nitrogen-containing organic compound according to the present invention is added to the suspension.
Tensile index (SCAN-P 67:93) was tested on the paper sheets treated with the nitrogen-containing organic compounds and compared with the reference in order to investigate if the nitrogen-containing organic compounds have had a negative effect on the paper strength.
The results are shown in Table 4.
Table 4 Nitrogen-containing AKD Nitrogen-containing Tensile index (Nm/g) organic compound (kg/tonne) organic compound (kg/tonne) Reference 1.0 - 29.7 A 1.0 0.25 29.1 B 1.0 0.25 30.6 C 1.0 0.25 29.9 D 1.0 0.25 29.9 Reference 1.5 - 30.9 A 1.5 0.25 27.3 B 1.5 0.25 28.5 C 1.5 0.25 30.0 D 1.5 0.25 30.3 A 1.0 0.50 27.9 B 1.0 0.50 29.6 C 1.0 0.50 28.1 D 1.0 0.50 30.5 A 1.5 0.50 28.3 B 1.5 0.50 30.6 C 1.5 0.50 30.3 D 1.5 0.50 30.5 The results show that the nitrogen-containing organic compounds do not have any significant effect on the tensile strength and therefore do not deteriorate paper/board quality.
Example 3 In this Example, sizing performance was tested as Cobb6o-value on paper when nitrogen-containing organic compounds were added in different addition modes. Further, sizing performance was tested when using a nitrogen-containing organic compound according to the present invention and polyDADMAC polymer.
The cellulosic suspension contained 80% hardwood and 20% softwood and had a fiber concentration of 0.5 %. No filler was added. The conductivity was 0.3 mS/cm and pH was about 8. Hand sheets were prepared according to the standard method SCAN-C26:76 and sizing property was measured as Cobb60 value according to the standard method Tappi T441.
A first retention system was used comprising 0.75 kg/tonne cationic polyacrylamide (Eka PL
1510) and 1 kg/tonne of silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension. The results are presented in Table 5. A second retention system was used comprising 5 kg/tonne of cationic potato starch (Perlbond 980) and 1 kg/tonne of silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension.
The results are presented in Table 6.
The dosage of the cationic polyacrylamide (EKA PL 1510) was reduced to 0.5 kg/tonne in the cases where polyDADMAC (F) was added to the paper fiber suspension.
The sizing agent AKD (Eka DR 28 HF) was added in an amount of 0.45 kg/tonne and the nitrogen-containing organic compound, Arquad HTB-75 (C), according to the invention was either added:
a) 2 minutes before AKD, b) premixed with AKD, c) simultaneously with AKD
d) after AKD.
The sizing results obtained by the addition of 0 kg/tonne, 0.25 kg/tonne and 0.5 kg/tonne of the nitrogen-containing organic compound (C) are shown in Tables 5 and 6, respectively.
The results can be compared with the results obtained by the absence of the nitrogen-containing organic compound or by addition of the polymer (F) instead of the nitrogen-containing organic compound according to the invention.
Table 5 Cobb60 (g/m ) Addition mode Reference F C
(0.25 kg/tonne) (0.25 kg/tonne) no addition 63 a) addition before AKD 230 36 b) premixed with AKD 33 c) addition simultaneously 38 32 with AKD
d) addition after AKD 31 Table 6 Cobb60 (g/m ) Addition mode Reference F C
(0.5 kg/tonne) (0.5 kg/tonne) no addition 98 a) addition before AKD 251 30 b) premixed with AKD 31 c) addition simultaneously 33 31 with AKD
d) addition after AKD 31 Example 4 In this Example, liquid packaging board was prepared on an experimental paper machine as described in Example 1 and the sizing performance was tested as Cobb6o-value according to the standard method Tappi T441. The cellulosic suspension contained 80%
hardwood (40% eucalyptus and 40% birch) and 20% softwood and had a fiber concentration of 1.5%.
No filler was added. The pH was 7.1. A retention system was used comprising 0.375 kg/tonne cationic polyacrylamide (Eka PL 1510) and 0.15 kg/tonne silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension. A nitrogen-containing organic compound, Arquad HTB-75 (C) or Armosoft DEQ (G), according to the invention was added before the sizing agent AKD (Eka DR 28 HF). In order to investigate the impact of dosing order on the sizing performance, Armosoft DEQ (G) was also added after the addition of the AKD. The sizing results are presented in Table Nos. 7 and 8, respectively. The results can be compared with the results obtained by the absence of the nitrogen-containing organic compound.
Table 7 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 24h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.5 127 127 102 28 28 - 0 0.75 105 98 46 26 26 - 0 1.0 97 72 48 25 25 C 0.25 0.5 127 93 53 31 29 C 0.25 0.75 76 46 30 24 26 C 0.25 1.0 46 35 28 23 23 C 0.5 0.5 83 56 42 38 45 C 0.5 0.75 49 29 28 24 28 C 0.5 1.0 31 27 24 22 24 G 0.25 0.5 103 76 38 27 25 G 0.25 0.75 45 36 36 25 26 G 0.25 1.0 41 35 27 25 23 G 0.5 0.5 63 35 29 28 28 G 0.5 0.75 38 29 25 24 25 G 0.5 1.0 32 25 27 22 24 It can be seen that the nitrogen-containing organic compounds according to the invention have a positive effect on the initial sizing of AKD. It is possible to reach low Cobb60-values already directly off machine. The final sizing degree is not affected by the addition of the nitrogen-containing organic compound.
Table 8 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 72h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.5 122 116 96 27 24 - 0 0.75 96 77 41 24 21 - 0 1.0 78 55 35 23 21 G 0.5 0.5 109 80 38 27 23 G 0.5 0.75 60 36 30 23 21 G 0.5 1.0 37 31 30 23 21 In this example it can be seen that it is possible to add the nitrogen-containing organic 5 compound before or after the addition of AKD.
Example 5 In this Example, liquid packaging board was prepared on an experimental paper machine as 10 described in Example 1 and the sizing performance was tested as Cobb6o-value according to the standard method Tappi T441. The cellulosic suspension comprised 100%
bleached CTMP, which had a fiber concentration of 1.35 %. No filler was added. The pH
was 5.6 and the conductivity was 219 pS/cm. A nitrogen-containing organic compound, Arquad (C) or Armosoft DEQ (G), was used in the tests. The addition of the nitrogen containing 15 compound to the cellulosic suspension took place after the machine chest. A
reference without addition of a nitrogen-containing organic compound was also performed.
The AKD
(Eka DH 28HF) sizing agent was added before the second pumping arrangement (P2).
Cationic starch (Raisamyl 142) was added before P2 (5 kg/tonne) and a silica sol (Eka NP
442) was added after the P2 (0.15 kg/tonne), calculated as dry substances on dry cellulosic suspension. The nitrogen-containing organic compound, Arquad HTB-75 (C) or Armosoft DEQ (G), according to the invention was added before the sizing agent AKD (Eka HF).
Table 9 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 24h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.75 338 306 280 33 25 - 0 1.0 294 286 270 33 24 - 0 1.25 261 227 205 29 22 C 0.25 0.75 227 173 64 26 21 C 0.25 1.0 87 54 33 23 23 C 0.25 1.25 64 38 31 21 21 C 0.5 0.75 121 71 46 25 26 C 0.5 1.0 39 30 30 21 24 C 0.5 1.25 30 28 23 20 22 G 0.25 0.75 249 225 92 28 25 G 0.25 1.0 209 177 101 27 26 G 0.25 1.25 76 42 32 23 22 G 0.5 0.75 139 58 56 26 24 G 0.5 1.0 50 33 33 23 19 G 0.5 1.25 36 28 26 23 20 It can be seen that the nitrogen-containing organic compounds according to the invention have a positive effect on the initial sizing of AKD. It is possible to reach low Cobb60-values already after lh. The final sizing degree is not affected by the addition of the nitrogen-containing organic compound. The tensile index is not decreased by the addition of the nitrogen-containing organic compounds.
The nitrogen-containing organic compounds according to the invention function together with AKD in amounts of from about 0.05 to about 5 kg/tonne calculated on dry pulp, preferably from about 0.1 to about 3 kg/tonne calculated on dry pulp and most preferably from about 0.2 to about 1 kg/tonne calculated on dry pulp.
The nitrogen-containing organic compound and the aqueous dispersion of cellulose-reactive sizing agent, herein also referred to as sizing dispersion, can also be added to the cellulosic suspension as a pre-mix. In this embodiment, the nitrogen-containing organic compound and the sizing dispersion are mixed to form a pre-mix before addition to the cellulosic suspension. The mixing can be done by bringing into contact some time before the addition the nitrogen-containing organic compound, suitably an aqueous phase thereof and preferably an aqueous stream thereof, and the sizing dispersion, preferably an aqueous stream thereof.
The obtained aqueous phase or stream is then introduced to the cellulosic suspension.
Preferably, the contact time, i.e. the time from mixing the nitrogen-containing organic compound and the sizing dispersion to adding the pre-mix so formed to the cellulosic suspension, is short. This period of time can be less than about 20 minutes, suitably less than 4 minutes and preferably less than 2 minutes.
The mixing of aqueous streams of the nitrogen-containing organic compound and the sizing dispersion can be effected by directing the separate streams to be mixed towards each other, allowing them to impinge on each other and introducing the pre-mix stream so formed into the cellulosic suspension. Suitably mixing is carried out under turbulent flow conditions, which promote more intensive and rapid mixing of the streams. The streams can be mixed by means of any mixing device having at least two inlets into which separate streams to be mixed are supplied and having at least one outlet through which the resulting pre-mix is passed and subsequently introduced to the cellulosic suspension. This stream mixing embodiment is advantageous from a practical point of view and confers operational benefits.
The nitrogen-containing organic compound and the cellulose-reactive sizing agent can be added to the cellulosic suspension at any position, e.g. anywhere between the machine chest and the headbox.
The nitrogen-containing organic compound and the cellulose-reactive sizing agent can be added to the cellulosic suspension in amounts that can vary within wide limits, where the dosage is mainly dependent on the quality of the pulp or paper to be sized, the cellulose-reactive sizing agent used and the level of sizing desired. The nitrogen-containing organic compound is suitably added to the cellulosic suspension in an amount of from 0.005 to 0.5%
by weight, preferably of from 0.01 to 0.3% by weight and most preferably of from 0.02 to 0.1 % by weight based on the dry weight of the cellulosic suspension. The cellulose-reactive sizing agent is suitably added to the cellulosic suspension in an amount of from 0.01 to 1.0%
by weight, preferably of from 0.05 to 0.5% by weight based on the dry weight of the cellulosic suspension.
The term "paper", as used herein, is meant to include not only paper but all types of cellu-lose-based products in sheet and web form, including, for example, board, paperboard and particularly liquid packaging board. The process according to the invention can be used in the production of paper from different types of cellulosic suspensions of cellulose-containing fibres and the suspensions should suitably contain at least 25% by weight and preferably at least 50% by weight of such fibres, based on dry substance. The suspension can be based on fibres from chemical pulp such as sulphate, sulphite and organosolv pulps, mechanical pulp such as thermomechanical pulp, chemo-thermomechanical pulp, refiner pulp and groundwood pulp, from both hardwood and softwood, and can also be based on recycled fibres, optionally from de-inked pulps, and mixtures thereof. The cellulosic suspension may optionally also contain mineral fillers. Examples of mineral fillers of conventional types include kaolin, china clay, titanium dioxide, gypsum, talc and natural and synthetic calcium carbonates such as chalk, ground marble and precipitated calcium carbonate.
The pH of the cellulosic suspension can be within the range of from about 3 to about 10. The pH is suitably above 3.5 and preferably within the range of from 4 to 9.
Chemicals conventionally added to the cellulosic suspension in papermaking such as retention aids, aluminium compounds, dyes, wet-strength resins, optical brightening agents, etc., can of course be used in conjunction with the present dispersions.
Examples of aluminium compounds include alum, aluminates and polyaluminium compounds, e.g.
polyaluminium chlorides and sulphates. Examples of suitable retention aids include cationic polymers, anionic inorganic materials in combination with organic polymers, e.g. bentonite in combination with cationic polymers, silica-based sols in combination with cationic polymers or cationic and anionic polymers. Particularly good internal sizing can be obtained when using the nitrogen-containing organic compound and the cellulose-reactive sizing agent as described above in combination with retention aids comprising cationic polymers. Suitable cationic polymers include cationic starch, guar gum, acrylate-based and acrylamide-based polymers, polyethyleneimine, dicyandiamide-formaldehyde resins, polyamines, polyamido-amines and poly(diallyldimethyl ammoniumchloride) and combinations thereof.
Cationic starch and cationic acrylamide-based polymers are preferably used, either alone or in combination with each other or with other materials.
The invention is further illustrated in the following examples, which, however, are not intended to limit the same.
Example 1 AKD sizing of liquid packaging board was performed on an experimental paper machine which comprised a machine chest, two separate pumping arrangements, defoamer, screen, headbox and a wire, where the cellulosic suspension was dewatered to form a sheet.
The nitrogen-containing organic compounds used in the following Examples are those described in Table 1.
Table 1 Nitrogen-containing Description Molecular weight Trade name organic compound A Di(hydrogenated 560 Arquad 2HT-75PG
tallow)dimethylammonium chloride B Didecyldimethylammonium 360 Arquad 2.10-50 chloride C (Vegetableoil)benzyl- 410 Arquad HTB-75 dimethylammonium chloride D (Dodecyl)benzyl- 420 Croda N-Dodecyl dimethylammonium chloride E Quaternary imidazolinium 744 Incrosoft CFI-90 PG
F polyDADMAC 350,000 Eka ATC 6340 G Di(hydrogenatedtallow fatty 702 Armosoft DEQ
acids-2-hydroxyethyl ester) dimethyl ammonium chloride The cellulosic suspension comprised 100% bleached CTMP. Two different nitrogen-containing organic compounds were used in the tests: A and E. The addition of the nitrogen containing compound to the cellulosic suspension took place after the machine chest. A
reference without addition of nitrogen-containing organic compound was also performed.
Cationic starch (Raisamyl 142) was dosed at two points; after the first pumping arrangement (P1) 2 kg/tonne and before the second pumping arrangement (P2) 3 kg/tonne. The AKD
(Eka DH 28HF) sizing agent was dosed before the P2 and a silica sol (Eka NP
442) was dosed after the P2 (3 kg/tonne as received). pH at the head box was 8Ø
Edge Wick (EW) tests with lactic acid (1 %) were performed on the final paper after 1 h and 24h, respectively. The results are presented in Table 2.
Table 2 Nitrogen-containing 1 h EW (LA 1 %) (kg/m ) 24h EW (LA 1 %) (kg/m ) organic compound AKD AKD AKD AKD
(2kg/tonne) (3kg/tonne) (2kg/tonne) (3kg/tonne) Reference 1.29 0.96 0.68 0.56 E (0.5 kg/tonne) 0.9 0.78 0.63 0.60 A (0.5 kg/tonne) 0.83 0.67 0.6 0.55 A (1.0 kg/tonne) 0.75 0.62 0.63 0.54 As can be seen from Table 2, the tests using nitrogen-containing organic compounds according to the present invention showed lower EW values after 1 hour compared to references which did not contain any nitrogen-containing organic compound. It can be concluded that the addition of nitrogen-containing organic compounds shorten the curing time. After 24 hours, all samples show about the same EW values.
Example 2 The papermaking conditions were the same as in Example 1. Two different dosages (0.25 kg/tonne and 0.5 kg/tonne) of the nitrogen-containing organic compounds were tested at two dosage levels of AKD (1 kg/tonne and 1.5 kg/tonne).
Sizing performance was tested as Cobb6o-value on the paper directly after it had come off the machine, after lh, 3h, and finally after 24h according to the standard method Tappi T441. The results are shown in Table 3.
Table 3 Cobb60 (g/m ) Nitrogen- AKD Nitrogen- Off 1 h 3h 24h containing (kg/tonne) containing Machine organic organic compound compound (kg/tonne) Reference 1.0 0 220 127 39 20 A 1.0 0.25 68 39 26 18 B 1.0 0.25 111 47 31 21 C 1.0 0.25 42 30 25 19 D 1.0 0.25 84 41 26 21 Reference 1.5 0 41 29 23 17 A 1.5 0.25 28 24 21 17 B 1.5 0.25 35 24 21 17 C 1.5 0.25 24 22 19 17 D 1.5 0.25 28 24 21 18 A 1.0 0.5 31 26 23 20 B 1.0 0.5 42 30 24 20 C 1.0 0.5 31 26 22 20 D 1.0 0.5 58 40 26 21 A 1.5 0.5 22 20 18 17 B 1.5 0.5 26 21 19 17 C 1.5 0.5 24 19 18 17 D 1.5 0.5 27 23 20 18 Cobb60-values off machine and after lh of the paper samples treated with a nitrogen-5 containing organic compound show lower Cobb6o-values compared to Cobb60-values of the reference. After 24h, all the samples have reached approximately the same sizing degree.
From the results of Table 3 it can also be concluded that it is possible to decrease the AKD
dosage when a nitrogen-containing organic compound according to the present invention is added to the suspension.
Tensile index (SCAN-P 67:93) was tested on the paper sheets treated with the nitrogen-containing organic compounds and compared with the reference in order to investigate if the nitrogen-containing organic compounds have had a negative effect on the paper strength.
The results are shown in Table 4.
Table 4 Nitrogen-containing AKD Nitrogen-containing Tensile index (Nm/g) organic compound (kg/tonne) organic compound (kg/tonne) Reference 1.0 - 29.7 A 1.0 0.25 29.1 B 1.0 0.25 30.6 C 1.0 0.25 29.9 D 1.0 0.25 29.9 Reference 1.5 - 30.9 A 1.5 0.25 27.3 B 1.5 0.25 28.5 C 1.5 0.25 30.0 D 1.5 0.25 30.3 A 1.0 0.50 27.9 B 1.0 0.50 29.6 C 1.0 0.50 28.1 D 1.0 0.50 30.5 A 1.5 0.50 28.3 B 1.5 0.50 30.6 C 1.5 0.50 30.3 D 1.5 0.50 30.5 The results show that the nitrogen-containing organic compounds do not have any significant effect on the tensile strength and therefore do not deteriorate paper/board quality.
Example 3 In this Example, sizing performance was tested as Cobb6o-value on paper when nitrogen-containing organic compounds were added in different addition modes. Further, sizing performance was tested when using a nitrogen-containing organic compound according to the present invention and polyDADMAC polymer.
The cellulosic suspension contained 80% hardwood and 20% softwood and had a fiber concentration of 0.5 %. No filler was added. The conductivity was 0.3 mS/cm and pH was about 8. Hand sheets were prepared according to the standard method SCAN-C26:76 and sizing property was measured as Cobb60 value according to the standard method Tappi T441.
A first retention system was used comprising 0.75 kg/tonne cationic polyacrylamide (Eka PL
1510) and 1 kg/tonne of silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension. The results are presented in Table 5. A second retention system was used comprising 5 kg/tonne of cationic potato starch (Perlbond 980) and 1 kg/tonne of silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension.
The results are presented in Table 6.
The dosage of the cationic polyacrylamide (EKA PL 1510) was reduced to 0.5 kg/tonne in the cases where polyDADMAC (F) was added to the paper fiber suspension.
The sizing agent AKD (Eka DR 28 HF) was added in an amount of 0.45 kg/tonne and the nitrogen-containing organic compound, Arquad HTB-75 (C), according to the invention was either added:
a) 2 minutes before AKD, b) premixed with AKD, c) simultaneously with AKD
d) after AKD.
The sizing results obtained by the addition of 0 kg/tonne, 0.25 kg/tonne and 0.5 kg/tonne of the nitrogen-containing organic compound (C) are shown in Tables 5 and 6, respectively.
The results can be compared with the results obtained by the absence of the nitrogen-containing organic compound or by addition of the polymer (F) instead of the nitrogen-containing organic compound according to the invention.
Table 5 Cobb60 (g/m ) Addition mode Reference F C
(0.25 kg/tonne) (0.25 kg/tonne) no addition 63 a) addition before AKD 230 36 b) premixed with AKD 33 c) addition simultaneously 38 32 with AKD
d) addition after AKD 31 Table 6 Cobb60 (g/m ) Addition mode Reference F C
(0.5 kg/tonne) (0.5 kg/tonne) no addition 98 a) addition before AKD 251 30 b) premixed with AKD 31 c) addition simultaneously 33 31 with AKD
d) addition after AKD 31 Example 4 In this Example, liquid packaging board was prepared on an experimental paper machine as described in Example 1 and the sizing performance was tested as Cobb6o-value according to the standard method Tappi T441. The cellulosic suspension contained 80%
hardwood (40% eucalyptus and 40% birch) and 20% softwood and had a fiber concentration of 1.5%.
No filler was added. The pH was 7.1. A retention system was used comprising 0.375 kg/tonne cationic polyacrylamide (Eka PL 1510) and 0.15 kg/tonne silica sol (Eka NP 442), calculated as dry substances on dry cellulosic suspension. A nitrogen-containing organic compound, Arquad HTB-75 (C) or Armosoft DEQ (G), according to the invention was added before the sizing agent AKD (Eka DR 28 HF). In order to investigate the impact of dosing order on the sizing performance, Armosoft DEQ (G) was also added after the addition of the AKD. The sizing results are presented in Table Nos. 7 and 8, respectively. The results can be compared with the results obtained by the absence of the nitrogen-containing organic compound.
Table 7 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 24h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.5 127 127 102 28 28 - 0 0.75 105 98 46 26 26 - 0 1.0 97 72 48 25 25 C 0.25 0.5 127 93 53 31 29 C 0.25 0.75 76 46 30 24 26 C 0.25 1.0 46 35 28 23 23 C 0.5 0.5 83 56 42 38 45 C 0.5 0.75 49 29 28 24 28 C 0.5 1.0 31 27 24 22 24 G 0.25 0.5 103 76 38 27 25 G 0.25 0.75 45 36 36 25 26 G 0.25 1.0 41 35 27 25 23 G 0.5 0.5 63 35 29 28 28 G 0.5 0.75 38 29 25 24 25 G 0.5 1.0 32 25 27 22 24 It can be seen that the nitrogen-containing organic compounds according to the invention have a positive effect on the initial sizing of AKD. It is possible to reach low Cobb60-values already directly off machine. The final sizing degree is not affected by the addition of the nitrogen-containing organic compound.
Table 8 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 72h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.5 122 116 96 27 24 - 0 0.75 96 77 41 24 21 - 0 1.0 78 55 35 23 21 G 0.5 0.5 109 80 38 27 23 G 0.5 0.75 60 36 30 23 21 G 0.5 1.0 37 31 30 23 21 In this example it can be seen that it is possible to add the nitrogen-containing organic 5 compound before or after the addition of AKD.
Example 5 In this Example, liquid packaging board was prepared on an experimental paper machine as 10 described in Example 1 and the sizing performance was tested as Cobb6o-value according to the standard method Tappi T441. The cellulosic suspension comprised 100%
bleached CTMP, which had a fiber concentration of 1.35 %. No filler was added. The pH
was 5.6 and the conductivity was 219 pS/cm. A nitrogen-containing organic compound, Arquad (C) or Armosoft DEQ (G), was used in the tests. The addition of the nitrogen containing 15 compound to the cellulosic suspension took place after the machine chest. A
reference without addition of a nitrogen-containing organic compound was also performed.
The AKD
(Eka DH 28HF) sizing agent was added before the second pumping arrangement (P2).
Cationic starch (Raisamyl 142) was added before P2 (5 kg/tonne) and a silica sol (Eka NP
442) was added after the P2 (0.15 kg/tonne), calculated as dry substances on dry cellulosic suspension. The nitrogen-containing organic compound, Arquad HTB-75 (C) or Armosoft DEQ (G), according to the invention was added before the sizing agent AKD (Eka HF).
Table 9 Cobb60 (g/m ) Nitrogen- Nitrogen- AKD Off lh 3h 24h 10min.
containing containing kg/t machine 110 C
organic organic compound compound kg/t - 0 0.75 338 306 280 33 25 - 0 1.0 294 286 270 33 24 - 0 1.25 261 227 205 29 22 C 0.25 0.75 227 173 64 26 21 C 0.25 1.0 87 54 33 23 23 C 0.25 1.25 64 38 31 21 21 C 0.5 0.75 121 71 46 25 26 C 0.5 1.0 39 30 30 21 24 C 0.5 1.25 30 28 23 20 22 G 0.25 0.75 249 225 92 28 25 G 0.25 1.0 209 177 101 27 26 G 0.25 1.25 76 42 32 23 22 G 0.5 0.75 139 58 56 26 24 G 0.5 1.0 50 33 33 23 19 G 0.5 1.25 36 28 26 23 20 It can be seen that the nitrogen-containing organic compounds according to the invention have a positive effect on the initial sizing of AKD. It is possible to reach low Cobb60-values already after lh. The final sizing degree is not affected by the addition of the nitrogen-containing organic compound. The tensile index is not decreased by the addition of the nitrogen-containing organic compounds.
The nitrogen-containing organic compounds according to the invention function together with AKD in amounts of from about 0.05 to about 5 kg/tonne calculated on dry pulp, preferably from about 0.1 to about 3 kg/tonne calculated on dry pulp and most preferably from about 0.2 to about 1 kg/tonne calculated on dry pulp.
Claims (18)
1. Process for the production of paper which comprises:
(a) providing an aqueous cellulosic suspension;
(b) separately adding to the suspension:
(i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper.
(a) providing an aqueous cellulosic suspension;
(b) separately adding to the suspension:
(i) a nitrogen-containing organic compound having a molecular weight less than 1,000; and (ii) a cellulose-reactive sizing agent; and (c) dewatering the obtained suspension to form paper.
2. Process for the production of paper which comprises:
(a) providing a cellulosic suspension;
(b) mixing a nitrogen-containing organic compound having a molecular weight less than 1,000 with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix;
(c) adding the pre-mix to the suspension; and (d) dewatering the obtained suspension to form paper.
(a) providing a cellulosic suspension;
(b) mixing a nitrogen-containing organic compound having a molecular weight less than 1,000 with an aqueous dispersion of a cellulose-reactive sizing agent to form a pre-mix;
(c) adding the pre-mix to the suspension; and (d) dewatering the obtained suspension to form paper.
3. Process according to any one of claims 1 or 2, wherein the nitrogen-containing organic compound is a quaternary ammonium compound.
4. Process according to any one of claims 1 or 2, wherein the nitrogen-containing organic compound is an amine or an acid addition salt thereof.
5. Process according to any one of claims 2 to 4, wherein the mixing is carried out by bringing an aqueous stream of nitrogen-containing organic compound having molecular weight less than 1,000 into contact with an aqueous stream of a dispersion of a cellulose-reactive sizing agent and introducing the resulting stream into the cellulosic suspension.
6. Process according to any one of claims 2 to 5, wherein a contact time of the nitrogen-containing organic compound and the aqueous dispersion of the sizing agent in the pre-mixture is less than 20 minutes before the addition.
7. Process according to claim 1, wherein the nitrogen-containing organic compound is added to the cellulosic suspension prior to adding the cellulose-reactive sizing agent.
8. Process according to claim 1, wherein the nitrogen-containing organic compound is added to the cellulosic suspension separately but simultaneously with the cellulose-reactive sizing agent.
9. Process according to claim 1, wherein the nitrogen-containing organic compound is added to the cellulosic suspension after the cellulose-reactive sizing agent.
10. Process according to any one of the preceding claims, wherein the nitrogen-containing organic compound comprises any one of methyl bis[ethyl (tallowate)] - 2-hydroxyethyl ammonium methyl sulphate, di(hydrogenated tallow)dimethylammonium chloride, di(hydrogenated tallow fatty acids-2-hydroxyethyl ester) dimethyl ammonium chloride, didecyldimethylammonium chloride, (vegetableoil)benzyl-dimethylammoniumchloride or (dodecyl)benzyl-dimethylammonium chloride.
11. Process according to any one of claims 1 to 9, wherein the nitrogen-containing organic compound comprises quaternary imidazolinium.
12. Process according to any one of the preceding claims, wherein the nitrogen-containing organic compound is substantially free from silica-based particles.
13. Process according to any one of the preceding claims, wherein the cellulose-reactive sizing agent is a ketene dimer.
14. Process according to any one of claims 1 to 12, wherein the cellulose-reactive sizing agent is an acid anhydride.
15. Process according to any one of claims 1, 3, 4 and 7 to 14, wherein the sizing agent is added as an aqueous dispersion.
16. Process according to any one of the preceding claims, wherein the nitrogen-containing organic compound is added in an amount of greater than 20% by weight, based on the weight of the cellulose-reactive sizing agent.
17. Process according to any one of the preceding claims, wherein the nitrogen-containing organic compound is added in an amount of 0.005 to 0.5 % by weight, based on the dry weight of the aqueous cellulosic suspension.
18. Process according to any one of the preceding claims, wherein the sizing agent is added in an amount of 0.01 to 1.0 % by weight, based on the dry weight of the aqueous cellulosic suspension.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06114821 | 2006-06-01 | ||
EP06114821.9 | 2006-06-01 | ||
PCT/SE2007/050373 WO2007139500A1 (en) | 2006-06-01 | 2007-05-30 | Sizing of paper |
Publications (1)
Publication Number | Publication Date |
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CA2653791A1 true CA2653791A1 (en) | 2007-12-06 |
Family
ID=37038355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CA002653791A Abandoned CA2653791A1 (en) | 2006-06-01 | 2007-05-30 | Sizing of paper |
Country Status (9)
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EP (1) | EP2024564A1 (en) |
JP (1) | JP2009538998A (en) |
KR (1) | KR20090023579A (en) |
CN (1) | CN101460680A (en) |
AU (1) | AU2007268301A1 (en) |
BR (1) | BRPI0712698A2 (en) |
CA (1) | CA2653791A1 (en) |
RU (1) | RU2008152816A (en) |
WO (1) | WO2007139500A1 (en) |
Families Citing this family (5)
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CN102011344B (en) * | 2010-06-29 | 2013-04-17 | 上海东升新材料有限公司 | Surface sizing agent for electrostatic duplicating paper and preparation method and applications thereof |
FI126041B (en) * | 2011-09-12 | 2016-06-15 | Stora Enso Oyj | Method for controlling retention and intermediate used in the process |
CN105603818B (en) * | 2016-01-14 | 2018-06-12 | 青岛科技大学 | AKD neutral sizing agents and methods and applications prepared by a kind of cationic emulsifier |
CN106283868B (en) * | 2016-08-17 | 2017-10-03 | 中山市升信纸品有限公司 | A kind of preparation method of fast ripe water-resistant type AKD sizing agents |
CN106758536B (en) * | 2016-12-30 | 2018-09-18 | 安徽华邦古楼新材料有限公司 | A kind of production method of light coating digital thermal transfer printing paper |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US3046186A (en) * | 1957-06-12 | 1962-07-24 | American Cyanamid Co | Cationic sizing emulsions and paper sized therewith |
AR244372A1 (en) * | 1990-04-11 | 1993-10-20 | Hercules Inc | Pretreatment of filler with cationic ketene dimer |
SE9404201D0 (en) * | 1994-12-02 | 1994-12-02 | Eka Nobel Ab | Sizing dispersions |
US5969011A (en) * | 1997-02-05 | 1999-10-19 | Akzo Nobel Nv | Sizing of paper |
SE9704931D0 (en) * | 1997-02-05 | 1997-12-30 | Akzo Nobel Nv | Sizing of paper |
CN100558983C (en) * | 2002-03-04 | 2009-11-11 | 艾莫考国际公司 | Paper and material and production method thereof |
-
2007
- 2007-05-30 CA CA002653791A patent/CA2653791A1/en not_active Abandoned
- 2007-05-30 CN CNA2007800203288A patent/CN101460680A/en active Pending
- 2007-05-30 AU AU2007268301A patent/AU2007268301A1/en not_active Abandoned
- 2007-05-30 JP JP2009513101A patent/JP2009538998A/en not_active Withdrawn
- 2007-05-30 EP EP07748534A patent/EP2024564A1/en not_active Withdrawn
- 2007-05-30 KR KR1020087028685A patent/KR20090023579A/en not_active Application Discontinuation
- 2007-05-30 RU RU2008152816/12A patent/RU2008152816A/en not_active Application Discontinuation
- 2007-05-30 BR BRPI0712698-0A patent/BRPI0712698A2/en not_active IP Right Cessation
- 2007-05-30 WO PCT/SE2007/050373 patent/WO2007139500A1/en active Application Filing
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KR20090023579A (en) | 2009-03-05 |
AU2007268301A1 (en) | 2007-12-06 |
BRPI0712698A2 (en) | 2012-07-03 |
RU2008152816A (en) | 2010-07-20 |
EP2024564A1 (en) | 2009-02-18 |
WO2007139500A1 (en) | 2007-12-06 |
CN101460680A (en) | 2009-06-17 |
JP2009538998A (en) | 2009-11-12 |
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