CA2644871C - Method of measuring concentration of fuel - Google Patents
Method of measuring concentration of fuel Download PDFInfo
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- CA2644871C CA2644871C CA2644871A CA2644871A CA2644871C CA 2644871 C CA2644871 C CA 2644871C CA 2644871 A CA2644871 A CA 2644871A CA 2644871 A CA2644871 A CA 2644871A CA 2644871 C CA2644871 C CA 2644871C
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- concentration
- fuel
- reactive gas
- cathode
- supplying
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- 239000000446 fuel Substances 0.000 title claims abstract description 233
- 238000000034 method Methods 0.000 title claims abstract description 72
- 239000012528 membrane Substances 0.000 claims abstract description 20
- 239000007789 gas Substances 0.000 claims description 108
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 104
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 26
- 238000005259 measurement Methods 0.000 claims description 21
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 14
- 239000001569 carbon dioxide Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- -1 for example Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Fuel Cell (AREA)
Abstract
A method of measuring concentration of a fuel is provided. First, a fuel cell unit having at least an anode, a cathode, and a membrane electrode assembly (MEA) is provided. Next, a fuel is supplied to the anode, while a reactive gas is supplied to the cathode. Then, the amount of the reactive gas supplied to the cathode is adjusted and the concentration of the fuel is estimated in accordance with the consumption rate of the reactive gas in the fuel cell unit.
Description
METHOD OF MEASURING CONCENTRATION OF FUEL
BACKGROUND OF THE INVENTION
1. Field of the Invention [0001] The present invention generally relates to a method of measuring a concentration of the fuel, and more particularly a simple and high-accuracy method of measuring the concentration of the fuel.
BACKGROUND OF THE INVENTION
1. Field of the Invention [0001] The present invention generally relates to a method of measuring a concentration of the fuel, and more particularly a simple and high-accuracy method of measuring the concentration of the fuel.
2. Description of Related Art [0002] With the progress of industry, consumption of traditional energy sources, such as coal, petroleum, and natural gas, are continuously growing. Due to the limited reserves of natural energy, it is necessary to develop new alternative energy sources to replace the traditional energies, and among them, fuel cells are the important and practical one.
[0003] In brief, the fuel cells are basically a power generation device that converts chemical energy into electric energy through the inverse reaction of water electrolysis.
For example, a proton exchange membrane fuel cell (PEMFC) mainly includes a membrane electrode assembly (MEA) and two electrode plates. The MEA includes a proton exchange membrane, an anode catalyst layer, a cathode catalyst layer, an anode gas diffusion layer (GDL), and a cathode GDL. The anode catalyst layer and the cathode catalyst layer are respectively disposed at two sides of the proton exchange membrane. The anode GDL and the cathode GDL are respectively disposed on the anode catalyst layer and the cathode catalyst layer. Furthermore, the two electrode plates include an anode and a cathode respectively disposed on the anode GDL
and the cathode GDL.
For example, a proton exchange membrane fuel cell (PEMFC) mainly includes a membrane electrode assembly (MEA) and two electrode plates. The MEA includes a proton exchange membrane, an anode catalyst layer, a cathode catalyst layer, an anode gas diffusion layer (GDL), and a cathode GDL. The anode catalyst layer and the cathode catalyst layer are respectively disposed at two sides of the proton exchange membrane. The anode GDL and the cathode GDL are respectively disposed on the anode catalyst layer and the cathode catalyst layer. Furthermore, the two electrode plates include an anode and a cathode respectively disposed on the anode GDL
and the cathode GDL.
[0004] Currently, the common proton exchange membrane fuel cell is the direct methanol fuel cell (DMFC), which directly uses a methanol solution as a fuel supply source to generate current through the relevant electrode reaction of methanol and oxygen. The reaction formulae of the direct methanol fuel cells are expressed as follows:
Anode: CH3OH+H20 -* C02+6H++6e-Cathode: 3/202+6H++6e---* 3H20 [0005] During the reaction, the concentration of the methanol solution introduced to the anode has great impact on the stability of the output of the direct methanol fuel cell.
If the concentration of the methanol solution introduced to the anode is not properly controlled, disadvantages of poor power generation efficiency and unstable output power may be generated, and further, the MEA may be damaged. Therefore, it has become the important subject in the research and development of the direct methanol fuel cells how to properly supplement methanol so as to control the concentration of the methanol solution introduced into the anode in a suitable range.
Anode: CH3OH+H20 -* C02+6H++6e-Cathode: 3/202+6H++6e---* 3H20 [0005] During the reaction, the concentration of the methanol solution introduced to the anode has great impact on the stability of the output of the direct methanol fuel cell.
If the concentration of the methanol solution introduced to the anode is not properly controlled, disadvantages of poor power generation efficiency and unstable output power may be generated, and further, the MEA may be damaged. Therefore, it has become the important subject in the research and development of the direct methanol fuel cells how to properly supplement methanol so as to control the concentration of the methanol solution introduced into the anode in a suitable range.
[0006] The most direct way to control the concentration of the fuel in a fuel cell is to directly measure the concentration of the fuel by a sensor and determine the supplement amount of the fuel and water. This method has been disclosed in TWI
228591, US 6,589,671 B1, US 6,488,837, US 2002/076589 Al, US 2003/0196913 Al, WO 01/35478. US 6,488,837 and US 2003/0196913 Al have disclosed the MEA
serving as a sensor for directly measuring the concentration of methanol. It should be noted that the accuracy of the above method is liable to be affected by the impurities in the fuel, aging or instability of the MEA.
228591, US 6,589,671 B1, US 6,488,837, US 2002/076589 Al, US 2003/0196913 Al, WO 01/35478. US 6,488,837 and US 2003/0196913 Al have disclosed the MEA
serving as a sensor for directly measuring the concentration of methanol. It should be noted that the accuracy of the above method is liable to be affected by the impurities in the fuel, aging or instability of the MEA.
[0007] In the prior art, for example, in US 6,698,278 B2, the measured temperature and the current value are brought into an empirical formula to calculate the concentration of the fuel. This method can directly measure the concentration of the fuel without using a sensor. However, this method must be adjusted according to different fuel electrode systems so as to calculate the concentration of the fuel. US
6,589,679 and TW 1282639 have also disclosed the methods of directly measuring the concentration of the fuel without using a sensor.
6,589,679 and TW 1282639 have also disclosed the methods of directly measuring the concentration of the fuel without using a sensor.
[0008] Furthermore, since the concentration of the methanol solution is somewhat related to physical properties such as the transmission speed of the sound in the methanol solution, the dielectric constant of the methanol solution and the density of the methanol solution, the transmission speed of the sound in the methanol solution is used to calculate the concentration of the methanol solution in some prior arts. It is noted that TWI 251954 has disclosed that the dielectric constant and the density of the methanol solution can be used to calculate the concentration of the methanol solution.
However, the sensor used in this concentration calculating method is expensive and the precision of measurement is significantly affected by bubbles in the methanol solution, the methanol solution inside the sensor must be kept still and have no bubbles when measuring, which increase the difficulties in the measurement.
However, the sensor used in this concentration calculating method is expensive and the precision of measurement is significantly affected by bubbles in the methanol solution, the methanol solution inside the sensor must be kept still and have no bubbles when measuring, which increase the difficulties in the measurement.
[0009] In view of the above concentration measuring methods, the problems of difficult measurement, high measurement cost, unstable measurement accuracy exist.
Therefore, it is urgent to find a simple and high-accuracy method of measuring concentration of the fuel currently in this field.
SUMMARY OF THE INVENTION
Therefore, it is urgent to find a simple and high-accuracy method of measuring concentration of the fuel currently in this field.
SUMMARY OF THE INVENTION
[0010] Accordingly, an aspect of the present invention is directed to a simple, low-cost, and stable method capable of accurately measuring the concentration of a fuel.
[0011] An aspect of the present invention is directed to a method of measuring the concentration of the fuel, which includes the following steps. First, a fuel cell unit having at least an anode, a cathode, and a membrane electrode assembly (MEA) is provided. Next, a fuel is supplied to the anode, while a reactive gas is supplied to the cathode. Then, the amount of the reactive gas supplied to the cathode is adjusted and the concentration of the fuel is estimated in accordance with the consumption rate of the reactive gas in the fuel cell unit.
According to one aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one reactive gas concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one reactive gas concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain one reactive gas concentration vs. time curve; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain a new reactive gas concentration vs.
time curve thus considerably reducing a measurement time; and comparing the new reactive gas concentration vs. time curve with the at least one reactive gas concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to another aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one gaseous product concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one gaseous product concentration vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring concentration of a gaseous product in the cathode so as to obtain one gaseous product concentration vs. time curve; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode; (c)' stopping supplying the reactive gas to the cathode and measuring concentration of the gaseous product in the cathode so as to obtain a new gaseous product concentration vs. time curve thus considerably reducing a measurement time; and comparing the new gaseous product concentration vs. time curve with the at least one gaseous product concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to a further aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one open circuit voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one open circuit voltage vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain one open circuit voltage vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode; (c)' stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain a new open circuit voltage vs. time curve thus considerably reducing a measurement time; and comparing the new open circuit voltage vs. time curve with the at least one open circuit voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to still a further aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel 4a cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one output current vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output current vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain one output current vs. time curve thus considerably reducing a measurement time; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain a new output current vs. time curve; and comparing the new output current vs. time curve with the at least one output current vs.
time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to yet another aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one output voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output voltage vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain one output voltage vs. time curve thus considerably reducing a measurement time; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain a new output voltage vs. time curve; and comparing the new output voltage vs. time curve with the at least one output voltage vs.
time curve, so to estimate the concentration of the fuel having the unknown concentration.
4b BRIEF DESCRIPTION OF THE DRAWINGS
According to one aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one reactive gas concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one reactive gas concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain one reactive gas concentration vs. time curve; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain a new reactive gas concentration vs.
time curve thus considerably reducing a measurement time; and comparing the new reactive gas concentration vs. time curve with the at least one reactive gas concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to another aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one gaseous product concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one gaseous product concentration vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring concentration of a gaseous product in the cathode so as to obtain one gaseous product concentration vs. time curve; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode; (c)' stopping supplying the reactive gas to the cathode and measuring concentration of the gaseous product in the cathode so as to obtain a new gaseous product concentration vs. time curve thus considerably reducing a measurement time; and comparing the new gaseous product concentration vs. time curve with the at least one gaseous product concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to a further aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one open circuit voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one open circuit voltage vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain one open circuit voltage vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode; (c)' stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain a new open circuit voltage vs. time curve thus considerably reducing a measurement time; and comparing the new open circuit voltage vs. time curve with the at least one open circuit voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to still a further aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel 4a cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one output current vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output current vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain one output current vs. time curve thus considerably reducing a measurement time; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain a new output current vs. time curve; and comparing the new output current vs. time curve with the at least one output current vs.
time curve, so to estimate the concentration of the fuel having the unknown concentration.
According to yet another aspect of the present invention, there is provided a method of measuring concentration of a fuel, comprising: providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA); establishing at least one output voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output voltage vs. time curve comprises: (a) supplying the fuel having one known concentration to the anode; (b) supplying a reactive gas to the cathode; (c) stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain one output voltage vs. time curve thus considerably reducing a measurement time; (a)' supplying the fuel having an unknown concentration to the anode; (b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain a new output voltage vs. time curve; and comparing the new output voltage vs. time curve with the at least one output voltage vs.
time curve, so to estimate the concentration of the fuel having the unknown concentration.
4b BRIEF DESCRIPTION OF THE DRAWINGS
[0012] The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
[0013] FIGs. 1A and 1 B are schematic views of a method of measuring a concentration of a fuel according to the first embodiment of the present invention.
[0014] FIG. 2 shows a curve of a relationship between an open circuit voltage output by a fuel cell unit and a time when the supply of the reactive gas is stopped.
[0015] FIG. 3 shows a curve of a relationship between an open circuit voltage output by the fuel cell unit and a time when the supply of the reactive gas is stopped in the case of different fuel concentrations.
[0016] FIGs. 4A and 4B are schematic views of a method of measuring a concentration of a fuel according to the second embodiment of the present invention.
[0017] FIG. 5 shows a curve of a relationship between a current of a fuel cell unit 4c outputting electric energy under a constant voltage and a time when the supply of the reactive gas is stopped in the case of different fuel concentrations.
[0018] FIG. 6 shows a curve of a relationship between a voltage of a fuel cell unit outputting electric energy under a constant current and time ceasing the supply of the reactive gas at different fuel concentrations.
[0019] FIG. 7 is a schematic view of a method of measuring a concentration of a fuel according to the third embodiment of the present invention.
DESCRIPTION OF THE EMBODIMENTS
DESCRIPTION OF THE EMBODIMENTS
[0020] Reference will now be made in detail to the present embodiments of the invention, examples of which are illustrated in the accompanying drawings.
Wherever possible, the same reference numbers are used in the drawings and the description to refer to the same or like parts.
Wherever possible, the same reference numbers are used in the drawings and the description to refer to the same or like parts.
[0021] FIGs. IA and I B are schematic views of a method of measuring a concentration of a fuel according to the first embodiment of the present invention.
Referring to FIG. I A, first, a fuel cell unit 100 having an anode 110 and a cathode 120 is provided. In this embodiment, the fuel cell unit 100 may be a direct methanol fuel cell unit. In detail, the, fuel cell unit 100 at least has a membrane electrode assembly (MEA) 130 between the anode 110 and the cathode 120. The MEA 130 includes, for example, a proton exchange membrane 131, an anode catalyst layer 132, a cathode catalyst layer 133, an anode gas diffusion layer (GDL) 134 and a cathode GDL
135.
The anode catalyst layer 132 and the cathode catalyst layer 133 are respectively disposed at two sides of the proton exchange membrane 131, and the anode GDL
and the cathode GDL 135 are respectively disposed on the anode catalyst layer 132 and the cathode catalyst layer 133. Definitely, the fuel cell unit 100 in this embodiment may be a fuel cell unit of any form, such as a single cell or the fuel cell stack itself, and those of ordinary skill in the art can select a suitable fuel cell unit according to the actual requirements. It is noted that the above-mentioned fuel cell unit 100 may be a fuel cell stack installed in a fuel cell system.
Referring to FIG. I A, first, a fuel cell unit 100 having an anode 110 and a cathode 120 is provided. In this embodiment, the fuel cell unit 100 may be a direct methanol fuel cell unit. In detail, the, fuel cell unit 100 at least has a membrane electrode assembly (MEA) 130 between the anode 110 and the cathode 120. The MEA 130 includes, for example, a proton exchange membrane 131, an anode catalyst layer 132, a cathode catalyst layer 133, an anode gas diffusion layer (GDL) 134 and a cathode GDL
135.
The anode catalyst layer 132 and the cathode catalyst layer 133 are respectively disposed at two sides of the proton exchange membrane 131, and the anode GDL
and the cathode GDL 135 are respectively disposed on the anode catalyst layer 132 and the cathode catalyst layer 133. Definitely, the fuel cell unit 100 in this embodiment may be a fuel cell unit of any form, such as a single cell or the fuel cell stack itself, and those of ordinary skill in the art can select a suitable fuel cell unit according to the actual requirements. It is noted that the above-mentioned fuel cell unit 100 may be a fuel cell stack installed in a fuel cell system.
[0022] Then, a fuel 140 is supplied to the anode 110 of the fuel cell unit 100, and a reactive gas 150 is supplied to the cathode 120 of the fuel cell unit 100. In this embodiment, the fuel 140 supplied to the anode 110 is, for example, a methanol solution of an uncertain concentration. Definitely, the fuel 140 supplied to the anode 110 may also be another fuels, for example, ethanol solution and formic acid solution, and those of ordinary skill in the art may select a suitable fuel according to the actual requirements.
In addition, the reactive gas 150 supplied to the cathode 120 is, for example, air, oxygen, or other suitable gases. When the fuel 140 and the reactive gas 150 are continuously supplied to the fuel cell unit 100, a part of the fuel at the anode 110 reaches the cathode catalyst layer 133 of the MEA 130 by a crossover phenomena (e.g. the crossover fuel 160 shown in FIG. 1A), and is consumed by the combustion reaction with oxygen, and the reaction formula is expressed as follows:
3/2 02 + CH3OH 4 CO2 + 2H2O
In addition, the reactive gas 150 supplied to the cathode 120 is, for example, air, oxygen, or other suitable gases. When the fuel 140 and the reactive gas 150 are continuously supplied to the fuel cell unit 100, a part of the fuel at the anode 110 reaches the cathode catalyst layer 133 of the MEA 130 by a crossover phenomena (e.g. the crossover fuel 160 shown in FIG. 1A), and is consumed by the combustion reaction with oxygen, and the reaction formula is expressed as follows:
3/2 02 + CH3OH 4 CO2 + 2H2O
[0023] The combustion reaction consumes the oxygen at the cathode 120, and the fuel cell unit 100 maintains a suitable open circuit voltage OCV.
[0024] Referring to FIG. 1B, the supply of the reactive gas 150 to the cathode may be reduced or stopped by controlling a gas transmission component or switching a valve in this embodiment. Since the amount of the crossover fuel 160 reaching the cathode 120 is in direct proportion to the concentration of the fuel 140 at the anode 110, the amount of the crossover fuel 140 reaching the cathode 120 directly influences the consumption rate of the reactive gas 150 at the cathode 120. In detail, when the amount of the reactive gas 150 supplied to the cathode 120 is limited, since the reactive gas 150 in the cathode 120 may react with the crossover fuel 160 and be gradually consumed by the combustion reaction, the consumption rate of the reactive gas 150 may be estimated in accordance with the open circuit voltage of the fuel cell unit 100. In this embodiment, when the reactive gas 150 supplied to the cathode 120 is stopped, the reactive gas 150 in the cathode 120 can only allow maintaining the open circuit voltage OCV of the fuel cell unit 100 for a while, and the duration of the time period is closely related to the concentration of the fuel 140. In detail, the higher the concentration of the fuel 140 is, the higher the capability of crossover of the fuel 140 from the anode 110 to the cathode 120 will be, and meanwhile, the consumption rate of the reactive gas 150 is greater. Otherwise, the lower the concentration of the fuel 140 is, the lower the capability of crossover of the fuel 140 from the anode 110 to the cathode 120 will be, and meanwhile, the consumption rate of the reactive gas 150 is lower.
[0025] Accordingly, since the concentration of the fuel 140 is related to the consumption rate of the reactive gas 150, the present invention may rapidly calculate the concentration of the fuel 140 in accordance with the consumption rate of the reactive gas 150.
[0026] FIG. 2 shows a curve of a relationship between an open circuit voltage OCV
output by a fuel cell unit 100 and a time when the supply of the reactive gas 150 is stopped, and FIG. 3 shows a curve of a relationship between an open circuit voltage OCV output by the fuel cell unit 100 and a time when the supply of the reactive gas 150 is stopped in the case of different fuel concentrations. This embodiment may estimate the consumption of the reactive gas 150 in accordance with the measured open circuit voltage OCV. In detail, when the reactive gas 150 is exhausted, the open circuit voltage OCV will drop, and the time point at which the open circuit voltage OCV drops .5 may be used to calculate the concentration of the fuel 140.
output by a fuel cell unit 100 and a time when the supply of the reactive gas 150 is stopped, and FIG. 3 shows a curve of a relationship between an open circuit voltage OCV output by the fuel cell unit 100 and a time when the supply of the reactive gas 150 is stopped in the case of different fuel concentrations. This embodiment may estimate the consumption of the reactive gas 150 in accordance with the measured open circuit voltage OCV. In detail, when the reactive gas 150 is exhausted, the open circuit voltage OCV will drop, and the time point at which the open circuit voltage OCV drops .5 may be used to calculate the concentration of the fuel 140.
[0027] It would be apparent from FIG. 3 that, when the concentrations of the used methanol solution are 1%, 3%, 5%, 7%, or 9%, the time points at which the open circuit voltage OCV drops are apparently different. In other words, this embodiment may calculate the concentration of the fuel in accordance. with the time points at which the open circuit voltage OCV drops. This method has good measurement sensitivity.
[0028] In the above embodiment, the time points at which the open circuit voltage drops are used to calculate the concentrations of the fuel. However, the present invention is not limited thereto, and may also calculate the concentration of the fuel in accordance with the speed at which the open circuit voltage drops. In addition, this embodiment may further calculate the concentration of the fuel in accordance with the time period for the open circuit voltage OCV to drop to a certain value. As shown in FIG. 3, the higher the concentration of the methanol solution is, the shorter the time period for the open circuit voltage OCV to drop to a certain value will be.
Otherwise, the lower the concentration of the methanol solution is, the longer the time period for the open circuit voltage OCV to drop to a certain value will be. It should be noted that this embodiment may enlarge the time period for the open circuit voltage OCV
to drop to the certain value corresponding to different concentrations of the fuel by controlling the amount of the introduced reactive gas, thus achieving an easier estimation of the concentration of the fuel.
Otherwise, the lower the concentration of the methanol solution is, the longer the time period for the open circuit voltage OCV to drop to a certain value will be. It should be noted that this embodiment may enlarge the time period for the open circuit voltage OCV
to drop to the certain value corresponding to different concentrations of the fuel by controlling the amount of the introduced reactive gas, thus achieving an easier estimation of the concentration of the fuel.
[0029] It should be noted that the fuel cell unit 100 of the embodiment may be directly used as a fuel concentration sensor and may also be connected in a fuel circulation loop of a fuel cell system. The fuel concentration sensor when installed does not need to be connected in branch, and the fuel concentration sensor when operated will not affect the operation of the fuel cell system. In detail, since the present invention utilizes the fuel cell unit 100 to measure the concentration of the fuel, the present invention may use one or more units in the fuel cell stack as the fuel concentration sensor to measure the concentration of the fuel directly. At this time, the fuel cell stack does not need an additional fuel concentration sensor.
[0030] FIGs. 4A and 4B are schematic views of a method of measuring a concentration of a fuel according to the second embodiment of the present invention.
Referring to FIG. 4A, a fuel cell unit 400 of this embodiment is similar to the fuel cell unit 100 of the first embodiment except that the fuel cell unit 400 in FIG. 4A
outputs the electric energy to an external load 170 directly.
Referring to FIG. 4A, a fuel cell unit 400 of this embodiment is similar to the fuel cell unit 100 of the first embodiment except that the fuel cell unit 400 in FIG. 4A
outputs the electric energy to an external load 170 directly.
[0031] Referring to FIG. 4B, the fuel cell unit 400 may reduce or stop the supply of the reactive gas 150 to the cathode 120 by controlling a gas transmission component or switching a valve (not shown). When the amount of the reactive gas 150 supplied to the cathode 120 is limited, the reactive gas 150 in the cathode 120 is consumed by the reduction reaction of the fuel cell unit 400 and the combustion reaction with the crossover fuel 160. Since the amount of the crossover fuel 160 is in direct proportion to the concentration of the fuel 140 at the anode 110, the concentration of the fuel 140 may be calculated in accordance with the consumption rate of the reactive gas 150.
[0032] FIG. 5 shows a curve of a relationship between a current of a fuel cell unit outputting electric energy at a constant voltage and a time when the supply of the reactive gas is stopped in the case of different fuel concentrations. FIG. 6 shows a curve of a relationship between a voltage of a fuel cell unit outputting electric energy at a constant current and a time when the supply of the reactive gas is stopped in the case of different fuel concentrations. It would be apparent from FIGs. 5 and 6 that the measurement observer may rapidly calculate the concentration of the fuel 140 in accordance with the voltage variation rate or the current variation rate.
[0033] Referring to FIG. 5 again, based on the current-time curve in FIG. 5, the measurement observer may calculate the concentration of the fuel in accordance with the time period for the current to drop to a certain value. In detail, the higher the concentration of the fuel is, the shorter the time period for the current to drop to a certain value will be. Otherwise, the lower the concentration of the fuel is, the longer the time period for the current to drop to a certain value will be. In other embodiments, the measurement observer may also calculate the concentration of the fuel in accordance with the drop amount of the current in a specific time. In detail, the higher the concentration of the fuel is, the greater the drop amount of the current in a specific time will be. Otherwise, the lower the concentration of the fuel is, the less the drop amount of the current in a specific time will be.
[0034] Referring to FIG. 6, based on each voltage-time curve in FIG. 6, the measurement observer may calculate the concentration of the fuel in accordance with the time period for the voltage to drop to a certain value. In detail, the higher the concentration of the fuel is, the shorter the time period for the voltage to drop to a certain value will be. Otherwise, the lower the concentration of the fuel is, the longer the time period for the voltage to drop to a certain value will be. In other embodiments, the measurement observer may also calculate the concentration of the fuel in accordance with the drop amount of the voltage in a specific time. In detail, the higher the concentration of the fuel is, the greater the drop amount of the voltage in a specific time will be. Otherwise, the lower the concentration of the fuel is, the less the drop amount of the voltage in a specific time will be.
[0035] Accordingly, in the measurement methods in FIGs. 5 and 6, the concentration of the fuel may be easily estimated by controlling the introduced reactive gas.
[0036] FIG. 7 is a schematic view of a method of measuring a concentration of a fuel according to the third embodiment of the present invention. Referring to FIG. 7, the fuel cell unit 500 of the present embodiment is similar with the fuel cell unit 100 of except that the fuel cell unit 500 shown in FIG. 7 further includes a sensor 180.
Specifically, the concentration of the reactive gas 150 in the cathode 120 is measured through the sensor 180 first, for example. Then, the concentration of the fuel 140 is estimated in accordance with a relationship between the concentration of the reactive gas 150 and time. In the present embodiment, the sensor 180 is a sensor for measuring oxygen (02 sensor) or a pressure gauge, for example.
[0036] Since the concentration variation of the reactive gas 150 is measured through the sensor 180 directly, it is more convenience to estimate the concentration of the fuel 140 precisely.
Specifically, the concentration of the reactive gas 150 in the cathode 120 is measured through the sensor 180 first, for example. Then, the concentration of the fuel 140 is estimated in accordance with a relationship between the concentration of the reactive gas 150 and time. In the present embodiment, the sensor 180 is a sensor for measuring oxygen (02 sensor) or a pressure gauge, for example.
[0036] Since the concentration variation of the reactive gas 150 is measured through the sensor 180 directly, it is more convenience to estimate the concentration of the fuel 140 precisely.
[0037] Similarly, the concentration of the fuel 140 can be estimated in accordance with the time period for the concentration of the reactive gas 150 to drop to a certain value, or in accordance with the speed at which the concentration of the reactive gas 150 drops.
[0038] In the third embodiment, the sensor 180 is a sensor for measuring carbon dioxide (CO2 sensor). Since the consumption rate of the reactive gas at the cathode is proportional to the generation rate of the gaseous product such as carbon dioxide (CO2), the CO2 sensor may also be used in the present embodiment to measure the concentration of the carbon dioxide such that the concentration of the fuel 140 can also be estimated. Specifically, the CO2 sensor is used to measure the speed at which the concentration of the carbon dioxide increases or the time period for the concentration of the carbon dioxide to increase to a certain value.
[0039] In view of the above, as the present invention may estimate the concentration of the fuel in accordance with the consumption rate of the reactive gas at the cathode, the method of measuring a concentration of a fuel of the present invention is simple and accurate. Furthermore, the method of measuring a concentration of a fuel of the present invention has a high stability and will not be easily affected by the flow of the fuel and the bubbles in the fuel. Especially, one can just use operational fuel cell stack in the system to measure the fuel concentration.
[0040] It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the present invention cover modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents.
Claims (33)
1 A method of measuring concentration of a fuel, comprising:
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one reactive gas concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one reactive gas concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain one reactive gas concentration vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain a new reactive gas concentration vs. time curve thus considerably reducing a measurement time;
and comparing the new reactive gas concentration vs. time curve with the at least one reactive gas concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one reactive gas concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one reactive gas concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain one reactive gas concentration vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the reactive gas in the cathode so as to obtain a new reactive gas concentration vs. time curve thus considerably reducing a measurement time;
and comparing the new reactive gas concentration vs. time curve with the at least one reactive gas concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
2. The method as claimed in claim 1, wherein the fuel cell unit comprises a direct methanol fuel cell unit.
3. The method as claimed in claim 1, wherein the reactive gas comprises air or oxygen.
4. The method as claimed in claim 1, wherein the fuel comprises a methanol solution, an ethanol solution, or a formic acid solution.
5. The method as claimed in claim 1, wherein the concentration of the reactive gas is measured through a sensor.
6. The method as claimed in claim 5, wherein the sensor comprises a sensor for measuring oxygen or a pressure gauge.
7. The method as claimed in claim 1, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time period for the concentration of the reactive gas to drop to a certain value.
8. The method as claimed in claim 1, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with the speed at which the concentration of the reactive gas drops.
9. A method of measuring concentration of a fuel, comprising:
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one gaseous product concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one gaseous product concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring concentration of a gaseous product in the cathode so as to obtain one gaseous product concentration vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the gaseous product in the cathode so as to obtain a new gaseous product concentration vs. time curve thus considerably reducing a measurement time; and comparing the new gaseous product concentration vs. time curve with the at least one gaseous product concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one gaseous product concentration vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one gaseous product concentration vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring concentration of a gaseous product in the cathode so as to obtain one gaseous product concentration vs. time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring concentration of the gaseous product in the cathode so as to obtain a new gaseous product concentration vs. time curve thus considerably reducing a measurement time; and comparing the new gaseous product concentration vs. time curve with the at least one gaseous product concentration vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
10. The method as claimed in claim 9, wherein the concentration of the gaseous product is measured through a sensor.
11. The method as claimed in claim 10, wherein the sensor comprises a sensor for measuring carbon dioxide.
12. The method as claimed in claim 9, wherein the concentration of the fuel of the unknown concentration is estimated in accordance with the speed at which the concentration of the carbon dioxide increases or the time period for the concentration of the carbon dioxide to increase to a certain value.
13. A method of measuring concentration of a fuel, comprising:
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one open circuit voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one open circuit voltage vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain one open circuit voltage vs.
time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain a new open circuit voltage vs.
time curve thus considerably reducing a measurement time; and comparing the new open circuit voltage vs. time curve with the at least one open circuit voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one open circuit voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one open circuit voltage vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain one open circuit voltage vs.
time curve;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring open circuit voltage of the MEA so as to obtain a new open circuit voltage vs.
time curve thus considerably reducing a measurement time; and comparing the new open circuit voltage vs. time curve with the at least one open circuit voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
14. The method as claimed in claim 13, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time point at which the open circuit voltage drops.
15. The method as claimed in claim 13, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time period for the open circuit voltage to drop to a certain value.
16. The method as claimed in claim 13, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a speed at which the open circuit voltage drops.
17. The method as claimed in claim 13, wherein the fuel cell unit comprises a direct methanol fuel cell unit.
18. The method as claimed in claim 13, wherein the reactive gas comprises air or oxygen.
19. The method as claimed in claim 13, wherein the fuel comprises a methanol solution, an ethanol solution, or a formic acid solution.
20. A method of measuring concentration of a fuel, comprising:
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one output current vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output current vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain one output current vs. time curve thus considerably reducing a measurement time;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain a new output current vs. time curve;
and comparing the new output current vs. time curve with the at least one output current vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one output current vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output current vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain one output current vs. time curve thus considerably reducing a measurement time;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output current of the MEA so as to obtain a new output current vs. time curve;
and comparing the new output current vs. time curve with the at least one output current vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
21. The method as claimed in claim 20, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time point at which the output current drops.
22. The method as claimed in claim 20, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time period for the output current to drop to a certain value.
23. The method as claimed in claim 20, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a speed at which the output current drops.
24. The method as claimed in claim 20, wherein the fuel cell unit comprises a direct methanol fuel cell unit.
25. The method as claimed in claim 20, wherein the reactive gas comprises air or oxygen.
26. The method as claimed in claim 20, wherein the fuel comprises a methanol solution, an ethanol solution, or a formic acid solution.
27. A method of measuring concentration of a fuel, comprising:
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one output voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output voltage vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain one output voltage vs. time curve thus considerably reducing a measurement time;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain a new output voltage vs. time curve;
and comparing the new output voltage vs. time curve with the at least one output voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
providing a fuel cell unit comprising at least an anode, a cathode, and a membrane electrode assembly (MEA);
establishing at least one output voltage vs. time curve corresponding to at least one known concentration of a fuel, wherein the method of establishing the at least one output voltage vs. time curve comprises:
(a) supplying the fuel having one known concentration to the anode;
(b) supplying a reactive gas to the cathode;
(c) stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain one output voltage vs. time curve thus considerably reducing a measurement time;
(a)' supplying the fuel having an unknown concentration to the anode;
(b)' supplying the reactive gas to the cathode;
(c)' stopping supplying the reactive gas to the cathode and measuring output voltage of the MEA so as to obtain a new output voltage vs. time curve;
and comparing the new output voltage vs. time curve with the at least one output voltage vs. time curve, so to estimate the concentration of the fuel having the unknown concentration.
28. The method as claimed in claim 27, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time point at which the output voltage drops.
29. The method as claimed in claim 27, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a time period for the output voltage to drop to a certain value.
30. The method as claimed in claim 27, wherein the concentration of the fuel having the unknown concentration is estimated in accordance with a speed at which the output voltage drops.
31. The method as claimed in claim 27, wherein the fuel cell unit comprises a direct methanol fuel cell unit.
32. The method as claimed in claim 27, wherein the reactive gas comprises air or oxygen.
33. The method as claimed in claim 27, wherein the fuel comprises a methanol solution, an ethanol solution, or a formic acid solution.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW96144978 | 2007-11-27 | ||
| TW96144978 | 2007-11-27 | ||
| TW97143528 | 2008-11-11 | ||
| TW97143528A TWI473337B (en) | 2007-11-27 | 2008-11-11 | Method of measuring concentration of fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2644871A1 CA2644871A1 (en) | 2009-05-27 |
| CA2644871C true CA2644871C (en) | 2012-03-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2644871A Active CA2644871C (en) | 2007-11-27 | 2008-11-26 | Method of measuring concentration of fuel |
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|---|---|
| JP (1) | JP5366295B2 (en) |
| CA (1) | CA2644871C (en) |
Families Citing this family (1)
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|---|---|---|---|---|
| KR101105364B1 (en) | 2010-05-19 | 2012-01-16 | 한국과학기술연구원 | Sensor and method for sensing fuel concentration, method and system apparatus for fuel recirculation of fuel cell using the same, fuel cell usage apparatus using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4680530B2 (en) * | 2003-06-09 | 2011-05-11 | パナソニック株式会社 | Fuel cell system |
| JP4172792B2 (en) * | 2004-03-30 | 2008-10-29 | 株式会社東芝 | Method for detecting fuel concentration in direct methanol fuel cell and direct methanol fuel cell system |
-
2008
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- 2008-11-26 CA CA2644871A patent/CA2644871C/en active Active
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| JP2009146894A (en) | 2009-07-02 |
| CA2644871A1 (en) | 2009-05-27 |
| JP5366295B2 (en) | 2013-12-11 |
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