CA2614404A1 - Configurations and methods of integrated ngl recovery and lng liquefaction - Google Patents

Configurations and methods of integrated ngl recovery and lng liquefaction Download PDF

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Publication number
CA2614404A1
CA2614404A1 CA002614404A CA2614404A CA2614404A1 CA 2614404 A1 CA2614404 A1 CA 2614404A1 CA 002614404 A CA002614404 A CA 002614404A CA 2614404 A CA2614404 A CA 2614404A CA 2614404 A1 CA2614404 A1 CA 2614404A1
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Prior art keywords
absorber
demethanizer
separator
overhead product
cold
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CA002614404A
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French (fr)
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CA2614404C (en
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John Mak
Curt Graham
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Fluor Technologies Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209Natural gas or substitute natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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    • F25J1/0207Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as at least a three level SCR refrigeration cascade
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    • F25J1/0217Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle
    • F25J1/0218Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle with one or more SCR cycles, e.g. with a C3 pre-cooling cycle
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    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/0231Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the working-up of the hydrocarbon feed, e.g. reinjection of heavier hydrocarbons into the liquefied gas
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    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0235Heat exchange integration
    • F25J1/0237Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
    • F25J1/0239Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
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    • F25J1/0279Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0291Refrigerant compression by combined gas compression and liquid pumping
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    • F25J3/0238Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02Recycle of a stream in general, e.g. a by-pass stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/02Internal refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/12External refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/60Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/66Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

Contemplated plants include a NGL recovery portion and a LNG liquefaction portion, wherein the NGL recovery portion provides a low-temperature and high-pressure overhead product directly to the LNG liquefaction portion. Feed gas cooling and condensation are most preferably performed using refrigeration cycles that employ refrigerants other than the demethanizer/absorber overhead product. Thus, cold demethanizer/absorber overhead product is compressed with the turbo-expansion and delivered to a liquefaction portion at significantly lower temperature and higher pressure without net compression energy expenditure.

Claims (20)

1. A gas processing plant, comprising;

a separator that is configured to receive a partially expanded vapor portion of a natural gas feed stream, and that is further configured to produce a cold overhead product stream;

an expander operationally coupled to drive a compressor; wherein the expander is configured to produce the partially expanded vapor portion and wherein the compressor is configured to produce a compressed cryogenic overhead product stream from the cold overhead product stream;

wherein the separator and the compressor are fluidly coupled to each other such that the compressed cryogenic overhead product stream has a pressure of at least psig at a temperature of no warmer than -50 °F; and a natural gas liquefaction unit that is fluidly coupled to the compressor to receive the cryogenic overhead product stream at about the pressure and at about the temperature.
2. The plant of claim 1 wherein the separator is configured to receive another expanded vapor portion of the natural gas feed stream at a separate location.
3. The plant of claim 1 wherein the separator is configured to operate as a demethanizer.
4. The plant of claim 3 further comprising a deethanizer that is configured to produce a C3+ product and a C2 product.
5. The plant of claim 4 further comprising a conduit that provides at least part of the C2 product to the cold overhead product stream.
6. The plant of claim 1 wherein the separator is configured to operate as a refluxed absorber.
7. The plant of claim 6 wherein the demethanizer is configured to provide a reflux stream to the absorber.
8. The plant of claim 6 wherein the demethanizer is configured to operate at a lower pressure than the absorber.
9. The plant of claim 6 further comprising at least one of a conduit that provides a cooled absorber bottom product the absorber for C2 recovery and a conduit that provides a heated absorber bottom product the absorber for C2 rejection.
10. A method of producing a liquefied natural gas, comprising:

producing a cold overhead product stream in a separator and compressing the product stream in a compressor without prior substantial heating of the cold overhead product stream;

wherein the compressor is driven by an expander that expands a vapor portion of a natural gas feed, and wherein the expanded vapor portion is fed into the separator;
and liquefying the cold compressed product stream in a liquefaction unit.
11. The method of claim 10 wherein the separator is operated as a demethanizer that further receives another portion of a natural gas feed.
12. The method of claim 10 further comprising a deethanizer that receives a bottom product of the separator and that optionally provides a C2 product to the cold overhead product stream.
13. The method of claim 10 wherein the separator is operated as a refluxed absorber.
14. The method of claim 11 wherein a demethanizer provides a reflux stream to the absorber, wherein the absorber provides a bottom product to the demethanizer, and wherein the demethanizer is operated at a lower pressure than the absorber.
15. The method of claim 14 wherein the absorber bottom product is heated for rejection prior to entering the demethanizer or cooled for C2 recovery prior to entering the demethanizer.
16. The method of claim 14 wherein a deethanizer receives a bottom product of the demethanizer for C2 and C3+ recovery.
17. The method of claim 10 wherein the cold compressed product stream has a pressure of at least 700 psig and a temperature of no warmer than -50 °F.
18. A method of producing LNG comprising:

separating in a separator a cold overhead product from a natural gas containing feed gas;

compressing the cold overhead product using expansion energy from the feed gas to form a cryogenic vapor at a pressure of between 700 and 900 psig and temperature of between -50 and -80 °F suitable for liquefaction in a liquefaction unit;

wherein the cold compressed overhead product is formed at neutral or negative net compression energy requirement.
19. The method of claim 17 wherein the step of separating is performed in an absorber or a demethanizer.
20. The method of claim 17 wherein the cold compressed overhead product has a pressure of at least 700 psig and a temperature of no warmer than -50 °F.
CA2614404A 2005-07-07 2006-07-05 Configurations and methods of integrated ngl recovery and lng liquefaction Expired - Fee Related CA2614404C (en)

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EA011599B1 (en) 2009-04-28
US20070157663A1 (en) 2007-07-12
WO2007008525B1 (en) 2007-12-13
EP1904801A2 (en) 2008-04-02
AU2006269436B2 (en) 2009-11-12
EA200800267A1 (en) 2008-06-30
CA2614404C (en) 2011-05-24
US20130061633A1 (en) 2013-03-14
WO2007008525A2 (en) 2007-01-18
AU2006269436A1 (en) 2007-01-18
WO2007008525A3 (en) 2007-11-08
MX2007015604A (en) 2008-02-19

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