CA2614014A1 - Process for the manufacture of diesel range hydrocarbons - Google Patents
Process for the manufacture of diesel range hydrocarbons Download PDFInfo
- Publication number
- CA2614014A1 CA2614014A1 CA002614014A CA2614014A CA2614014A1 CA 2614014 A1 CA2614014 A1 CA 2614014A1 CA 002614014 A CA002614014 A CA 002614014A CA 2614014 A CA2614014 A CA 2614014A CA 2614014 A1 CA2614014 A1 CA 2614014A1
- Authority
- CA
- Canada
- Prior art keywords
- process according
- oil
- feed
- catalyst
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract 23
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract 6
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract 6
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 238000006317 isomerization reaction Methods 0.000 claims abstract 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000005864 Sulphur Substances 0.000 claims abstract 7
- 239000000194 fatty acid Substances 0.000 claims abstract 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 5
- 229930195729 fatty acid Natural products 0.000 claims abstract 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract 4
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000003054 catalyst Substances 0.000 claims 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 239000003925 fat Substances 0.000 claims 6
- 235000019197 fats Nutrition 0.000 claims 6
- 239000003085 diluting agent Substances 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- -1 fatty acid esters Chemical class 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000003921 oil Substances 0.000 claims 3
- 235000019198 oils Nutrition 0.000 claims 3
- 239000000377 silicon dioxide Substances 0.000 claims 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910052906 cristobalite Inorganic materials 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 229910052763 palladium Inorganic materials 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 229910052682 stishovite Inorganic materials 0.000 claims 2
- 229910052905 tridymite Inorganic materials 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 241000251468 Actinopterygii Species 0.000 claims 1
- 240000002791 Brassica napus Species 0.000 claims 1
- 235000006008 Brassica napus var napus Nutrition 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 241001465754 Metazoa Species 0.000 claims 1
- 229910003294 NiMo Inorganic materials 0.000 claims 1
- 235000019482 Palm oil Nutrition 0.000 claims 1
- 235000019483 Peanut oil Nutrition 0.000 claims 1
- 235000019484 Rapeseed oil Nutrition 0.000 claims 1
- 235000019486 Sunflower oil Nutrition 0.000 claims 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims 1
- 239000000828 canola oil Substances 0.000 claims 1
- 235000019519 canola oil Nutrition 0.000 claims 1
- 239000004359 castor oil Substances 0.000 claims 1
- 235000019438 castor oil Nutrition 0.000 claims 1
- 229960001777 castor oil Drugs 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 229910001657 ferrierite group Inorganic materials 0.000 claims 1
- 235000013305 food Nutrition 0.000 claims 1
- 235000021588 free fatty acids Nutrition 0.000 claims 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims 1
- 239000010460 hemp oil Substances 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 239000000944 linseed oil Substances 0.000 claims 1
- 235000021388 linseed oil Nutrition 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- 239000008164 mustard oil Substances 0.000 claims 1
- 239000004006 olive oil Substances 0.000 claims 1
- 235000008390 olive oil Nutrition 0.000 claims 1
- 239000002540 palm oil Substances 0.000 claims 1
- 239000000312 peanut oil Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 239000010773 plant oil Substances 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- 239000003549 soybean oil Substances 0.000 claims 1
- 235000012424 soybean oil Nutrition 0.000 claims 1
- 239000002600 sunflower oil Substances 0.000 claims 1
- 239000003784 tall oil Substances 0.000 claims 1
- 239000003760 tallow Substances 0.000 claims 1
- 239000010698 whale oil Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
- C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1018—Biomass of animal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/802—Diluents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Abstract
The invention relates to a process for the manufacture of diesel range hydro-carbons wherein a feed comprising fresh feed is hydrotreated in a hy-drotreating step and isomerised in an isomerisation step and the fresh feed contains at least 20 % by weight triglyceride C12-C16 fatty acids or C12-C16fatty acid esters or C12-C16 fatty acids or combinations of thereof and feed contains 50 - 20000 w-ppm sulphur calculated as elemental sulphur.
Claims (20)
1. Process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, characterized in that the feed comprises fresh feed containing at least 20 %
by weight of triglyceride C12-C16 fatty acids or C12-C16 fatty acid esters or C12-fatty acids or combinations of thereof and the total feed contains 50 - 20000 w-ppm sulphur calculated as elemental sulphur.
by weight of triglyceride C12-C16 fatty acids or C12-C16 fatty acid esters or C12-fatty acids or combinations of thereof and the total feed contains 50 - 20000 w-ppm sulphur calculated as elemental sulphur.
2. Process according to claim 1, characterized in that the fresh feed contains at least 30 % by weight and preferably at least 40 % by weight of triglyceride C16 fatty acids or other fatty acid esters or combinations of thereof.
3. Process according to claim 1 or 2, characterized in that the fresh feed contains more than 5 % by weight of free fatty acids.
4. Process according to any one of claims 1- 3, characterised in that the feed contains less than 10 w-ppm alkaline and alkaline earth metals, calculated as ele-mental alkaline and alkaline earth metals, less than 10 w-ppm other metals, calcu-lated as elemental metals and less than 30 w-ppm phosphorus, calculated as ele-mental phosphorus.
5. Process according to any one of claims 1- 4, characterized in that the feed comprises less than 20 wt-% of fresh feed and additionally at least one diluting agent.
6. Process according to claim 5, characterized in that the diluting agent is dilut-ing agent is selected from hydrocarbons and recycled products of the process or mixtures thereof and the diluting agent / fresh feed-ratio is 5-30:1, preferably 10-30:1 and most preferably 12-25:1.
7. Process according to any one of claims 1- 6, characterized in that the feed contains 1000-8000 w-ppm and preferably 2000-5000 w-ppm of sulphur calcu-lated as elemental sulphur.
8. Process according to any one of claims 1- 7, characterized in that at least one inorganic or organic sulphur compound or a refinery gas and/or liquid stream con-taining sulphur compounds is added to the feed.
9. Process according to any one of claims 1- 8, characterized in that the fresh feed is of biological origin selected from plant oils/fats, animal fats/oils, fish fats/oils, fats contained in plants bred by means of gene manipulation, recycled fats of the food industry and mixtures thereof.
10. Process according to any one of claims 1- 9, characterized in that the fresh feed is selected from rapeseed oil, colza oil, canola oil, tall oil, sunflower oil, soy-bean oil, hempseed oil, olive oil, linseed oil, mustard oil, palm oil, peanut oil, cas-tor oil, coconut oil, lard, tallow, train oil or fats contained in milk or mixtures thereof.
11. Process according to any one of claims 1- 10, characterized in that the fresh feed comprises feed of biological origin and a hydrocarbon/hydrocarbons.
12. Process according to any of the claims 1- 11, characterized in that in the hydrotreatment step a catalyst bed system is used comprising one or more catalyst beds.
13. Process according to any of the above claims 1-12, characterized in that in the hydrotreating step, the pressure varies in the range of 2-15 MPa, preferably in the range of 3-10 MPa, the temperature varying between 200 and 400 °C, prefera-bly between 250 and 350 °C, and most preferably between 280 and 345 °C.
14. Process according to any of the above claims 1-13, characterized in that in the isomerisation step, the pressure varies in the range of 2-15 MPa, preferably in the range of 3-10 MPa, the temperature varying between 200 and 500 °C, prefera-bly between 280 and 400 °C.
15. Process according to any of the above claims 1-14, characterized in that the hydrotreatment is carried out in the presence of a hydrogenation catalyst, said hy-drogenation catalyst containing a metal from the Group VIII and/or VIB of the Periodic System.
16. Process according to claim 15, characterized in that the hydrotreating catalyst is a supported Pd, Pt, Ni, NiMo or a CoMo catalyst, the support being alumina and/or silica.
17. Process according to any of the above claims 1-16, characterized in that an isomerisation catalyst containing molecular sieve is used in the isomerisation step.
18. Process according to claim 17, characterized in that isomerisation catalyst comprises a metal from the Element Group VIII.
19. Process according to claim 17 or 18, characterized in that the isomerisation catalyst contains Al2O3 or SiO2.
20. Process according to any one of claims 17 -19, characterized in that the isom-erisation catalyst contains SAPO-11 or SAPO-41 or ZSM-22 or ZSM-23 or ferrier-ite and Pt or Pd or Ni and Al2O3 or SiO2.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05014426.0A EP1741767B2 (en) | 2005-07-04 | 2005-07-04 | Process for the manufacture of diesel range hydrocarbons |
| EP05014426.0 | 2005-07-04 | ||
| US69585205P | 2005-07-05 | 2005-07-05 | |
| US60/695,852 | 2005-07-05 | ||
| PCT/FI2006/050300 WO2007003708A1 (en) | 2005-07-04 | 2006-06-29 | Process for the manufacture of diesel range hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2614014A1 true CA2614014A1 (en) | 2007-01-11 |
| CA2614014C CA2614014C (en) | 2012-07-24 |
Family
ID=37122665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2614014A Active CA2614014C (en) | 2005-07-04 | 2006-06-29 | Process for the manufacture of diesel range hydrocarbons |
Country Status (11)
| Country | Link |
|---|---|
| KR (1) | KR101037583B1 (en) |
| AU (1) | AU2006264899B2 (en) |
| CA (1) | CA2614014C (en) |
| EA (1) | EA013754B1 (en) |
| EG (1) | EG25348A (en) |
| HK (1) | HK1119734A1 (en) |
| MA (1) | MA29689B1 (en) |
| MX (1) | MX2008000290A (en) |
| NO (1) | NO20080282L (en) |
| TN (1) | TNSN07486A1 (en) |
| WO (1) | WO2007003708A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2910483B1 (en) * | 2006-12-21 | 2010-07-30 | Inst Francais Du Petrole | METHOD OF CONVERTING CHARGES FROM RENEWABLE SOURCES IN GOODLY GASOLINE FUEL BASES. |
| BRPI0811967B1 (en) * | 2007-06-01 | 2023-01-17 | Terravia Holdings, Inc | MICROALGAE CHLORELLA OR PROTOTHECA AND METHOD FOR THE PRODUCTION OF MICROBIAL LIPIDS |
| US20080312480A1 (en) * | 2007-06-15 | 2008-12-18 | E. I. Du Pont De Nemours And Company | Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks |
| US8158842B2 (en) * | 2007-06-15 | 2012-04-17 | Uop Llc | Production of chemicals from pyrolysis oil |
| WO2009120242A1 (en) * | 2007-12-21 | 2009-10-01 | Uop Llc | Production of aviation fuel from biorenewable feedstocks |
| GB2462054A (en) * | 2008-04-29 | 2010-01-27 | Statoilhydro Asa | Biodiesel |
| US8581013B2 (en) | 2008-06-04 | 2013-11-12 | Syntroleum Corporation | Biorenewable naphtha composition and methods of making same |
| US20090300971A1 (en) | 2008-06-04 | 2009-12-10 | Ramin Abhari | Biorenewable naphtha |
| KR100934331B1 (en) * | 2008-06-17 | 2009-12-29 | 에스케이루브리컨츠 주식회사 | Manufacturing method of high quality naphthenic base oil |
| US7960597B2 (en) * | 2008-07-24 | 2011-06-14 | Chevron U.S.A. Inc. | Conversion of vegetable oils to base oils and transportation fuels |
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|---|---|---|---|---|
| US4518485A (en) * | 1982-05-18 | 1985-05-21 | Mobil Oil Corporation | Hydrotreating/isomerization process to produce low pour point distillate fuels and lubricating oil stocks |
| US7232935B2 (en) * | 2002-09-06 | 2007-06-19 | Fortum Oyj | Process for producing a hydrocarbon component of biological origin |
| ATE356858T1 (en) * | 2002-09-06 | 2007-04-15 | Neste Oil Oyj | METHOD FOR PRODUCING A HYDROCARBON COMPONENT OF BIOLOGICAL ORIGIN |
| DE10327059B4 (en) * | 2003-06-16 | 2005-12-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for converting fat and oil containing raw materials and waste into high hydrocarbon content mixtures, products made by this process and their use |
| ES2670344T3 (en) * | 2003-09-05 | 2018-05-30 | Infineum International Limited | Additive compositions for stabilized diesel fuel |
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2006
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- 2006-06-29 EA EA200800243A patent/EA013754B1/en not_active IP Right Cessation
- 2006-06-29 KR KR1020087002773A patent/KR101037583B1/en active IP Right Grant
- 2006-06-29 AU AU2006264899A patent/AU2006264899B2/en active Active
- 2006-06-29 MX MX2008000290A patent/MX2008000290A/en active IP Right Grant
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| TNSN07486A1 (en) | 2009-03-17 |
| EA200800243A1 (en) | 2008-06-30 |
| KR101037583B1 (en) | 2011-05-30 |
| EA013754B1 (en) | 2010-06-30 |
| CA2614014C (en) | 2012-07-24 |
| EG25348A (en) | 2011-12-15 |
| NO20080282L (en) | 2008-04-02 |
| MA29689B1 (en) | 2008-08-01 |
| WO2007003708A1 (en) | 2007-01-11 |
| AU2006264899A1 (en) | 2007-01-11 |
| MX2008000290A (en) | 2008-03-11 |
| HK1119734A1 (en) | 2009-03-13 |
| AU2006264899B2 (en) | 2011-03-31 |
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