CA2594153A1

CA2594153A1 - Use of polyethylene glycol esters of fatty acids as lubricants for plastics

Info

Publication number: CA2594153A1
Application number: CA002594153A
Authority: CA
Inventors: Ernst-Udo Brand; Peter Daute
Original assignee: Cognis Oleochemicals GmbH
Current assignee: Emery Oleochemicals GmbH
Priority date: 2006-07-20
Filing date: 2007-07-20
Publication date: 2008-01-20
Anticipated expiration: 2027-07-20
Also published as: ATE458024T1; CA2594153C; US20080051303A1; EP1881025B1; DE502006006177D1; EP1881025A1

Abstract

The invention relates to the use of polyethylene glycol esters of fatty acids corresponding to the following formula:
R1-CO-O-(CH2-CH2-O)n-OC-R2 (I) in which R1 and R2 independently of one another represent alkyl groups containing 7 to 23 carbon atoms, which may be saturated or unsaturated, linear or branched, and n is a number of 2 to 50, as lubricants in the processing of thermoplastics.

Description

Use of Polyethylene Glycol Esters of Fatty Acids as Lubricants for Plastics Field of the Invention This invention relates to the use of polyethylene glycol esters of fatty acids as lubricants for plastics.

Prior Art In the processing of thermoplastics, lubricants are added as processing aids. On the one hand, the lubricants are capable of reducing the internal friction between plastic particles which makes the plastics easier to melt and promotes the formation of a homogeneous, flowable melt. Lubricants acting in this way are also commonly referred to as internal lubricants. On the other hand, lubricants used in the processing of plastics are capable of reducing the adhesion of the plastic melt to hot surfaces of machine parts or to the walls of the molds. It is assumed that the lubricants, which, after their incorporation in the plastic, migrate from the plastic to the surface on account of their limited compatibility, reduce adhesion. Lubricants acting in this way are also known as external lubricants or as "mold release agents".
In principle, the use of the lubricants also has a considerable bearing on the morphology, homogeneity and surface qualities of the plastic products.
Whether an additive acts as internal or external lubricant depends on many factors, more particularly on its structure and on the nature of the plastic. In many cases, internal and external lubricating effects may even be developed alongside one another. Initial observations on lubricants in PVC and their effect as internal and external lubricants can be found in the overview in Gachter/Muller, Kunststoffadditive (2"d Edition, pp. 320-327).
Known lubricants for plastics include, for example, fatty acids, fatty I

alcohols, fatty acid esters, fatty acid complex esters, wax esters, dicarboxylic acid esters, amide waxes, metal soaps, montan waxes, hydrocarbon waxes or oxidized hydrocarbons.
Polyethylene glycol monoesters are used as antistatic and antifogging agents in thermoplastics (cf. Antistatic PVC Materials, Sheverdyaev, O.N. USSR, Plasticheskie Massy (1985), (4), 21-2; ISSN:
0554-2901; in Russian; reported in CAPLUS: 1985:423262).

Description of the Invention The problem addressed by the present invention was to provide lubricants, more especially internal lubricants, which could be used in the processing of thermoplastics.
It has surprisingly been found that polyethylene glycol esters of fatty acids can be used in excellent fashion as lubricants and preferably as internal lubricants in the processing of thermoplastics. The compounds are highly compatible with the polymers and lead during processing to an improvement in the plasticization of the polymer. Another advantage lies in the low inherent volatility of the polyethylene glycol esters of fatty acids.
The lubricants to be used in accordance with the invention are characterized by the following formula:

R1-CO-O-(CH2-CH2-O)n-OC-R2 (I) in which R' and R2 independently of one another represent alkyl groups containing 7 to 23 carbon atoms, which may be saturated or unsaturated, linear or branched, and n is a number of 2 to 50.
Accordingly, the present invention relates to the use of polyethylene glycol esters of fatty acids corresponding to the following formula:

R'-CO-O-(CH2-CH2-O)n-OC-R2 (I) in which R' and R2 independently of one another represent alkyl groups containing 7 to 23 carbon atoms, which may be saturated or unsaturated, linear or branched, and n is a number of 2 to 50, as lubricants in the processing of thermoplastics. In a preferred embodiment, n has a value of 2 to 4.
The term "lubricant" in the context of the present invention denotes lubricants in the broader sense, i.e. external and/or internal lubricants. If a narrower meaning is intended, it is explicitly indicated (i.e. the expression "internal lubricant" is expressly used).
The compounds (I) to be used in accordance with the invention are preferably used in quantities of 0.05 to 5.0 parts by weight, based on the thermoplastic. The range from 0.1 to 2.0 parts by weight is particularly preferred.
Suitable C$_24 fatty acids are both native and synthetic or branched and saturated or unsaturated compounds. The fatty acids may be used in the form of mixtures. Examples of suitable fatty acids are lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid. Fatty acids containing hydroxyl or keto groups, such as 12-hydroxystearic acid, are also suitable.
Fatty acids such as these can be obtained from naturally occurring fats and oils, for example by lipolysis at elevated temperature and pressure and subsequent separation of the fatty acid mixtures obtained, optionally followed by hydrogenation of the double bonds present. Technical fatty acids are preferably used. Technical fatty acids are generally mixtures of different fatty acids of a certain chain length range with one fatty acid as the main constituent. C12_1$ fatty acids individually or in admixture are preferably used.
Basically, there are no restrictions with regard to the thermoplastics.
Thermoplastics selected from the group consisting of polycarbonates, polyamides, polyesters, polystyrenes and polyvinyl chloride and copolymers thereof are preferred. These thermoplastics may be stabilized, pigmented, filled with fillers or modified.
In a preferred embodiment, the compounds (I) are used as internal lubricants. All that has been said in the foregoing in regard to the use of the compounds (I) as lubricants also applies to their use as internal lubricants.
The compounds (I) to be used in accordance with the invention -where they are used as lubricants or as internal lubricants - may be used as such or in combination with other typical lubricants different from the compounds (I) or other additives for plastics.
Other typical lubricants are C12_24 fatty acids, C12_24 fatty alcohols, esters of C12_24 fatty acids and C12_24 fatty alcohols (so-called wax esters), esters of C12_24 fatty acids and polyhydric alcohols containing 4 to 6 hydroxyl groups (so-called polyol esters), dicarboxylic acid esters of dicarboxylic acids and C12_24 fatty alcohols and complex esters of dicarboxylic acids, polyols and monocarboxylic acids. The standard lubricants mentioned may be used both individually and in admixture with one another.
The following observations apply to the optional other lubricants different from the compounds of formula (I):

= Suitable C12_24 fatty acids are both native and synthetic, linear saturated compounds. If fatty acid mixtures are used, they may contain unsaturated fatty acids. Examples of suitable fatty acids are lauric, tridecanoic, myristic, pentadecanoic, palmitic, margaric, stearic, behenic and lignoceric acid. Fatty acids containing hydroxyl groups, such as 12-hydroxystearic acid, are also suitable. Fatty acids such as these can be obtained from naturally occurring fats and oils, for example through lipolysis at elevated temperature and pressure and subsequent separation of the fatty acid mixtures obtained, optionally followed by hydrogenation of the double bonds present. Technical fatty acids are preferably used here. They are generally mixtures of different fatty acids of a certain chain length range with one fatty acid as the main constituent. C12.18 fatty acids individually or in admixture are preferably used.

= The C12_24 fatty alcohols are mostly linear saturated representatives which may be obtained inter alia from naturally occurring fats and oils by transesterification with methanol, subsequent catalytic hydrogenation of the methyl esters obtained and fractional distillation.
Examples of such fatty alcohols are lauryl, myristyl, cetyl, stearyl and behenyl alcohol. These compounds may be used individually and in admixture with one another. Technical fatty alcohols are preferably used. They are normally mixtures of different fatty alcohols of a limited chain length range in which one particular fatty alcohol is present as the main constituent. Technical C12_1$ fatty alcohol mixtures are preferred.

= Other suitable additional lubricants are wax esters, i.e. esters of C12-24 fatty acids and C12_24 fatty alcohols which preferably correspond to formula (II):

R3CO-OR4 (I I) in which R3CO is a saturated and/or unsaturated acyl group containing 12 to 24 and preferably 12 to 18 carbon atoms and R2 is an alkyl and/or alkenyl group containing 12 to 24 and preferably 12 to 18 carbon atoms. Typical examples are esters of lauric acid, isotridecanoic acid, myristic acid, palmitic acid, paimitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and technical mixtures thereof with lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linoyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and technical mixtures thereof. Preferred wax esters are stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl erucate, oleyl paimitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl paimitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl oleate and mixtures thereof. Stearyl stearate is particularly preferred as the wax ester. It is important in this regard to bear in mind that stearyl stearate is normally produced from technical starting materials which in turn are mixtures so that the ester is also a mixture.
The esters mentioned may be obtained by known methods of organic synthesis, for example by heating stoichiometric quantities of fatty acid and fatty alcohol to 180-250 C, optionally in the presence of a suitable esterification catalyst, such as tin grindings, and in an inert gas atmosphere, and distilling off the water of reaction.
= Suitable additional lubricants are polyol fatty acid esters, i.e. esters of C12_24 fatty acids and polyols containing 4 to 6 hydroxyl groups. The alcohol component may be selected, above all, from aliphatic polyols containing 4 to 12 carbon atoms, for example erythritol, pentaerythritol, dipentaerythritol, ditrimethylol propane, diglycerol, triglycerol, tetraglycerol, mannitol and sorbitol. These polyol esters may be full esters in which all the hydroxyl groups of the polyol are esterified with fatty acid. However, polyol partial esters containing one or more free hydroxyl groups in the molecule are also suitable. These polyol fatty acid esters may also be obtained by known methods of organic synthesis by esterification of the polyols with stoichiometric or sub-stoichiometric quantities of free fatty acids. Examples of such polyol fatty acid esters are the stearic acid and stearic acid/palmitic acid full esters of erythritol, pentaerythritol and diglycerol, the dilaurates of dipentaerythritol, ditrimethylolpropane, triglycerol, mannitol and sorbitol, the distearates of erythritol, pentaerythritol, dipentaerythritol and tetraglycerol and the so-called sesquiesters of pentaerythritol, dipentaerythritol, mannitol and sorbitol in whose production 1.5 mol fatty acid, more particularly palmitic and/or stearic acid, is used to 1 mol polyol. The polyol fatty acid esters mentioned are generally mixtures simply because of the particular starting materials used.

= Other suitable additional lubricants are complex esters which are also known per se from the prior art. In principle, the complex esters are produced from dicarboxylic acids, polyols and monocarboxylic acids.
The following dicarboxylic acids may be used for the production of the complex esters: oxalic, malonic, succinic, glutaric, adipic, pimelic, suberic, azelaic, sebacic, nonanedicarboxylic, undecanedicarboxylic, eicosanedicarboxylic, maleic, fumaric, citraconic, mesaconic, itaconic, cyclopropanedicarboxylic, cyclobutanedicarboxylic, cyclopentane-dicarboxylic, camphor, hexahydrophthalic, phthalic, terephthalic, isophthalic, naphthalic and diphenyl-o,o'-dicarboxylic acid. The following compounds are generally used as aliphatic polyols containing 2 to 6 hydroxyl groups: ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,4-butanediol, 2,3-butanediol, 1,5-pentanediol, 1,6-hexanediol, glycerol, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, xylitol, mannitol and sorbitol. Suitable monocarboxylic acids are linear or branched, synthetic or native acids, for example lauric, myristic, paimitic, margaric, stearic, arachic, behenic, lignoceric, cerotic acid, montanic acid, oleic, elaidic, erucic, linoleic, linolenic and isostearic acid and mixtures of these acids, particularly those obtainable from natural fats and oils. Preferred complex esters are produced from aliphatic dicarboxylic acids containing 4 to 8 carbon atoms, polyols containing 3 or 4 hydroxyl groups and aliphatic monocarboxylic acids containing 14 to 22 carbon atoms. Excellent results are obtained with complex esters of adipic acid, pentaerythritol and monocarboxylic acids containing 14 to 22 carbon atoms.

= According to the invention, other suitable additional lubricants are dicarboxylic acid esters of fatty alcohols containing 12 to 24 carbon atoms. Suitable dicarboxylic acids have already been mentioned by way of example in connection with the complex esters. Suitable fatty acids are the fatty acids already discussed above. Phthalic acid esters, more especially distearyl phthalate, are particularly preferred.
= Other additional lubricants, which may be used individually or in combination, are hydrocarbon waxes melting at temperatures in the range from 70 to 130 C, oxidized polyethylene waxes, a-olefins, ethylenediamine distearate, montanic acid esters of diols, for example ethanediol, 1,3-butanediol and glycerol, mixtures of such montanic acid esters with unesterified montanic acids and metal soaps, more particularly salts of organic monocarboxylic acids with metals of the second main and/or secondary group of the periodic system, such as calcium soaps and zinc soaps.
Accordingly, the present invention also relates to the use of lubricant combinations for thermoplastics containing (a) one or more fatty acid polyethylene glycol esters (I) and (b) one or more additional lubricants (not covered by formula (I)), with the proviso that components (a) and (b) are used in a ratio by weight of 10:90 to 90:10 and preferably in a ratio by weight of 20:80 to 80:20.
The expression "lubricant combinations" applies both to lubricants and to internal lubricants.
In practice, the lubricant mixtures according to the invention are applied by addition to the thermoplastics to be processed in quantities of 0.05 to 5 and more particularly 0.1 to 2 parts by weight to 100 parts by weight of thermoplastic. The lubricant mixtures are preferably added to the melt formed during production of the thermoplastic or are applied to the plastic granules or powder at elevated temperatures.
The thermoplastics may optionally contain additional additives.
Examples of suitable additives are antistatic agents, antifogging agents, antioxidants, UV stabilizers, coupling agents, calendering aids, parting agents, lubricants, plasticizers, perfumes, flame retardants, fillers and agents for increasing heat stability (heat stabilizers).
The thermoplastics may readily be further processed by standard methods, for example by extrusion, pressing, rolling, calendering, sintering, spinning, blow moulding, foaming, injection moulding or processing by the plastisol method.

Examples 1. Production of the lubricants according to the invention Example 1 237 g diethylene glycol (Fluka), 1151 g technical stearic acid (Cognis) and 0.7 g tin(II) oxalate (Goldschmidt) were heated under nitrogen. The esterification reaction began at ca. 170 C with the formation of water. After 3 hours, removal of the water of reaction was continued by application of vacuum, the vacuum being lowered to ca. 15 mbar over a period of 4 hours. The final temperature was 200 C.
The reaction was terminated at an acid value (AV) of <6. The reaction mixture was cooled to 90 C and filtered. Yield 1296 g, AV = 1.6, SV (saponification value) = 184.

Example 2 PEG-600 distearate was produced from 167 g PEG 600 (Fluka) and 147 g technical stearic acid (Cognis) in the same way as in Example 1.
Yield 298 g, AV = 5.9, SV = 102.

2. Production of dry blends Using a Henschel mixer, a dry blend was produced from PVC
powder and various additives (quantity of material = 3 kg, heating temperature = 120 C, subsequent cooling). The compositions are set out in the following Table (the numbers in the Table represent parts by weight).

Example C1 C2 C3 E3 E4 PVC Evipol SH 6520 (Ineos) 100 100 100 100 100 Pb sulfate, tribasic 2 2 2 2 2 Lead stearate (28% Pb) 0.5 0.5 0.5 0.5 0.5 Calcium stearate 0.5 0.5 0.5 0.5 0.5 Hydrogenated castor oil - 1.0 - - -Distearyl phthalate - - 1.0 - -Lubricant of Example 1 - - 1.0 -Lubricant of Example 2 - - - 1.0 In this Table, Cl to C3 are comparison Examples. In Cl, no lubricant was added. In C2, hydrogenated castor oil was used; it is the most important internal lubricant for PVC bottles (cf. Plastics Additives Handbook, 5th Edition, Hanser Verlag, p. 537). In C3, distearyl phthalate - an internal lubricant for profile extrusion - was used. E4 and E5 represent formulations according to the invention.

3. Production of ribbons The above-mentioned dry blends were extruded to ribbons in a Weber twin-screw extruder (extrusion parameters: screw speed = 15 r.p.m.: temperature = 190 C). The power consumed by the extruder, the machine load (in %), was evaluated as a measure of plasticization. Early plasticization leads to an increase in the machine load. The melt pressure (bar) before the die was used as a measure of lubricant performance. A
low melt pressure signifies a good lubricating effect.

Example Machine load (%) Melt pressure (bar) C 1 48.7 347 C2 56.6 354 C3 46.0 324 E4 51.1 344 E5 57.8 336 Examples E4 and E5 according to the invention led to earlier plasticization (increase in machine load) at a relatively low melt pressure than Comparison Example Cl. Comparison Examples C2 and C3 lead either to better plasticization for an increase in melt pressure or impair plasticization.

Claims

1. Use of polyethylene glycol esters of fatty acids corresponding to the following formula:

R1-CO-O-(CH2-CH2-O)n-OC-R2 (I) in which R1 and R2 independently of one another represent alkyl groups containing 7 to 23 carbon atoms, which may be saturated or unsaturated, linear or branched, and n is a number of 2 to 50, as lubricants in the processing of thermoplastics.

2. Use claimed in claim 1, wherein n is a number of 2 to 4.

3. Use claimed in claim 1, wherein R1 and R2 independently of one another are saturated alkyl groups containing 7 to 23 carbon atoms.

4. Use claimed in any of claims 1 to 3, wherein the lubricants are used as internal lubricants.

5. Use of lubricant combinations for thermoplastics containing (a) one or more fatty acid polyethylene glycol esters (I) and (b) one or more additional lubricants (not covered by formula (I)), with the proviso that components (a) and (b) are used in a ratio by weight of 10:90 to 90:10 and preferably 20:80 to 80:20.

6. Use claimed in claim 5, the lubricant combinations being used as internal lubricants.