CA2561916A1 - Coating material - Google Patents
Coating material Download PDFInfo
- Publication number
- CA2561916A1 CA2561916A1 CA002561916A CA2561916A CA2561916A1 CA 2561916 A1 CA2561916 A1 CA 2561916A1 CA 002561916 A CA002561916 A CA 002561916A CA 2561916 A CA2561916 A CA 2561916A CA 2561916 A1 CA2561916 A1 CA 2561916A1
- Authority
- CA
- Canada
- Prior art keywords
- weight percent
- specifically
- coating material
- less
- accordance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract 21
- 238000000576 coating method Methods 0.000 title claims abstract 21
- 239000000463 material Substances 0.000 title claims abstract 18
- 239000000945 filler Substances 0.000 claims abstract 10
- 239000013543 active substance Substances 0.000 claims abstract 9
- 239000011230 binding agent Substances 0.000 claims abstract 8
- 239000002245 particle Substances 0.000 claims abstract 6
- 230000001699 photocatalysis Effects 0.000 claims abstract 4
- 230000003746 surface roughness Effects 0.000 claims abstract 3
- 238000004140 cleaning Methods 0.000 claims abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 6
- 239000000049 pigment Substances 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 3
- 239000000654 additive Substances 0.000 claims 2
- 239000004815 dispersion polymer Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000000499 gel Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 239000002114 nanocomposite Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 239000010453 quartz Substances 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 238000003980 solgel method Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/305—Titanium oxide, e.g. titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0092—Temporary binders, mortars or concrete, i.e. materials intended to be destroyed or removed after hardening, e.g. by acid dissolution
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/455—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application the coating or impregnating process including a chemical conversion or reaction
- C04B41/4558—Coating or impregnating involving the chemical conversion of an already applied layer, e.g. obtaining an oxide layer by oxidising an applied metal layer
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2061—Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
Abstract
The invention relates to a coating material comprising a binding agent, at least one filler containing particles having a size and/or surface roughness of 100 pm or less, and a photocatalytically active agent. According to the invention, the binding agent is at least partially decomposed by a photocatalytic action, and a microstructured, self-cleaning surface is formed.
Claims (14)
1. Coating material for the coating of facades and other building surfaces, comprising a binding agent and at least one filler containing particles having a size and/or surface roughness of 10 µm or less, preferably 1 µm or less, specifically 0.1 µm or less, as well as a photocatalytically active agent, characterized in that the binding agent is capable of being decomposed, at least partially, by the photocatalytic action of the photocatalytically active agent in such a way that the photocatalytic decomposition is equivalent or less than chalking level 1 as per DIN EN ISO 4628-6, and so that a microstructured, self-cleaning surface is created by the photocatalytic reduction of the layer thickness of an external coating, formed by the coating material, by 0.1 µm or more, preferably 1 µm or more, per year, given external weathering as per EN ISO 2810 (Klima Da, Probenkörper vertikal and derv Äquator zugewandt [Sample vertical and oriented in the direction of the equator]).
2. Coating material in accordance with claim 1, characterized in that the binding agent is at least partially photocatalytically degradable and the catalytically active agent has at least one photocatalytically active metal oxide.
3. Coating material in accordance with claim 1 or 2, characterized in that the binding agent exhibits an aqueous polymer dispersion, a polymer dispersion capable of being redispersed in water, a hydrophobic resin and/or a preliminary resin product or so-called nano composite.
4. Coating material in accordance with any of the preceding claims, characterized in that the binding agent contains silicone or silicate.
5. Coating material in accordance with any of the preceding claims, characterized in that the catalytically active agent exhibits an oxide of titanium, zinc, iron, manganese, molybdenum and/or tungsten, at a level of 60 weight percent or more, preferably 80 weight percent or more, specifically 90 weight percent or more, relative to the total weight of the catalytically active agent.
6. Coating material in accordance with any of the preceding claims, characterized in that the catalytically active agent exhibits at least one additive, specifically ion, selected from C, N, S and/or from the group consisting of Pt, Rh, Mn, Cr, Ru, Ni, Pd, Fe, Co, Ir, Cu, Mo, Zr, Re, Ag and Au in the form of their oxides and/or halogenides; preferably at a level of 40 weight percent or less, especially preferably 20 weight percent or less, specifically 10 weight percent or less and more than 1 weight percent, preferably more than 2.5 weight percent, specifically 5 weight percent or more, relative to the total weight of the catalytically active agent.
7. Coating material in accordance with any of the preceding claims, characterized in that the photocatalytically active agent consists of titanium dioxide, specifically of TiO2 endowed with C, N and/or S, in amorphous form, partially crystalline form or in the form of anatas.
8. Coating material in accordance with any of the preceding claims, characterized in that the filler exhibits particles having a size and/or surface roughness of 10 µm or less; specifically 1 µm or less, especially preferably nano fillers in the form of highly disperse silica.
9. Coating material in accordance with any of the preceding claims, characterized in that the nano fillers in the form of highly disperse silica are silica gels, which are preferably produced by precipitation using the sol gel process.
10. Coating material in accordance with any of the preceding claims, characterized in that at least one filler exhibits a monomodal particle size distribution with a mean particle diameter of 10 µm or less, specifically 1 µm or less, especially preferably 0.1 µm or less.
11. Coating material in accordance with any of the preceding claims, characterized in that the coating material is formulated using an excess of filler.
12. Coating material in accordance with any of the preceding claims, characterized in that it exhibits pigments and/or commercially available additives, specifically accelerators and/or retarders.
13. Coating material in accordance with any of the preceding claims with 10 to 30 weight percent, specifically ca. 20 weight percent of a photocatalytically degradable binding agent, 2 to 30 weight percent, specifically 5 to 15 weight percent, especially preferably ca. 10 weight percent of a filler having a mean particle size of 1 µm or less, specifically 0.1 µm or less, such as nanoscaled silica, 2 to 15 weight percent, specifically 3 to 8 weight percent, especially preferably ca. 5 weight percent of a photocatalytically active pigment, such as TiO2 endowed, if necessary, with C, N and/or S, as well as optionally 0.01 to 0.1 weight percent, specifically 0.05 weight percent of a pigment distributor, 0.1 to 1 weight percent, specifically ca. 0.3 weight percent of a thickener, 5 to 30 weight percent, specifically 10 to 20 weight percent of another filler, such as e.g.
a fine quartz filler, 10 to 20 weight percent, specifically ca. 15 weight percent of a pigment, 2 to 8 weight percent, specifically ca. 6 weight percent, of a hydrophobization agent, up to 4 weight percent of a solvent, up to 0.8 weight percent of a preservative and/or up to 35 weight percent of water.
a fine quartz filler, 10 to 20 weight percent, specifically ca. 15 weight percent of a pigment, 2 to 8 weight percent, specifically ca. 6 weight percent, of a hydrophobization agent, up to 4 weight percent of a solvent, up to 0.8 weight percent of a preservative and/or up to 35 weight percent of water.
14. Use of a coating material in accordance with any of the preceding claims for the coating of facades, specifically external facades, and/or other parts of buildings.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004018338.4 | 2004-04-15 | ||
| DE102004018338A DE102004018338A1 (en) | 2004-04-15 | 2004-04-15 | coating material |
| PCT/EP2005/004033 WO2005100459A1 (en) | 2004-04-15 | 2005-04-15 | Coating material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2561916A1 true CA2561916A1 (en) | 2005-10-27 |
| CA2561916C CA2561916C (en) | 2011-07-19 |
Family
ID=34964663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2561916A Expired - Fee Related CA2561916C (en) | 2004-04-15 | 2005-04-15 | Coating material |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7955430B2 (en) |
| EP (1) | EP1735372B1 (en) |
| JP (1) | JP2007532737A (en) |
| CN (1) | CN1968996A (en) |
| AT (1) | ATE541883T1 (en) |
| CA (1) | CA2561916C (en) |
| DE (1) | DE102004018338A1 (en) |
| DK (1) | DK1735372T3 (en) |
| NO (1) | NO333774B1 (en) |
| RU (1) | RU2377267C2 (en) |
| WO (1) | WO2005100459A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008020977A1 (en) | 2007-04-30 | 2008-11-06 | Henkel Ag & Co. Kgaa | Deodorizing cosmetic agent, useful for non-therapeutic, cosmetic deodorizing treatment of the body, comprises a photocatalytic effective metal-oxide, as a smell reducing active agent, in a carrier |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1834935A1 (en) * | 2006-03-16 | 2007-09-19 | QUARELLA S.p.A. | Wall and floor tiles and slabs consisting of agglomerated stone with photocatalytic properties |
| DE202006018244U1 (en) * | 2006-12-01 | 2008-04-10 | Thorwesten Vent Gmbh | Apparatus for compensating pressure surges in closed systems, such as silos or the like. |
| CN101784619B (en) | 2007-08-28 | 2012-11-28 | 巴斯夫欧洲公司 | Photoactive TiO2 in coating materials |
| JP2011524920A (en) * | 2008-06-03 | 2011-09-08 | ビーエーエスエフ ソシエタス・ヨーロピア | Titanium dioxide compositions containing titanium dioxide nanoparticles and their manufacture and use |
| DE102008035236A1 (en) * | 2008-07-29 | 2010-02-04 | Dyckerhoff Ag | Concrete Release Agents |
| RU2478469C1 (en) * | 2011-11-03 | 2013-04-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Петербургский государственный университет путей сообщения" | Method of producing articles from foam concrete not autoclaved |
| EP2722370B1 (en) | 2012-10-17 | 2014-05-28 | STO SE & Co. KGaA | Photocatalytic coatings with fillers |
| WO2014097309A1 (en) | 2012-12-17 | 2014-06-26 | Asian Paints Ltd. | Stimuli responsive self cleaning coating |
| RU2625059C1 (en) * | 2016-04-18 | 2017-07-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Владимирский Государственный Университет имени Александра Григорьевича и Николая Григорьевича Столетовых" (ВлГУ) | Facade decorative composite material |
| US9926459B2 (en) * | 2016-05-19 | 2018-03-27 | Behr Process Corporation | Energy saving self-cleaning roof paint |
| EP3505247A1 (en) | 2017-11-30 | 2019-07-03 | STO SE & Co. KGaA | Photocatalytic coatings with sulphidic semiconductors |
| CN115322612B (en) * | 2022-10-18 | 2023-01-10 | 天津大吕电力科技股份有限公司 | Inorganic filler dispersion liquid, super-hydrophobic insulating wear-resistant paint and preparation method |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU676299B2 (en) * | 1993-06-28 | 1997-03-06 | Akira Fujishima | Photocatalyst composite and process for producing the same |
| US5916947A (en) * | 1994-12-02 | 1999-06-29 | Cape Cod Research, Inc. | Zinc oxide photoactive antifoulant material |
| JPH11512336A (en) * | 1995-09-15 | 1999-10-26 | ロディア シミ | Substrate with photocatalytic coating based on titanium dioxide and organic dispersion based on titanium dioxide |
| JPH10130539A (en) * | 1996-10-28 | 1998-05-19 | Asahi Glass Co Ltd | Water-repellent material |
| JP3182107B2 (en) * | 1996-12-13 | 2001-07-03 | 松下電工株式会社 | Functional coatings, their production methods and applications |
| DE69826342T2 (en) * | 1997-02-06 | 2005-10-06 | Shin-Etsu Chemical Co., Ltd. | Coating compositions, hydrophilic film and hydrophilic film coated articles |
| US6337129B1 (en) * | 1997-06-02 | 2002-01-08 | Toto Ltd. | Antifouling member and antifouling coating composition |
| FR2776944B1 (en) * | 1998-04-03 | 2000-05-12 | Ahlstrom Paper Group Research | PHOTOCATALYTIC COMPOSITION |
| GB9816269D0 (en) * | 1998-07-27 | 1998-09-23 | Pilkington Plc | Plastic glazings |
| JP2001152138A (en) * | 1998-10-20 | 2001-06-05 | Sentan Kagaku Gijutsu Incubation Center:Kk | Planing film and its preparation process |
| JP2001152139A (en) * | 1998-10-20 | 2001-06-05 | Sentan Kagaku Gijutsu Incubation Center:Kk | Water-repellent film and its preparation process |
| DE29923250U1 (en) * | 1998-12-24 | 2000-08-31 | Ispo Gmbh | Molding or coating material |
| JP2001207123A (en) * | 1999-11-16 | 2001-07-31 | Sentan Kagaku Gijutsu Incubation Center:Kk | Film having high hardness and high droplet slidability and method for producing the same |
| WO2002060998A2 (en) * | 2001-01-30 | 2002-08-08 | The Procter & Gamble Company | Rinse aid surface coating compositions for modifying dishware surfaces |
| DE10106213A1 (en) * | 2001-02-10 | 2002-08-22 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Self-cleaning paint coatings and methods and means of making the same |
| JP2003013007A (en) * | 2001-06-29 | 2003-01-15 | Nippon Unicar Co Ltd | Coating composition and building material using the same |
| DE10134477A1 (en) * | 2001-07-16 | 2003-02-06 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
| JP3717868B2 (en) * | 2001-08-30 | 2005-11-16 | 東陶機器株式会社 | Photocatalytic coating agent, photocatalytic composite material and production method thereof |
| AU2003241999A1 (en) * | 2002-05-30 | 2003-12-19 | Jhcc Ltd | Photocatalytic coating material, photocatalytic composite material and process for producing the same, self-cleaning water-based coating compositions, and self-cleaning member |
| EP2000502A1 (en) | 2007-05-30 | 2008-12-10 | Sachtleben Chemie GmbH | Composite particles |
-
2004
- 2004-04-15 DE DE102004018338A patent/DE102004018338A1/en not_active Withdrawn
-
2005
- 2005-04-15 US US10/599,950 patent/US7955430B2/en not_active Expired - Fee Related
- 2005-04-15 CA CA2561916A patent/CA2561916C/en not_active Expired - Fee Related
- 2005-04-15 RU RU2006140238/04A patent/RU2377267C2/en not_active IP Right Cessation
- 2005-04-15 CN CNA2005800192000A patent/CN1968996A/en active Pending
- 2005-04-15 EP EP05732406A patent/EP1735372B1/en not_active Revoked
- 2005-04-15 JP JP2007507769A patent/JP2007532737A/en active Pending
- 2005-04-15 AT AT05732406T patent/ATE541883T1/en active
- 2005-04-15 WO PCT/EP2005/004033 patent/WO2005100459A1/en active Application Filing
- 2005-04-15 DK DK05732406.3T patent/DK1735372T3/en active
-
2006
- 2006-09-26 NO NO20064341A patent/NO333774B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008020977A1 (en) | 2007-04-30 | 2008-11-06 | Henkel Ag & Co. Kgaa | Deodorizing cosmetic agent, useful for non-therapeutic, cosmetic deodorizing treatment of the body, comprises a photocatalytic effective metal-oxide, as a smell reducing active agent, in a carrier |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1735372B1 (en) | 2012-01-18 |
| DK1735372T3 (en) | 2012-03-19 |
| NO333774B1 (en) | 2013-09-16 |
| NO20064341L (en) | 2006-11-15 |
| ATE541883T1 (en) | 2012-02-15 |
| US20070157853A1 (en) | 2007-07-12 |
| JP2007532737A (en) | 2007-11-15 |
| WO2005100459A1 (en) | 2005-10-27 |
| RU2377267C2 (en) | 2009-12-27 |
| CA2561916C (en) | 2011-07-19 |
| DE102004018338A1 (en) | 2005-11-10 |
| US7955430B2 (en) | 2011-06-07 |
| CN1968996A (en) | 2007-05-23 |
| EP1735372A1 (en) | 2006-12-27 |
| RU2006140238A (en) | 2008-05-20 |
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