CA2532964A1 - Transmission lubricating compositions with improved performance, containing acid/polyamine condensation product - Google Patents
Transmission lubricating compositions with improved performance, containing acid/polyamine condensation product Download PDFInfo
- Publication number
- CA2532964A1 CA2532964A1 CA002532964A CA2532964A CA2532964A1 CA 2532964 A1 CA2532964 A1 CA 2532964A1 CA 002532964 A CA002532964 A CA 002532964A CA 2532964 A CA2532964 A CA 2532964A CA 2532964 A1 CA2532964 A1 CA 2532964A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- weight percent
- hydrocarbyl
- hydrocarbyl group
- borate ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 23
- 230000001050 lubricating effect Effects 0.000 title claims abstract 11
- 239000007859 condensation product Substances 0.000 title claims abstract 6
- 229920000768 polyamine Polymers 0.000 title claims abstract 6
- 230000005540 biological transmission Effects 0.000 title claims abstract 3
- 239000002253 acid Substances 0.000 title 1
- -1 alkyl phosphite Chemical compound 0.000 claims abstract 17
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 5
- 239000002270 dispersing agent Substances 0.000 claims abstract 5
- 229930195729 fatty acid Natural products 0.000 claims abstract 5
- 239000000194 fatty acid Substances 0.000 claims abstract 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 11
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000004593 Epoxy Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 150000001639 boron compounds Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000012141 concentrate Substances 0.000 claims 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000036647 reaction Effects 0.000 claims 1
- 229960002317 succinimide Drugs 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M157/00—Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential
- C10M157/10—Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential at least one of them being a compound containing atoms of elements not provided for in groups C10M157/02 - C10M157/08
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/30—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
- C10M2227/062—Cyclic esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/04—Oxidation, e.g. ozonisation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Abstract
A lubricating composition comprises (a) an alkyl phosphite, wherein the alkyl group contains 14 to 20 carbon atoms; (b) a condensation product of a fatty acid with a polyamine or an alkylenepolyamine; (c) a borate ester; (d) a borated dispersant; and (e) an oil of lubricating viscosity. The lubricating composition has improved wear resistance, and further provides anti-shudder properties and appropriate friction properties. The lubricating composition can be used in automatic transmission fluids.
Claims (11)
1. A composition comprising:
(a) a hydrocarbyl phosphite, wherein the hydrocarbyl group contains at least 8 carbon atoms;
(b) a condensation product of a fatty acid with a polyamine;
(c) a borate ester;
(d) a borated dispersant; and (e) an oil of lubricating viscosity.
(a) a hydrocarbyl phosphite, wherein the hydrocarbyl group contains at least 8 carbon atoms;
(b) a condensation product of a fatty acid with a polyamine;
(c) a borate ester;
(d) a borated dispersant; and (e) an oil of lubricating viscosity.
2. The composition of claim 1, wherein the hydrocarbyl phosphite is represented by the formula:
wherein at least one of R1 and R2 is a hydrocarbyl group and the other of R1 and R2 can be hydrogen or a hydrocarbyl group, wherein the hydrocarbyl phosphite contains a hydrocarbyl group with at least 12 carbon atoms.
wherein at least one of R1 and R2 is a hydrocarbyl group and the other of R1 and R2 can be hydrogen or a hydrocarbyl group, wherein the hydrocarbyl phosphite contains a hydrocarbyl group with at least 12 carbon atoms.
3. The composition of claim 1, wherein the condensation product of a fatty acid with a polyamine comprises (a) a hydrocarbyl imidazoline represented by the formula:
wherein R7 is a hydrocarbyl group containing 10 or more carbon atoms; and R8 is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group; or (b) a hydrocarbyl amide represented by the formula:
wherein R9 is a hydrocarbyl group containing 10 or more carbon atoms and R10 is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group; or mix-tures thereof.
wherein R7 is a hydrocarbyl group containing 10 or more carbon atoms; and R8 is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group; or (b) a hydrocarbyl amide represented by the formula:
wherein R9 is a hydrocarbyl group containing 10 or more carbon atoms and R10 is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group; or mix-tures thereof.
4. The composition of claim 1, wherein the borate ester is prepared by the reac-tion of a boron compound and at least one compound selected from epoxy com-pounds, alcohols and mixtures thereof.
5. The composition of claim 4 further comprising an optional borate ester represented by the formula:
wherein R11, R12, and R13 are all hydrocarbyl groups containing 1 to 8 carbon atoms, provided the total number of carbon atoms in R11, R12, and R13 is 4 or more, further provided that the optional borate ester contains at least 2 fewer carbons atoms than the borate ester of component (c).
wherein R11, R12, and R13 are all hydrocarbyl groups containing 1 to 8 carbon atoms, provided the total number of carbon atoms in R11, R12, and R13 is 4 or more, further provided that the optional borate ester contains at least 2 fewer carbons atoms than the borate ester of component (c).
6. The composition of claim 1, wherein the borated dispersant is derived from an N-substituted long chain alkenyl succinimide.
7. The composition of claim 1, wherein the oil of lubricating viscosity is se-lected from the group consisting of API Group II, III, IV oil and mixtures thereof.
8. The composition of claim 1, wherein (a) the hydrocarbyl phosphite is present from 0.01 weight percent to 5 weight percent of the composition; (b) the con-densation product of a fatty acid with a polyamine is present from 0.01 weight percent to 3 weight percent of the composition; (c) the borate ester is present from 0.01 weight percent to 3 weight percent of the composition; (d) the borated dispersant is present from 0.03 weight percent to 6 weight percent of the com-position; and (e) the oil of lubricating viscosity is present from 78 weight percent to 99.9 weight percent of the composition.
9. The composition of claim 1, wherein the oil of lubricating viscosity is present in an amount less than 50 weight percent, to form a concentrate.
10. A process for the preparation of a composition comprising mixing:
(a) a hydrocarbyl phosphite;
(b) a condensation product of a fatty acid with a polyamine;
(c) a borate ester;
(d) a borated dispersant; and (e) an oil of lubricating viscosity.
(a) a hydrocarbyl phosphite;
(b) a condensation product of a fatty acid with a polyamine;
(c) a borate ester;
(d) a borated dispersant; and (e) an oil of lubricating viscosity.
11. A method for lubricating a power transmission system, comprising supply-ing thereto a lubricant comprising the composition of claim 1.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/621,154 US20050014656A1 (en) | 2003-07-16 | 2003-07-16 | Transmission lubricating compositions with improved performance, containing acid/polyamine condensation product |
US10/621,154 | 2003-07-16 | ||
PCT/US2004/020856 WO2005010134A1 (en) | 2003-07-16 | 2004-06-29 | Transmission lubricating compositions with improved performance, containing acid-polyamine condensation product |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2532964A1 true CA2532964A1 (en) | 2005-02-03 |
CA2532964C CA2532964C (en) | 2012-09-18 |
Family
ID=34062932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2532964A Active CA2532964C (en) | 2003-07-16 | 2004-06-29 | Transmission lubricating compositions with improved performance, containing acid/polyamine condensation product |
Country Status (5)
Country | Link |
---|---|
US (1) | US20050014656A1 (en) |
EP (1) | EP1648985A1 (en) |
JP (2) | JP4939939B2 (en) |
CA (1) | CA2532964C (en) |
WO (1) | WO2005010134A1 (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050059561A1 (en) * | 2003-09-17 | 2005-03-17 | Nubar Ozbalik | Power transmitting fluids and additive compositions |
US20050065043A1 (en) * | 2003-09-23 | 2005-03-24 | Henly Timothy J. | Power transmission fluids having extended durability |
US7637592B2 (en) * | 2006-05-26 | 2009-12-29 | Fujifilm Dimatix, Inc. | System and methods for fluid drop ejection |
US8202829B2 (en) * | 2004-11-04 | 2012-06-19 | Afton Chemical Corporation | Lubricating composition |
US20060276352A1 (en) * | 2005-06-02 | 2006-12-07 | James N. Vinci | Oil composition and its use in a transmission |
AU2006266095B2 (en) | 2005-06-29 | 2010-08-05 | The Lubrizol Corporation | Zinc-free farm tractor fluid |
US20070238626A1 (en) * | 2006-04-07 | 2007-10-11 | The Lubrizol Corporation | Metal containing hydraulic composition |
WO2008038701A1 (en) * | 2006-09-28 | 2008-04-03 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
US8163680B2 (en) * | 2006-09-28 | 2012-04-24 | Chevron Oronite Company Llc | Method of demulsing a natural gas dehydrator |
JP5565899B2 (en) * | 2006-12-18 | 2014-08-06 | ザ ルブリゾル コーポレイション | Functional fluid |
US8623797B2 (en) * | 2007-06-29 | 2014-01-07 | Infineum International Limited | Boron-containing lubricating oils having improved friction stability |
CN102002064A (en) * | 2010-11-25 | 2011-04-06 | 山东国邦药业股份有限公司 | Preparation method of trimethyl borate |
JP5877199B2 (en) * | 2011-05-27 | 2016-03-02 | Jx日鉱日石エネルギー株式会社 | Lubricating oil additive and lubricating oil composition |
US20150299603A1 (en) * | 2012-12-03 | 2015-10-22 | The Lubrizol Corporation | Industrial Gear Oils Imparting Reduced Gearbox Operating Temperatures |
US20160108337A1 (en) | 2013-05-14 | 2016-04-21 | The Lubrizol Corporation | Lubricating Composition and Method of Lubricating a Transmission |
GB201502002D0 (en) | 2015-02-06 | 2015-03-25 | Castrol Ltd | Uses and compositions |
CA3045129A1 (en) * | 2016-12-16 | 2018-06-21 | The Lubrizol Corporation | Lubrication of an automatic transmission with reduced wear on a needle bearing |
JP2021509929A (en) * | 2018-01-04 | 2021-04-08 | ザ ルブリゾル コーポレイションThe Lubrizol Corporation | Boron-containing automotive gear oil |
US10640723B2 (en) * | 2018-03-16 | 2020-05-05 | Afton Chemical Corporation | Lubricants containing amine salt of acid phosphate and hydrocarbyl borate |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5334329A (en) * | 1988-10-07 | 1994-08-02 | The Lubrizol Corporation | Lubricant and functional fluid compositions exhibiting improved demulsibility |
US5006270A (en) * | 1989-05-01 | 1991-04-09 | Mobil Oil Corporation | Mixed resorcinol-hydroxyester borates as antioxidants |
US5858929A (en) * | 1995-06-09 | 1999-01-12 | The Lubrizol Corporation | Composition for providing anti-shudder friction durability performance for automatic transmissions |
JPH10168480A (en) * | 1995-10-18 | 1998-06-23 | Lubrizol Corp:The | Composition for heightening nonabrasiveness of lubricant and functional fluid |
US5759965A (en) * | 1995-10-18 | 1998-06-02 | The Lubrizol Corporation | Antiwear enhancing composition for lubricants and functional fluids |
US6103673A (en) * | 1998-09-14 | 2000-08-15 | The Lubrizol Corporation | Compositions containing friction modifiers for continuously variable transmissions |
US6482777B2 (en) * | 1998-10-19 | 2002-11-19 | The Lubrizol Corporation | Lubricating compositions with improved thermal stability and limited slip performance |
US6451745B1 (en) * | 1999-05-19 | 2002-09-17 | The Lubrizol Corporation | High boron formulations for fluids continuously variable transmissions |
JP4741088B2 (en) * | 2001-02-02 | 2011-08-03 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition |
ATE430793T1 (en) * | 2001-02-07 | 2009-05-15 | Lubrizol Corp | LOW SULFUR AND PHOSPHORUS LUBRICANT OIL COMPOSITION CONTAINING BORON |
US20020151441A1 (en) * | 2001-02-14 | 2002-10-17 | Sanjay Srinivasan | Automatic transmission fluids with improved anti-shudder properties |
US6528458B1 (en) * | 2002-04-19 | 2003-03-04 | The Lubrizol Corporation | Lubricant for dual clutch transmission |
-
2003
- 2003-07-16 US US10/621,154 patent/US20050014656A1/en not_active Abandoned
-
2004
- 2004-06-29 EP EP04777253A patent/EP1648985A1/en not_active Withdrawn
- 2004-06-29 WO PCT/US2004/020856 patent/WO2005010134A1/en active Search and Examination
- 2004-06-29 JP JP2006520193A patent/JP4939939B2/en active Active
- 2004-06-29 CA CA2532964A patent/CA2532964C/en active Active
-
2011
- 2011-05-02 JP JP2011103304A patent/JP2011149031A/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
EP1648985A1 (en) | 2006-04-26 |
WO2005010134A1 (en) | 2005-02-03 |
JP2007523963A (en) | 2007-08-23 |
US20050014656A1 (en) | 2005-01-20 |
JP4939939B2 (en) | 2012-05-30 |
JP2011149031A (en) | 2011-08-04 |
CA2532964C (en) | 2012-09-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |