CA2513488A1 - Papers comprising a boron-containing compound and a method of making same - Google Patents

Papers comprising a boron-containing compound and a method of making same Download PDF

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Publication number
CA2513488A1
CA2513488A1 CA002513488A CA2513488A CA2513488A1 CA 2513488 A1 CA2513488 A1 CA 2513488A1 CA 002513488 A CA002513488 A CA 002513488A CA 2513488 A CA2513488 A CA 2513488A CA 2513488 A1 CA2513488 A1 CA 2513488A1
Authority
CA
Canada
Prior art keywords
starch
paper
boron
paperboard
containing compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002513488A
Other languages
French (fr)
Other versions
CA2513488C (en
Inventor
Yan C. Huang
M. Bruce Lyne
Kapil M. Singh
Yaoliang Hong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Paper Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2513488A1 publication Critical patent/CA2513488A1/en
Application granted granted Critical
Publication of CA2513488C publication Critical patent/CA2513488C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/12Organo-metallic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents

Landscapes

  • Paper (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Saccharide Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention involves papers having either an internal starch or a size pre ss applied starch and a boron-containing compound which is added in proportion to the starch and which is believed to interact with the starch to provide improved physical and mechanical properties in the paper. Method of forming the papers are also disclosed.

Claims (48)

1. A method for forming a paper or paperboard comprising:
providing a papermaking furnish comprising cellulosic fibers, starch and a boron-containing forming a fibrous web from the papermaking furnish; and drying the web.
2. The method of Claim 1 further comprising calendering the web to provide a finished paper or paperboard.
3. The method of Claim 1 wherein the amount of starch is equal to or less than about 200 lbs per ton of fiber.
4. The method of claim 1 wherein the amount of boron containing compound is equal to or less than about 7% by weight of the starch.
5. The method of Claim 1 which further comprises mixing converted starch and at least a portion of the boron-containing compound to provide a slurry and adding the slurry to a cellulosic fiber furnish to provide the papermaking furnish.
6. The method of Claim ~ which further comprises mixing unconverted starch and at least a portion of the boron-containing compound to provide a slurry, cooking the slurry to convert the starch and adding the cooked slurry to a cellulosic fiber furnish to provide the papermaking furnish.
7. The method of Claim 1 which further comprises adding the boron-containing compound and the converted starch individually to a cellulosic fiber furnish to provide the papermaking furnish.
8. The method of Claim 1 wherein the boron-containing compound is selected from the group consisting of boric acid and borate metal salts.
9. The method of Claim 8 wherein the boron-containing compound is selected from the group consisting of boric acid, borax, and zinc borate.
10. The method of Claim 1 wherein the boron-containing compound and the starch form a complex.
11. The method of Claim 1 wherein the starch is an anionic starch.
12. The method of Claim 1 wherein the starch is a cationic starch.
13. The method of Claim 1 wherein the starch is an amphipathic starch.
14. The method of Claim 1 wherein the starch is selected from the group consisting of corn starch, wheat starch, potato starch, rice starch, tapioca starch, and sago starch.
15. A paper or paperboard comprising a paper web that comprises cellulosic fibers starch and a boron-containing compound.
16. The paper or paperboard of Claim 14 wherein the amount of starch is equal to or less than about 200 lbs per ton of fiber.
17.The paper or paperboard of Claim 14 wherein the amount of boron containing compound is equal to or less than about 7%by weight of the starch.
18. The paper or paperboard of Claim 14 wherein the boron-containing compound is selected from the group consisting of boric acid and borate metal salts.
19. The paper or paperboard of Claim 17 wherein the boron-containing compound is selected from the group consisting of boric acid, borax, and zinc borate.
20. The paper or paperboard of Claim 14 wherein the boron-containing compound and the starch form a complex.
21. The paper or paperboard of Claim 11 wherein the starch is an anionic starch.
22. The paper or paperboard of Claim 11 wherein the starch is a cationic starch.
23. The paper or paperboard of Claim 11 wherein the starch is an amphipathic starch.
24. The paper or paperboard of Claim 11 wherein the starch is selected from the group consisting of corn starch, wheat starch, potato starch, rice starch, tapioca starch, and sago starch.
25. A method for forming a paper or paperboard comprising:
providing a papermaking furnish including cellulosic fibers;
forming a fibrous web from the papermaking furnish;
drying the web; and sizing the web by applying slurry to the web, the slung including starch solids and a boron-containing compound,
26. The method of Claim 24 further comprising calendering the web to provide a finished paper or paperboard.
27. The method of Claim 24 wherein the slurry is cooked to convert the starch prior to being applied to the web.
28. The method of Claim 24 wherein the amount of starch is equal to or less than about 200 lbs per ton of fiber.
29. The method of Claim 24 wherein the amount of boron containing compound is equal to or less than about 7% by weight of the starch.
30. The method of Claim 24 wherein the boron-containing compound is selected from the group consisting of boric acid and borate metal salts.
31. The method of Claim 29 wherein the boron-containing compound is selected from the group consisting of boric acid, borax, and zinc borate.
32. The method of Claim 29 wherein the boron-containing compound and the starch form a complex.
33. The method of Claim 29 wherein the starch is an anionic starch.
34. The method of Claim 29 wherein the starch is a cationic starch.
35. The method of Claim 29 wherein the starch is an amphipathic starch.
36. The method of Claim 29 wherein the starch is selected from the group consisting of corn starch, wheat starch, potato starch, rice starch, tapioca starch, and sago starch.
37. A paper or paperboard comprising a paper web comprising cellulosic fibers and having a sizing applied to the paper web, the sizing comprising starch solids and a boron-containing compound,
38. The paper or paperboard of Claim 36 wherein the amount of starch is equal to or less than about 200 lbs per ton of fiber.
39. The paper or paperboard of Claim 36 wherein the amount of boron containing compound is equal to or less than about 7%by weight of the starch.
40. The paper or paperboard of Claim 36 wherein the boron-containing compound is selected from the group consisting of boric acid and borate metal salts.
41. The paper or paperboard of Claim 39 wherein the boron-containing compound is selected from the group consisting of boric acid, borax, and zinc borate.
42. The paper or paperboard of Claim 36 wherein the boron-containing compound and the starch form a complex.
43. The paper or paperboard of Claim 36 wherein the starch is an anionic starch.
44. The paper or paperboard of Claim 36 wherein the starch is a cationic starch.
45. The paper or paperboard of Claim 36 wherein the starch is an amphipathic starch.
46. The paper or paperboard of Claim 36 wherein the starch is selected from the group consisting of corn starch, wheat starch, potato starch, rice starch, tapioca starch, and sago starch.
47. The paper or paperboard of Claim 14 wherein the major portion of the boron-containing com-pound and the starch is at or near the surfaces of said web.
48. The paper or paperboard of Claim 14 wherein the major portion of the boron-containing compound and the starch is distributed throughout said web.
CA2513488A 2002-09-17 2003-09-17 Papers comprising a boron-containing compound and a method of making same Expired - Fee Related CA2513488C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41131902P 2002-09-17 2002-09-17
US60/411,319 2002-09-17
PCT/IB2003/003983 WO2004027149A1 (en) 2002-09-17 2003-09-17 Papers comprising a boron-containing compound and a method of making same

Publications (2)

Publication Number Publication Date
CA2513488A1 true CA2513488A1 (en) 2004-04-01
CA2513488C CA2513488C (en) 2010-12-07

Family

ID=32030663

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2513488A Expired - Fee Related CA2513488C (en) 2002-09-17 2003-09-17 Papers comprising a boron-containing compound and a method of making same

Country Status (8)

Country Link
EP (1) EP1540081B1 (en)
CN (2) CN102767114A (en)
AT (1) ATE478196T1 (en)
AU (1) AU2003260833A1 (en)
BR (1) BR0314311A (en)
CA (1) CA2513488C (en)
DE (1) DE60333841D1 (en)
WO (1) WO2004027149A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7608166B2 (en) * 2003-09-17 2009-10-27 International Paper Company Papers having borate-based complexing and method of making same
AT413549B (en) * 2003-11-03 2006-03-15 Spezialpappenfabrik Rosegg Bet NEW PAPER, CARTON BZW. CARDBOARD MATERIAL
CA2628310C (en) * 2005-11-04 2013-12-31 Jagannadh V. Satyavolu Lecithin-containing starch compositions, preparation thereof and paper products having oil and grease resistance, and/or release properties
WO2011057044A2 (en) 2009-11-06 2011-05-12 Hercules Incorporated Surface application of polymers and polymer mixtures to improve paper strength
CA2813996C (en) 2010-11-05 2015-01-27 Hercules Incorporated Surface application of polymers to improve paper strength
CN103966890B (en) * 2013-02-05 2017-03-22 金东纸业(江苏)股份有限公司 papermaking process
CN103966886A (en) * 2013-02-05 2014-08-06 金东纸业(江苏)股份有限公司 Papermaking technology
CN103966892A (en) * 2013-02-05 2014-08-06 金东纸业(江苏)股份有限公司 Papermaking auxiliary agent, papermaking process and paper product
CN103966894A (en) * 2013-02-05 2014-08-06 金东纸业(江苏)股份有限公司 Papermaking process
US8801899B1 (en) * 2013-09-06 2014-08-12 International Paper Company Paperboards having improved bending stiffness and method for making same
CN106661843A (en) 2014-07-03 2017-05-10 巴斯夫欧洲公司 Aqueous surface-coating agent for paper and paperboard
CN104389238A (en) * 2014-10-09 2015-03-04 金东纸业(江苏)股份有限公司 Papermaking method and sized paper and coated paper obtained by papermaking method
CN107663813A (en) * 2016-07-29 2018-02-06 华南理工大学 A kind of damp-prrof packing paper and compound glue application solution and their preparation method
EP4303358A1 (en) 2022-07-04 2024-01-10 Eti Maden Isletmeleri Genel Mudurlugu The use of boron compounds in paper pulping, paper production and caustic recovery

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3112214A (en) * 1962-10-24 1963-11-26 Corn Products Co Process for sizing cellulose sheets with a starch derivative bearing vicinalglycol groups
US3740253A (en) * 1968-12-13 1973-06-19 T Hattori Method for the manufacture of a highly water resistant paper
JPS59144696A (en) * 1983-02-07 1984-08-18 荒川化学工業株式会社 Paper size agent
FI72557C (en) * 1984-01-11 1992-01-08 Kemira Oy Paper making process and blend composition for use therein
JPH0647826A (en) * 1992-07-29 1994-02-22 Nitto Boseki Co Ltd Manufacture of fiber plate for building
TW268970B (en) * 1994-08-16 1996-01-21 Cheng Loong Co Ltd Paper adhesive with improved wet adhesion strength and its production process
KR100362082B1 (en) * 1999-12-17 2002-11-23 한국조폐공사 Process for preparing paper having good strength, dimensional stability and antibacterial property
JP2002266285A (en) * 2001-02-27 2002-09-18 Unitika Chem Co Ltd Paper coating agent and method for producing coated paper

Also Published As

Publication number Publication date
EP1540081A1 (en) 2005-06-15
CN102767114A (en) 2012-11-07
EP1540081B1 (en) 2010-08-18
CA2513488C (en) 2010-12-07
WO2004027149A1 (en) 2004-04-01
DE60333841D1 (en) 2010-09-30
AU2003260833A1 (en) 2004-04-08
BR0314311A (en) 2005-07-26
ATE478196T1 (en) 2010-09-15
CN1705797A (en) 2005-12-07

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Effective date: 20140917