CA2508698A1 - Ni-based single crystal super alloy - Google Patents

Ni-based single crystal super alloy Download PDF

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Publication number
CA2508698A1
CA2508698A1 CA002508698A CA2508698A CA2508698A1 CA 2508698 A1 CA2508698 A1 CA 2508698A1 CA 002508698 A CA002508698 A CA 002508698A CA 2508698 A CA2508698 A CA 2508698A CA 2508698 A1 CA2508698 A1 CA 2508698A1
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single crystal
based single
super alloy
crystal super
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CA002508698A
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French (fr)
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CA2508698C (en
Inventor
Toshiharu Kobayashi
Yutaka Koizumi
Tadaharu Yokokawa
Hiroshi Harada
Yasuhiro Aoki
Mikiya Arai
Shoju Masaki
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IHI Corp
National Institute for Materials Science
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/057Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

The object of the present invention is to provide an Ni-based single crystal super alloy capable of improving strength by preventing precipitation of a TCP phase at high temperatures.
This object is achieved by an Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 1.1-4.5 wt% of Mo, 4.0-10.0 wt% of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co and 4.1-14.0 wt% of Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities.

Claims (24)

1. An Ni-single crystal super alloy having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 1.1-4.5 wt% of Mo, 4.0-10.0 wt% of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf,
2.0-5.0 w% of Cr, 0-9.9 wt% of Co and 4.1-14.0 wt% of Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities.

2. An Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt% of Al, 4.0-6.0 wt% of Ta, 1.1-4.5 wt% of Mo, 4.0-10.0 wt% of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5.0 wt% of Cr, 0.9.9 wt% of Co, and 4.1-14.0 wt% of Ru in terms of weight ratio, with the remainder consisting of Ni and unavoidable impurities.
3. An Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt% of Al,
4.0-6.0 wt% of Ta, 2.9-4.5 wt% of Mo, 4.0-10.0 wt% of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co and 4.1-14.0 wt% of Ru in terms of weight ratio, with the remainder consisting of Ni and unavoidable impurities.

4. An Ni-based single crystal super alloy according to anyone of clams 1 to 3 having a composition comprising 5.9 wt% of Al, 5.9 wt% of Ta, 3.9 wt% of Mo, 5.9 wt% of W, 4.9 wt% of Re, 0.10 wt% of Hf, 2.9 wt% of Cr, 5.9 wt% of Co and 5.0 wt% of Ru in terms of weight ratio, with the remainder consisting of Ni and unavoidable impurities.
5. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.8 wt% of Al, 5.6 wt% of Ta 3.1 wt% of Mo, 5.8 wt% of W, 4.9 wt% of Re, 0.10 wt% of Hf, 2.9 wt% of Cr, 5.8 wt% of Co and 5.0 wt% of Ru in terms of weight ratio, with the remainder consisting of Ni and unavoidable impurities.
6. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.8 wt% of Al, 5.8 wt% of Ta, 3.9 wt% of Mo, 5.8 wt% of W, 4.9 wt% of Re, 0.10 wt% of Hf, 2.9 wt% of Cr, 5.8 wt% of Co and 6.0 wt% of Ru in terms of weight ratio, with the remainder consisting of Ni and unavoidable impurities.
7. An Ni-based single crystal super alloy according to anyone of claims 1 to 6 further comprising 0-2.0 wt% of Ti in terms of weight ratio.
8. An Ni-based single crystal super alloy according to anyone of claims 1 to 7 further comprising 0-4.0 wt% of Nb in terms of weight ratio.
9, An Ni-based single crystal super alloy according to anyone of claims 1 to 8 further comprising at least one of elements selected from B, C, Si, Y, La, Ce, V and Zr.
10. An Ni-based single crystal super alloy according to claim 9 having a composition comprising 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% ar less of La, 0.1 wt% or less of Ce, l wt% or less of V and 0.1 wt% or less of Zr in terms of weight ratio.
11. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 1.1-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt%/a of Hf, 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co,10.0-14.0 wt%
of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% ar less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0,1 wt% or less of La, 0.1 wt% or less of Ce, l wt% or less of V and 0.1 wt% or less of Zr.
12. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.8-7.0 wt% of Al, 4.0-5.6 wt% of Ta, 3.3-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 w% of Re, 0-0.50 wt% of Hf, 2.9-4,3 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La, 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
13. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 1.1-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.9-5.0 wt% of Cr, 0-9.9 wt% of Co, 6.5-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La, 0,1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
14. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-6.0 wt% of Ta, 3.3-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La, 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
15. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-5.6 wt% of Ta, 3.3-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
16. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7,0 wt% of Al, 4.0-10.0 wt% of Ta, 3.1-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La, 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
17. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.8-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 3.1-4.5 wt% of MO, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2.0-5,0 wt% of Cr, 0-9.9 wt:% of Co, 4.1-14.0 wt% of Ru, 4.0 wt% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt% or less of Y, 0.1 wt% or less of La, 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
18. An Ni-based single crystal super alloy according to anyone of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta, 3.1-4.5 wt% of Mo, 4.0-10.0 wt%
of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf, 2,9.3 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru. 4.0 wr% or less of Nb, 2.0 wt% or less of Ti, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0,1 wt% or legs of Y, 0.1 wt% or less of La, 0.1 wt% or less of Ce, 1 wt% or less of V and 0.1 wt% or less of Zr.
19. An Ni-based single crystal super alloy according to anymore of claims 1 to 3 having a composition comprising 5.0-7.0 wt% of Al, 4.0-10.0 wt% of Ta+Nb+Ti, 3.3.5 wt%
of Mo, 4.0-10.0 w% of W, 3.1-8.0 wt% of Re, 0-0.50 wt% of Hf 2.0-5.0 wt% of Cr, 0-9.9 wt% of Co, 4.1-14.0 wt% of Ru, 0.05 wt% or less of B, 0.15 wt% or less of C, 0.1 wt% or less of Si, 0.1 wt%
or less of Y, 0.1 wt% or less of La 0.1 wt% or less of Ce, 1 wt% or less of V
and 0.1 wt% or less of Zr..
20. An Ni-based single crystal super alloy according to anyone of claims 1 to 19 wherein when lattice constant of mix is taken to be a1 and lattice constant of precipitation phase is taken to be a2, a2 <= 0.999x1.
21. An Ni-based single crystal super alloy according to claim 20 wherein the lattice constant of the precipitation phase a2 is 0.9965 or less of the lattice constant of the matrix al.
22. An Ni-based single crystal super alloy, wherein lattice constant of its precipitation phase a2 is 0.9965 or less of lattice constant of its matrix a1, and having a composition including Re and Ru, and 2.9-4.5 wt% of Mo.
23. An Ni-based single crystal super alloy, wherein lattice constant of its precipitation phase a2 is 0.9965 or less of lattice constant of its matrix al, and having a composition including 2.9.5 wt% of Mo, 3.1-8.0 wt% of Re and 4.1-14.0 wt% of Ru.
24. An Ni-based single crystal super alloy according to anyone of claims 1 to 23 wherein a dislocation space of the alloy is 40 nm or less.
CA2508698A 2002-12-06 2003-12-05 Ni-based single crystal super alloy Expired - Lifetime CA2508698C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2002-355756 2002-12-06
JP2002355756 2002-12-06
PCT/JP2003/015619 WO2004053177A1 (en) 2002-12-06 2003-12-05 Ni-BASE SINGLE CRYSTAL SUPERALLOY

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CA2508698A1 true CA2508698A1 (en) 2004-06-24
CA2508698C CA2508698C (en) 2012-05-15

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US (1) US20060011271A1 (en)
EP (1) EP1568794B1 (en)
JP (1) JP3814662B2 (en)
CN (1) CN100357467C (en)
AU (1) AU2003289214A1 (en)
CA (1) CA2508698C (en)
DE (1) DE60326083D1 (en)
WO (1) WO2004053177A1 (en)

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Publication number Publication date
CN1745186A (en) 2006-03-08
EP1568794A1 (en) 2005-08-31
AU2003289214A8 (en) 2004-06-30
JP3814662B2 (en) 2006-08-30
EP1568794B1 (en) 2009-02-04
JPWO2004053177A1 (en) 2006-04-13
DE60326083D1 (en) 2009-03-19
CN100357467C (en) 2007-12-26
CA2508698C (en) 2012-05-15
AU2003289214A1 (en) 2004-06-30
US20060011271A1 (en) 2006-01-19
EP1568794A4 (en) 2006-11-02
WO2004053177A1 (en) 2004-06-24

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