CA2496994A1 - Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions - Google Patents
Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions Download PDFInfo
- Publication number
- CA2496994A1 CA2496994A1 CA002496994A CA2496994A CA2496994A1 CA 2496994 A1 CA2496994 A1 CA 2496994A1 CA 002496994 A CA002496994 A CA 002496994A CA 2496994 A CA2496994 A CA 2496994A CA 2496994 A1 CA2496994 A1 CA 2496994A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- softening
- composition
- weight
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Landscapes
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Sanitary Thin Papers (AREA)
Abstract
Disclosed is a composition for softening an absorbent tissue comprising a quaternary ammonium softening active ingredient; free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio greater than about 0.06 and less than about 0.2; and a vehicle in which said softening active ingredient is dispersed. Also disclosed is a tissue paper product having such a composition deposited thereon.
Claims (10)
1. A composition for softening an absorbent tissue comprising:
a) a quaternary ammonium softening active ingredient, preferably selected from the group consisting of quaternary compounds; mono-, di-, and tri-ester quaternary ammonium compounds, and mixtures thereof, preferably wherein the softening active ingredient comprises at least about 10% by weight of the composition and no more than about 60% by weight of the composition, more preferably at least about 25%
and no more than about 45%.;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.06 and less than about 0.2, preferably greater than about 0.08 and less than about 0.18; and c) a vehicle in which said softening active ingredient is dispersed, preferably the vehicle is water.
a) a quaternary ammonium softening active ingredient, preferably selected from the group consisting of quaternary compounds; mono-, di-, and tri-ester quaternary ammonium compounds, and mixtures thereof, preferably wherein the softening active ingredient comprises at least about 10% by weight of the composition and no more than about 60% by weight of the composition, more preferably at least about 25%
and no more than about 45%.;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.06 and less than about 0.2, preferably greater than about 0.08 and less than about 0.18; and c) a vehicle in which said softening active ingredient is dispersed, preferably the vehicle is water.
2. The composition according to any of the preceding claims wherein said softening active ingredient is a mono-, di-, or tri-ester quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y
is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 3;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably selected from the group consisting of chloride or methyl sulfate..
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y
is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 3;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably selected from the group consisting of chloride or methyl sulfate..
3. The composition according to any of the preceding claims further comprising from about 2% to about 75%, preferably from about 5% to about 50%, by weight of a plasticizer.
4. The composition according to any of the preceding claims 1 further comprising up to about 25%, preferably from about 0.1% to about 10%, by weight of an electrolyte.
5. The composition according to any of the preceding claims further comprising from about 1% to about 20% by weight of a bilayer disrupter.
6. The composition according to any of the preceding claims further comprising from about 0.01% to about 5% by weight of a high polymer.
7. A soft tissue paper product, said soft tissue paper product comprising:
a) one or more plies of a tissue paper; and b) a chemical softening composition deposited on at least one outer surface of said tissue, said chemical softening composition comprising:
i) a softening active ingredient, preferably the softening active ingredient is a quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 2;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably X- is selected from the group consisting of chloride or methyl sulfate ii) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than 0.06 and less than about 0.2;
and iii) a vehicle.
a) one or more plies of a tissue paper; and b) a chemical softening composition deposited on at least one outer surface of said tissue, said chemical softening composition comprising:
i) a softening active ingredient, preferably the softening active ingredient is a quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 2;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably X- is selected from the group consisting of chloride or methyl sulfate ii) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than 0.06 and less than about 0.2;
and iii) a vehicle.
8. The tissue paper according to Claim 7 wherein the softening composition comprises:
a) from about 25% to about 45% by weight of a quaternary ammonium softening active ingredient;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.08 and less than about 0.18;
c) from about 5% to about 50% by weight of a plasticizer;
d) from about 0.1% to about 10% by weight of an electrolyte; and e) a vehicle consisting of water, in which said softening active ingredient is dispersed.
a) from about 25% to about 45% by weight of a quaternary ammonium softening active ingredient;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.08 and less than about 0.18;
c) from about 5% to about 50% by weight of a plasticizer;
d) from about 0.1% to about 10% by weight of an electrolyte; and e) a vehicle consisting of water, in which said softening active ingredient is dispersed.
9. The tissue paper of Claim 8 wherein said chemical softening composition further comprises a high polymer.
10. The tissue paper according to any of Claims 7 through 9 wherein said chemical softening composition is deposited as uniform, discrete surface deposits, spaced apart at a frequency between about 5 areas per lineal inch and about 100 areas per lineal inch.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/251,295 US7311853B2 (en) | 2002-09-20 | 2002-09-20 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
US10/251,295 | 2002-09-20 | ||
PCT/US2003/029838 WO2004027148A2 (en) | 2002-09-20 | 2003-09-18 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2496994A1 true CA2496994A1 (en) | 2004-04-01 |
CA2496994C CA2496994C (en) | 2010-07-13 |
Family
ID=31992704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2496994A Expired - Fee Related CA2496994C (en) | 2002-09-20 | 2003-09-18 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
Country Status (12)
Country | Link |
---|---|
US (1) | US7311853B2 (en) |
EP (1) | EP1546456A2 (en) |
JP (1) | JP2005538808A (en) |
CN (1) | CN1308547C (en) |
AR (1) | AR041324A1 (en) |
AU (1) | AU2003276907B2 (en) |
CA (1) | CA2496994C (en) |
MX (1) | MXPA05002299A (en) |
PE (1) | PE20040355A1 (en) |
SA (1) | SA03240382A (en) |
TW (1) | TW200422491A (en) |
WO (1) | WO2004027148A2 (en) |
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US20080271867A1 (en) * | 2007-05-03 | 2008-11-06 | The Procter & Gamble Company | Soft tissue paper having a chemical softening agent applied onto a surface thereof |
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US8968517B2 (en) | 2012-08-03 | 2015-03-03 | First Quality Tissue, Llc | Soft through air dried tissue |
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US10538882B2 (en) | 2015-10-13 | 2020-01-21 | Structured I, Llc | Disposable towel produced with large volume surface depressions |
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US11220394B2 (en) | 2015-10-14 | 2022-01-11 | First Quality Tissue, Llc | Bundled product and system |
US20170121911A1 (en) * | 2015-11-04 | 2017-05-04 | Georgia-Pacific Consumer Products Lp | Tissue softness by waterless chemistry application and processes thereof |
MX2018009679A (en) | 2016-02-11 | 2019-07-04 | Belt or fabric including polymeric layer for papermaking machine. | |
CA3015649C (en) * | 2016-02-29 | 2022-08-16 | Kemira Oyj | A softener composition |
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-
2002
- 2002-09-20 US US10/251,295 patent/US7311853B2/en not_active Expired - Fee Related
-
2003
- 2003-09-18 JP JP2004538403A patent/JP2005538808A/en active Pending
- 2003-09-18 WO PCT/US2003/029838 patent/WO2004027148A2/en active Application Filing
- 2003-09-18 CA CA2496994A patent/CA2496994C/en not_active Expired - Fee Related
- 2003-09-18 MX MXPA05002299A patent/MXPA05002299A/en active IP Right Grant
- 2003-09-18 AU AU2003276907A patent/AU2003276907B2/en not_active Ceased
- 2003-09-18 CN CNB038222523A patent/CN1308547C/en not_active Expired - Fee Related
- 2003-09-18 EP EP03797921A patent/EP1546456A2/en not_active Withdrawn
- 2003-09-19 PE PE2003000960A patent/PE20040355A1/en not_active Application Discontinuation
- 2003-09-19 AR ARP030103415A patent/AR041324A1/en not_active Application Discontinuation
- 2003-09-22 TW TW092126081A patent/TW200422491A/en unknown
- 2003-11-11 SA SA03240382A patent/SA03240382A/en unknown
Also Published As
Publication number | Publication date |
---|---|
SA03240382A (en) | 2005-12-03 |
MXPA05002299A (en) | 2005-06-08 |
CN1681995A (en) | 2005-10-12 |
CA2496994C (en) | 2010-07-13 |
PE20040355A1 (en) | 2004-07-02 |
CN1308547C (en) | 2007-04-04 |
WO2004027148A2 (en) | 2004-04-01 |
JP2005538808A (en) | 2005-12-22 |
AU2003276907A1 (en) | 2004-04-08 |
US7311853B2 (en) | 2007-12-25 |
US20040057982A1 (en) | 2004-03-25 |
WO2004027148A3 (en) | 2004-07-29 |
AU2003276907B2 (en) | 2007-02-01 |
TW200422491A (en) | 2004-11-01 |
AR041324A1 (en) | 2005-05-11 |
EP1546456A2 (en) | 2005-06-29 |
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