CA2496994A1 - Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions - Google Patents
Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions Download PDFInfo
- Publication number
- CA2496994A1 CA2496994A1 CA002496994A CA2496994A CA2496994A1 CA 2496994 A1 CA2496994 A1 CA 2496994A1 CA 002496994 A CA002496994 A CA 002496994A CA 2496994 A CA2496994 A CA 2496994A CA 2496994 A1 CA2496994 A1 CA 2496994A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- softening
- composition
- weight
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Landscapes
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Sanitary Thin Papers (AREA)
Abstract
Disclosed is a composition for softening an absorbent tissue comprising a quaternary ammonium softening active ingredient; free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio greater than about 0.06 and less than about 0.2; and a vehicle in which said softening active ingredient is dispersed. Also disclosed is a tissue paper product having such a composition deposited thereon.
Claims (10)
1. A composition for softening an absorbent tissue comprising:
a) a quaternary ammonium softening active ingredient, preferably selected from the group consisting of quaternary compounds; mono-, di-, and tri-ester quaternary ammonium compounds, and mixtures thereof, preferably wherein the softening active ingredient comprises at least about 10% by weight of the composition and no more than about 60% by weight of the composition, more preferably at least about 25%
and no more than about 45%.;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.06 and less than about 0.2, preferably greater than about 0.08 and less than about 0.18; and c) a vehicle in which said softening active ingredient is dispersed, preferably the vehicle is water.
a) a quaternary ammonium softening active ingredient, preferably selected from the group consisting of quaternary compounds; mono-, di-, and tri-ester quaternary ammonium compounds, and mixtures thereof, preferably wherein the softening active ingredient comprises at least about 10% by weight of the composition and no more than about 60% by weight of the composition, more preferably at least about 25%
and no more than about 45%.;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.06 and less than about 0.2, preferably greater than about 0.08 and less than about 0.18; and c) a vehicle in which said softening active ingredient is dispersed, preferably the vehicle is water.
2. The composition according to any of the preceding claims wherein said softening active ingredient is a mono-, di-, or tri-ester quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y
is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 3;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably selected from the group consisting of chloride or methyl sulfate..
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y
is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 3;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably selected from the group consisting of chloride or methyl sulfate..
3. The composition according to any of the preceding claims further comprising from about 2% to about 75%, preferably from about 5% to about 50%, by weight of a plasticizer.
4. The composition according to any of the preceding claims 1 further comprising up to about 25%, preferably from about 0.1% to about 10%, by weight of an electrolyte.
5. The composition according to any of the preceding claims further comprising from about 1% to about 20% by weight of a bilayer disrupter.
6. The composition according to any of the preceding claims further comprising from about 0.01% to about 5% by weight of a high polymer.
7. A soft tissue paper product, said soft tissue paper product comprising:
a) one or more plies of a tissue paper; and b) a chemical softening composition deposited on at least one outer surface of said tissue, said chemical softening composition comprising:
i) a softening active ingredient, preferably the softening active ingredient is a quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 2;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably X- is selected from the group consisting of chloride or methyl sulfate ii) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than 0.06 and less than about 0.2;
and iii) a vehicle.
a) one or more plies of a tissue paper; and b) a chemical softening composition deposited on at least one outer surface of said tissue, said chemical softening composition comprising:
i) a softening active ingredient, preferably the softening active ingredient is a quaternary ammonium compound having the formula:
(R1)4-m - N+ - [(CH2)n - Y - R3]m X-wherein Y is -O-(O)C-, or -C(O)-O-, or -NH-C(O)-, or -C(O)-NH-, preferably Y is -O-(O)C-, or -C(O)-O-;
m is 1 to 3, preferably equal to 2;
n is 0 to 4, preferably equal to 2;
each R1 is a C1-C6 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R1 is methyl;
each R3 is a C13-C21 alkyl or alkenyl group, hydroxyalkyl group, hydrocarbyl or substituted hydrocarbyl group, alkoxylated group, benzyl group, or mixtures thereof, preferably R3 is C15-C17 alkyl or alkenyl; and X is any softener-compatible anion, preferably X- is selected from the group consisting of chloride or methyl sulfate ii) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than 0.06 and less than about 0.2;
and iii) a vehicle.
8. The tissue paper according to Claim 7 wherein the softening composition comprises:
a) from about 25% to about 45% by weight of a quaternary ammonium softening active ingredient;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.08 and less than about 0.18;
c) from about 5% to about 50% by weight of a plasticizer;
d) from about 0.1% to about 10% by weight of an electrolyte; and e) a vehicle consisting of water, in which said softening active ingredient is dispersed.
a) from about 25% to about 45% by weight of a quaternary ammonium softening active ingredient;
b) free amine compounds at a level such that the softening composition has a tertiary to quaternary amine ratio of greater than about 0.08 and less than about 0.18;
c) from about 5% to about 50% by weight of a plasticizer;
d) from about 0.1% to about 10% by weight of an electrolyte; and e) a vehicle consisting of water, in which said softening active ingredient is dispersed.
9. The tissue paper of Claim 8 wherein said chemical softening composition further comprises a high polymer.
10. The tissue paper according to any of Claims 7 through 9 wherein said chemical softening composition is deposited as uniform, discrete surface deposits, spaced apart at a frequency between about 5 areas per lineal inch and about 100 areas per lineal inch.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/251,295 | 2002-09-20 | ||
| US10/251,295 US7311853B2 (en) | 2002-09-20 | 2002-09-20 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
| PCT/US2003/029838 WO2004027148A2 (en) | 2002-09-20 | 2003-09-18 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2496994A1 true CA2496994A1 (en) | 2004-04-01 |
| CA2496994C CA2496994C (en) | 2010-07-13 |
Family
ID=31992704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2496994A Expired - Fee Related CA2496994C (en) | 2002-09-20 | 2003-09-18 | Paper softening compositions containing quaternary ammonium compound and high levels of free amine and soft tissue paper products comprising said compositions |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7311853B2 (en) |
| EP (1) | EP1546456A2 (en) |
| JP (1) | JP2005538808A (en) |
| CN (1) | CN1308547C (en) |
| AR (1) | AR041324A1 (en) |
| AU (1) | AU2003276907B2 (en) |
| CA (1) | CA2496994C (en) |
| MX (1) | MXPA05002299A (en) |
| PE (1) | PE20040355A1 (en) |
| SA (1) | SA03240382A (en) |
| TW (1) | TW200422491A (en) |
| WO (1) | WO2004027148A2 (en) |
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| US20080271864A1 (en) * | 2007-05-03 | 2008-11-06 | The Procter & Gamble Company | Soft tissue paper having a chemical softening agent applied onto a surface thereof |
| US20080271867A1 (en) * | 2007-05-03 | 2008-11-06 | The Procter & Gamble Company | Soft tissue paper having a chemical softening agent applied onto a surface thereof |
| US8361278B2 (en) | 2008-09-16 | 2013-01-29 | Dixie Consumer Products Llc | Food wrap base sheet with regenerated cellulose microfiber |
| JP5833294B2 (en) * | 2010-03-26 | 2015-12-16 | 大王製紙株式会社 | Manufacturing method of tissue paper products |
| US8486427B2 (en) | 2011-02-11 | 2013-07-16 | Kimberly-Clark Worldwide, Inc. | Wipe for use with a germicidal solution |
| JP5800656B2 (en) * | 2011-09-29 | 2015-10-28 | 日本製紙クレシア株式会社 | Manufacturing method of sanitary paper |
| US8968517B2 (en) | 2012-08-03 | 2015-03-03 | First Quality Tissue, Llc | Soft through air dried tissue |
| MX2016014887A (en) | 2014-05-16 | 2018-03-01 | First Quality Tissue Llc | Flushable wipe and method of forming the same. |
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| US10273635B2 (en) | 2014-11-24 | 2019-04-30 | First Quality Tissue, Llc | Soft tissue produced using a structured fabric and energy efficient pressing |
| US9719213B2 (en) | 2014-12-05 | 2017-08-01 | First Quality Tissue, Llc | Towel with quality wet scrubbing properties at relatively low basis weight and an apparatus and method for producing same |
| US10099425B2 (en) | 2014-12-05 | 2018-10-16 | Structured I, Llc | Manufacturing process for papermaking belts using 3D printing technology |
| MX2018004621A (en) | 2015-10-13 | 2019-08-12 | First Quality Tissue Llc | Disposable towel produced with large volume surface depressions. |
| US10538882B2 (en) | 2015-10-13 | 2020-01-21 | Structured I, Llc | Disposable towel produced with large volume surface depressions |
| CN109328166A (en) | 2015-10-14 | 2019-02-12 | 上品纸制品有限责任公司 | The system and method for being bundled product and forming bundle product |
| US20170121911A1 (en) * | 2015-11-04 | 2017-05-04 | Georgia-Pacific Consumer Products Lp | Tissue softness by waterless chemistry application and processes thereof |
| JP2019504939A (en) | 2016-02-11 | 2019-02-21 | ストラクチャード アイ、エルエルシー | Belts or fabrics containing polymer layers for paper machines |
| PL3423632T3 (en) * | 2016-02-29 | 2020-11-16 | Kemira Oyj | A softener composition |
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-
2002
- 2002-09-20 US US10/251,295 patent/US7311853B2/en not_active Expired - Fee Related
-
2003
- 2003-09-18 EP EP03797921A patent/EP1546456A2/en not_active Withdrawn
- 2003-09-18 CN CNB038222523A patent/CN1308547C/en not_active Expired - Fee Related
- 2003-09-18 JP JP2004538403A patent/JP2005538808A/en active Pending
- 2003-09-18 CA CA2496994A patent/CA2496994C/en not_active Expired - Fee Related
- 2003-09-18 AU AU2003276907A patent/AU2003276907B2/en not_active Ceased
- 2003-09-18 WO PCT/US2003/029838 patent/WO2004027148A2/en active Application Filing
- 2003-09-18 MX MXPA05002299A patent/MXPA05002299A/en active IP Right Grant
- 2003-09-19 PE PE2003000960A patent/PE20040355A1/en not_active Application Discontinuation
- 2003-09-19 AR ARP030103415A patent/AR041324A1/en not_active Application Discontinuation
- 2003-09-22 TW TW092126081A patent/TW200422491A/en unknown
- 2003-11-11 SA SA03240382A patent/SA03240382A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SA03240382A (en) | 2005-12-03 |
| EP1546456A2 (en) | 2005-06-29 |
| PE20040355A1 (en) | 2004-07-02 |
| US7311853B2 (en) | 2007-12-25 |
| JP2005538808A (en) | 2005-12-22 |
| AU2003276907A1 (en) | 2004-04-08 |
| US20040057982A1 (en) | 2004-03-25 |
| AR041324A1 (en) | 2005-05-11 |
| CN1681995A (en) | 2005-10-12 |
| WO2004027148A2 (en) | 2004-04-01 |
| WO2004027148A3 (en) | 2004-07-29 |
| CN1308547C (en) | 2007-04-04 |
| AU2003276907B2 (en) | 2007-02-01 |
| TW200422491A (en) | 2004-11-01 |
| MXPA05002299A (en) | 2005-06-08 |
| CA2496994C (en) | 2010-07-13 |
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