CA2493965C - A soil resist agent comprising a polyfluorochemical organic compound and an anionic non-fluorinated surfactant - Google Patents
A soil resist agent comprising a polyfluorochemical organic compound and an anionic non-fluorinated surfactant Download PDFInfo
- Publication number
- CA2493965C CA2493965C CA2493965A CA2493965A CA2493965C CA 2493965 C CA2493965 C CA 2493965C CA 2493965 A CA2493965 A CA 2493965A CA 2493965 A CA2493965 A CA 2493965A CA 2493965 C CA2493965 C CA 2493965C
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- Prior art keywords
- salt
- carpet
- surfactant
- organic compound
- sulfonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 229940102838 methylmethacrylate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000004812 organic fluorine compounds Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- ZLMJMSJWJFRBEC-OUBTZVSYSA-N potassium-40 Chemical compound [40K] ZLMJMSJWJFRBEC-OUBTZVSYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/33—Esters containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/295—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/207,405 | 2002-07-29 | ||
| US10/207,405 US6740251B2 (en) | 2002-07-29 | 2002-07-29 | Fluorinated treatment for soil resistance |
| PCT/US2003/023815 WO2004011714A2 (en) | 2002-07-29 | 2003-07-29 | Fluorinated treatment for soil resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2493965A1 CA2493965A1 (en) | 2004-02-05 |
| CA2493965C true CA2493965C (en) | 2011-07-19 |
Family
ID=30770423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2493965A Expired - Lifetime CA2493965C (en) | 2002-07-29 | 2003-07-29 | A soil resist agent comprising a polyfluorochemical organic compound and an anionic non-fluorinated surfactant |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6740251B2 (enExample) |
| EP (1) | EP1540071B1 (enExample) |
| JP (1) | JP4500678B2 (enExample) |
| KR (1) | KR101043171B1 (enExample) |
| CN (1) | CN1671915B (enExample) |
| AU (1) | AU2003257022B2 (enExample) |
| BR (1) | BR0313030A (enExample) |
| CA (1) | CA2493965C (enExample) |
| MX (1) | MXPA05001016A (enExample) |
| WO (1) | WO2004011714A2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6824854B2 (en) * | 2002-07-29 | 2004-11-30 | E. I. Du Pont De Nemours And Company | Carpets treated for soil resistance |
| US7258925B2 (en) * | 2003-07-11 | 2007-08-21 | E.I. Du Pont De Nemours And Company | Fluorochemical finishes for paint applicators |
| US20090110840A1 (en) * | 2007-10-24 | 2009-04-30 | Peter Michael Murphy | Hydrophillic fluorinated soil resist copolymers |
| US7754092B2 (en) * | 2007-10-31 | 2010-07-13 | E.I. Du Pont De Nemours And Company | Soil resist additive |
| US7901589B2 (en) * | 2009-06-29 | 2011-03-08 | E.I. Du Pont De Nemours And Company | Propanediol soil resist compositions |
| US20130017398A1 (en) | 2011-07-15 | 2013-01-17 | E. I. Du Pont De Nemours And Company | Soil resist compositions |
| JP2015532949A (ja) * | 2012-09-19 | 2015-11-16 | インヴィスタ テクノロジーズ エスアエルエル | 撥水性かつ撥油性のｂｃｆ糸を作製するための過程 |
| WO2014047138A1 (en) * | 2012-09-19 | 2014-03-27 | Invista Technologies S.À R.L. | Processes to dye and treat bcf yarn |
| US10856437B2 (en) * | 2018-01-30 | 2020-12-01 | Quanta Computer Inc. | System for automatically classifying electrical devices for fan control application |
| KR102221452B1 (ko) | 2019-05-03 | 2021-03-02 | 주식회사 포스코 | 전단가공성이 우수한 초고강도 강판 및 그 제조방법 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3124605A (en) * | 1963-12-05 | 1964-03-10 | Biuret polyisocyanates | |
| US3923715A (en) | 1973-07-26 | 1975-12-02 | Du Pont | Aqueous dispersions of perfluoroalkyl esters and vinyl polymers for treating textiles |
| US4043923A (en) * | 1974-02-26 | 1977-08-23 | Minnesota Mining And Manufacturing Company | Textile treatment composition |
| NL7505229A (nl) | 1974-05-07 | 1975-11-11 | Hoechst Ag | Werkwijze en middel voor het vuilafstotend en antistatisch afwerken van vezelmateriaal. |
| US4140709A (en) | 1975-03-21 | 1979-02-20 | Diamond Shamrock Corporation | Anionic fluorochemical surfactants |
| DE2528258A1 (de) | 1975-06-25 | 1977-01-13 | Hoechst Ag | Verfahren und mittel zur ausruestung von fasermaterial |
| US4029585A (en) | 1975-07-26 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Aqueous dispersions of perfluoroalkyl esters for treating textiles |
| US5223340A (en) | 1989-04-20 | 1993-06-29 | Peach State Labs, Inc. | Stain resistant polyamide fibers |
| US5414111A (en) * | 1989-12-29 | 1995-05-09 | E. I. Du Pont De Nemours And Company | Polyfluoro nitrogen-containing organic compounds |
| US5411766A (en) | 1989-12-29 | 1995-05-02 | E. I. Du Pont De Nemours And Company | Substrates treated with polyfluoro nitrogen containing organic compounds |
| CA2032813C (en) * | 1989-12-29 | 2002-09-24 | Jack R. Kirchner | Polyfluoro nitrogen-containing organic compounds |
| US5410073A (en) | 1989-12-29 | 1995-04-25 | E. I. Du Pont De Nemours And Company | Manufacture of polyfluoro nitrogen containing organic compounds |
| US5580645A (en) * | 1989-12-29 | 1996-12-03 | E. I. Du Pont De Nemours And Company | Substrates treated with polyfluoro nitrogen-containing organic compounds |
| US5509939A (en) * | 1989-12-29 | 1996-04-23 | E. I. Du Pont De Nemours And Company | Soil-release process |
| US6048952A (en) | 1991-07-10 | 2000-04-11 | 3M Innovative Properties Company | Perfluoroalkyl halides and derivatives |
| US5534167A (en) * | 1994-06-13 | 1996-07-09 | S. C. Johnson & Son, Inc. | Carpet cleaning and restoring composition |
| US5714082A (en) | 1995-06-02 | 1998-02-03 | Minnesota Mining And Manufacturing Company | Aqueous anti-soiling composition |
| US5770656A (en) | 1995-09-22 | 1998-06-23 | E.I. Du Pont De Nemours And Company | Partial fluoroesters or thioesters of maleic acid polymers and their use as soil and stain resists |
| US5827919A (en) * | 1995-10-06 | 1998-10-27 | E. I. Du Pont De Nemours And Company | Fluorourethane additives for water-dispersed coating compositions |
| US5672651A (en) * | 1995-10-20 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Durable repellent fluorochemical compositions |
| US5712240A (en) | 1996-04-25 | 1998-01-27 | Reckitt & Colman Inc. | Aqueous cleaning compositions providing water and oil repellency to fiber substrates |
| GB2315783B (en) | 1996-07-27 | 2000-08-23 | Reckitt & Colman Inc | Cleaning composition imparting water and oil repellency |
| EP0934383A2 (en) | 1996-10-25 | 1999-08-11 | E.I. Du Pont De Nemours And Company | Cleaning formulation for fabricated yarn products |
| GB2321251B (en) | 1997-01-16 | 2001-03-14 | Reckitt & Colman Inc | Carpet cleaning and treatment compositions |
| US5948480A (en) | 1997-03-31 | 1999-09-07 | E.I. Du Pont De Nemours And Company | Tandem application of soil and stain resists to carpeting |
| US6197378B1 (en) | 1997-05-05 | 2001-03-06 | 3M Innovative Properties Company | Treatment of fibrous substrates to impart repellency, stain resistance, and soil resistance |
| JP3807130B2 (ja) | 1998-11-13 | 2006-08-09 | 旭硝子株式会社 | 水分散型防汚加工剤組成物 |
| US6117353A (en) | 1999-01-11 | 2000-09-12 | 3M Innovative Properties Company | High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion |
| US6479612B1 (en) * | 1999-08-10 | 2002-11-12 | E. I. Du Pont De Nemours And Company | Fluorochemical water and oil repellents |
| JP2001279578A (ja) | 2000-03-30 | 2001-10-10 | Daikin Ind Ltd | 繊維製品への撥水撥油処理 |
-
2002
- 2002-07-29 US US10/207,405 patent/US6740251B2/en not_active Expired - Lifetime
-
2003
- 2003-07-29 KR KR1020057001579A patent/KR101043171B1/ko not_active Expired - Fee Related
- 2003-07-29 MX MXPA05001016A patent/MXPA05001016A/es active IP Right Grant
- 2003-07-29 BR BR0313030-4A patent/BR0313030A/pt not_active IP Right Cessation
- 2003-07-29 CA CA2493965A patent/CA2493965C/en not_active Expired - Lifetime
- 2003-07-29 AU AU2003257022A patent/AU2003257022B2/en not_active Ceased
- 2003-07-29 JP JP2004524198A patent/JP4500678B2/ja not_active Expired - Fee Related
- 2003-07-29 CN CN038181185A patent/CN1671915B/zh not_active Expired - Fee Related
- 2003-07-29 WO PCT/US2003/023815 patent/WO2004011714A2/en not_active Ceased
- 2003-07-29 EP EP03772091A patent/EP1540071B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006501374A (ja) | 2006-01-12 |
| KR20050031462A (ko) | 2005-04-06 |
| EP1540071B1 (en) | 2011-11-09 |
| JP4500678B2 (ja) | 2010-07-14 |
| CA2493965A1 (en) | 2004-02-05 |
| US20040016901A1 (en) | 2004-01-29 |
| WO2004011714A2 (en) | 2004-02-05 |
| CN1671915B (zh) | 2010-05-26 |
| KR101043171B1 (ko) | 2011-06-20 |
| WO2004011714A3 (en) | 2004-04-01 |
| BR0313030A (pt) | 2005-07-12 |
| US6740251B2 (en) | 2004-05-25 |
| MXPA05001016A (es) | 2005-05-16 |
| AU2003257022A1 (en) | 2004-02-16 |
| HK1083113A1 (zh) | 2006-06-23 |
| AU2003257022B2 (en) | 2008-10-23 |
| EP1540071A2 (en) | 2005-06-15 |
| CN1671915A (zh) | 2005-09-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |