CA2463781C - Appareil et procede pour eliminer le phosphore des effluents d'un etang d'epuration - Google Patents
Appareil et procede pour eliminer le phosphore des effluents d'un etang d'epuration Download PDFInfo
- Publication number
- CA2463781C CA2463781C CA 2463781 CA2463781A CA2463781C CA 2463781 C CA2463781 C CA 2463781C CA 2463781 CA2463781 CA 2463781 CA 2463781 A CA2463781 A CA 2463781A CA 2463781 C CA2463781 C CA 2463781C
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- Prior art keywords
- crystallizer
- ammonia
- bed
- liquid
- struvite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 214
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 213
- 239000011574 phosphorus Substances 0.000 title claims abstract description 213
- 238000000034 method Methods 0.000 title claims abstract description 85
- 239000002699 waste material Substances 0.000 title claims abstract description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 517
- 239000011777 magnesium Substances 0.000 claims abstract description 378
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 256
- CKMXBZGNNVIXHC-UHFFFAOYSA-L ammonium magnesium phosphate hexahydrate Chemical compound [NH4+].O.O.O.O.O.O.[Mg+2].[O-]P([O-])([O-])=O CKMXBZGNNVIXHC-UHFFFAOYSA-L 0.000 claims abstract description 171
- 229910052567 struvite Inorganic materials 0.000 claims abstract description 171
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 92
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 91
- 239000002351 wastewater Substances 0.000 claims abstract description 65
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims description 344
- 239000002245 particle Substances 0.000 claims description 184
- 238000001556 precipitation Methods 0.000 claims description 77
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 81
- 238000004458 analytical method Methods 0.000 description 70
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 64
- 239000000463 material Substances 0.000 description 59
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 58
- 238000012360 testing method Methods 0.000 description 58
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- 238000002474 experimental method Methods 0.000 description 43
- 239000001569 carbon dioxide Substances 0.000 description 40
- 229910002092 carbon dioxide Inorganic materials 0.000 description 40
- 150000002500 ions Chemical class 0.000 description 40
- 229910019142 PO4 Inorganic materials 0.000 description 36
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- 229910052757 nitrogen Inorganic materials 0.000 description 31
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- 239000000395 magnesium oxide Substances 0.000 description 24
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- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
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- 101100083515 Mus musculus Plcb1 gene Proteins 0.000 description 3
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- 235000011010 calcium phosphates Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013400 design of experiment Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- ZMVCHCYEHYRAFI-UHFFFAOYSA-K dimagnesium;carbonate;hydroxide;trihydrate Chemical compound O.O.O.[OH-].[Mg+2].[Mg+2].[O-]C([O-])=O ZMVCHCYEHYRAFI-UHFFFAOYSA-K 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 239000006052 feed supplement Substances 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003295 industrial effluent Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- QQFLQYOOQVLGTQ-UHFFFAOYSA-L magnesium;dihydrogen phosphate Chemical compound [Mg+2].OP(O)([O-])=O.OP(O)([O-])=O QQFLQYOOQVLGTQ-UHFFFAOYSA-L 0.000 description 1
- YQRTZUSEPDULET-UHFFFAOYSA-K magnesium;potassium;phosphate Chemical compound [Mg+2].[K+].[O-]P([O-])([O-])=O YQRTZUSEPDULET-UHFFFAOYSA-K 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000004590 silicone sealant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5209—Regulation methods for flocculation or precipitation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/006—Water distributors either inside a treatment tank or directing the water to several treatment tanks; Water treatment plants incorporating these distributors, with or without chemical or biological tanks
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Removal Of Specific Substances (AREA)
Abstract
L'invention concerne un appareil (10) et un procédé pour éliminer le phosphore d'un débit d'effluents d'eaux usées (16) provenant d'un étang d'épuration d'effluents porcins. Le débit d'effluents d'eaux usées (16) est placé au fond d'un cristallisoir continu en forme de cône inversé (12) contenant un lit fluidisé de struvite. Une quantité efficace d'ammoniac (20) est introduite dans les effluents (16), au fond du cristallisoir (12), pour en augmenter le pH d'une valeur préétablie. Une quantité efficace de magnésium (18) est également introduite dans les effluents (16), au fond du cristallisoir (12). Les effluents d'eaux usées, dont la composition est rajustée, sont ensuite circulés en continu vers le haut, au travers du lit fluidisé de struvite, afin de réduire la teneur totale en phosphore des effluents (16) d'une quantité préétablie d'environ 80 % ou plus. Le débit d'effluents d'eaux usées traité (24) est retiré du sommet du cristallisoir (12), et les cristaux de struvite suffisamment grands pour s'enfoncer du fond du cristallisoir (12) sont périodiquement retirés du collecteur (22) situé sous le cristallisoir.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/659,239 US6994782B2 (en) | 2003-09-09 | 2003-09-09 | Apparatus for removing phosphorus from waste lagoon effluent |
| US10/659,239 | 2003-09-09 | ||
| PCT/US2003/029330 WO2004024637A1 (fr) | 2002-09-13 | 2003-09-15 | Appareil et procede pour eliminer le phosphore des effluents d'un etang d'epuration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2463781A1 CA2463781A1 (fr) | 2004-03-25 |
| CA2463781C true CA2463781C (fr) | 2013-12-31 |
Family
ID=34622386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2463781 Expired - Lifetime CA2463781C (fr) | 2003-09-09 | 2003-09-15 | Appareil et procede pour eliminer le phosphore des effluents d'un etang d'epuration |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2003275019A1 (fr) |
| CA (1) | CA2463781C (fr) |
| WO (1) | WO2004024637A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MA34312B1 (fr) * | 2010-05-18 | 2013-06-01 | Ostara Nutrient Recovery Technologies Inc | Traitement d'eaux usées contenant des phosphates |
| FR2962433B1 (fr) * | 2010-07-08 | 2014-02-07 | Naskeo Environnement | Production d'un compose solide utilisable en tant qu'intrant agricole |
| CN102616966B (zh) * | 2012-04-09 | 2013-06-05 | 河海大学 | 一种地下水除氟装置及除氟方法 |
| CN104944561B (zh) * | 2015-06-16 | 2017-11-24 | 景德镇陶瓷大学 | 一种基于菱镁石的废水脱氮除磷方法 |
| CN106706485B (zh) * | 2017-02-15 | 2023-06-06 | 辽宁科技大学 | 一种快速粒度测量壶及测量方法 |
| CN108358294A (zh) * | 2018-05-04 | 2018-08-03 | 谢晓进 | 畜禽养殖污水提取磷肥的设备及其使用方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3892539A (en) * | 1969-09-26 | 1975-07-01 | Merck & Co Inc | Process for production of crystals in fluidized bed crystallizers |
| NL187312C (nl) * | 1978-05-18 | 1991-08-16 | Dhv Raadgevend Ing | Werkwijze voor het defosfateren van water. |
| US5360546A (en) * | 1992-04-01 | 1994-11-01 | Ngk Insulators, Ltd. | Method for treating organic sludge |
| US6287471B1 (en) * | 1998-03-09 | 2001-09-11 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Treatment of aqueous effluents by injection of carbon dioxide |
| AU6144600A (en) * | 1999-07-20 | 2001-02-05 | Zenon Environmental Inc. | Biological process for removing phosphorus involving a membrane filter |
-
2003
- 2003-09-15 WO PCT/US2003/029330 patent/WO2004024637A1/fr active Application Filing
- 2003-09-15 CA CA 2463781 patent/CA2463781C/fr not_active Expired - Lifetime
- 2003-09-15 AU AU2003275019A patent/AU2003275019A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2463781A1 (fr) | 2004-03-25 |
| WO2004024637A1 (fr) | 2004-03-25 |
| AU2003275019A1 (en) | 2004-04-30 |
| WO2004024637A9 (fr) | 2004-05-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20230915 |