CA2432200A1 - Catalyst with bimodal pore radius distribution - Google Patents

Catalyst with bimodal pore radius distribution Download PDF

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Publication number
CA2432200A1
CA2432200A1 CA002432200A CA2432200A CA2432200A1 CA 2432200 A1 CA2432200 A1 CA 2432200A1 CA 002432200 A CA002432200 A CA 002432200A CA 2432200 A CA2432200 A CA 2432200A CA 2432200 A1 CA2432200 A1 CA 2432200A1
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CA
Canada
Prior art keywords
pore radius
catalyst
radius distribution
bimodal pore
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002432200A
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French (fr)
Other versions
CA2432200C (en
Inventor
Daniel Heineke
Klaus Harth
Uwe Stabel
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BASF SE
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Individual
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Publication of CA2432200A1 publication Critical patent/CA2432200A1/en
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Publication of CA2432200C publication Critical patent/CA2432200C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Catalysts with bimodal pore radius distribution, comprising a) 10 to 99.9 wt.
% zirconium dioxide, b) 0 to 60 wt. % aluminium oxide, silicon dioxide and/or titanium dioxide and c) 0.1 to 10 wt. % of at least one element of the first or second main group, an element of the third sub-group, an element of the eighth sub-group of the periodic element system, lanthanum and/or zinc, with the proviso that the total of the weight percentages is 100.
CA002432200A 2000-12-22 2000-12-22 Catalyst with bimodal pore radius distribution Expired - Fee Related CA2432200C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2000/013160 WO2002051547A1 (en) 2000-12-22 2000-12-22 Catalyst with bimodal pore radius distribution

Publications (2)

Publication Number Publication Date
CA2432200A1 true CA2432200A1 (en) 2002-07-04
CA2432200C CA2432200C (en) 2007-06-26

Family

ID=8164221

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002432200A Expired - Fee Related CA2432200C (en) 2000-12-22 2000-12-22 Catalyst with bimodal pore radius distribution

Country Status (10)

Country Link
EP (1) EP1351765B1 (en)
JP (1) JP4148775B2 (en)
KR (1) KR100679001B1 (en)
BR (1) BR0017392B1 (en)
CA (1) CA2432200C (en)
DK (1) DK1351765T3 (en)
DZ (1) DZ3488A1 (en)
EA (1) EA007454B1 (en)
MX (1) MXPA03005017A (en)
WO (1) WO2002051547A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7932408B2 (en) 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
CN115888681A (en) * 2022-12-23 2023-04-04 南京克米斯璀新能源科技有限公司 Catalyst for isomerizing cis-m-pentadiene into trans-m-pentadiene and preparation method and application thereof

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10219879A1 (en) * 2002-05-03 2003-11-20 Basf Ag Catalyst support and process for its manufacture
JP4562360B2 (en) * 2003-07-18 2010-10-13 旭化成株式会社 Porous crystalline zirconia material and method for producing the same
WO2007033934A2 (en) * 2005-09-20 2007-03-29 Basf Se Method for determining tortuosity, catalyst support, catalyst, and method for dehydrogenating hydrocarbons
KR101218453B1 (en) * 2008-12-30 2013-01-04 주식회사 효성 dehydrogenation catalyst
KR101440694B1 (en) * 2012-12-27 2014-09-25 삼성토탈 주식회사 A catalyst for dehydrogenation and dehydroisomerization of n-butane and a method for producing a mixture of n-butane, 1,3-butadiene and iso-butene in high yield using the same
CN109384639B (en) * 2017-08-07 2021-05-11 中国石油化工股份有限公司 Propane dehydrogenation catalyst, preparation method thereof and method for preparing propylene by propane dehydrogenation
CN113839047B (en) * 2020-06-24 2023-01-24 中国石油化工股份有限公司 Organic liquid fuel cell electrode material, preparation method and application thereof, organic liquid fuel cell electrode and fuel cell

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3898155A (en) * 1973-12-19 1975-08-05 Gulf Research Development Co Heavy oil demetallization and desulfurization process
US3960710A (en) * 1974-11-08 1976-06-01 Universal Oil Products Company Hydrocarbon conversion with an acidic multimetallic catalytic composite
US4102822A (en) * 1976-07-26 1978-07-25 Chevron Research Company Hydrocarbon hydroconversion catalyst and the method for its preparation
US4549977A (en) * 1976-09-29 1985-10-29 Colgate-Palmolive Company Bottled particulate detergent
US4549957A (en) * 1981-06-17 1985-10-29 Amoco Corporation Hydrotreating catalyst and process
US4454026A (en) * 1981-06-17 1984-06-12 Standard Oil Company (Indiana) Hydrotreating catalyst and process
US4568655A (en) * 1984-10-29 1986-02-04 Mobil Oil Corporation Catalyst composition comprising Zeolite Beta
DE3918013A1 (en) * 1989-06-02 1990-12-06 Huels Chemische Werke Ag ZIRCONDIOXIDE POWDER, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR THE PRODUCTION OF SINTERED BODIES
DE3932780A1 (en) * 1989-09-30 1991-04-11 Huels Chemische Werke Ag ZIRCONDIOXIDE POWDER, METHOD FOR THE PRODUCTION THEREOF, THE USE THEREOF AND THE SINTER BODIES MADE THEREOF
US5221656A (en) * 1992-03-25 1993-06-22 Amoco Corporation Hydroprocessing catalyst
US5322821A (en) * 1993-08-23 1994-06-21 W. R. Grace & Co.-Conn. Porous ceramic beads
DE19533486A1 (en) * 1995-09-12 1997-03-13 Basf Ag Monomodal and polymodal catalyst supports and catalysts with narrow pore size distributions and their manufacturing processes
DE59706719D1 (en) * 1996-04-26 2002-05-02 Basf Ag Process for the reaction of an organic compound in the presence of a ruthenium catalyst formed in situ
DE19937107A1 (en) * 1999-08-06 2001-02-08 Basf Ag Catalyst with bimodal pore radius distribution
DE19937106A1 (en) * 1999-08-06 2001-02-08 Basf Ag Multicomponent catalysts

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7932408B2 (en) 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
US9101918B2 (en) 2006-09-29 2015-08-11 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
CN115888681A (en) * 2022-12-23 2023-04-04 南京克米斯璀新能源科技有限公司 Catalyst for isomerizing cis-m-pentadiene into trans-m-pentadiene and preparation method and application thereof

Also Published As

Publication number Publication date
DK1351765T3 (en) 2005-03-21
EA007454B1 (en) 2006-10-27
EA200300636A1 (en) 2003-12-25
KR100679001B1 (en) 2007-02-07
JP2004522570A (en) 2004-07-29
BR0017392A (en) 2004-02-03
EP1351765A1 (en) 2003-10-15
CA2432200C (en) 2007-06-26
DZ3488A1 (en) 2002-07-04
BR0017392B1 (en) 2014-09-30
WO2002051547A1 (en) 2002-07-04
EP1351765B1 (en) 2005-01-05
MXPA03005017A (en) 2003-09-25
KR20030072365A (en) 2003-09-13
JP4148775B2 (en) 2008-09-10

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