CA2428820A1 - Fire extinguishing methods utilizing hydrofluoroethers - Google Patents
Fire extinguishing methods utilizing hydrofluoroethers Download PDFInfo
- Publication number
- CA2428820A1 CA2428820A1 CA002428820A CA2428820A CA2428820A1 CA 2428820 A1 CA2428820 A1 CA 2428820A1 CA 002428820 A CA002428820 A CA 002428820A CA 2428820 A CA2428820 A CA 2428820A CA 2428820 A1 CA2428820 A1 CA 2428820A1
- Authority
- CA
- Canada
- Prior art keywords
- cf3cf
- fire
- fluorinated
- fire extinguishing
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims description 22
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- -1 CF3CF2CF2H Chemical compound 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 4
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 claims description 3
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims description 3
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims 4
- AQHKYFLVHBIQMS-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,3,3,3-hexafluoropropane Chemical compound COC(F)(F)C(C(F)(F)F)C(F)(F)F AQHKYFLVHBIQMS-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229910052794 bromium Inorganic materials 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
- 230000001629 suppression Effects 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920004449 Halon® Polymers 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- RJCQBQGAPKAMLL-UHFFFAOYSA-N bromotrifluoromethane Chemical compound FC(F)(F)Br RJCQBQGAPKAMLL-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- MEXUFEQDCXZEON-UHFFFAOYSA-N bromochlorodifluoromethane Chemical compound FC(F)(Cl)Br MEXUFEQDCXZEON-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- KVBKAPANDHPRDG-UHFFFAOYSA-N dibromotetrafluoroethane Chemical compound FC(F)(Br)C(F)(F)Br KVBKAPANDHPRDG-UHFFFAOYSA-N 0.000 description 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 125000004785 fluoromethoxy group Chemical group [H]C([H])(F)O* 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 231100000683 possible toxicity Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/12—Saturated ethers containing halogen
- C07C43/123—Saturated ethers containing halogen both carbon chains are substituted by halogen atoms
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0057—Polyhaloalkanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
- C07C41/22—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of halogens; by substitution of halogen atoms by other halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24968400P | 2000-11-17 | 2000-11-17 | |
| US60/249,684 | 2000-11-17 | ||
| PCT/US2001/044256 WO2002040102A2 (en) | 2000-11-17 | 2001-11-14 | Fire extinguishing methods utilizing hydrofluoroethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2428820A1 true CA2428820A1 (en) | 2002-05-23 |
Family
ID=22944548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002428820A Abandoned CA2428820A1 (en) | 2000-11-17 | 2001-11-14 | Fire extinguishing methods utilizing hydrofluoroethers |
Country Status (20)
| Country | Link |
|---|---|
| EP (1) | EP1333889B1 (enExample) |
| JP (1) | JP2004516871A (enExample) |
| KR (1) | KR100536885B1 (enExample) |
| CN (1) | CN1612765A (enExample) |
| AT (1) | ATE355874T1 (enExample) |
| AU (2) | AU2002237679B2 (enExample) |
| BR (1) | BR0115450A (enExample) |
| CA (1) | CA2428820A1 (enExample) |
| CZ (1) | CZ20031329A3 (enExample) |
| DE (1) | DE60127160T2 (enExample) |
| HU (1) | HUP0303867A2 (enExample) |
| IL (2) | IL155854A0 (enExample) |
| MX (1) | MXPA03004354A (enExample) |
| NO (1) | NO20032238L (enExample) |
| NZ (1) | NZ525864A (enExample) |
| PL (1) | PL361876A1 (enExample) |
| SK (1) | SK6002003A3 (enExample) |
| WO (1) | WO2002040102A2 (enExample) |
| YU (1) | YU38203A (enExample) |
| ZA (1) | ZA200303784B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7329786B2 (en) | 2001-09-28 | 2008-02-12 | Great Lakes Chemical Corporation | Processes for producing CF3CFHCF3 |
| US7223351B2 (en) * | 2003-04-17 | 2007-05-29 | Great Lakes Chemical Corporation | Fire extinguishing mixtures, methods and systems |
| US20050038302A1 (en) | 2003-08-13 | 2005-02-17 | Hedrick Vicki E. | Systems and methods for producing fluorocarbons |
| US9540316B2 (en) | 2013-07-25 | 2017-01-10 | 3M Innovative Properties Company | Nitrogen containing hydrofluoroethers and methods of making same |
| CN111433865B (zh) | 2017-12-13 | 2021-11-09 | 3M创新有限公司 | 电介质流体和电气装置中的全氟化1-烷氧基丙烯 |
| KR102730629B1 (ko) | 2017-12-13 | 2024-11-14 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 퍼플루오르화 1-알콕시프로펜, 조성물, 및 이를 사용하기 위한 방법 및 장치 |
| US11535579B2 (en) | 2017-12-13 | 2022-12-27 | 3M Innovative Properties Company | Hydrofluoroolefin ethers, compositions, apparatuses and methods for using same |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2730543A (en) * | 1950-05-20 | 1956-01-10 | Minnesota Mining & Mfg | Fluorinated nitriles |
| US3557294A (en) * | 1967-10-12 | 1971-01-19 | Allied Chem | Fluorinated ethers as inhalation convulsants |
| US3943256A (en) * | 1973-06-25 | 1976-03-09 | Baxter Laboratories, Inc. | Antipsychotic agents |
| US5278342A (en) * | 1992-03-25 | 1994-01-11 | Hampshire Chemical Corp. | Vapor phase chlorination of difluoromethyl methyl ether |
| US5605882A (en) * | 1992-05-28 | 1997-02-25 | E. I. Du Pont De Nemours And Company | Azeotrope(like) compositions of pentafluorodimethyl ether and difluoromethane |
| JP2589917B2 (ja) * | 1992-08-11 | 1997-03-12 | 工業技術院長 | １，１−ジフルオロエチル メチル エーテル及びその製造方法並びにそれを成分とする作動流体 |
| US5611210A (en) * | 1993-03-05 | 1997-03-18 | Ikon Corporation | Fluoroiodocarbon blends as CFC and halon replacements |
| JPH10506926A (ja) * | 1995-06-07 | 1998-07-07 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | ヒドロフルオロエーテルまたはフルオロエーテルをベースにした冷媒 |
| US5730894A (en) * | 1996-04-16 | 1998-03-24 | E. I. Du Pont De Nemours And Company | 1,1,2,2,3,3,4,4-octafluorobutane azeotropic (like) compositions |
| US6023002A (en) * | 1998-01-26 | 2000-02-08 | 3M Innovative Properties Company | Process for preparing hydrofluoroethers |
| JP4666855B2 (ja) * | 1999-07-20 | 2011-04-06 | スリーエム イノベイティブ プロパティズ カンパニー | 消火組成物中でのフッ素化ケトンの使用法 |
| US6849194B2 (en) * | 2000-11-17 | 2005-02-01 | Pcbu Services, Inc. | Methods for preparing ethers, ether compositions, fluoroether fire extinguishing systems, mixtures and methods |
-
2001
- 2001-11-14 JP JP2002542468A patent/JP2004516871A/ja active Pending
- 2001-11-14 EP EP01986486A patent/EP1333889B1/en not_active Expired - Lifetime
- 2001-11-14 WO PCT/US2001/044256 patent/WO2002040102A2/en not_active Ceased
- 2001-11-14 MX MXPA03004354A patent/MXPA03004354A/es active IP Right Grant
- 2001-11-14 CN CNA018190561A patent/CN1612765A/zh active Pending
- 2001-11-14 PL PL36187601A patent/PL361876A1/xx not_active IP Right Cessation
- 2001-11-14 KR KR10-2003-7006460A patent/KR100536885B1/ko not_active Expired - Fee Related
- 2001-11-14 HU HU0303867A patent/HUP0303867A2/hu unknown
- 2001-11-14 AU AU2002237679A patent/AU2002237679B2/en not_active Ceased
- 2001-11-14 NZ NZ525864A patent/NZ525864A/en unknown
- 2001-11-14 YU YU38203A patent/YU38203A/sh unknown
- 2001-11-14 CA CA002428820A patent/CA2428820A1/en not_active Abandoned
- 2001-11-14 IL IL15585401A patent/IL155854A0/xx active IP Right Grant
- 2001-11-14 DE DE60127160T patent/DE60127160T2/de not_active Expired - Fee Related
- 2001-11-14 AT AT01986486T patent/ATE355874T1/de not_active IP Right Cessation
- 2001-11-14 BR BR0115450-8A patent/BR0115450A/pt not_active Application Discontinuation
- 2001-11-14 CZ CZ20031329A patent/CZ20031329A3/cs unknown
- 2001-11-14 AU AU3767902A patent/AU3767902A/xx active Pending
- 2001-11-14 SK SK600-2003A patent/SK6002003A3/sk unknown
-
2003
- 2003-05-12 IL IL155854A patent/IL155854A/en not_active IP Right Cessation
- 2003-05-14 ZA ZA200303784A patent/ZA200303784B/en unknown
- 2003-05-16 NO NO20032238A patent/NO20032238L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030065510A (ko) | 2003-08-06 |
| AU3767902A (en) | 2002-05-27 |
| NO20032238L (no) | 2003-07-10 |
| KR100536885B1 (ko) | 2005-12-16 |
| HK1058013A1 (en) | 2004-04-30 |
| IL155854A (en) | 2007-10-31 |
| ZA200303784B (en) | 2004-08-16 |
| DE60127160T2 (de) | 2007-11-22 |
| ATE355874T1 (de) | 2007-03-15 |
| JP2004516871A (ja) | 2004-06-10 |
| BR0115450A (pt) | 2004-01-06 |
| IL155854A0 (en) | 2003-12-23 |
| SK6002003A3 (en) | 2003-11-04 |
| WO2002040102A3 (en) | 2003-05-30 |
| HUP0303867A2 (hu) | 2004-03-01 |
| MXPA03004354A (es) | 2005-01-25 |
| AU2002237679B2 (en) | 2007-08-16 |
| CN1612765A (zh) | 2005-05-04 |
| EP1333889A2 (en) | 2003-08-13 |
| NZ525864A (en) | 2005-01-28 |
| WO2002040102A2 (en) | 2002-05-23 |
| DE60127160D1 (de) | 2007-04-19 |
| NO20032238D0 (no) | 2003-05-16 |
| YU38203A (sh) | 2005-11-28 |
| EP1333889B1 (en) | 2007-03-07 |
| PL361876A1 (en) | 2004-10-04 |
| CZ20031329A3 (cs) | 2003-12-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |