CA2423607A1 - Coated, granular n-alkylammonium acetonitrile salts and their use as bleach activators - Google Patents
Coated, granular n-alkylammonium acetonitrile salts and their use as bleach activators Download PDFInfo
- Publication number
- CA2423607A1 CA2423607A1 CA002423607A CA2423607A CA2423607A1 CA 2423607 A1 CA2423607 A1 CA 2423607A1 CA 002423607 A CA002423607 A CA 002423607A CA 2423607 A CA2423607 A CA 2423607A CA 2423607 A1 CA2423607 A1 CA 2423607A1
- Authority
- CA
- Canada
- Prior art keywords
- acid
- group
- combination
- sodium
- waxes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000007844 bleaching agent Substances 0.000 title claims 9
- 239000012190 activator Substances 0.000 title claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- -1 hydrogen sulphate anion Chemical class 0.000 claims abstract 6
- 239000000463 material Substances 0.000 claims abstract 6
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 2
- 125000005842 heteroatom Chemical group 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 230000002209 hydrophobic effect Effects 0.000 claims abstract 2
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims 8
- 239000001993 wax Substances 0.000 claims 7
- 150000002191 fatty alcohols Chemical class 0.000 claims 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 4
- 239000011248 coating agent Substances 0.000 claims 4
- 238000000576 coating method Methods 0.000 claims 4
- 239000003599 detergent Substances 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- 238000004061 bleaching Methods 0.000 claims 3
- 229920001223 polyethylene glycol Polymers 0.000 claims 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 3
- ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 239000004115 Sodium Silicate Substances 0.000 claims 2
- 235000021355 Stearic acid Nutrition 0.000 claims 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 229920001400 block copolymer Polymers 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 2
- 238000004851 dishwashing Methods 0.000 claims 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims 2
- 239000000194 fatty acid Substances 0.000 claims 2
- 229930195729 fatty acid Natural products 0.000 claims 2
- 150000004677 hydrates Chemical class 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims 2
- 239000008117 stearic acid Substances 0.000 claims 2
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
- 125000006658 (C1-C15) hydrocarbyl group Chemical group 0.000 claims 1
- 125000006686 (C1-C24) alkyl group Chemical group 0.000 claims 1
- WREFNFTVBQKRGZ-UHFFFAOYSA-N 2-decylbutanediperoxoic acid Chemical compound CCCCCCCCCCC(C(=O)OO)CC(=O)OO WREFNFTVBQKRGZ-UHFFFAOYSA-N 0.000 claims 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims 1
- YTWUZAQZEVOPGG-UHFFFAOYSA-N 3-acetyl-1-phenylimidazolidine-2,4-dione Chemical compound O=C1N(C(=O)C)C(=O)CN1C1=CC=CC=C1 YTWUZAQZEVOPGG-UHFFFAOYSA-N 0.000 claims 1
- UZJGVXSQDRSSHU-UHFFFAOYSA-N 6-(1,3-dioxoisoindol-2-yl)hexaneperoxoic acid Chemical compound C1=CC=C2C(=O)N(CCCCCC(=O)OO)C(=O)C2=C1 UZJGVXSQDRSSHU-UHFFFAOYSA-N 0.000 claims 1
- PFPSOZSOSPOAPX-UHFFFAOYSA-N 7-(7-oxoazepane-2-carbonyl)azepan-2-one Chemical compound C1CCCC(=O)NC1C(=O)C1CCCCC(=O)N1 PFPSOZSOSPOAPX-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 1
- FSNHHUJGITXRNL-UHFFFAOYSA-N CC(C)CCCCCC(=O)OS(=O)(=O)C1=CC=CC=C1 Chemical class CC(C)CCCCCC(=O)OS(=O)(=O)C1=CC=CC=C1 FSNHHUJGITXRNL-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 claims 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
- 229920005682 EO-PO block copolymer Polymers 0.000 claims 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 claims 1
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 claims 1
- 239000005639 Lauric acid Substances 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 239000004435 Oxo alcohol Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 1
- 229920001131 Pulp (paper) Polymers 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 claims 1
- ZYPMNZKYVVSXOJ-YNEHKIRRSA-N [(2r,3s,4r)-2,3,4-triacetyloxy-5-oxopentyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O ZYPMNZKYVVSXOJ-YNEHKIRRSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 125000005263 alkylenediamine group Polymers 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 229940088990 ammonium stearate Drugs 0.000 claims 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims 1
- TXOWNVNZROTODR-UHFFFAOYSA-N benzenesulfonyl dodecanoate Chemical class CCCCCCCCCCCC(=O)OS(=O)(=O)C1=CC=CC=C1 TXOWNVNZROTODR-UHFFFAOYSA-N 0.000 claims 1
- 229910021538 borax Inorganic materials 0.000 claims 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- 235000010338 boric acid Nutrition 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000000645 desinfectant Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 claims 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 150000004668 long chain fatty acids Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 150000004682 monohydrates Chemical class 0.000 claims 1
- LTUGGBOPBQPPGK-UHFFFAOYSA-A octadecasodium;hexaphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LTUGGBOPBQPPGK-UHFFFAOYSA-A 0.000 claims 1
- 150000004967 organic peroxy acids Chemical class 0.000 claims 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 235000019809 paraffin wax Nutrition 0.000 claims 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims 1
- 235000019271 petrolatum Nutrition 0.000 claims 1
- 150000003009 phosphonic acids Chemical class 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 235000019353 potassium silicate Nutrition 0.000 claims 1
- 229920005604 random copolymer Polymers 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims 1
- 235000019795 sodium metasilicate Nutrition 0.000 claims 1
- 229960001922 sodium perborate Drugs 0.000 claims 1
- 229940045872 sodium percarbonate Drugs 0.000 claims 1
- 235000019830 sodium polyphosphate Nutrition 0.000 claims 1
- 235000019794 sodium silicate Nutrition 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 239000004328 sodium tetraborate Substances 0.000 claims 1
- 235000010339 sodium tetraborate Nutrition 0.000 claims 1
- PHIMXFJEDZOCMI-UHFFFAOYSA-M sodium;2-hexanoyloxy-3,4,5-trimethylbenzenesulfonate Chemical compound [Na+].CCCCCC(=O)OC1=C(C)C(C)=C(C)C=C1S([O-])(=O)=O PHIMXFJEDZOCMI-UHFFFAOYSA-M 0.000 claims 1
- OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 claims 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims 1
- 150000004685 tetrahydrates Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000013256 coordination polymer Substances 0.000 description 3
- 101150039515 Tfpt gene Proteins 0.000 description 2
- 101150051977 AAT2 gene Proteins 0.000 description 1
- 241000182988 Assa Species 0.000 description 1
- 241000937413 Axia Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000012905 Brassica oleracea var viridis Nutrition 0.000 description 1
- 101100315624 Caenorhabditis elegans tyr-1 gene Proteins 0.000 description 1
- 241000350052 Daniellia ogea Species 0.000 description 1
- QAHFOPIILNICLA-UHFFFAOYSA-N Diphenamid Chemical compound C=1C=CC=CC=1C(C(=O)N(C)C)C1=CC=CC=C1 QAHFOPIILNICLA-UHFFFAOYSA-N 0.000 description 1
- 241001303048 Ditta Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 101000583961 Halorubrum pleomorphic virus 1 Matrix protein Proteins 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- 101100533577 Leptosphaeria maculans sirP gene Proteins 0.000 description 1
- 101100523604 Mus musculus Rassf5 gene Proteins 0.000 description 1
- 101100260017 Mus musculus Tbx19 gene Proteins 0.000 description 1
- 101100246822 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pyr-7 gene Proteins 0.000 description 1
- 101100169989 Rattus norvegicus Ddah1 gene Proteins 0.000 description 1
- 101100091149 Rattus norvegicus Rnf39 gene Proteins 0.000 description 1
- 241000490025 Schefflera digitata Species 0.000 description 1
- 235000015107 ale Nutrition 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- FRZJZRVZZNTMAW-UHFFFAOYSA-N n,n-diethyl-3-(hydroxymethyl)benzamide Chemical compound CCN(CC)C(=O)C1=CC=CC(CO)=C1 FRZJZRVZZNTMAW-UHFFFAOYSA-N 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
Abstract
The invention relates to granular, coated N-alkylammonium acetonitrile salts of general formula (I) R2R3N R1-CR4R5-CN+Y-, wherein R1 means a C1- to C24- alkyl group which can be interrupted by non-adjacent oxygen atoms or can additionally carry hydroxyl groups, a C4- to C24-cycloalkyl group, a C7- to C24 alkaryl group or a grouping of formula -CR4R5-CN; R2 and R3 each have, independently of each other, the meaning of R1 or together represent, in the nitrogen atom to which they are bonded, a saturated four to nine-membered ri ng with at least one C-atom and at least one other hetero atom from the followi ng group: oxygen, sulphur and nitrogen; R4 and R5 each mean, independently of each other, hydrogen, a C1- to C24 alkyl group which can be interrupted by n on- adjacent oxygen atoms or can additionally carry hydroxyl groups, a C4- to C2 4- cycloalkyl group or a C7- to C24-alkaryl group; and Y represents a sulphate or hydrogen sulphate anion in the appropriate stoichiometric quantity; which ar e coated with a material selected from the following group: organic, inorganic , hydrophilic and hydrophobic substances.
Description
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Claims (11)
- We claim:
A bleach activator / bleaching performance booster combination comprising at least one granular, coated N-alkylammonium-acetonitrile salt of the formula (I) R2R3NR1-CR4R5-CN"Y" (1) in which is a C1-C24-alky group which may be interrupted by nonadjacent oxygen atoms or may additionally carry hydroxyl groups, a C4-C24-cycloalky group, a C7-C24-alkaryl group or a group of the formula -CR4R5-CN, R2 and R3 in each case independently of one another have the meaning of R1 or together with the nitrogen atom to which they are bound are a saturated four- to nine-membered ring having at least one carbon atom and at least one further heteroatom from the group consisting of oxygen, sulfur and nitrogen, R4 and R5 in each case independently of one another are hydrogen, a C1-C24-alkyl group which may be interrupted by nonadjacent oxygen atoms or may additionally carry hydroxyl groups, a C4-C24-cycloalkyl group or a C7-C24-alkaryl group and is a sulfate or hydrogensulfate anion in the corresponding stoichiometric amount.
where the salts of the formula (1) are coated with a material is chosen from the group consisting of organic, inorganic, hydrophilic and hydrophobic substances, and at least one bleach performance booster. - 2. A combination as claimed in claim 1, wherein the coating materials are chosen from the group consisting of fatty alcohols, fatty alcohol/ammonium stearate mixtures, ethoxylated fatty alcohols, in particular C8-C31-fatty alcohol polyalkoxylates having 1 to 150 moles of ethylene oxide, ethoxylated oxo alcohols, fatty acids, in particular lauric acid, myristic acid, stearic acid and the Na, K, Ca and ammonium salts of these acids, fatty acid esters, waxes, in particular paraffin waxes, montan ester waxes, montan acid waxes, polyethylene waxes, oxidized polyethylene waxes, ethylene/acrylic acid copolymer waxes, ethylene/vinyl acetate copolymer waxes, polyalkyl vinyl ether waxes, dispersions of suitable polymers, in particular of polyalkyl acrylate, polystyrene, alkyl acrylate/(meth)acrylic acid copolymers, maleic acid/olefin copolymers, vinyl chloride/ethylene copolymers and vinyl chloride/ethylene/methacrylate copolymers.
- 3. A combination as claimed in claim 1, wherein the inorganic coating material is chosen from the group consisting of magnesium sulfate, sodium hexaphosphate, dihydrogen phosphate, pyrophosphate, phosphonic acids, sodium metaborate, sodium metasilicate, waterglass, sodium polyphosphate, sodium sulfate, sodium carbonate, sodium silicate, sodium bicarbonate, borax, magnesium sulfate and boric acid.
- 4. A combination as claim 1, wherein the organic, hydrophilic coating material is chosen from the group consisting of polyethylene glycols having a molecular weight of from 1 000 to 50 000 and block copolymers and random copolymers of ethylene glycol and propylene glycol.
- 5. A combination as claimed in any of claims 1 to 4, wherein the coating material is chosen from the group consisting of polyethylene glycols having a molecular weight >= 1 500, long-chain fatty acids, fatty alcohol ethoxylates and block copolymers of ethylene oxide and propylene oxide, in particular from the group consisting of polyethylene glycols having a molecular weight of about 6 000, fatty alcohol ethoxylates of C16-C18-fatty alcohols, ethylene oxide/propylene oxide block copolymers having an ethylene oxide content of about 80% and a molecular weight of about 8 000, and stearic acid.
- 6. A combination as claimed is any of claims 1 to 5, wherein R2 and R3 together with the nitrogen atom to which they are bonded form a six-membered ring which may optionally contain a further nitrogen atom or an oxygen atom, or R1 to R3 are identical or different and are a C1-C4-alkyl radical, in particular N-methylmorpholiniumacetonitrile sulfate or hydrogensulfate or trimetheylammoniumacetonitrile sulfate or hydrogensulfate.
- 7. A combination as claimed in any of claims 1 to 6, which is used in combination with other bleach activators, preferably polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), glucose pentacetate (GPA), xylose tetraacetate (TAX), sodium 4-benzoyloxybenzene-sulfonate (SBOBS), sodium trimethylhexanoyloxybenzenesulfonate (STHOBS), tetraacetylglucoluril (TAGU), tetraacetylcyanic acid (TACA), di-N-acetyldimethylglyoxime (ADMG), 1-phenyl-3-acetylhydantoin (PAH), acylated phenolsulfonates, nonanoylbenzenesulfonates (NOBS), isononanoylbenzenesulfonates (isoNOBS), lauroylbenzenesulfonates (LOBS), carbonylbiscaprolactam and/or bis(2-propylimino)carbonate.
- 8. A combination as claimed in any of claims 1 to 7, wherein the bleaching performance booster is selected from low molecular weight, oligomeric or polymeric compounds containing secondary amine groups -NHR1, wherein R1 is a C1-C30, preferably a C1-C15 hydrocarbyl rest.
- 9. A combination according to any of the claims 1 to 8, wherein the bleaching performance booster is selected from the group consisting of secondary amines of the formula R1NH-[(CR3R4)m-NH]N-R2 (II) where N is an integer from 0 to 20 and m is an integer from 2 to 4, the radicals R3 and R4 independently of one another are C1-C30-hydrocarbyl radicals, preferably C1-C15-hydrocarbyl radicals, and the radicals R1 and R2 independently of one another are C1-C30-hydrocarbyl radicals, preferably C1-C15-hydrocarbyl radicals, which may together form a cyclic radical.
- 10. A combination as claimed in any of claims 1 to 9, which is used together with bleaches from the group consisting of alkali metal perborates and hydrates thereof, alkali metal percarbonates, in particular sodium perborate in the form of the mono- or tetrahydrate, sodium percarbonate and hydrates thereof, persulfates, hydrogen peroxide, oxygen bleaches, preferably organic peracids, in particular perbenzoic acid, peroxyalphanaphthoic acid, peroxylauric acid, peroxystearic acid, phthalimidoperoxycaproic acid, nonylimidoperoxysuccinic acid, nonylimidoperoxyadipic acid, 1,12-diperoxydodecanedioic acid, 1,9-diperoxyazelaic acid, diperoxoisophthalic acid, and 2-decyl-diperoxybutane-1,4-dioic acid, cationic peroxy acids and sulfonylperoxy acids.
- 11. A detergent, cleaner, dishwashing detergent, stain-removal salt, disinfectant, denture cleaner, fiber bleach, in particular cellulose bleach, wood pulp bleach or cotton fiber bleach, or a hair bleach, in particular a detergent or a dishwashing detergent, comprising a combination as claimed in any of claims 1 to 10.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2000149237 DE10049237A1 (en) | 2000-09-28 | 2000-09-28 | Coated, granular N-alkylammonium acetonitrile salts and their use as a bleach activator |
| DE10049237.1 | 2000-09-28 | ||
| PCT/EP2001/011290 WO2002026927A1 (en) | 2000-09-28 | 2001-09-28 | Coated, granular n-alkylammonium acetonitrile salts and their use as bleach activators |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2423607A1 true CA2423607A1 (en) | 2003-03-25 |
Family
ID=7658719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002423607A Abandoned CA2423607A1 (en) | 2000-09-28 | 2001-09-28 | Coated, granular n-alkylammonium acetonitrile salts and their use as bleach activators |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1322744A1 (en) |
| JP (1) | JP2004510033A (en) |
| CN (1) | CN1471572A (en) |
| AU (1) | AU2001289940A1 (en) |
| BR (1) | BR0114325A (en) |
| CA (1) | CA2423607A1 (en) |
| DE (1) | DE10049237A1 (en) |
| MX (1) | MXPA03002615A (en) |
| WO (1) | WO2002026927A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10159388A1 (en) * | 2001-12-04 | 2003-06-12 | Henkel Kgaa | Process for the production of coated bleach activator granules |
| DE10161766A1 (en) * | 2001-12-15 | 2003-06-26 | Clariant Gmbh | Bleach co-granules |
| WO2003101940A2 (en) | 2002-05-31 | 2003-12-11 | Henkel Kommanditgesellschaft Auf Aktien | Deodorisation of cationic ammonium acetonitrile derivatives |
| DE10314442A1 (en) * | 2003-03-31 | 2004-11-04 | Henkel Kgaa | Detergent portions, especially for automatic dishwasher, contain cationic, quaternized aminoacetonitrile in deep-drawn, cast or injection molded, water-soluble or water-dispersible container, |
| ATE357497T1 (en) | 2002-12-20 | 2007-04-15 | Henkel Kgaa | DETERGENTS OR CLEANING PRODUCTS CONTAINING BLEACH |
| ATE373073T1 (en) * | 2002-12-24 | 2007-09-15 | Dalli Werke Gmbh & Co Kg | OPTIMIZED DETERGENT AND CLEANING SYSTEM FOR IMPROVED BLEACHING EFFECT AT LOWER TEMPERATURES |
| DE102004012568A1 (en) * | 2004-03-12 | 2005-12-08 | Henkel Kgaa | Bleach activators and process for their preparation |
| DE102006029344A1 (en) * | 2006-06-23 | 2007-12-27 | Henkel Kgaa | Dental treatment agent with enhanced bleaching effect |
| DE102007062519A1 (en) | 2007-12-20 | 2009-06-25 | Henkel Ag & Co. Kgaa | cleaning supplies |
| MX2019002056A (en) * | 2016-08-30 | 2019-07-15 | Colgate Palmolive Co | Stable whitening dentifrice composition with colorant-containing particles. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888419A (en) * | 1995-06-07 | 1999-03-30 | The Clorox Company | Granular N-alkyl ammonium acetontrile compositions |
| US5814242A (en) * | 1995-06-07 | 1998-09-29 | The Clorox Company | Mixed peroxygen activator compositions |
| DE19611992A1 (en) * | 1996-03-26 | 1997-10-02 | Basf Ag | Use of amine with specified acidity as bleaching enhancer |
| DE19740671A1 (en) * | 1997-09-16 | 1999-03-18 | Clariant Gmbh | Bleach activator granulate containing ammonium nitrile and layered silicate |
| DE19740669A1 (en) * | 1997-09-16 | 1999-03-18 | Clariant Gmbh | Coated ammonium nitrile bleach activator granules used in e.g. detergents |
-
2000
- 2000-09-28 DE DE2000149237 patent/DE10049237A1/en not_active Withdrawn
-
2001
- 2001-09-28 EP EP01969797A patent/EP1322744A1/en not_active Withdrawn
- 2001-09-28 AU AU2001289940A patent/AU2001289940A1/en not_active Abandoned
- 2001-09-28 CA CA002423607A patent/CA2423607A1/en not_active Abandoned
- 2001-09-28 MX MXPA03002615A patent/MXPA03002615A/en not_active Application Discontinuation
- 2001-09-28 CN CNA018180736A patent/CN1471572A/en active Pending
- 2001-09-28 JP JP2002530693A patent/JP2004510033A/en not_active Withdrawn
- 2001-09-28 BR BR0114325-5A patent/BR0114325A/en not_active IP Right Cessation
- 2001-09-28 WO PCT/EP2001/011290 patent/WO2002026927A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03002615A (en) | 2004-04-02 |
| AU2001289940A1 (en) | 2002-04-08 |
| CN1471572A (en) | 2004-01-28 |
| WO2002026927A1 (en) | 2002-04-04 |
| JP2004510033A (en) | 2004-04-02 |
| DE10049237A1 (en) | 2002-04-11 |
| EP1322744A1 (en) | 2003-07-02 |
| BR0114325A (en) | 2003-10-07 |
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| Date | Code | Title | Description |
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| FZDE | Discontinued |