CA2410362A1 - Long lasting coatings for modifying hard surfaces and processes for applying the same - Google Patents

Long lasting coatings for modifying hard surfaces and processes for applying the same Download PDF

Info

Publication number
CA2410362A1
CA2410362A1 CA002410362A CA2410362A CA2410362A1 CA 2410362 A1 CA2410362 A1 CA 2410362A1 CA 002410362 A CA002410362 A CA 002410362A CA 2410362 A CA2410362 A CA 2410362A CA 2410362 A1 CA2410362 A1 CA 2410362A1
Authority
CA
Canada
Prior art keywords
hard surfaces
coating
hard
long lasting
articles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002410362A
Other languages
French (fr)
Other versions
CA2410362C (en
Inventor
Robert Henry Rohrbaugh
Alan Scott Goldstein
Michael Ray Mcdonald
Helen Frances O'connor
Heather Anne Liddle
John Michael Jensen
Nabil Yaqub Sakkab
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2000/016349 external-priority patent/WO2001096516A1/en
Application filed by Individual filed Critical Individual
Publication of CA2410362A1 publication Critical patent/CA2410362A1/en
Application granted granted Critical
Publication of CA2410362C publication Critical patent/CA2410362C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043For use with aerosol devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/02Cleaning by the force of jets or sprays
    • B08B3/026Cleaning by making use of hand-held spray guns; Fluid preparations therefor
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013Liquid compositions with insoluble particles in suspension
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3792Amine oxide containing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes
    • C11D2111/42Application of foam or a temporary coating on the surface to be cleaned

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Materials for coating, coating compositions, methods and articles of manufacture comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of inanimate hard surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to modified hard surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, quick drying, uniform drying, soil removal, self-cleaning, anti-spotting, anti-soil deposition, cleaner appearance, enhanced gloss, enhanced color, minor surface defect repair, smoothness, anti-hazing, modification of surface friction, release of actives and transparency, relative to hard surfaces unmodified with such nanoparticle systems. Actively curing the coating composition on the hard surfaces, including, but not limited to by radiative heating the air surrounding the hard surface with the coating thereon can be used to increase the durability of the hard surface coating.
CA002410362A 2000-06-14 2001-06-14 Long lasting coatings for modifying hard surfaces and processes for applying the same Expired - Fee Related CA2410362C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
USPCT/US00/16349 2000-06-14
PCT/US2000/016349 WO2001096516A1 (en) 2000-06-14 2000-06-14 Process for cleaning a surface
US26505901P 2001-01-30 2001-01-30
US60/265,059 2001-01-30
PCT/US2001/019059 WO2001096512A2 (en) 2000-06-14 2001-06-14 Long lasting coatings for modifying hard surfaces and processes for applying the same

Publications (2)

Publication Number Publication Date
CA2410362A1 true CA2410362A1 (en) 2001-12-20
CA2410362C CA2410362C (en) 2008-08-12

Family

ID=26680257

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002410362A Expired - Fee Related CA2410362C (en) 2000-06-14 2001-06-14 Long lasting coatings for modifying hard surfaces and processes for applying the same

Country Status (8)

Country Link
EP (1) EP1290123A2 (en)
JP (1) JP4097136B2 (en)
KR (1) KR20030036223A (en)
CN (1) CN1436104A (en)
AU (1) AU2001268404A1 (en)
CA (1) CA2410362C (en)
MX (1) MXPA02012432A (en)
WO (1) WO2001096512A2 (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6562142B2 (en) 2001-01-30 2003-05-13 The Procter & Gamble Company System and method for cleaning and/or treating vehicles and the surfaces of other objects
AR032424A1 (en) 2001-01-30 2003-11-05 Procter & Gamble COATING COMPOSITIONS TO MODIFY SURFACES.
US7265174B2 (en) 2001-03-22 2007-09-04 Clemson University Halogen containing-polymer nanocomposite compositions, methods, and products employing such compositions
DE10118346A1 (en) 2001-04-12 2002-10-17 Creavis Tech & Innovation Gmbh Self-cleaning, water-repellent textiles, used e.g. for tents, sports clothing and carpets, made by impregnating textile material with a suspension of hydrophobic particles and then removing the solvent
US20030064086A1 (en) * 2001-08-31 2003-04-03 Danuvio Carrion Cosmetic compositions comprising nanoparticles and processes for using the same
DE10210027A1 (en) 2002-03-07 2003-09-18 Creavis Tech & Innovation Gmbh Hydrophilic surfaces
US7081441B2 (en) 2002-05-24 2006-07-25 The Procter & Gamble Co. Composition for cleaning and/or treating surfaces
US20060063911A1 (en) * 2004-05-27 2006-03-23 Cayton Roger H Enhanced scratch resistance of articles containing a combination of nano-crystalline metal oxide particles, polymeric dispersing agents, and surface active materials
DE102004043908A1 (en) * 2004-09-10 2006-03-30 GRÄTER, Stefan Surface-structured polymeric substrates and their preparation
WO2007029293A1 (en) * 2005-09-02 2007-03-15 Mitsubishi Chemical Mkv Company Surface-modified plastic film and process for producing the same
EP1984465B1 (en) * 2006-02-14 2012-01-25 The Procter & Gamble Company Responsive coated substrates
DE102007037254A1 (en) * 2007-08-07 2009-02-12 Manroland Ag Sensor device and printing machine with a sensor device
US20090280252A1 (en) * 2008-05-06 2009-11-12 Andrew Armstrong Method for Extending and Improving the Functionality of a Hard Surface
ES2749998T3 (en) * 2009-12-10 2020-03-24 Invista Textiles Uk Ltd Use of aqueous dirt repellent dispersions, soft dirt repellent articles, and methods of making them
BR112012018293A2 (en) 2010-01-22 2018-06-05 Asahi Glass Company, Limited process for producing resin substrate having duct coating layer, and resin substrate having hard coating layer
US11624115B2 (en) 2010-05-12 2023-04-11 Sio2 Medical Products, Inc. Syringe with PECVD lubrication
EP2601040B1 (en) * 2010-08-02 2017-06-28 Oechsler Aktiengesellschaft Process for producing a coloured fibre composite material and this fibre composite material, and formed part produced therefrom
US9878101B2 (en) 2010-11-12 2018-01-30 Sio2 Medical Products, Inc. Cyclic olefin polymer vessels and vessel coating methods
CN103930595A (en) 2011-11-11 2014-07-16 Sio2医药产品公司 Passivation, ph protective or lubricity coating for pharmaceutical package, coating process and apparatus
US11116695B2 (en) 2011-11-11 2021-09-14 Sio2 Medical Products, Inc. Blood sample collection tube
EP2812130B1 (en) * 2012-02-07 2018-03-28 Chemetall GmbH Method for coating metallic surfaces of substrates
JP5945379B2 (en) * 2012-02-23 2016-07-05 国立大学法人埼玉大学 Method for forming organic thin film and solar cell formed using the same
EP2838862A4 (en) 2012-04-20 2016-05-11 Grace W R & Co Stabilized defoamers for cementitious compositions
US9764093B2 (en) 2012-11-30 2017-09-19 Sio2 Medical Products, Inc. Controlling the uniformity of PECVD deposition
KR102211788B1 (en) * 2013-03-11 2021-02-04 에스아이오2 메디컬 프로덕츠, 인크. Coated Packaging
EP3122917B1 (en) 2014-03-28 2020-05-06 SiO2 Medical Products, Inc. Antistatic coatings for plastic vessels
KR20180048694A (en) 2015-08-18 2018-05-10 에스아이오2 메디컬 프로덕츠, 인크. Packaging containers for medicines and other products with low oxygen transfer rates
CN105733845B (en) * 2016-03-28 2019-09-06 山东天竞电子科技有限公司 A kind of LED electronic display screen cleaning agent and preparation method and clean method
CN107234403A (en) * 2017-07-29 2017-10-10 合肥海宝节能科技有限公司 A kind of manufacture method of environment protection type box
CN107446402B (en) * 2017-08-30 2021-01-19 深圳先进技术研究院 Charge transfer type automatic redox nano material, preparation method and application thereof, marine antifouling agent and marine antifouling paint
CN108645674B (en) * 2018-05-11 2021-01-26 西安公路研究院 Method for rapidly detecting light transmittance of bright asphalt
JP2023504905A (en) * 2019-12-08 2023-02-07 アンケルポールト エヌフェー Fine-grained filler with improved wettability

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69625944D1 (en) * 1995-03-17 2003-03-06 Sumitomo Chemical Co Anti-fogging composition and agricultural film coated with it
ATE240370T1 (en) * 1996-09-30 2003-05-15 Basf Corp SCRATCH-RESISTANT CLEAR COATS CONTAINING SURFACE-REACTIVE MICROPARTICLES AND METHOD FOR THE PRODUCTION THEREOF
US5853809A (en) * 1996-09-30 1998-12-29 Basf Corporation Scratch resistant clearcoats containing suface reactive microparticles and method therefore
DE19719948A1 (en) * 1997-05-13 1998-11-19 Inst Neue Mat Gemein Gmbh Production of nano-structured mouldings and coatings
DE19726814A1 (en) * 1997-06-25 1999-01-07 Murjahn Amphibolin Werke Coating agent to reduce the tendency to soiling on facades
DE19811790A1 (en) * 1998-03-18 1999-09-23 Bayer Ag Transparent paint binders containing nanoparticles with improved scratch resistance, a process for their preparation and their use

Also Published As

Publication number Publication date
JP4097136B2 (en) 2008-06-11
KR20030036223A (en) 2003-05-09
EP1290123A2 (en) 2003-03-12
CA2410362C (en) 2008-08-12
AU2001268404A1 (en) 2001-12-24
WO2001096512A2 (en) 2001-12-20
WO2001096512A3 (en) 2002-10-17
JP2004504925A (en) 2004-02-19
CN1436104A (en) 2003-08-13
MXPA02012432A (en) 2003-04-25

Similar Documents

Publication Publication Date Title
CA2410600A1 (en) Coating compositions for modifying hard surfaces
CA2410362A1 (en) Long lasting coatings for modifying hard surfaces and processes for applying the same
CA2431780A1 (en) Coatings for modifying hard surfaces and processes for applying the same
AR033536A1 (en) LONG-TERM COATINGS TO MODIFY HARD SURFACES AND PROCESSES FOR THE APPLICATION OF THE SAME
CA2433059A1 (en) Coating compositions for modifying surfaces
CN101119860B (en) Coated metal product, method to produce it and use of the method
PT1874875E (en) Coated particles and coating compositions comprising coated particles
WO2008087877A1 (en) Coating composition, coating method, heat exchanger and air conditioner
US8961671B2 (en) Super hydrophobic and antistatic composition
TW200615139A (en) Release sheet and molded articles using the same
WO2016047780A1 (en) Decorative sheet and decorative plate
Guduru et al. Nanoceramics: surfaces and coatings for consumer goods
BR0215161A (en) Method of applying coatings
CA2832983A1 (en) A water pressure transfer method, a coating agent for water pressure transfer film and a water pressure transfer article
Papadopoulos et al. A versatile approach towards development of easy-to-clean transparent nanocoating systems with pronounced anti-static properties for various substrates.
CN1903970B (en) Stain-proofing agent and building board using same
Myers History of coatings science and technology
CN113083640A (en) Spraying method of anti-fingerprint nano coating
JP2004082516A (en) Metallic sheet precoated with acrylic resin containing silica
JP2007014911A (en) Designed coating film, its forming method and coated article
JP4011653B2 (en) Transfer foil
FR2797451B1 (en) COMPOSITION FOR USE AS A REINFORCING FILLER IN POLYMER COMPOSITIONS
Sepeur et al. Commercial applications of nanocomposite sol-gel coatings
AR029140A1 (en) COATING COMPOSITIONS TO MODIFY HARD SURFACES
BR0111681A (en) Long lasting coatings for hard surface modification and methods for applying them

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed