CA2401859A1 - Process for the production of olefins - Google Patents
Process for the production of olefins Download PDFInfo
- Publication number
- CA2401859A1 CA2401859A1 CA002401859A CA2401859A CA2401859A1 CA 2401859 A1 CA2401859 A1 CA 2401859A1 CA 002401859 A CA002401859 A CA 002401859A CA 2401859 A CA2401859 A CA 2401859A CA 2401859 A1 CA2401859 A1 CA 2401859A1
- Authority
- CA
- Canada
- Prior art keywords
- component
- catalyst
- group
- rhodium
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 51
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 121
- 239000010948 rhodium Substances 0.000 claims abstract description 59
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 48
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 40
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 40
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 37
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 34
- 150000003624 transition metals Chemical class 0.000 claims abstract description 34
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 claims abstract description 32
- 239000002184 metal Substances 0.000 claims abstract description 32
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 25
- 239000010949 copper Substances 0.000 claims abstract description 20
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052802 copper Inorganic materials 0.000 claims abstract description 18
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 17
- 239000010941 cobalt Substances 0.000 claims abstract description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007789 gas Substances 0.000 claims abstract description 13
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 10
- 238000011068 loading method Methods 0.000 claims description 28
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000002485 combustion reaction Methods 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052762 osmium Inorganic materials 0.000 claims description 6
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052702 rhenium Inorganic materials 0.000 claims description 6
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 description 46
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 16
- 239000006260 foam Substances 0.000 description 14
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 11
- 239000005977 Ethylene Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 7
- -1 platinum group metals Chemical class 0.000 description 7
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 6
- 235000011150 stannous chloride Nutrition 0.000 description 6
- 238000004227 thermal cracking Methods 0.000 description 6
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 6
- BMQADCHCFVPVPR-UHFFFAOYSA-K trichlororhodium dihydrate Chemical compound O.O.Cl[Rh](Cl)Cl BMQADCHCFVPVPR-UHFFFAOYSA-K 0.000 description 6
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 4
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- PDJBCBKQQFANPW-UHFFFAOYSA-L azanide;platinum(2+);dichloride Chemical compound [NH2-].[NH2-].[NH2-].[NH2-].Cl[Pt]Cl PDJBCBKQQFANPW-UHFFFAOYSA-L 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005235 decoking Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/18—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/36—Rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/50—Silver
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0006384.2A GB0006384D0 (en) | 2000-03-16 | 2000-03-16 | Process for production of olefins |
| GB0006384.2 | 2000-03-16 | ||
| GB0028231.9 | 2000-11-18 | ||
| GBGB0028231.9A GB0028231D0 (en) | 2000-03-16 | 2000-11-18 | Process for the production of olefins |
| PCT/GB2001/000759 WO2001068571A1 (en) | 2000-03-16 | 2001-02-22 | Process for the production of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2401859A1 true CA2401859A1 (en) | 2001-09-20 |
Family
ID=26243886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002401859A Abandoned CA2401859A1 (en) | 2000-03-16 | 2001-02-22 | Process for the production of olefins |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7164053B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1263699B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2003527362A (cg-RX-API-DMAC7.html) |
| CN (1) | CN1183068C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE359252T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU779630B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR0109274A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2401859A1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE60127824T2 (cg-RX-API-DMAC7.html) |
| GB (2) | GB0006384D0 (cg-RX-API-DMAC7.html) |
| GC (1) | GC0000274A (cg-RX-API-DMAC7.html) |
| MY (1) | MY127067A (cg-RX-API-DMAC7.html) |
| NO (1) | NO20024400D0 (cg-RX-API-DMAC7.html) |
| TW (1) | TW588030B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2001068571A1 (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA200206811B (cg-RX-API-DMAC7.html) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040068148A1 (en) * | 2002-10-08 | 2004-04-08 | Conoco Inc. | Oxidative dehydrogenation of hydrocarbons using catalysts with trace promoter metal loading |
| GB0312966D0 (en) | 2003-06-05 | 2003-07-09 | Bp Chem Int Ltd | Process for the production of olefins |
| CN1835797A (zh) * | 2003-08-13 | 2006-09-20 | 哈尔多托普森公司 | 催化还原和氧化方法 |
| US7067455B2 (en) | 2003-11-21 | 2006-06-27 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| US20060149115A1 (en) * | 2004-12-30 | 2006-07-06 | Foral Michael J | Refrigeration system for the production and recovery of olefins |
| US8815080B2 (en) * | 2009-01-26 | 2014-08-26 | Lummus Technology Inc. | Adiabatic reactor to produce olefins |
| CN107970931A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 一种混合烷烃脱氢生产烯烃的催化剂、制备方法及应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3119883A (en) | 1960-08-08 | 1964-01-28 | Du Pont | Dehydrogenation of ethane |
| JPS4945364B1 (cg-RX-API-DMAC7.html) * | 1966-11-10 | 1974-12-04 | ||
| US3856880A (en) * | 1970-03-02 | 1974-12-24 | Petro Tex Chem Corp | Oxidative dehydrogenation catalyzed with promoted zinc ferrite |
| US3751512A (en) | 1970-03-02 | 1973-08-07 | Petro Tex Chem Corp | Promoted oxidative dehydrogenation process |
| US3758609A (en) | 1971-01-11 | 1973-09-11 | Phillips Petroleum Co | Processes for the oxidative dehydrogenation of hydrocarbon feedstocks |
| US3862255A (en) | 1971-05-06 | 1975-01-21 | Phillips Petroleum Co | Oxidative dehydrogenation processes |
| US3810954A (en) | 1972-04-10 | 1974-05-14 | Phillips Petroleum Co | Oxidative dehydrogenation processes |
| US3821324A (en) | 1972-04-19 | 1974-06-28 | Phillips Petroleum Co | Oxidative dehydrogenation processes |
| US3933933A (en) | 1972-04-19 | 1976-01-20 | Phillips Petroleum Company | Oxidative dehydrogenation processes |
| US4164519A (en) | 1972-04-19 | 1979-08-14 | Phillips Petroleum Company | Oxidative dehydrogenation processes |
| US4010114A (en) | 1975-04-30 | 1977-03-01 | Phillips Petroleum Company | Oxidative dehydrogenation catalyst |
| US4731351A (en) | 1983-10-14 | 1988-03-15 | Phillips Petroleum Company | Catalyst composition |
| GB8805447D0 (en) | 1988-03-08 | 1988-04-07 | British Petroleum Co Plc | Chemical process |
| US5028577A (en) | 1989-01-11 | 1991-07-02 | Amoco Corporation | Lower alkane conversion catalysts |
| US5905180A (en) | 1996-01-22 | 1999-05-18 | Regents Of The University Of Minnesota | Catalytic oxidative dehydrogenation process and catalyst |
| KR100669000B1 (ko) | 1998-09-03 | 2007-01-17 | 다우 글로벌 테크놀로지스 인크. | 올레핀의 자기열식 제조방법 |
| AU2858400A (en) | 1999-01-25 | 2000-08-07 | University Of Delaware | Oxidative dehydrogenation process and catalyst |
| AU3601900A (en) | 1999-02-22 | 2000-09-04 | Symyx Technologies, Inc. | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
-
2000
- 2000-03-16 GB GBGB0006384.2A patent/GB0006384D0/en not_active Ceased
- 2000-11-18 GB GBGB0028231.9A patent/GB0028231D0/en not_active Ceased
-
2001
- 2001-02-22 EP EP01905974A patent/EP1263699B1/en not_active Expired - Lifetime
- 2001-02-22 AU AU33938/01A patent/AU779630B2/en not_active Ceased
- 2001-02-22 WO PCT/GB2001/000759 patent/WO2001068571A1/en not_active Ceased
- 2001-02-22 JP JP2001567672A patent/JP2003527362A/ja not_active Withdrawn
- 2001-02-22 AT AT01905974T patent/ATE359252T1/de not_active IP Right Cessation
- 2001-02-22 BR BR0109274-0A patent/BR0109274A/pt not_active IP Right Cessation
- 2001-02-22 US US10/221,752 patent/US7164053B2/en not_active Expired - Fee Related
- 2001-02-22 DE DE60127824T patent/DE60127824T2/de not_active Expired - Fee Related
- 2001-02-22 CA CA002401859A patent/CA2401859A1/en not_active Abandoned
- 2001-02-22 CN CNB018066011A patent/CN1183068C/zh not_active Expired - Fee Related
- 2001-03-14 GC GCP20011229 patent/GC0000274A/en active
- 2001-03-15 MY MYPI20011206A patent/MY127067A/en unknown
- 2001-03-15 TW TW090106091A patent/TW588030B/zh not_active IP Right Cessation
-
2002
- 2002-08-26 ZA ZA200206811A patent/ZA200206811B/xx unknown
- 2002-09-13 NO NO20024400A patent/NO20024400D0/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE60127824D1 (de) | 2007-05-24 |
| EP1263699A1 (en) | 2002-12-11 |
| ZA200206811B (en) | 2003-09-23 |
| ATE359252T1 (de) | 2007-05-15 |
| EP1263699B1 (en) | 2007-04-11 |
| AU3393801A (en) | 2001-09-24 |
| US20050277798A1 (en) | 2005-12-15 |
| MY127067A (en) | 2006-11-30 |
| JP2003527362A (ja) | 2003-09-16 |
| GB0028231D0 (en) | 2001-01-03 |
| US7164053B2 (en) | 2007-01-16 |
| WO2001068571A1 (en) | 2001-09-20 |
| NO20024400L (no) | 2002-09-13 |
| NO20024400D0 (no) | 2002-09-13 |
| BR0109274A (pt) | 2002-12-17 |
| GC0000274A (en) | 2006-11-01 |
| CN1183068C (zh) | 2005-01-05 |
| CN1418181A (zh) | 2003-05-14 |
| TW588030B (en) | 2004-05-21 |
| DE60127824T2 (de) | 2007-08-16 |
| AU779630B2 (en) | 2005-02-03 |
| GB0006384D0 (en) | 2000-05-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0638534B1 (en) | Dehydrogenation | |
| EP0332289B1 (en) | A process for the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons having two or more carbon atoms | |
| AU779630B2 (en) | Process for the production of olefins | |
| WO2004033082A2 (en) | Oxidative dehydrogenation of hydrocarbons using catalysts with trace promoter metal loading | |
| CA2395380C (en) | Process for the production of olefins | |
| AU777050B2 (en) | Process for the production of olefins | |
| KR100780586B1 (ko) | 올레핀 제조 방법 | |
| US20070073094A1 (en) | Process for the production of olefins | |
| ZA200204925B (en) | Process for the production of olefins. | |
| AU2006201072A1 (en) | Process for the production of olefins |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |