CA2371774A1 - Procede d'hydrogenation d'alcyne - Google Patents

Procede d'hydrogenation d'alcyne Download PDF

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Publication number
CA2371774A1
CA2371774A1 CA002371774A CA2371774A CA2371774A1 CA 2371774 A1 CA2371774 A1 CA 2371774A1 CA 002371774 A CA002371774 A CA 002371774A CA 2371774 A CA2371774 A CA 2371774A CA 2371774 A1 CA2371774 A1 CA 2371774A1
Authority
CA
Canada
Prior art keywords
hydrocarbon
alkali metal
catalyst
alkyne
reaction zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002371774A
Other languages
English (en)
Inventor
Ricardo J. Callejas
L. Alberto Morales
James B. Kimble
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2371774A1 publication Critical patent/CA2371774A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C07C7/167—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/66—Silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Cette invention a trait à un procédé permettant d'améliorer le fonctionnement d'un processus de conversion d'alcynes portant de 2 à 6 atomes de carbone (de l'acétylène, de préférence) contenus dans un fluide contenant un hydrocarbure au moyen d'hydrogène pour produire les alcènes correspondants. Avant que des améliorations n'y aient été apportées, ce processus utilisait un certain volume de catalyseur d'hydrogénation nécessaire pour assurer la conversion des alcynes portant de 2 à 6 atomes de carbone en produit converti contenant moins d'alcynes que le fluide contenant un hydrocarbure. Les améliorations apportées consistent à mettre en contact, dans une zone de réaction adiabatique à un seul étage, dans des conditions de réaction, le fluide contenant un hydrocarbure renfermant des alcynes portant de 2 à 6 atomes de carbone (de l'acétylène, de préférence) avec un catalyseur contenant du palladium, de l'argent et un composé à base de fluorure de métal alcalin, sous un volume de conversion approprié inférieur au volume de catalyseur d'hydrogénation.
CA002371774A 1999-02-18 2000-02-14 Procede d'hydrogenation d'alcyne Abandoned CA2371774A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US25295499A 1999-02-18 1999-02-18
US09/252,954 1999-02-18
PCT/US2000/003659 WO2000048970A1 (fr) 1999-02-18 2000-02-14 Procédé d'hydrogénation d'alcyne

Publications (1)

Publication Number Publication Date
CA2371774A1 true CA2371774A1 (fr) 2000-08-24

Family

ID=22958251

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002371774A Abandoned CA2371774A1 (fr) 1999-02-18 2000-02-14 Procede d'hydrogenation d'alcyne

Country Status (4)

Country Link
EP (1) EP1150936A4 (fr)
AU (1) AU2880600A (fr)
CA (1) CA2371774A1 (fr)
WO (1) WO2000048970A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005103025A1 (fr) * 2004-04-21 2005-11-03 Novogen Research Pty Ltd Procede de synthese d'isoflavene et catalyseur
CN114442561A (zh) * 2020-10-20 2022-05-06 中国石油化工股份有限公司 碳二前加氢反应器的自动控制方法及系统

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4762956A (en) * 1983-04-13 1988-08-09 Beijing Research Institute Of Chemical Industry He Ping Li Novel catalyst and process for hydrogenation of unsaturated hydrocarbons
US5488024A (en) * 1994-07-01 1996-01-30 Phillips Petroleum Company Selective acetylene hydrogenation
US5583274A (en) * 1995-01-20 1996-12-10 Phillips Petroleum Company Alkyne hydrogenation process
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung

Also Published As

Publication number Publication date
EP1150936A1 (fr) 2001-11-07
AU2880600A (en) 2000-09-04
EP1150936A4 (fr) 2002-04-17
WO2000048970A1 (fr) 2000-08-24

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Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued
FZDE Discontinued

Effective date: 20040216