CA2352057A1 - Systeme de generation d'energie de pile a combustible a reformeur autothermique - Google Patents

Systeme de generation d'energie de pile a combustible a reformeur autothermique Download PDF

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Publication number
CA2352057A1
CA2352057A1 CA002352057A CA2352057A CA2352057A1 CA 2352057 A1 CA2352057 A1 CA 2352057A1 CA 002352057 A CA002352057 A CA 002352057A CA 2352057 A CA2352057 A CA 2352057A CA 2352057 A1 CA2352057 A1 CA 2352057A1
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Canada
Prior art keywords
stream
fuel
hydrogen
fuel cell
burner
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Abandoned
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CA002352057A
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English (en)
Inventor
Richard Sederquist
Craig Louie
Ryan Cownden
David S. Watkins
Joseph Clausi
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Ballard Power Systems Inc
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Individual
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Publication of CA2352057A1 publication Critical patent/CA2352057A1/fr
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01B—BOILING; BOILING APPARATUS ; EVAPORATION; EVAPORATION APPARATUS
    • B01B1/00—Boiling; Boiling apparatus for physical or chemical purposes ; Evaporation in general
    • B01B1/005—Evaporation for physical or chemical purposes; Evaporation apparatus therefor, e.g. evaporation of liquids for gas phase reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005—Catalytic processes under superatmospheric pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
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    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
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    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • B01J2208/023—Details
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1604—Starting up the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1609—Shutting down the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1614—Controlling the temperature
    • C01B2203/1619—Measuring the temperature
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • C01B2203/1633—Measuring the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • C01B2203/1638—Adjusting the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/169—Controlling the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

L'invention concerne un système de génération d'énergie de pile à combustible comprenant (a) un sous-système de traitement de combustible comportant un reformeur autothermique (112); (b) un séparateur (140) hydrogène qui sépare le flux de reformat du sous-système de traitement de combustible en flux riche en hydrogène et en flux de produit raffiné; (c) un bloc de piles de combustible comportant au moins une pile de combustible fluidiquement reliée de façon à recevoir un flux oxydant, et le flux riche en hydrogène provenant du système de traitement de combustible; et (d) un brûleur (170) fluidiquement relié destiné à pour recevoir le flux de produit raffiné et à le brûler afin de produire un flux de sortie de brûleur composé de dioxyde de carbone et d'oxygène. Dans un mode réalisation, le système comprend en outre un épurateur (182) de dioxyde de carbone fluidiquement relié pour recevoir le flux de sortie de brûleur afin d'évacuer au moins une partie du dioxyde de carbone dudit flux de sortie et de récupérer au moins une partie d'oxygène de ce flux de sortie et d'alimenter le brûleur en flux contenant de l'oxygène. Dans un autre mode de réalisation, ledit système comporte également un turbo-compresseur mécaniquement relié à un turbo-expanseur. Le turbo-compresseur comprime l'air afin de produire un flux oxydant. Le turbo-expanseur est fluidiquement relié pour recevoir le flux de sortie de brûleur. L'invention traite enfin de procédés de fonctionnement de ce système.
CA002352057A 1999-10-05 2000-10-05 Systeme de generation d'energie de pile a combustible a reformeur autothermique Abandoned CA2352057A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US15773199P 1999-10-05 1999-10-05
US60/157,731 1999-10-05
US67990400A 2000-10-05 2000-10-05
PCT/CA2000/001145 WO2001025140A1 (fr) 1999-10-05 2000-10-05 Systeme de generation d'energie de pile a combustible a reformeur autothermique
US09/679,904 2000-10-05

Publications (1)

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CA2352057A1 true CA2352057A1 (fr) 2001-04-12

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CA002352057A Abandoned CA2352057A1 (fr) 1999-10-05 2000-10-05 Systeme de generation d'energie de pile a combustible a reformeur autothermique

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EP (1) EP1144301A1 (fr)
AU (1) AU7765100A (fr)
CA (1) CA2352057A1 (fr)
WO (1) WO2001025140A1 (fr)

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US6916564B2 (en) 2000-05-31 2005-07-12 Nuvera Fuel Cells, Inc. High-efficiency fuel cell power system with power generating expander
US6921595B2 (en) * 2000-05-31 2005-07-26 Nuvera Fuel Cells, Inc. Joint-cycle high-efficiency fuel cell system with power generating turbine
US6531238B1 (en) 2000-09-26 2003-03-11 Reliant Energy Power Systems, Inc. Mass transport for ternary reaction optimization in a proton exchange membrane fuel cell assembly and stack assembly
US20020114747A1 (en) * 2000-12-28 2002-08-22 Kevin Marchand Fuel processing system and apparatus therefor
US7025875B2 (en) 2001-05-14 2006-04-11 Delphi Technologies, Inc. Diesel fuel reforming strategy
US6660416B2 (en) * 2001-06-28 2003-12-09 Ballard Power Systems Inc. Self-inerting fuel processing system
AU2002359575A1 (en) 2001-12-05 2003-06-23 Lawrence G. Clawson High efficiency otto cycle engine with power generating expander
DE10222803B4 (de) * 2002-05-23 2007-04-26 Daimlerchrysler Ag Verfahren zum Betreiben eines Gaserzeugungssystems zum Bereitstellen eines wasserstoffhaltigen Gases
BRPI0506746A (pt) 2004-01-08 2007-05-22 Syntroleum Corp processo para dar a partida em reformador autotérmico
US20050155754A1 (en) * 2004-01-20 2005-07-21 Jeroen Valensa Reformate cooling system for use in a fuel processing subsystem
CA2575629A1 (fr) 2004-06-11 2006-08-10 Nuvera Fuel Cells, Inc. Generateur d'hydrogene a combustible
FR2886765B1 (fr) * 2005-06-06 2010-10-22 Renault Sas Systeme de pile a combustible, et procede associe
US8940660B2 (en) 2008-12-04 2015-01-27 Uop Llc Simultaneous warm gas desulfurization and complete CO-shift for improved syngas cleanup
US20100327231A1 (en) * 2009-06-26 2010-12-30 Noah Whitmore Method of producing synthesis gas
FR2960450B1 (fr) * 2010-05-25 2013-02-22 Inst Francais Du Petrole Procede de production anaerobie d'hydrogene
CN102086522A (zh) * 2010-12-20 2011-06-08 苏州竞立制氢设备有限公司 氢氧分离器洗涤装置
RU2561345C1 (ru) * 2014-09-30 2015-08-27 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ генерации энергии в анаэробной системе
EP3441360B1 (fr) 2017-08-10 2020-07-29 Sener Ingenieria Y Sistemas, S.A. Système de reformage d'alcools et de la production d'hydrogène, des unités de système et procédé associé
EP3693338B1 (fr) 2019-02-07 2021-09-01 Sener Ingenieria Y Sistemas, S.A. Système auto-thermique haute pression pour réformer de l'alcool et produire de l'hydrogène, et procédé correspondant
EP3838841B1 (fr) 2019-12-19 2023-11-01 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Procédé de démarrage de reformeur autothermique

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GB9724203D0 (en) * 1997-11-17 1998-01-14 Johnson Matthey Plc Hydrogen generator

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EP1144301A1 (fr) 2001-10-17
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