CA2333046A1 - Diesel engine antifreeze composition - Google Patents

Diesel engine antifreeze composition

Info

Publication number
CA2333046A1
CA2333046A1 CA002333046A CA2333046A CA2333046A1 CA 2333046 A1 CA2333046 A1 CA 2333046A1 CA 002333046 A CA002333046 A CA 002333046A CA 2333046 A CA2333046 A CA 2333046A CA 2333046 A1 CA2333046 A1 CA 2333046A1
Authority
CA
Canada
Prior art keywords
corrosion
aluminum
combination
polymeric polycarboxylates
cavitation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002333046A
Other languages
French (fr)
Other versions
CA2333046C (en
Inventor
David E. Turcotte
Frances E. Lockwood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Composites IP LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2333046A1 publication Critical patent/CA2333046A1/en
Application granted granted Critical
Publication of CA2333046C publication Critical patent/CA2333046C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides heavy duty long life corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, a combination of nitrite and nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
The addition of selected polymeric polycarboxylates not only significantly reduces glycol based coolant cavitation erosion-corrosion, heat rejecting aluminum corrosion, and hard water precipitates and scale, it has been discovered that polymeric polycarboxylates in combination with siloxane stabilized silicates enhance secondary silicate stabilization leading to improvement in an aluminum corrosion protection and coolant life when utilized with selected amounts of the above-identified additives. The formulations are particularly suitable for automotive applications.
CA002333046A 1998-05-22 1999-05-21 Diesel engine antifreeze composition Expired - Lifetime CA2333046C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8382198A 1998-05-22 1998-05-22
US09/083,821 1998-05-22
PCT/US1999/011324 WO1999061545A1 (en) 1998-05-22 1999-05-21 Diesel engine antifreeze composition

Publications (2)

Publication Number Publication Date
CA2333046A1 true CA2333046A1 (en) 1999-12-02
CA2333046C CA2333046C (en) 2007-02-06

Family

ID=22180917

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002333046A Expired - Lifetime CA2333046C (en) 1998-05-22 1999-05-21 Diesel engine antifreeze composition

Country Status (4)

Country Link
CN (1) CN1246415C (en)
AU (1) AU743301B2 (en)
CA (1) CA2333046C (en)
WO (1) WO1999061545A1 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7754097B2 (en) 2005-08-12 2010-07-13 Honeywell International Inc. Method for stabilizing an engine coolant concentrate and preventing hard water salt formation upon dilution
EP1941076B1 (en) 2005-10-25 2013-03-27 Prestone Products Corporation Heat transfer fluid compositions for cooling systems containing magnesium or magnesium alloys
CN100441657C (en) * 2006-06-12 2008-12-10 蓝星环境工程有限公司 Cooling fluid of engine
CN102272260B (en) * 2008-11-07 2016-04-20 霍尼韦尔国际公司 Heat-transfer fluid and corrosion inhibitor formulations used thereof
US9994755B2 (en) 2012-09-07 2018-06-12 Prestone Products Corporation Heat transfer fluids and corrosion inhibitor formulations for use thereof
US8617416B1 (en) * 2012-09-07 2013-12-31 Prestone Products Corporation Heat transfer fluids and corrosion inhibitor formulations for use thereof
US9080093B2 (en) 2013-02-13 2015-07-14 Basf Se Antifreeze concentrate with corrosion protection and aqueous coolant composition produced therefrom
BR112015018314B1 (en) * 2013-02-13 2021-12-28 Basf Se ANTIFREEZE CONCENTRATE WITH CORROSION PROTECTION, AQUEOUS REFRIGERANT COMPOSITION, USES OF AN AQUEOUS REFRIGERANT COMPOSITION AND A COMPOUND, AND, METHOD FOR REDUCING ALUMINUM HYDROXIDE GEL PRECIPITATION
CN103666389B (en) * 2013-09-30 2016-08-24 安阳化学工业集团有限责任公司 The engine coolant prepared with coal-ethylene glycol waste material
CN103694966B (en) * 2013-09-30 2016-08-24 安阳化学工业集团有限责任公司 Process units and the technique thereof of engine coolant is prepared with coal-ethylene glycol waste material
CN104562039B (en) * 2013-10-24 2017-05-17 中国石油化工股份有限公司 Corrosion inhibitor composition and preparation method thereof
CN104862709A (en) * 2015-04-28 2015-08-26 安徽不二越精工轴承有限公司 Steel material anticorrosion conditioning fluid
CN104804713B (en) * 2015-05-04 2018-04-27 宁波保税区韬鸿化工科技有限公司 Automobile engine water-free cooling
CN104893687B (en) * 2015-06-03 2018-05-29 辽宁石油化工大学 A kind of method that coal-ethylene glycol process waste liquor anti-icing fluid directly processed is quickly handled using inorganic base
JP6734658B2 (en) * 2016-02-15 2020-08-05 株式会社松風 2 Paste type root canal sealer composition
CN108504337A (en) * 2018-04-09 2018-09-07 徐冬 A kind of preparation method of modified ethylene glycol-based antifreeze coolant liquid
CN112143464A (en) * 2020-09-24 2020-12-29 中盐金坛盐化有限责任公司 Nitrate system molten salt heat transfer and storage medium and preparation method thereof
CN113185986A (en) * 2021-04-22 2021-07-30 陕西省交通建设集团公司宜富分公司 Long-acting antifreezing flame-retardant additive for water and preparation method thereof
CN113930221B (en) * 2021-10-27 2023-12-26 常州市鑫光新材料科技有限公司 Special coolant for diesel locomotive
CN114672287B (en) * 2022-04-01 2023-08-18 陶普斯化学科技(北京)有限公司 High corrosion inhibition low conductivity heat transfer medium and preparation method and application thereof

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4370255A (en) * 1978-03-30 1983-01-25 Dow Corning Corporation Stabilization of aqueous silicates using alkali siliconates of silylalkyl phosphonates
US4362644A (en) * 1981-04-01 1982-12-07 Basf Wyandotte Corporation Arylalkyl silicone sulfonate-silicate copolymers
US4354002A (en) * 1981-04-01 1982-10-12 Basf Wyandotte Corporation Novel aliphatic sulfosiloxane-silicate copolymers
US4548787A (en) * 1981-10-26 1985-10-22 Basf Wyandotte Corporation Aqueous liquids containing metal cavitation-erosion corrosion inhibitors
US4440721A (en) * 1981-10-26 1984-04-03 Basf Wyandotte Corporation Aqueous liquids containing metal cavitation-erosion corrosion inhibitors
US4728452A (en) * 1986-01-17 1988-03-01 Pony Industries, Inc. Metal corrosion inhibition in closed cooling systems
US5290469A (en) * 1991-07-23 1994-03-01 Basf Corporation Glycol-based polycarboxylate-containing antifreeze/coolant formulations for resisting cavitation erosion-corrosion on aluminum
US5290468A (en) * 1991-07-23 1994-03-01 Basf Corporation Polycarboxylate-containing antifreeze/coolant additive for use in hard water applications
US5290467A (en) * 1991-07-23 1994-03-01 Basf Corporation Polycarboxylate-containing antifreeze/coolant additive for resisting cavitation erosion-corrosion on aluminum
US5320771A (en) * 1991-07-23 1994-06-14 Basf Corp. Polycarboxylate-containing antifreeze/coolant additive for reducing corrosion in heat rejecting aluminum
US5330670A (en) * 1991-07-23 1994-07-19 Basf Corporation Glycol-based polycarboxylate-containing antifreeze coolant formulations
US5288419A (en) * 1991-07-23 1994-02-22 Basf Corporation Glycol-based polycarboxylate-containing antifreeze/coolant formulations for resisting cavitation erosion-corrosion on aluminum
US5702631A (en) * 1992-11-24 1997-12-30 Ashland Inc. Aqueous corrosion inhibitor formulations

Also Published As

Publication number Publication date
CA2333046C (en) 2007-02-06
AU4094399A (en) 1999-12-13
WO1999061545A1 (en) 1999-12-02
AU743301B2 (en) 2002-01-24
CN1246415C (en) 2006-03-22
CN1308663A (en) 2001-08-15

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Effective date: 20190521