CA2319455A1 - Post-reticulation d'hydrogels a l'aide d'esters boriques - Google Patents

Post-reticulation d'hydrogels a l'aide d'esters boriques Download PDF

Info

Publication number
CA2319455A1
CA2319455A1 CA002319455A CA2319455A CA2319455A1 CA 2319455 A1 CA2319455 A1 CA 2319455A1 CA 002319455 A CA002319455 A CA 002319455A CA 2319455 A CA2319455 A CA 2319455A CA 2319455 A1 CA2319455 A1 CA 2319455A1
Authority
CA
Canada
Prior art keywords
water
acid
weight
polymers
boric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002319455A
Other languages
English (en)
Inventor
Rudiger Funk
Volker Frenz
Uwe Stuven
Friedrich Engelhardt
Thomas Daniel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2319455A1 publication Critical patent/CA2319455A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/245—Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F2013/530481—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne un procédé pour la post-réticulation en surface de polymères hydroabsorbants par traitement de ces derniers avec une solution permettant la post-réticulation en surface. Pendant ou après l'aspersion, les polymères subissent une post-réticulation et sont séchés par élévation de la température à une valeur comprise entre 50 et 250 ·C, et l'agent de réticulation renferme un ester de l'acide borique avec un alcool bivalent ou trivalent dissous dans un solvant inerte. L'invention concerne également des polymères hydroabsorbants s'obtenant selon le procédé précité, ainsi que leur utilisation dans des articles d'hygiène, des matériaux d'emballage et des non-tissés.
CA002319455A 1998-02-21 1999-02-19 Post-reticulation d'hydrogels a l'aide d'esters boriques Abandoned CA2319455A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19807501.4 1998-02-21
DE19807501A DE19807501C1 (de) 1998-02-21 1998-02-21 Verfahren zur Nachvernetzung von Hydrogelen mittels Borsäureestern
PCT/EP1999/001093 WO1999042515A1 (fr) 1998-02-21 1999-02-19 Post-reticulation d'hydrogels a l'aide d'esters boriques

Publications (1)

Publication Number Publication Date
CA2319455A1 true CA2319455A1 (fr) 1999-08-26

Family

ID=7858614

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002319455A Abandoned CA2319455A1 (fr) 1998-02-21 1999-02-19 Post-reticulation d'hydrogels a l'aide d'esters boriques

Country Status (6)

Country Link
EP (1) EP1056800B1 (fr)
JP (1) JP2002504580A (fr)
CA (1) CA2319455A1 (fr)
DE (2) DE19807501C1 (fr)
ES (1) ES2172310T3 (fr)
WO (1) WO1999042515A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6482344B1 (en) * 2000-08-23 2002-11-19 Stockhausen Gmbh & Co. Kg Superabsorbent polymer fibers having improved absorption characteristics
DE10125599A1 (de) 2001-05-25 2002-11-28 Stockhausen Chem Fab Gmbh Superabsorber, Verfahren zu ihrer Herstellung und ihre Verwendung
EP1732974A1 (fr) * 2004-03-30 2006-12-20 Basf Aktiengesellschaft Procede perfectionne de fabrication de polymeres superabsorbants
EP1757641A1 (fr) * 2005-08-23 2007-02-28 The Procter and Gamble Company Procédé de réticulation de la surface de particules de polymères super-absorbants hautement neutralisées en utilisant des acides de Bronsted
JP4694922B2 (ja) * 2005-09-07 2011-06-08 財団法人川村理化学研究所 ホウ酸塩基含有ヒドロゲル及びその製造方法
US20080039542A1 (en) * 2006-08-11 2008-02-14 General Electric Company Composition and associated method
US20090004747A1 (en) * 2007-06-29 2009-01-01 Agree Alan M Film sensors for detecting free chlorine
CN113509918B (zh) * 2020-11-25 2022-06-10 中国科学院青海盐湖研究所 一种用于液体铷铯资源提取的杂多酸盐离子筛吸附剂颗粒制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6018690B2 (ja) * 1981-12-30 1985-05-11 住友精化株式会社 吸水性樹脂の吸水性改良方法
GB2126591B (en) * 1982-09-02 1986-07-30 Kao Corp Process for producing highly water absorptive polymer
JPS60163956A (ja) * 1984-02-04 1985-08-26 Arakawa Chem Ind Co Ltd 吸水性樹脂の製法
FR2606778B1 (fr) * 1986-11-14 1989-02-10 Charbonnages Ste Chimique Procede de reticulation
US4889664A (en) * 1988-11-25 1989-12-26 Vistakon, Inc. Method of forming shaped hydrogel articles including contact lenses
ES2097235T3 (es) * 1991-09-03 1997-04-01 Hoechst Celanese Corp Polimero superabsorbente que tiene propiedades de absorcion mejoradas.
DE4138408A1 (de) * 1991-11-22 1993-05-27 Cassella Ag Hydrophile, hochquellfaehige hydrogele
US5502082A (en) * 1991-12-20 1996-03-26 Alliedsignal Inc. Low density materials having good compression strength and articles formed therefrom
US5662708A (en) * 1995-08-08 1997-09-02 Novamed Medical Products Manufacturing, Inc. Rheologically modified and osmotically balanced fill material for implant

Also Published As

Publication number Publication date
EP1056800A1 (fr) 2000-12-06
ES2172310T3 (es) 2002-09-16
DE59900628D1 (de) 2002-02-21
WO1999042515A1 (fr) 1999-08-26
JP2002504580A (ja) 2002-02-12
EP1056800B1 (fr) 2002-01-16
DE19807501C1 (de) 1999-07-29

Similar Documents

Publication Publication Date Title
US6472478B1 (en) Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones
US6657015B1 (en) Method for the secondary cross-linking of hydrogels with 2-oxotetrahydro-1,3-oxazines
US6559239B1 (en) Method for the secondary cross-linking of hydrogels with N-acyl-2-oxazolidinones
US6503979B1 (en) Method for cross-linking hydrogels with bis- and poly-2-oxazolidinones
US7754822B2 (en) Method for the secondary crosslinking of hydrogels with bicyclic amide acetals
CA2319455A1 (fr) Post-reticulation d'hydrogels a l'aide d'esters boriques
US7655733B2 (en) Postcrosslinking of water absorbing polymers with cyclic carbamates and/or cyclic ureas
CA2319457A1 (fr) Reticulation d'hydrogels avec des esters phosphoriques
MXPA00007062A (en) Secondary cross-linking of hydrogels by means of boric acid esters
MXPA00007001A (en) Cross-linking of hydrogels with phosphoric acid esters
MXPA00007695A (en) Secondary cross-linking of hydrogels with 2-oxazolidinones
MXPA01004094A (en) Method for the secondary cross-linking of hydrogels with 2-oxotetrahydro-1,3-oxazines
MXPA00007225A (en) Method for cross-linking hydrogels with bis- and poly-2-oxazolidinones

Legal Events

Date Code Title Description
FZDE Dead