CA2305193A1 - Alkoxylated amines and their use in cleaning compositions - Google Patents
Alkoxylated amines and their use in cleaning compositions Download PDFInfo
- Publication number
- CA2305193A1 CA2305193A1 CA002305193A CA2305193A CA2305193A1 CA 2305193 A1 CA2305193 A1 CA 2305193A1 CA 002305193 A CA002305193 A CA 002305193A CA 2305193 A CA2305193 A CA 2305193A CA 2305193 A1 CA2305193 A1 CA 2305193A1
- Authority
- CA
- Canada
- Prior art keywords
- composition according
- anionic surfactant
- mole ratio
- amine
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 19
- 150000001412 amines Chemical class 0.000 title claims abstract 5
- 238000004140 cleaning Methods 0.000 title claims abstract 5
- 239000003945 anionic surfactant Substances 0.000 claims abstract 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 3
- 238000007046 ethoxylation reaction Methods 0.000 claims abstract 3
- 230000008021 deposition Effects 0.000 claims abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000003752 hydrotrope Substances 0.000 claims 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 230000000979 retarding effect Effects 0.000 claims 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides an alkoxylated aliphatic amine with 8-18 carbon atoms and 1-8 moles ethoxylation wherein the mole ratio of saturated to unsaturated aliphatic residues falls in the range 40:60 to 80:20. The invention also provides a cleaning composition which comprises: (a) 0.01-15 wt.% an alkoxylated aliphatic amine with 8-18 carbon ataoms and 1-8 moles ethoxylation wherein the mole ratio of saturated to unsaturated aliphatic residues falls in the range 40:60 to 80:20, and (b) 0.01-15 wt.% of an anionic surfactant. Cleaning compositions which comprise the amine show improved viscosity stability on storage. In the presence of the anionic surfactant at low pH the deposition of limescale on surfaces which have been treated with the composition is retarded.
Claims (13)
1. A cleaning composition comprising an alkoxylated aliphatic amine and an anionic surfactant characterised in that it comprises:
a) 0.01-15%wt of an alkoxylated aliphatic amine with 8-18 carbon atoms and 1-8 moles ethoxylation wherein the mole ratio of saturated to unsaturated aliphatic residues falls in the range 40:60 to 80:20.
b) an anionic surfactant in an amount such that the mole ratio of the ethoxylated amine to the anionic surfactant is in the range of 3 to 3.5.
a) 0.01-15%wt of an alkoxylated aliphatic amine with 8-18 carbon atoms and 1-8 moles ethoxylation wherein the mole ratio of saturated to unsaturated aliphatic residues falls in the range 40:60 to 80:20.
b) an anionic surfactant in an amount such that the mole ratio of the ethoxylated amine to the anionic surfactant is in the range of 3 to 3.5.
2. A composition according to claim 1 wherein the ethoxylated aliphatic amine is according to the general formula:
H(A) x-N(R)-(A)y H
wherein R is an alkyl or alkenyl group comprising 8-18 carbon atoms, A is an ethoxy group and x and y may be the same or different and are integers from 1-3.
H(A) x-N(R)-(A)y H
wherein R is an alkyl or alkenyl group comprising 8-18 carbon atoms, A is an ethoxy group and x and y may be the same or different and are integers from 1-3.
3. A composition according to claim 2 wherein x and y are both 1.
4. A composition according to claim 1 wherein R is mixed saturated and unsaturated C14-C18 alkyl.
5. A composition according to claim 1 wherein the mole ratio of saturated to unsaturated fatty acids in the alkoxylated aliphatic amine falls into the range 50:50 to 66:33.
6. A composition according to claim 1 wherein the pH of the composition is less than 1Ø
7. A composition according to claim 1 wherein the mole ratio of the ethoxylated amine and the anionic surfactant is 3.25-3.5.
8. A composition according to claim 1 wherein the anionic surfactant is an alkylaryl sulphonate hydrotrope
9. A composition according to claim 1 having a viscosity between 50 mPas and 1000 mPas when measured at 11.7 sec-1 shear and at 25°C using Haake RV2 rotoviscometer and an MV1 bob.
10. A composition according to claim 1 comprising 0.01-15%wt of a limescale removing acid.
11. A composition according to claim 1 which further comprises a peroxygen compound.
12. A composition according to claim 1 which comprises:
a) 1-10%wt, preferably 3-5%wt sulphamic acid, b) 1-10%wt, preferably 2-5%wt ethoxylated amine, c) 0-5%wt, preferably 0.05-l%wt, nonionic surfactant, d) anionic surfactant hydrotrope, and, e) 1-10%wt, preferably 4-6%wt, hydrogen peroxide
a) 1-10%wt, preferably 3-5%wt sulphamic acid, b) 1-10%wt, preferably 2-5%wt ethoxylated amine, c) 0-5%wt, preferably 0.05-l%wt, nonionic surfactant, d) anionic surfactant hydrotrope, and, e) 1-10%wt, preferably 4-6%wt, hydrogen peroxide
13. A process for retarding the deposition of limescale on a surface which comprises the step of treating said surface with a cleaning composition according to any of claims 1-12 said composition having a pH of less than 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9721691.5A GB9721691D0 (en) | 1997-10-13 | 1997-10-13 | Improvements relating to acidic cleaning compositions |
| GB9721691.5 | 1997-10-13 | ||
| PCT/EP1998/006633 WO1999019431A1 (en) | 1997-10-13 | 1998-10-09 | Alkoxylated amines and their use in cleaning compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2305193A1 true CA2305193A1 (en) | 1999-04-22 |
| CA2305193C CA2305193C (en) | 2010-03-23 |
Family
ID=10820480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2305193A Expired - Fee Related CA2305193C (en) | 1997-10-13 | 1998-10-09 | Alkoxylated amines and their use in cleaning compositions |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP1023423B1 (en) |
| JP (1) | JP4323093B2 (en) |
| KR (1) | KR20010015748A (en) |
| AR (1) | AR017315A1 (en) |
| AU (1) | AU735924B2 (en) |
| BR (1) | BR9813044A (en) |
| CA (1) | CA2305193C (en) |
| DE (1) | DE69821636T2 (en) |
| ES (1) | ES2214747T3 (en) |
| GB (1) | GB9721691D0 (en) |
| HU (1) | HU224521B1 (en) |
| ID (1) | ID24420A (en) |
| IN (1) | IN185797B (en) |
| MY (1) | MY123176A (en) |
| PL (1) | PL188434B1 (en) |
| SK (1) | SK5302000A3 (en) |
| TR (1) | TR200000972T2 (en) |
| WO (1) | WO1999019431A1 (en) |
| ZA (1) | ZA989144B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6617303B1 (en) | 1999-01-11 | 2003-09-09 | Huntsman Petrochemical Corporation | Surfactant compositions containing alkoxylated amines |
| WO2003076559A1 (en) * | 2002-03-13 | 2003-09-18 | Cognis Iberia, S.L. | Concentrated peroxide solutions |
| DE102004055492A1 (en) * | 2004-11-17 | 2006-07-13 | Chemische Fabrik Dr. Weigert Gmbh & Co. Kg | Clean rinse, useful in machine cleaning of plastic parts, tableware, medical and surgical instruments, comprises an alkyl-bis(2-hydroxyalkyl)amine and an acid e.g. citric acid |
| GB0804727D0 (en) * | 2008-03-14 | 2008-04-16 | Reckitt Benckiser Inc | Thickened hard surface cleaning compositions comprising fatty amine alkoxylate compounds |
| US9006286B2 (en) * | 2011-05-10 | 2015-04-14 | Ecolab Usa Inc. | Couplers for medium-chain fatty acids and disinfecting compositions |
| DE102022207153A1 (en) * | 2022-07-13 | 2024-01-18 | Henkel Ag & Co. Kgaa | Detergent-active compounds based on a combination of anions and cationic surfactant |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2459830A1 (en) * | 1979-06-26 | 1981-01-16 | Voreppe Ind Chimiques | Cleaning and descaling compsn. based on aq. sulphamic acid soln. - contg. fatty alkylamine and various ethoxylated cpds. |
| DE3603579A1 (en) * | 1986-02-06 | 1987-08-13 | Henkel Kgaa | USE OF ETHOXYLATED FAT AMINES AS SOLUTION MEDIATOR |
| NO170944C (en) * | 1987-01-24 | 1992-12-30 | Akzo Nv | THICKNESSED, MOISTURE PREPARATIONS, AND USE OF SUCH |
-
1997
- 1997-10-13 GB GBGB9721691.5A patent/GB9721691D0/en active Pending
-
1998
- 1998-10-05 IN IN642BO1998 patent/IN185797B/en unknown
- 1998-10-07 ZA ZA9809144A patent/ZA989144B/en unknown
- 1998-10-09 SK SK530-2000A patent/SK5302000A3/en unknown
- 1998-10-09 BR BR9813044-7A patent/BR9813044A/en not_active IP Right Cessation
- 1998-10-09 AR ARP980105039A patent/AR017315A1/en active IP Right Grant
- 1998-10-09 DE DE69821636T patent/DE69821636T2/en not_active Expired - Lifetime
- 1998-10-09 ES ES98955491T patent/ES2214747T3/en not_active Expired - Lifetime
- 1998-10-09 PL PL98339808A patent/PL188434B1/en not_active IP Right Cessation
- 1998-10-09 JP JP2000515989A patent/JP4323093B2/en not_active Expired - Fee Related
- 1998-10-09 EP EP98955491A patent/EP1023423B1/en not_active Expired - Lifetime
- 1998-10-09 HU HU0004913A patent/HU224521B1/en not_active IP Right Cessation
- 1998-10-09 AU AU12298/99A patent/AU735924B2/en not_active Ceased
- 1998-10-09 KR KR1020007003926A patent/KR20010015748A/en not_active Application Discontinuation
- 1998-10-09 TR TR2000/00972T patent/TR200000972T2/en unknown
- 1998-10-09 ID IDW20000660A patent/ID24420A/en unknown
- 1998-10-09 WO PCT/EP1998/006633 patent/WO1999019431A1/en active IP Right Grant
- 1998-10-09 CA CA2305193A patent/CA2305193C/en not_active Expired - Fee Related
- 1998-10-12 MY MYPI98004650A patent/MY123176A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU735924B2 (en) | 2001-07-19 |
| JP2001520259A (en) | 2001-10-30 |
| WO1999019431A1 (en) | 1999-04-22 |
| EP1023423A1 (en) | 2000-08-02 |
| ZA989144B (en) | 2000-04-07 |
| MY123176A (en) | 2006-05-31 |
| KR20010015748A (en) | 2001-02-26 |
| SK5302000A3 (en) | 2000-09-12 |
| CA2305193C (en) | 2010-03-23 |
| DE69821636D1 (en) | 2004-03-18 |
| TR200000972T2 (en) | 2000-11-21 |
| PL188434B1 (en) | 2005-01-31 |
| ES2214747T3 (en) | 2004-09-16 |
| AU1229899A (en) | 1999-05-03 |
| ID24420A (en) | 2000-07-20 |
| BR9813044A (en) | 2000-08-15 |
| JP4323093B2 (en) | 2009-09-02 |
| HUP0004913A3 (en) | 2005-06-28 |
| PL339808A1 (en) | 2001-01-02 |
| HUP0004913A2 (en) | 2001-05-28 |
| HU224521B1 (en) | 2005-10-28 |
| EP1023423B1 (en) | 2004-02-11 |
| GB9721691D0 (en) | 1997-12-10 |
| DE69821636T2 (en) | 2004-07-29 |
| AR017315A1 (en) | 2001-09-05 |
| IN185797B (en) | 2001-05-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20151009 |