CA2294127A1 - Anti-reflective films - Google Patents

Anti-reflective films Download PDF

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Publication number
CA2294127A1
CA2294127A1 CA002294127A CA2294127A CA2294127A1 CA 2294127 A1 CA2294127 A1 CA 2294127A1 CA 002294127 A CA002294127 A CA 002294127A CA 2294127 A CA2294127 A CA 2294127A CA 2294127 A1 CA2294127 A1 CA 2294127A1
Authority
CA
Canada
Prior art keywords
coating
metal oxide
refractive index
reflective films
equals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002294127A
Other languages
French (fr)
Other versions
CA2294127C (en
Inventor
Richard J. Mccurdy
Michel J. Soubeyrand
Ronald D. Goodman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pilkington North America Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2294127A1 publication Critical patent/CA2294127A1/en
Application granted granted Critical
Publication of CA2294127C publication Critical patent/CA2294127C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G02B1/113—Anti-reflection coatings using inorganic layer materials only
    • G02B1/115—Multilayers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
    • C03C17/3435—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a nitride, oxynitride, boronitride or carbonitride
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G02B1/113—Anti-reflection coatings using inorganic layer materials only
    • G02B1/115—Multilayers
    • G02B1/116—Multilayers including electrically conducting layers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/73—Anti-reflective coatings with specific characteristics
    • C03C2217/734—Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)

Abstract

An anti-reflective glass article including a glass substrate, a first coating of a metal oxide and a second coating of a metal oxide. The first coating of metal oxide is applied over the substrate. The refractive index of the first coating of metal oxide ranges from 1.8 to 2.6. The thickness of the first coating is greater than 1/(4*n), wherein 1 equals a design wavelength in the visible spectrum and n equals the refractive index of said first coating of metal oxide. The second coating of metal oxide is applied over the first coating. The second coating of metal oxide has a refractive index of about 1.45 to about 1.6 and a thickness of less than 1/4(n).
CA002294127A 1997-07-07 1998-07-06 Anti-reflective films Expired - Fee Related CA2294127C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US5179997P 1997-07-07 1997-07-07
US60/051,799 1997-07-07
US09/024,228 US5935716A (en) 1997-07-07 1998-02-17 Anti-reflective films
US024,228 1998-02-17
PCT/US1998/013968 WO1999002338A1 (en) 1997-07-07 1998-07-06 Anti-reflective films

Publications (2)

Publication Number Publication Date
CA2294127A1 true CA2294127A1 (en) 1999-01-21
CA2294127C CA2294127C (en) 2007-09-11

Family

ID=26698202

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002294127A Expired - Fee Related CA2294127C (en) 1997-07-07 1998-07-06 Anti-reflective films

Country Status (13)

Country Link
US (1) US5935716A (en)
EP (1) EP1009629B1 (en)
JP (1) JP4908661B2 (en)
KR (1) KR100574720B1 (en)
CN (1) CN1131145C (en)
AT (1) ATE408499T1 (en)
AU (1) AU731891B2 (en)
BR (1) BR9810688A (en)
CA (1) CA2294127C (en)
DE (1) DE69840026D1 (en)
MY (1) MY123926A (en)
TW (1) TW483874B (en)
WO (1) WO1999002338A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746121A (en) * 2019-11-08 2020-02-04 中国南玻集团股份有限公司 Composite glass and preparation method and application thereof

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US6165598A (en) * 1998-08-14 2000-12-26 Libbey-Owens-Ford Co. Color suppressed anti-reflective glass
JP2001209038A (en) * 1999-11-17 2001-08-03 Nippon Sheet Glass Co Ltd Substrate for liquid crystal display element
EP1176434B1 (en) 2000-07-27 2006-09-06 Asahi Glass Company Ltd. Substrate provided with antireflection films and its production method
JP4033286B2 (en) * 2001-03-19 2008-01-16 日本板硝子株式会社 High refractive index dielectric film and manufacturing method thereof
JP2003121606A (en) * 2001-08-07 2003-04-23 Fuji Photo Film Co Ltd Antireflection film, polarizing plate and image display device
US20030049464A1 (en) 2001-09-04 2003-03-13 Afg Industries, Inc. Double silver low-emissivity and solar control coatings
CN1620336A (en) * 2001-12-21 2005-05-25 日本板硝子株式会社 Member having photocatalytic function and method for manufacture thereof
DE602005003234T2 (en) 2004-07-12 2008-08-28 Cardinal Cg Co., Eden Prairie MAINTENANCE-FREE COATINGS
US8092660B2 (en) 2004-12-03 2012-01-10 Cardinal Cg Company Methods and equipment for depositing hydrophilic coatings, and deposition technologies for thin films
US7923114B2 (en) 2004-12-03 2011-04-12 Cardinal Cg Company Hydrophilic coatings, methods for depositing hydrophilic coatings, and improved deposition technology for thin films
CN101072735B (en) * 2004-12-06 2011-08-10 日本板硝子株式会社 Glass member having photocatalytic function and heat ray reflective function, and double layer glass employing it
FR2898295B1 (en) * 2006-03-10 2013-08-09 Saint Gobain TRANSPARENT ANTIREFLECTION SUBSTRATE WITH NEUTRAL COLOR IN REFLECTION
WO2007121211A2 (en) 2006-04-11 2007-10-25 Cardinal Cg Company Photocatalytic coatings having improved low-maintenance properties
US7989094B2 (en) 2006-04-19 2011-08-02 Cardinal Cg Company Opposed functional coatings having comparable single surface reflectances
US20080011599A1 (en) 2006-07-12 2008-01-17 Brabender Dennis M Sputtering apparatus including novel target mounting and/or control
WO2009036284A1 (en) * 2007-09-14 2009-03-19 Cardinal Cg Company Low-maintenance coatings, and methods for producing low-maintenance coatings
KR101028017B1 (en) * 2007-10-01 2011-04-13 현대자동차주식회사 Preparation of non-colored and high transparent F-dopped Tin oxide film by postprocessing of polymer
FR2973023B1 (en) 2011-03-25 2019-08-02 Saint-Gobain Glass France MULTIPLE INSULATION GLAZING COMPRISING TWO LOW EMISSIVE STACKS
BE1019988A3 (en) * 2011-05-24 2013-03-05 Agc Glass Europe TRANSPARENT VERRIER SUBSTRATE CARRYING A COATING OF SUCCESSIVE LAYERS.
JP6082907B2 (en) * 2012-02-17 2017-02-22 株式会社Ｊｏｌｅｄ Display device and manufacturing method of display device
US9684097B2 (en) 2013-05-07 2017-06-20 Corning Incorporated Scratch-resistant articles with retained optical properties
US9359261B2 (en) 2013-05-07 2016-06-07 Corning Incorporated Low-color scratch-resistant articles with a multilayer optical film
US9703011B2 (en) 2013-05-07 2017-07-11 Corning Incorporated Scratch-resistant articles with a gradient layer
US9110230B2 (en) 2013-05-07 2015-08-18 Corning Incorporated Scratch-resistant articles with retained optical properties
US9366784B2 (en) 2013-05-07 2016-06-14 Corning Incorporated Low-color scratch-resistant articles with a multilayer optical film
US9335444B2 (en) 2014-05-12 2016-05-10 Corning Incorporated Durable and scratch-resistant anti-reflective articles
US11267973B2 (en) 2014-05-12 2022-03-08 Corning Incorporated Durable anti-reflective articles
GB201409408D0 (en) * 2014-05-28 2014-07-09 Pilkington Group Ltd A glazing
US9790593B2 (en) 2014-08-01 2017-10-17 Corning Incorporated Scratch-resistant materials and articles including the same
EP3212590B1 (en) * 2014-10-31 2020-12-09 Pilkington Group Limited Anti-reflective coated glass article
KR101691423B1 (en) * 2014-12-24 2017-01-02 한라대학교 산학협력단 Method for producing fluorine doped tin oxide thin film
EP3300520B1 (en) 2015-09-14 2020-11-25 Corning Incorporated High light transmission and scratch-resistant anti-reflective articles
CN105366958A (en) * 2015-11-30 2016-03-02 太仓市建兴石英玻璃厂 Special-shaped quartz glass tube
EP3541762B1 (en) 2016-11-17 2022-03-02 Cardinal CG Company Static-dissipative coating technology
GB201718715D0 (en) 2017-11-13 2017-12-27 Pilkington Nederland B V Multifunctional glazing unit
CN111094200B (en) 2018-08-17 2022-01-07 康宁股份有限公司 Inorganic oxide articles with thin durable antireflective structures
CN113574024A (en) * 2019-03-14 2021-10-29 皮尔金顿集团有限公司 Glass article with anti-reflective coating
WO2023111568A1 (en) 2021-12-16 2023-06-22 Pilkington Group Limited Glazing unit

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US2478385A (en) * 1946-12-07 1949-08-09 Libbey Owens Ford Glass Co Multilayer low light reflecting film
GB2119360B (en) * 1982-04-30 1986-03-26 Glaverbel Coating vitreous substrates
GB2136316B (en) * 1983-03-17 1986-05-29 Glaverbel Coated glazing materials
US5508091A (en) * 1992-12-04 1996-04-16 Photran Corporation Transparent electrodes for liquid cells and liquid crystal displays
US5749931A (en) * 1993-07-08 1998-05-12 Libbey-Owens-Ford Co. Coatings on glass
US5450238A (en) * 1993-12-10 1995-09-12 Viratec Thin Films, Inc. Four-layer antireflection coating for deposition in in-like DC sputtering apparatus
US5579162A (en) * 1994-10-31 1996-11-26 Viratec Thin Films, Inc. Antireflection coating for a temperature sensitive substrate
US5744215A (en) * 1996-01-04 1998-04-28 Ppg Industries, Inc. Reduction of haze in transparent coatings
US5750265A (en) * 1996-01-11 1998-05-12 Libbey-Owens-Ford Co. Coated glass article having a pyrolytic solar control coating
US5698262A (en) * 1996-05-06 1997-12-16 Libbey-Owens-Ford Co. Method for forming tin oxide coating on glass
US5780149A (en) * 1996-09-13 1998-07-14 Libbey-Ownes-Ford Co. Glass article having a solar control coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746121A (en) * 2019-11-08 2020-02-04 中国南玻集团股份有限公司 Composite glass and preparation method and application thereof

Also Published As

Publication number Publication date
CN1131145C (en) 2003-12-17
ATE408499T1 (en) 2008-10-15
BR9810688A (en) 2000-09-05
US5935716A (en) 1999-08-10
JP4908661B2 (en) 2012-04-04
CA2294127C (en) 2007-09-11
AU731891B2 (en) 2001-04-05
KR20010021525A (en) 2001-03-15
JP2002511048A (en) 2002-04-09
TW483874B (en) 2002-04-21
KR100574720B1 (en) 2006-04-28
EP1009629A4 (en) 2005-01-05
MY123926A (en) 2006-06-30
CN1261847A (en) 2000-08-02
WO1999002338A1 (en) 1999-01-21
DE69840026D1 (en) 2008-10-30
AU8290098A (en) 1999-02-08
EP1009629A1 (en) 2000-06-21
EP1009629B1 (en) 2008-09-17

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