CA2247921C - Heat transfer fluid - Google Patents
Heat transfer fluid Download PDFInfo
- Publication number
- CA2247921C CA2247921C CA002247921A CA2247921A CA2247921C CA 2247921 C CA2247921 C CA 2247921C CA 002247921 A CA002247921 A CA 002247921A CA 2247921 A CA2247921 A CA 2247921A CA 2247921 C CA2247921 C CA 2247921C
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- CA
- Canada
- Prior art keywords
- heat transfer
- cooling fluid
- heat
- trimethyl glycine
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention relates to a heat transfer/cooling fluid for low temperatures.
The heat transfer/cooling fluid contains trimethyl glycine 15...70 % and water 30...85 %. The heat transfer fluid of the invention is environment-friendly and non-toxic, it has good heat tranfer properties, and it is suitable, for example, for the needs of the food industry and for solar panels.
The heat transfer/cooling fluid contains trimethyl glycine 15...70 % and water 30...85 %. The heat transfer fluid of the invention is environment-friendly and non-toxic, it has good heat tranfer properties, and it is suitable, for example, for the needs of the food industry and for solar panels.
Description
Heat transfer fluid The invention relates to a heat transfer/cooling fluid for a wide range of uses, especially fox heat transfer uses presupposing environment-friendliness and health viewpoints, for example non-toxicity and a wide temperature range.
Heat transfer/cooling fluids are commonly used in industry, technical installations in buildings, refrigeration equipment and motor applications.
Good heat transfer properties are important in heat transfer/cooling fluids.
This presupposes a good specific thermal capacity, thermal conductivity and pumpability.
A low viscosity value at low temperatures is typical of heat transfer fluids, because in such a case the fluid can be brought into a turbulent flow with a lower pump power.
In addition to the above properties, important properties of heat transfer fluids often also include environment-friendliness and non-toxicity, in particular when used in the food industry and in the heating of household water. The heat transfer fluid must not be in any way harmful to the products being processed. Slight leakages of the fluid into the process could cause severe accidents. Therefore non-toxicity of the fluid is one of the most crucial factors.
The most typical fluids are organic and water-containing heat transfer/cooling fluids.
The problem with organic fluids is the difficulty in their use and their toxicity. With respect to most of its properties, water is a nearly perfect heat exchange fluid. It has good heat transfer and pumpability properties. In addition, water is completely non-toxic and non-hazardous to the environment. In addition, it is in no way flammable.
Indeed, the major disadvantage of water is the narrow temperature range for its use.
Heat transfer/cooling fluids are commonly used in industry, technical installations in buildings, refrigeration equipment and motor applications.
Good heat transfer properties are important in heat transfer/cooling fluids.
This presupposes a good specific thermal capacity, thermal conductivity and pumpability.
A low viscosity value at low temperatures is typical of heat transfer fluids, because in such a case the fluid can be brought into a turbulent flow with a lower pump power.
In addition to the above properties, important properties of heat transfer fluids often also include environment-friendliness and non-toxicity, in particular when used in the food industry and in the heating of household water. The heat transfer fluid must not be in any way harmful to the products being processed. Slight leakages of the fluid into the process could cause severe accidents. Therefore non-toxicity of the fluid is one of the most crucial factors.
The most typical fluids are organic and water-containing heat transfer/cooling fluids.
The problem with organic fluids is the difficulty in their use and their toxicity. With respect to most of its properties, water is a nearly perfect heat exchange fluid. It has good heat transfer and pumpability properties. In addition, water is completely non-toxic and non-hazardous to the environment. In addition, it is in no way flammable.
Indeed, the major disadvantage of water is the narrow temperature range for its use.
As is known, water freezes at 0 °C and boils at 100 °C.
Furthermore, water causes corrosion, especially in connection with iron-containing materials.
As to the state of the art regarding heat transfer fluids used at low temperatures, reference can be made to, for example, EP application publication 0641849, which discloses a heat transfer fluid composition comprising an alkylmethylsiloxane fluid or a combination of alkylmethylsiloxane fluids and various fluids based on polydiorganosiloxane with terminal trimethylsilyl groups.
The most typical water-based heat transfer fluids are aqueous mixtures of ethylene glycol, propylene glycol and ethanol. Ethylene glycol is one of the best known heat transfer fluids, and it is used in particular in the automobile industry.
However, the use of ethylene glycol has disadvantages in that the substance is toxic and is not very environment-friendly. Propylene glycol is indeed often used instead of ethylene glycol in applications in which less toxic properties are required. Although propylene glycol is relatively non-toxic, it is, nevertheless, a substance which pollutes the environment. One disadvantage of propylene glycol is the great increase in its vis-cosity at low temperatures; this increases the required pump power.
The non-toxicity of ethanol as compared with ethylene glycol is an advantage in its use, but its use has the disadvantage in its great volatility and consequently in its constituting a fire hazard and great increase in its viscosity at low temperatures, the latter being, however, more advantageous than with propylene glycols. For this reason ethanol is a commonly used substance as a heat transfer fluid in laboratories and in conditions requiring non-toxicity. However, the use of ethanol involves the problem that it requires permits from the health authorities, a factor which compli-Gates the use of this fluid.
Corrosion, in particular in the case of glycols, has forced users to seek expensive and effective corrosion inhibitors. The monitoring of the composition and concentra-tion of corrosion inhibitors is difficult. In general, an effective inhibitor makes an otherwise highly non toxic liquitd toxic. Typically complicated solutions increase the cost of the end solution_ As regards the state of the art associated with corrosion inlu'bitors, referetxe can be made to EP application publication 0369100. which discloses a heat transfer fluid which contains a dicarboxylic acid mixture as a corrosion inhibitor and in which the cooling fluid composition compzises a water-Soluble liquid alcohol to lower the freezing point; for example ethylene glycol and a mixnire of ~ycol and dierhylene glycol have been used in that capacity.
The goal of the present invention is to provide a heal transfer/cooling fluid in which the problems and disadvantages of state-of-the-art options have bees eliminated, or at least substantially minimized_ It is an object of the invention to provide a heat transfer/cooling fluid which is suitable for use at Iow temperatures and which is safe in terms of health and the environment and technically economical to use.
The heat tra~ferlcooling fluid according to tile invention is primarily characterized in that it contains trimerhyl glycine or a derivative thereof 15_..0 ~ gad water 30...85 % . The most typical cooling fluid accordi~ to the invention contains tri-methyl dlyciae 35 % .
According to one aspect of the present invention, there is provided a heat transfer/cooling fluid, wherein the heat transfer/cooling fluid comprises about 15 to about 70 % of trimethyl glycine or derivatives thereof and about 30 to about 85 % weight of water.
According to a further aspect of the present invention, there is provided a method for transferring heat comprising the steps of generating a heat transferlcooling fluid comprising from about 15 to about 70 % weight of trimethyl glycine or salts of trimethyl glycine hydrate by weight and from about 30 to about 85 % weight of water by weight, and adding the fluid to a heat transfer fluid system.
3a A preferred compound for use as a component is the heat transfer fluid is trimeth~l glycine or salu of trimethyl glycine hydrate. An especially preferred compaiund is trimethyl alycine, i.e. betaiae. The lager can be prepared by isolating ii from natural products. e.g. sugar beet; this enables a heat transfer fluid of a biologic origin, haviag an advantageous life cycle, to be prepared.
The heat transfer/cooling fluid according to the invention has the advantages of non-tozicity and simplicity. Its physical properties are the same as those of glycol soiuuons_ .The heat cransferJcooling fluid according to the invention is suitable for use at temperatures of -50... + 100 °C. A preferred temperature range in heat pumps and in refrigeration equipment is -40... +70 °C. Furthermore, a heat transfer/cooling fluid according to the invention withstands boiling, which occasion-ally occurs in solar panels.
Together with the heat transfer/cooling fluid according to the invention it is possible to use conventional corrosion inhibitors, stabilizing agents and marking agents, necessary at a given time, which are well known in the art.
The heat transfer/cooling fluid according to the invention is less toxic and more environment-friendly than known cooling fluids. It is not classified as a problem waste, and its easy destruction decreases the costs. The handling of the waste of a heat transfer fluid according to the invention does not require special measures; it can be absorbed into soil or be run into a drain, whereas the ethylene and propylene glycols and ethanol used in state-of the-art options have to be treated either at a problem waste treatment plant or under the supervision of public authorities.
The heat transfer/cooling fluid according to the invention is suitable for use in various applications, especially in those in which the temperatures are low and which require the fluid to be environment-friendly and non-toxic, for example in the food industry. Some applications which can be mentioned include solar heat systems, heat pumps, refrigeration equipment, ventilation and air-conditioning equipment, in which in particular heat or~cold is recovered from the exit air and is transferred to the inlet air. One application which can be mentioned is solar panels.
Example 1 The toxicity of the fluids was assessed on the basis of LDSO values obtained from the literature. The LDS~ values used have been tested orally on rats. The values are shown in Table I.
Table I
Material LDSo/mg/kg Ethylene glycol 4 700 5 Propylene glycol 20 000 Ethanol 7 060 Trimethyl glycine 11 179 Example II
The viscosity values of fluids at the same concentrations are compared in Table II.
Table III shows a comparison at a concentration corresponding to a freezing point of -15 °C. The freezing point is the temperature at which the first crystals are formed in the solution.
Table II
Fluid Concentra-Kinetic tion viscosity Wt% mm2/s Temperature 20 C 0 C - I 0 -20 C C
Ethylene glycol 50 3,48 7,40 11,7 19,6 Propylene glycol 50 6,44 18,70 38 87 Ethanol 50 3,10 7,22 12,20 23 Trimethyl 50 5,90 12,80 21,50 38 glycine Table III
Fluid Concentra- Kinetic tion viscosity Wt % mm2/s Temperature 20C 0C -10C -15C
Ethylene glycol 30,5 2,1 4,3 6,5 8,2 Propylene glycol 33 3,3 7,8 14,4 20 Ethanol 24,5 2,5 5,9 10,9 15,8 Trimethyl 35 2,1 5,1 11 17,2 glycine Example III
The lowering of the freezing point for various solutions at a concentration of 50 wt. % is shown in Table IV.
Table IV
Fluid Freezing point for a 50 wt. % solution / C
Ethyl glycol -35 Propyl glycol -34 Ethanol -38 Trimethyl glycine -43 The invention is described above with reference to only a few of its preferred examples; however, the purpose is not to limit the invention strictly to the details of the examples. Many modifications and variations are possible within the inventive idea defined in the following patent claims.
Furthermore, water causes corrosion, especially in connection with iron-containing materials.
As to the state of the art regarding heat transfer fluids used at low temperatures, reference can be made to, for example, EP application publication 0641849, which discloses a heat transfer fluid composition comprising an alkylmethylsiloxane fluid or a combination of alkylmethylsiloxane fluids and various fluids based on polydiorganosiloxane with terminal trimethylsilyl groups.
The most typical water-based heat transfer fluids are aqueous mixtures of ethylene glycol, propylene glycol and ethanol. Ethylene glycol is one of the best known heat transfer fluids, and it is used in particular in the automobile industry.
However, the use of ethylene glycol has disadvantages in that the substance is toxic and is not very environment-friendly. Propylene glycol is indeed often used instead of ethylene glycol in applications in which less toxic properties are required. Although propylene glycol is relatively non-toxic, it is, nevertheless, a substance which pollutes the environment. One disadvantage of propylene glycol is the great increase in its vis-cosity at low temperatures; this increases the required pump power.
The non-toxicity of ethanol as compared with ethylene glycol is an advantage in its use, but its use has the disadvantage in its great volatility and consequently in its constituting a fire hazard and great increase in its viscosity at low temperatures, the latter being, however, more advantageous than with propylene glycols. For this reason ethanol is a commonly used substance as a heat transfer fluid in laboratories and in conditions requiring non-toxicity. However, the use of ethanol involves the problem that it requires permits from the health authorities, a factor which compli-Gates the use of this fluid.
Corrosion, in particular in the case of glycols, has forced users to seek expensive and effective corrosion inhibitors. The monitoring of the composition and concentra-tion of corrosion inhibitors is difficult. In general, an effective inhibitor makes an otherwise highly non toxic liquitd toxic. Typically complicated solutions increase the cost of the end solution_ As regards the state of the art associated with corrosion inlu'bitors, referetxe can be made to EP application publication 0369100. which discloses a heat transfer fluid which contains a dicarboxylic acid mixture as a corrosion inhibitor and in which the cooling fluid composition compzises a water-Soluble liquid alcohol to lower the freezing point; for example ethylene glycol and a mixnire of ~ycol and dierhylene glycol have been used in that capacity.
The goal of the present invention is to provide a heal transfer/cooling fluid in which the problems and disadvantages of state-of-the-art options have bees eliminated, or at least substantially minimized_ It is an object of the invention to provide a heat transfer/cooling fluid which is suitable for use at Iow temperatures and which is safe in terms of health and the environment and technically economical to use.
The heat tra~ferlcooling fluid according to tile invention is primarily characterized in that it contains trimerhyl glycine or a derivative thereof 15_..0 ~ gad water 30...85 % . The most typical cooling fluid accordi~ to the invention contains tri-methyl dlyciae 35 % .
According to one aspect of the present invention, there is provided a heat transfer/cooling fluid, wherein the heat transfer/cooling fluid comprises about 15 to about 70 % of trimethyl glycine or derivatives thereof and about 30 to about 85 % weight of water.
According to a further aspect of the present invention, there is provided a method for transferring heat comprising the steps of generating a heat transferlcooling fluid comprising from about 15 to about 70 % weight of trimethyl glycine or salts of trimethyl glycine hydrate by weight and from about 30 to about 85 % weight of water by weight, and adding the fluid to a heat transfer fluid system.
3a A preferred compound for use as a component is the heat transfer fluid is trimeth~l glycine or salu of trimethyl glycine hydrate. An especially preferred compaiund is trimethyl alycine, i.e. betaiae. The lager can be prepared by isolating ii from natural products. e.g. sugar beet; this enables a heat transfer fluid of a biologic origin, haviag an advantageous life cycle, to be prepared.
The heat transfer/cooling fluid according to the invention has the advantages of non-tozicity and simplicity. Its physical properties are the same as those of glycol soiuuons_ .The heat cransferJcooling fluid according to the invention is suitable for use at temperatures of -50... + 100 °C. A preferred temperature range in heat pumps and in refrigeration equipment is -40... +70 °C. Furthermore, a heat transfer/cooling fluid according to the invention withstands boiling, which occasion-ally occurs in solar panels.
Together with the heat transfer/cooling fluid according to the invention it is possible to use conventional corrosion inhibitors, stabilizing agents and marking agents, necessary at a given time, which are well known in the art.
The heat transfer/cooling fluid according to the invention is less toxic and more environment-friendly than known cooling fluids. It is not classified as a problem waste, and its easy destruction decreases the costs. The handling of the waste of a heat transfer fluid according to the invention does not require special measures; it can be absorbed into soil or be run into a drain, whereas the ethylene and propylene glycols and ethanol used in state-of the-art options have to be treated either at a problem waste treatment plant or under the supervision of public authorities.
The heat transfer/cooling fluid according to the invention is suitable for use in various applications, especially in those in which the temperatures are low and which require the fluid to be environment-friendly and non-toxic, for example in the food industry. Some applications which can be mentioned include solar heat systems, heat pumps, refrigeration equipment, ventilation and air-conditioning equipment, in which in particular heat or~cold is recovered from the exit air and is transferred to the inlet air. One application which can be mentioned is solar panels.
Example 1 The toxicity of the fluids was assessed on the basis of LDSO values obtained from the literature. The LDS~ values used have been tested orally on rats. The values are shown in Table I.
Table I
Material LDSo/mg/kg Ethylene glycol 4 700 5 Propylene glycol 20 000 Ethanol 7 060 Trimethyl glycine 11 179 Example II
The viscosity values of fluids at the same concentrations are compared in Table II.
Table III shows a comparison at a concentration corresponding to a freezing point of -15 °C. The freezing point is the temperature at which the first crystals are formed in the solution.
Table II
Fluid Concentra-Kinetic tion viscosity Wt% mm2/s Temperature 20 C 0 C - I 0 -20 C C
Ethylene glycol 50 3,48 7,40 11,7 19,6 Propylene glycol 50 6,44 18,70 38 87 Ethanol 50 3,10 7,22 12,20 23 Trimethyl 50 5,90 12,80 21,50 38 glycine Table III
Fluid Concentra- Kinetic tion viscosity Wt % mm2/s Temperature 20C 0C -10C -15C
Ethylene glycol 30,5 2,1 4,3 6,5 8,2 Propylene glycol 33 3,3 7,8 14,4 20 Ethanol 24,5 2,5 5,9 10,9 15,8 Trimethyl 35 2,1 5,1 11 17,2 glycine Example III
The lowering of the freezing point for various solutions at a concentration of 50 wt. % is shown in Table IV.
Table IV
Fluid Freezing point for a 50 wt. % solution / C
Ethyl glycol -35 Propyl glycol -34 Ethanol -38 Trimethyl glycine -43 The invention is described above with reference to only a few of its preferred examples; however, the purpose is not to limit the invention strictly to the details of the examples. Many modifications and variations are possible within the inventive idea defined in the following patent claims.
Claims (18)
1. A heat transfer/cooling fluid, wherein the heat transfer/cooling fluid comprises about 15 to about 70% weight of trimethyl glycine or derivatives thereof and about 30 to about 85% weight of water.
2. A heat transfer/cooling fluid according to claim 1, wherein the heat transfer/cooling fluid contains salts of trimethyl glycine hydrate.
3. A heat transfer/cooling fluid according to claim 1, wherein the heat transfer/cooling fluid contains trimethyl glycine.
4. A heat transfer/cooling fluid according to claim 3, wherein the trimethyl glycine is of a biologic origin.
5. A heat transfer/cooling fluid according to claim 3 or 4, wherein the heat transfer/cooling fluid comprises about 30 to about 50% weight of trimethyl glycine and about 50 to about 70% weight of water.
6. A heat transfer/cooling fluid according to claim 3, 4 or 5, wherein the heat transfer/cooling fluid contains approximately 35% weight of trimethyl glycine and approximately 65% weight of water.
7. A heat transfer/cooling fluid according to any one of claims 1 to 6, wherein the temperature range of use of the heat transfer/cooling fluid is from about -50 to about +100 °C.
8. A heat transfer/cooling fluid according to any one of claims 1 to 6, wherein the temperature range of use of the heat transfer/cooling fluid is from about -40 to about +70 °C.
9. Use of the heat transfer/cooling fluid as defined in any one of claims 1 to 8, in a solar based system, a heat pump, refrigeration equipment, ventilation equipment or air-conditioning equipment.
10. A method for transferring heat comprising the steps of:
generating a heat transfer/cooling fluid comprising from about 15 to about 70%
weight of trimethyl glycine or salts of trimethyl glycine hydrate by weight and from about 30 to about 85% weight of water by weight; and adding said fluid to a heat transfer fluid system.
generating a heat transfer/cooling fluid comprising from about 15 to about 70%
weight of trimethyl glycine or salts of trimethyl glycine hydrate by weight and from about 30 to about 85% weight of water by weight; and adding said fluid to a heat transfer fluid system.
11. A method for transferring heat according to claim 10, wherein the heat transfer/cooling fluid contains salts of trimethyl glycine hydrate.
12. A method for transferring heat according to claim 10, wherein the heat transfer/cooling fluid contains trimethyl glycine.
13. A method for transferring heat according to claim 12, wherein the trimethyl glycine is of a biologic origin.
14. A method for transferring heat according to claim 12 or 13, wherein the heat transfer/cooling fluid comprises from about 30 to about 50% trimethyl glycine and from about 50 to about 70% of water.
15. A method for transferring heat according to claim 12, 13 or 14, wherein the heat transfer/cooling fluid contains approximately 35% of trimethyl glycine and approximately 65% of water.
16. A method for transferring heat according to any one of claims 10 to 15, wherein the temperature range of use of the heat transfer/cooling liquid is from about -50 to about +100° C.
17. A method for transferring heat according to any one of claims 10 to 15, wherein the temperature range of use of the heat transfer/cooling is from about -40 to about +70° C.
18. A method for transferring heat according to any one of claims 10 to 17, wherein said heat transfer system is selected from a solar based system, heat pump system, refrigeration equipment system, ventilation equipment system and air-conditioning equipment system.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI960971 | 1996-03-01 | ||
| FI960971A FI99260C (en) | 1996-03-01 | 1996-03-01 | Heat Transfer fluid |
| PCT/FI1997/000131 WO1997031988A1 (en) | 1996-03-01 | 1997-02-27 | Heat transfer fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2247921A1 CA2247921A1 (en) | 1997-09-04 |
| CA2247921C true CA2247921C (en) | 2006-05-23 |
Family
ID=36481483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002247921A Expired - Lifetime CA2247921C (en) | 1996-03-01 | 1997-02-27 | Heat transfer fluid |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2247921C (en) |
-
1997
- 1997-02-27 CA CA002247921A patent/CA2247921C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2247921A1 (en) | 1997-09-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20170227 |