CA2244725C - Wrap material with woven fabric - Google Patents

Wrap material with woven fabric Download PDF

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Publication number
CA2244725C
CA2244725C CA002244725A CA2244725A CA2244725C CA 2244725 C CA2244725 C CA 2244725C CA 002244725 A CA002244725 A CA 002244725A CA 2244725 A CA2244725 A CA 2244725A CA 2244725 C CA2244725 C CA 2244725C
Authority
CA
Canada
Prior art keywords
layer
film
shrink
article
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002244725A
Other languages
French (fr)
Other versions
CA2244725A1 (en
Inventor
Gregory L. Todt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Transhield Technology AS
Original Assignee
Transhield Technology AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Transhield Technology AS filed Critical Transhield Technology AS
Publication of CA2244725A1 publication Critical patent/CA2244725A1/en
Application granted granted Critical
Publication of CA2244725C publication Critical patent/CA2244725C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B32B7/14Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • B32B7/027Thermal properties
    • B32B7/028Heat-shrinkability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/002Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers in shrink films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1328Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826Spot bonds connect components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249962Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249962Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
    • Y10T428/249964Fibers of defined composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3854Woven fabric with a preformed polymeric film or sheet
    • Y10T442/3886Olefin polymer or copolymer sheet or film [e.g., polypropylene, polyethylene, ethylene-butylene copolymer, etc.]

Abstract

A method and material for shrink wrapping articles includes wrapping the article with a shrink wrapping material having a shrink/stretch film outer layer and an inner layer of a woven fabric. The shrink/stretch film responds to heat by shrinking around the article being wrapped, while the woven fabric, which does not shrink or shrinks very little, forms pockets which bunch and gather up as shrinking takes place, thereby forming a cushion between the film and the object being wrapped. The woven fabric acts as a reenforcement for the film, both before and after shrinking, thus protecting the article wrapped from a hurled object and other similar hazards, and also protecting the article from direct engagement from the shrink/stretch film, which is relatively abrasive.

Description

(a) TITLE OF THE INVENTION
WRAP MATERIAL WITH WOVEN FABRIC
(b) TECHNICAL FIELD TO WHICH THE INVENTION RELATES
This invention relates to a shrink wrap material, a method of manufacturing a shrink wrap material, and to a method for protecting articles by wrapping them in the shrink wrap material.
(c) BACKGROUND ART
Large articles, e.g., automobiles, vans, machinery and boats often must be be transported from the factory to the customer on open trucks where they are exposed to the elements. Customers expect that new vehicles, machinery, and other large articles to be in pristine condition when they are delivered, and will not tolerate flaws, even if such flaws are no fault of the manufacturer and have occurred after the article has been shipped from the factory. Damage may be caused by any number of factors. For example, acid rain is an increasingly common phenomena, and, if the acid rain is of sufficient concentration, damaged paint may occur. Furthermore, open transport of such articles subjects the articles to damage due to small rocks and stones which may be hurled against the article during transportation. One way to protect even large articles from the environment is through shrink wrapping, which is most commonly employed on very small household articles.
However, it is difficult to shrink wrap large articles, e.g., vehicles, machinery or boats. When the shrink wrap film is heated during shrinking, it becomes very vulnerable. Accordingly, holes are often pulled in the shrink wrap film as the latter is applied over the vehicle or other large object. Furthermore, the shrink wrap film itself is abrasive and can damage paint when the shrink wrap film is applied to an article.
(d) DESCRIPTION OF THE INVENTION
Thus, according to one aspect of the present invention, a two layer shrink wrap material includes a shrink/stretch film as the outer layer and am inner layer composed of a woven fabric. The outer layer may be any conventional shrink/stretch film, e.g., a polyolefin in the ethylene vinyl acetate copolymer family. The fibres of the woven layer may be, for example, polyester or cotton fibres. It is necessary only that the inner woven layer have a melt point and melting point significantly greater than the melting point and melt point of the outer shrink/stretch layer. It is also necessary that the outer shrink/stretch film has a significantly greater shrink response in response to heat applied to material than does the woven layer. During shrinking, film shrinks around the object being protected, forming a tight package. Since the inner woven layer either does not shrink or shrinks very little, the woven material bunches up and forms pockets as well hereinafter be described to form a soft cushion against the surface being protected.
During the heat shrink processes, the majority of the heat is absorbed by the film and a great deal of the remainder of the heat is reflected away from the object being protected by the fibres of the woven fabric, causing the heated film to shrink even faster due to reflected heat. At the same time, this reflection of heat shields the surface being protected from the heat. Thus, a cushion is formed by the bunching up of the woven layer which supports the film away from the surface of the object being protected. Since only the outer layer of the material crystallizes during the heating and shrinking process, and the woven inner layer remains in the same physical state, the problems associated with conventional shrink wrapping films and shrink wrapping processes, in which the films actually melt against the surface being protected, causing finish damage as well as heat damage, are eliminated.
The woven inner layer acts as a reinforcement for the shrink/stretch film outer layer both before and after shrinking. Before shrinking, the woven fabric acts as a typical reinforcement. After shrinking, the outer layer crystallizes, thus improving the strength of the film, and the fabric, although it bunches up, continues to act as a reenforcement of the outer layer. Accordingly, the material according to an aspect of the present invention has higher puncture resistance and tear resistance than other similar wrapping materials.
(e) DESCRIPTION OF THE FIGURES
In the accompanying drawings, Figure 1 is a schematic illustration of the manner in which the shrink wrapping material according to an aspect of the present invention is manufactured;
Figure 2 is a view in perspective, with a portion of the outer film cut away, of the fabric according to an aspect of the present invention before the material is shrunk;
Figure 3 is a view similar to Figure 1 but illustrating material after the material is shrunk; and Figure 4 is a view in perspective taken through the side of the material opposite the side from which Figures 2 and 3 are taken, illustrating the pockets formed by the inner layer after shrinking has occurred.
(t7 AT LEAST ONE MODE FOR CARRYING OUT THE INVENTION
Referring now to Figures 2-4 of the drawing, the material 10 according to an aspect of the present invention consists of an outer layer 12 of a shrink/stretch film and a woven fabric inner layer generally indicated by the numeral 14. As discussed above, the film outer layer 12 may be any conventional shrink/stretch film but is preferably a polyolefm in the ethylene vinyl acetate copolymer family. The inner layer may be woven of any well-known fibre, e.g., polyester or cotton. It is necessary only that the fibres of the inner layer 14 have a significantly higher melt point and melting point than does the outer film layer 12. Accordingly, during the shrinking process, heat applied to the outer shrink film 12 causes the film to crystallize and thus change state to shrink to 85 % of its initial dimensions. Since the inner layer 14 does not change state, the inner layer 14 does not shrink, or shrinks very little. The film layer 12 is bonded to the inner woven layer 14 at intermittent points generally indicated by the numeral 16.
As will hereinafter be explained, an adhesive is applied on the film at the intermittent points 16 and then the film layer 12 and the woven fabric layer 14 are then brought together, causing the adhesive to adhere the film layer 12 to the woven fabric layer 14.
The material 10 is placed around the object to be protected, with the woven layer engaging the surface to be protected and the film 12 being the outer layer.
Heat is then applied to the film to shrink the film in any conventional manner. As discussed in my prior U.S. Patent No. 5,491,017, the material 10 is particularly suitable for wrapping large articles, e.g., automobiles, vans, motorcycles, lawn and garden equipment, military products, etc. The reenforcement provided by the inner layer 14 makes wrapping such large articles possible, because it is quite difficult to stretch the film alone over the vehicle or other large object during shrinking, since. the film is vulnerable to damage and rupture during the shrinking process.
Since the outer layer 12 shrinks and the inner layer 14 does not shrink or shrinks very little and since the inner layer 14 is only intermittently bonded at points 16, the inner layer forms pockets such as the pockets 19 illustrated in Figure 4 during shrinking of the outer layer. These pockets 19 engage the article being protected, and gathers and bunches up as shown in Figure 4, thus providing a soft cushion against the article being protected and supporting the film layer 12 away from the article being protected, since the film layer 12 is abrasive and may damage the article being protected if the film contacts the article directly. It is also known, as set forth in my U.S.
Patent No.
1 S 5,712,008, to add an additive to the adhesive securing the inner layer 14 to the outer layer 12. This additive may be a vapour-releasing additive, e.g., a vapour corrosion inhibitor, that creates a protective atmosphere around the article wrapped by the material 10. The woven fabric 14 is permeable to the vapour, but the film layer 12 is not;
accordingly, the additive is prevented from escaping from the enclosure which is formed by the material 10 around the object being protected.
Referring now to Figure 1, the material 10 is manufactured by feeding the film from a roll 18 and the woven fabric 14 from a roll 20. The film 12 is fed through a gluing station 22 where a hot melt adhesive is stored in a container 24 and applied to the film 12 by a graver or similar contoured roller 26. The roller 26 is well known and skilled in the art, and the contours on the roller apply glue at only intermittent points on the film 12 as it passes through the gluing stations 22. The adhesive may be any suitable adhesive, preferably a hot melt adhesive of the block copolymer family. The film 12 and fabric 14 are then fed to a bonding station 28 after the adhesive has been applied to the film 12. The bonding station 28 is adjusted that the film is brought into engagement with the fabric 14. Since the hot melt adhesive is very tacky, it is only necessary to touch the fabric and film together lightly in order to achieve bonding. The finished material 10 is then rolled up on a take-up roll 30.
S

Claims (16)

CLAIMS:
1. Material for shrink wrapping articles comprising a shrinkable, stretchable film first layer having a predetermined shrink response in response to heat applied to the film and a woven fabric second layer engaging said first layer, said second layer being secured to said first layer by intermittent bonds distributed across the engaging surfaces of the film.
2. Material for shrink wrapping articles as claimed in claim 1, wherein said first layer shrinks at a greater rate than said second layer whereby said second layer bunches up to form pockets providing a cushion between said first layer and the article being wrapped.
3. Material for shrink wrapping articles as claimed in claim 1, wherein said first layer is secured to said second layer by an adhesive.
4. Material for shrink wrapping articles as claimed in claim 3, wherein said adhesive secures said first layer to said second layer at discrete points, said layers being unbonded between said discrete points.
5. Material for shrink wrapping articles comprising a shrinkable stretchable film first layer having a predetermined shrink response in response to heat applied to the film and a woven fabric second layer engaging said first layer, said first layer having a shrink response such that the first layer shrinks at a greater rate than said second layer whereby said second layer bunches up to form pockets providing a cushion between said first layer and the article being wrapped.
6. Material for shrink wrapping articles as claimed in claim 5, wherein said first layer is secured to said second layer by an adhesive.
7. Material for shrink wrapping articles as claimed in claim 6, wherein said adhesive secures said first layer to said second layer at discrete points, said layers being unbonded between said discrete points.
8. Method of manufacturing material for shrink wrapping articles comprising the steps of providing a shrinkable, stretchable film first layer, providing a quantity of a woven fabric second layer, engaging said film first layer on a surface thereof with a surface of the fabric second layer, and forming intermittent bonds across the engaged surfaces of the fabric and the film.
9. Method of manufacturing material as claimed in claim 8, wherein said intermittent bonds are formed by applying an adhesive intermittently across the surface of one of said layers.
10. Method of manufacturing material as claimed in claim 9, wherein the adhesive is applied to the film first layer.
11. Method of manufacturing material as claimed in claim 9, wherein said adhesive is applied to said one layer by a contoured roller.
12. Method of manufacturing material as claimed in claim 9, wherein said layers are brought into touching engagement with one another without compressing either layer after the adhesive is applied to the one layer.
13. Method of protecting articles against surface damage comprising the steps of providing a wrap material comprising a shrinkable, stretchable film first layer having a predetermined shrink response in response to heat applied to said film, and a woven fabric second layer engaging said first layer, said second layer being secured to said first layer by intermittent bonds which are distributed across the engaging surfaces of said film;
arranging said wrap material around an article to be protected such that said wrap material covers said article with said second woven fabric layer against said article and with said first film layer away from said article; and causing said first film layer to shrink to an extent such that said second woven fabric layer folds and bunches up to support said first film layer away from said article.
14. Method of protecting articles as claimed in claim 13, wherein said first layer is shrunk by applying heat to the wrap material.
15. Method of protecting articles as claimed in claim 13, wherein the first film layer and said second woven fabric layer of said wrap material are intermittently bonded together by applying an adhesive at intermittent points over the surface of one of said layers.
16. Method of protecting articles as claimed in claim 15, wherein a vapour corrosion inhibitor that creates a protective atmosphere around said article is mixed with said adhesive to control the environment in which the article is stored.
CA002244725A 1996-02-12 1996-10-15 Wrap material with woven fabric Expired - Fee Related CA2244725C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/599,783 US5712008A (en) 1996-02-12 1996-02-12 Wrap material with woven fabric
US08/599,783 1996-02-12
PCT/US1996/016370 WO1997029027A1 (en) 1996-02-12 1996-10-15 Wrap material with woven fabric

Publications (2)

Publication Number Publication Date
CA2244725A1 CA2244725A1 (en) 1997-08-14
CA2244725C true CA2244725C (en) 2002-08-06

Family

ID=24401070

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002244725A Expired - Fee Related CA2244725C (en) 1996-02-12 1996-10-15 Wrap material with woven fabric

Country Status (17)

Country Link
US (1) US5712008A (en)
EP (1) EP0880460B1 (en)
JP (1) JP3610072B2 (en)
KR (1) KR100303474B1 (en)
AT (1) ATE192403T1 (en)
AU (1) AU7662596A (en)
BR (1) BR9612492A (en)
CA (1) CA2244725C (en)
CZ (1) CZ249898A3 (en)
DE (1) DE69608135T2 (en)
DK (1) DK0880460T3 (en)
ES (1) ES2146914T3 (en)
GR (1) GR3033958T3 (en)
NO (1) NO983654L (en)
PT (1) PT880460E (en)
RU (1) RU2170199C2 (en)
WO (1) WO1997029027A1 (en)

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CA2244725A1 (en) 1997-08-14
GR3033958T3 (en) 2000-11-30
CZ249898A3 (en) 1999-11-17
PT880460E (en) 2000-08-31
ATE192403T1 (en) 2000-05-15
EP0880460B1 (en) 2000-05-03
NO983654D0 (en) 1998-08-10
JP3610072B2 (en) 2005-01-12
ES2146914T3 (en) 2000-08-16
AU7662596A (en) 1997-08-28
DE69608135D1 (en) 2000-06-08
EP0880460A1 (en) 1998-12-02
RU2170199C2 (en) 2001-07-10
US5712008A (en) 1998-01-27
NO983654L (en) 1998-08-10
DK0880460T3 (en) 2000-08-07
BR9612492A (en) 1999-07-20
DE69608135T2 (en) 2000-11-09
KR19990082467A (en) 1999-11-25
KR100303474B1 (en) 2001-11-30
WO1997029027A1 (en) 1997-08-14
JP2002500597A (en) 2002-01-08

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